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Supramolecular Stereochemistry
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Book Synopsis Supramolecular Stereochemistry by : J.S. Siegel
Download or read book Supramolecular Stereochemistry written by J.S. Siegel and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 263 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the NATO Advanced Research Workshop, Hveragerdi, Iceland, September 14--19, 1994
Book Synopsis Chirality in Supramolecular Assemblies by : F. Richard Keene
Download or read book Chirality in Supramolecular Assemblies written by F. Richard Keene and published by John Wiley & Sons. This book was released on 2017-01-03 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: Supramolecular chemistry deals with the organisation of molecules into defined assemblies using non-covalent interactions, including weaker and reversible interactions such as hydrogen bonds, and metal-ligand interactions. The aspect of stereochemistry within such chemical architectures, and in particular chirality, is of special interest as it impacts on considerations of molecular recognition, the development of functional materials, the vexed question of homochirality, nanoscale effects of interactions at interfaces, biocatalysis and enzymatic catalysis, and applications in organic synthesis. Chirality in Supramolecular Assemblies addresses many of these aspects, presenting a broad overview of this important and rapidly developing interdisciplinary field. Topics covered include: Origins of molecular and topological chirality Homochirogenesis Chirality in crystallinity Host-guest behavior Chiral influences in functional materials Chirality in network solids and coordination solids Aspects of chirality at interfaces Chirality in organic assemblies Chirality related to biocatalysis and enzymes in organic synthesis. This book is a valuable reference for researchers in the molecular sciences, materials science and biological science working with chiral supramolecular systems. It provides summaries and special insights by acknowledged international experts in the various fields.
Book Synopsis Synthesis and Stereochemistry of Templated Supramolecular Compounds by : Craig Robert Woods
Download or read book Synthesis and Stereochemistry of Templated Supramolecular Compounds written by Craig Robert Woods and published by . This book was released on 1998 with total page 582 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Topics in Stereochemistry, Volume 25 by : Scott E. Denmark
Download or read book Topics in Stereochemistry, Volume 25 written by Scott E. Denmark and published by John Wiley & Sons. This book was released on 2006-05-05 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: Topics in Stereochemistry, previously edited by "the father of stereochemistry" Ernest L. Eliel, is a longstanding, successful series covering the most important advances in the field. The much-anticipated Volume 25 includes chapters on the following topics: * Stereochemistry of Molecules in Inclusion Crystals * Torsional Motion of Stilbene-type Molecules in Crystals * Supramolecular Networks of Porphyrins * Homo- and Heterochirality in Crystals * Supramolecular Synthesis of 1D Chains and 2D Layers in Hydrogen Bond Networks of Ureas and 2-D Pyrimidinones * Chiral Auxiliaries Powerful for Both Enantioresolution and Determination of Absolutely Stereochemistry by X-Ray Crystallograph * Engineering Stereospecific Reactoins in Crystals: Synthesis of Compounds with Adjacent Stereogenic Quaternary Centers by Photodecarbonylation of Crystalline Ketones * The CH/ Hydrogen Bond: An Important Molecular Force in Controlling the Crystal Conformation of Organic Compounds and Three-Dimensional Structure of Biopolymers * Stereoselective Thermal Solid-State Reactions * Crystal Structures and Functionalities of Platinum (II) Complexes Controlled by Various Intermolecular Interactions
Book Synopsis Supramolecular Science by : Rocco Ungaro
Download or read book Supramolecular Science written by Rocco Ungaro and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 331 pages. Available in PDF, EPUB and Kindle. Book excerpt: A summary of all the most important aspects of supramolecular science, from molecular recognition in chemical and biological systems to supramolecular devices, materials and catalysis. The 17 chapters cover calixarenes, catenanes, cavitands, cholophanes, dendrimers, membranes and self-assembly systems, molecular modelling, molecular level devices, organic materials, peptides and protein surfaces, recognition of carbohydrates, rotaxanes, supramolecular catalysis. A forward-looking chapter written by J.-M. Lehn indicated the future prospects for the entire field. Audience: Ph.D. students and young researchers in chemistry, physics and biology.
