Author : Mark Abubekerov
Publisher :
ISBN 13 :
Total Pages : 327 pages
Book Rating : 4.:/5 (17 download)
Book Synopsis Symmetrically and Non-symmetrically Substituted 1,1'-ferrocenes as Supporting Ligands for Divalent Metals in Catalysis by : Mark Abubekerov
Download or read book Symmetrically and Non-symmetrically Substituted 1,1'-ferrocenes as Supporting Ligands for Divalent Metals in Catalysis written by Mark Abubekerov and published by . This book was released on 2017 with total page 327 pages. Available in PDF, EPUB and Kindle. Book excerpt: The synthesis of new polymers is motivated by the limitations of current materials. Recently, interest in copolymers containing blocks that display different or complementary properties has been increasing since these materials have potential for further performance enhancements. Inspired by recent developments in olefin polymerization catalysts, and based on the interest of the Diaconescu group in the reactivity of complexes supported by ferrocene-based chelating ligands, we developed a new ferrocene-chelating heteroscorpionate supporting ligand and investigated its applications in combination with late transition metals to redox-switchable catalysis for the production of multiblock copolymers. Additionally, we began investigations into the influence of the iron-secondary metal interactions on redox-switchable catalysis in complexes supported by symmetrically substituted, neutral ferrocene-based ligands.