Book Synopsis Modern Physical Organic Chemistry by : Eric V. Anslyn
Download or read book Modern Physical Organic Chemistry written by Eric V. Anslyn and published by University Science Books. This book was released on 2006 with total page 1148 pages. Available in PDF, EPUB and Kindle. Book excerpt: In additionto covering thoroughly the core areas of physical organic chemistry -structure and mechanism - this book will escortthe practitioner of organic chemistry into a field that has been thoroughlyupdated.
Book Synopsis NMR in Supramolecular Chemistry by : M. Pons
Download or read book NMR in Supramolecular Chemistry written by M. Pons and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: NMR is better suited than any other experimental technique for the characterization of supramolecular systems in solution. The presentations included here can be broadly divided into three classes. The first class illustrates the state of the art in the design of supramolecular systems and includes examples of different classes of supramolecular complexes: catenanes, rotaxanes, hydrogen-bonded rosettes, tubes, capsules, dendrimers, and metal-containing hosts. The second class comprises contributions to NMR methods that can be applied to address the main structural problems that arise in supramolecular chemistry. The third class includes biological supramolecular systems studied by state-of-the-art NMR techniques.
Book Synopsis Chemical Synthesis by : C. Chatgilialoglu
Download or read book Chemical Synthesis written by C. Chatgilialoglu and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Synthesis: Gnosis to Prognosis (XTUllKtl ~uv8eoTr ana TT) rVWOT) OTT) npaYVWOT)) " . . . . other things being equal, that field has the most merit which contributes most heavily to, and illuminates most brightly, its neighbouring scientific disciplines[l] One hundred scientists, a blend of students, industrialists, and academics from twenty countries gathered to circumscribe, understand, and elaborate this topic in the magical setting of Ravello, Italy. The mandate of this workshop? To survey existing knowledge, assess current work, and discuss the future directions of chemical synthesis as it impinges on three exciting interdisciplinary themes of science in the 1990's: bioactive molecules, man-made chemical materials, and molecular recognition. This tempting but inexact menu summoned diverse students and scientists who wished to seriously reflect upon, dissect, and eject ideas and own experiences into open debate on this topic, which is at a crossroad in internal evolution and impact on the life and material sciences. The group arrived from many directions and in various forms of transportation, matters soon forgotten, when it found itself in the village which nurtured Wagner's inspiration and set to work immediately to ponder the question which has received extensive thought, prediction, and caveat from illustrious chemists over a period of time [2], two of which, to the delight of all, in presence among the Lectures.
Book Synopsis Current Challenges on Large Supramolecular Assemblies by : Georges Tsoucaris
Download or read book Current Challenges on Large Supramolecular Assemblies written by Georges Tsoucaris and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 421 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objectives of the ARW were: - identifying areas and highlighting approaches by which large Supramolecular (SM) Assemblies can be synthesised - reviewing and combining methods to characterise and analyse such assemblies. The first part of the ARW is devoted to reviewing synthetic achievements in recent years for several families of SM compounds, and to bringing out principles for crystal structure design, including novel quantum mechanical methods. Synthesis pertains both to the chemical synthesis of components for SM assembly, and to the subsequent assembly process based on complementarity and non-covalent interactions. The elaboration of multiple recognition "algorithms" concurrently employed (for instance, 1t-1t and hydrogen bonds) has recently reached a high degree of sophistication in the sequence: Molecules -7 Supermolecule -7 SM array -7 Crystal or Conglomerate Novel Large Assemblies comprise synthetic entities with molecular weight as high as 15000, and hybrid SM assemblies between synthetic molecules and DNA. Further developments are foreseen at a higher level of organisation, such as between supermolecules or with electromagnetic fields in photochemical processes. Creation of 2D Assemblies is now a powerful tool for creation and study of SM interactions. Moreover, much is to be learned in going from 2D to 3D assemblies in crystal growth and other forms of organisation such as micelles or liquid crystals. On the other hand, crystal engineering based on Molecular Recognition in the Crystal State leads to novel 2D assemblies occurring within predesigned crystal structures (hydrophobic organic clays or nanoporous networks).
Book Synopsis Magnetism: A Supramolecular Function by : O. Kahn
Download or read book Magnetism: A Supramolecular Function written by O. Kahn and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 657 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular magnetism is a new field of research dealing with the synthesis and study of the physical properties of molecular assemblies involving open-shell units. It is essentially interdisciplinary, joining together organic, organometallic and inorganic chemists, as well as theoreticians, physicists and materials scientists. At the core of research into molecular magnetism lie design and synthesis of new molecular assemblies exhibiting bulk properties such as long-range magnetic ordering or bistability with an hysteresis effect, which confers a memory effect on the system. In such terms, magnetism may be considered a supramolecular function. The first eight contributions to this volume present the state of the art in organic supramolecular chemistry, emphasising interlocked systems and molecular trees. The following six articles are devoted to molecular materials constructed from organic radicals and transition metal units. Molecular bistability is then focused on, followed by metal-organic and coordination magnetic materials. A new approach to nano-sized particles closes the work.
Book Synopsis Supramolecular Chemistry at Surfaces by : David B. Amabilino
Download or read book Supramolecular Chemistry at Surfaces written by David B. Amabilino and published by Royal Society of Chemistry. This book was released on 2016-04-26 with total page 518 pages. Available in PDF, EPUB and Kindle. Book excerpt: A complete overview of the different methods of preparing and studying self-assembled structures at surfaces and interfaces.
Book Synopsis Electronic and Magnetic Properties of Chiral Molecules and Supramolecular Architectures by : Ron Naaman
Download or read book Electronic and Magnetic Properties of Chiral Molecules and Supramolecular Architectures written by Ron Naaman and published by Springer Science & Business Media. This book was released on 2011-01-25 with total page 323 pages. Available in PDF, EPUB and Kindle. Book excerpt: Time-dependent density functional response theory for electronic chiroptical properties of chiral molecules; by Jochen Autschbach, Lucia Nitsch–Velasquez, and Mark Rudolph * Chiroptical Properties of Charge-Transfer Compounds; by Yoshihisa Inoue, Tadashi Mori * G-C content independent long-range charge transfer through DNA; by Tetsuro Majima * Induced chirality in porphiryn aggregates: the role of weak and strong interactions; by Roberto Purrello * Vibrational circular dichroism spectroscopy of chiral molecules in solution; by Yunjie Xu * Magneto-electric properties of self-assembled monolayers of chiral molecules; by Zeev Vager and Ron Naaman * Theory of adsorption induced chirality and electron transfer through chiral systems; by Spiros Skourtis and David Beratan * Chiral-selective surface chemistry induced by spin-polarized secondary electrons; by Richard Rosenberg
Book Synopsis Topics in Stereochemistry, Volume 20 by : Ernest L. Eliel
Download or read book Topics in Stereochemistry, Volume 20 written by Ernest L. Eliel and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 362 pages. Available in PDF, EPUB and Kindle. Book excerpt: This seminal series, first edited by Ernest Eliel, responsible for some of the major advances in stereochemistry and the winner of the ACS Priestley Medal in 1996, provides coverage of the major developments of the field of stereochemistry. The scope of this series is broadly defined to encompass all fields of chemical and biological sciences that are founded on molecular and supramolecular interactions. Insofar as chemical, physical, and biological properties are determined by molecular shape and structure, the importance of stereochemistry is fundamental to and consequential for all natural sciences. Topics in Stereochemistry serves as a multidisciplinary series that enriches all of chemistry. Aimed at advanced students, university professors and teachers as well as researchers in pharmaceutical, agricultural, biotechnological, polymer, materials, and fine chemical industries, Topics in Stereochemistry publishes definitive and scholarly reviews in stereochemistry and has long been recognized as the gold standard reference work in this field. Covering the effect of chirality on all aspects of molecular interaction from the fundamental physical chemical properties of molecules and their molecular physics to the application of chirality in new areas such as its applications in materials science, Topics in Stereochemistry explores a wide variety of properties, both physical and chemical of isomers with a view to their applications in a number of disciplines from biochemistry to materials science.
Book Synopsis Topics in Stereochemistry, Volume 25 by : Scott E. Denmark
Download or read book Topics in Stereochemistry, Volume 25 written by Scott E. Denmark and published by John Wiley & Sons. This book was released on 2006-04-27 with total page 435 pages. Available in PDF, EPUB and Kindle. Book excerpt: Topics in Stereochemistry, previously edited by "the father of stereochemistry" Ernest L. Eliel, is a longstanding, successful series covering the most important advances in the field. The much-anticipated Volume 25 includes chapters on the following topics: * Stereochemistry of Molecules in Inclusion Crystals * Torsional Motion of Stilbene-type Molecules in Crystals * Supramolecular Networks of Porphyrins * Homo- and Heterochirality in Crystals * Supramolecular Synthesis of 1D Chains and 2D Layers in Hydrogen Bond Networks of Ureas and 2-D Pyrimidinones * Chiral Auxiliaries Powerful for Both Enantioresolution and Determination of Absolutely Stereochemistry by X-Ray Crystallograph * Engineering Stereospecific Reactoins in Crystals: Synthesis of Compounds with Adjacent Stereogenic Quaternary Centers by Photodecarbonylation of Crystalline Ketones * The CH/ Hydrogen Bond: An Important Molecular Force in Controlling the Crystal Conformation of Organic Compounds and Three-Dimensional Structure of Biopolymers * Stereoselective Thermal Solid-State Reactions * Crystal Structures and Functionalities of Platinum (II) Complexes Controlled by Various Intermolecular Interactions
Book Synopsis Thin Layer Chromatography in Chiral Separations and Analysis by : Teresa Kowalska
Download or read book Thin Layer Chromatography in Chiral Separations and Analysis written by Teresa Kowalska and published by CRC Press. This book was released on 2007-06-22 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thin layer chromatography (TLC) is well suited for performing enantioseparations for research as well as larger-scale applications. A fast, inexpensive, and versatile separation technique, there are many practical considerations that contribute to its effectiveness. Thin Layer Chromatography in Chiral Separations and Analysis is the first bo
Book Synopsis Stereochemical Aspects of Drug Action and Disposition by : Michel F. Eichelbaum
Download or read book Stereochemical Aspects of Drug Action and Disposition written by Michel F. Eichelbaum and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 455 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book aims to guide and inspire drug researchers as they enter the 21st century. Stereochemistry is an essential dimension in pharmacology and should be understood as such by all drug researchers whatever their background. When used as probes or medicines, stereoisomeric drugs offer invaluable insights or innovative therapeutic strategies. The book spans the subject from the molecular to the clinical. The first section on chemical aspects contains chapters on chemical synthesis, analysis, natural products, chiral stability (racemezation) and physical properties. The second section is on experimental pharmacology, with chapters on drug-receptor interactions, chiral recognition, ion channels, and molecular toxicology. The third section focuses on drug disposition, with chapters on absorption, distribution, protein binding, metabolism and elimination. The final section is dedicated to regulatory and clinical aspects.
Book Synopsis Dynamic Stereochemistry of Chiral Compounds by : Christian Wolf
Download or read book Dynamic Stereochemistry of Chiral Compounds written by Christian Wolf and published by Royal Society of Chemistry. This book was released on 2008 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive overview of fundamental concepts of asymmetric synthesis along with in-depth discussion. Recent developments that address important synthetic challenges are presented and highlighted with hundreds of examples.