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Study On Low Temperature Oxidation Of Diesel Particulate Matters By Oxygen Storage Component For The Catalyzed Diesel Particulate Filter
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Book Synopsis Study on Low Temperature Oxidation of Diesel Particulate Matters by Oxygen Storage Component for the Catalyzed Diesel Particulate Filter by : Kenji Suzuki
Download or read book Study on Low Temperature Oxidation of Diesel Particulate Matters by Oxygen Storage Component for the Catalyzed Diesel Particulate Filter written by Kenji Suzuki and published by . This book was released on 2007 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry by : Daniel Duprez
Download or read book Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry written by Daniel Duprez and published by World Scientific. This book was released on 2014-07-24 with total page 1035 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive overview of the most recent developments in both total oxidation and combustion and also in selective oxidation. For each topic, fundamental aspects are paralleled with industrial applications. The book covers oxidation catalysis, one of the major areas of industrial chemistry, outlining recent achievements, current challenges and future opportunities. One distinguishing feature of the book is the selection of arguments which are emblematic of current trends in the chemical industry, such as miniaturization, use of alternative, greener oxidants, and innovative systems for pollutant abatement. Topics outlined are described in terms of both catalyst and reaction chemistry, and also reactor and process technology.
Book Synopsis Review of Automotive Engineering JSAE Vol.29 No.3 by :
Download or read book Review of Automotive Engineering JSAE Vol.29 No.3 written by and published by 社団法人自動車技術会(JSAE). This book was released on with total page 30 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Advanced Direct Injection Combustion Engine Technologies and Development by : H Zhao
Download or read book Advanced Direct Injection Combustion Engine Technologies and Development written by H Zhao and published by Elsevier. This book was released on 2009-12-18 with total page 761 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 2 of the two-volume set Advanced direct injection combustion engine technologies and development investigates diesel DI combustion engines, which despite their commercial success are facing ever more stringent emission legislation worldwide. Direct injection diesel engines are generally more efficient and cleaner than indirect injection engines and as fuel prices continue to rise DI engines are expected to gain in popularity for automotive applications. Two exclusive sections examine light-duty and heavy-duty diesel engines. Fuel injection systems and after treatment systems for DI diesel engines are discussed. The final section addresses exhaust emission control strategies, including combustion diagnostics and modelling, drawing on reputable diesel combustion system research and development. Investigates how HSDI and DI engines can meet ever more stringent emission legislation Examines technologies for both light-duty and heavy-duty diesel engines Discusses exhaust emission control strategies, combustion diagnostics and modelling
Book Synopsis Annual Index/abstracts of SAE Technical Papers by :
Download or read book Annual Index/abstracts of SAE Technical Papers written by and published by . This book was released on 2007 with total page 1218 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis EXPERIMENTAL AND MODELING STUDY OF PARTICULATE MATTER OXIDATION UNDER LOADING CONDITIONS FOR A SCR CATALYST ON A DIESEL PARTICULATE FILTER by :
Download or read book EXPERIMENTAL AND MODELING STUDY OF PARTICULATE MATTER OXIDATION UNDER LOADING CONDITIONS FOR A SCR CATALYST ON A DIESEL PARTICULATE FILTER written by and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract : The heavy-duty diesel engines use a Diesel Oxidation Catalyst (DOC), a Catalyzed Particulate Filter (CPF), a Selective Catalytic Reduction (SCR) with urea injection and a Ammonia Oxidation Catalyst (AMOX), to meet the US EPA 2010/2013 particulate matter (PM) and NOx emission standards. However, it is not possible to achieve the 2015 California low NOx standards with this arrangement. Hence, there is a need to improve the existing aftertreatment system. This can be achieved by coating the SCR catalyst on a diesel particulate filter (DPF), thus combining the PM filtration and NOx reduction functionality into a single device. This reduces the overall volume/weight of the system and provides opportunity for packaging flexibility and improved thermal management along with the possibility of higher NOx reduction with a downstream SCR system. The SCR catalyst on a DPF used in this study is known as a SCRF℗ʼ which was supplied by Johnson Matthey and Corning. Previous research on the CPF and SCRF℗ʼ at MTU highlighted that the reactivity of PM retained in the CPF and SCRF℗ʼ is higher during loading conditions compared to passive oxidation conditions i.e. when the flow rate of PM entering the CPF or SCRF℗ʼ is higher in loading conditions compared to the low flow rate and higher PM reaction rate during passive oxidation conditions. A 2013 Cummins ISB engine with a DOC-SCRF℗ʼ arrangement was used to perform twelve tests (eight tests without urea injection and four tests with urea injection) in order to determine the NO2 assisted passive oxidation performance of the SCRF℗ʼ under loading conditions with and without urea injection. The primary focus of this study was to carry out Loading Tests with and without Urea injection and measure species concentrations, PM mass retained, exhaust flowrates, substrate temperature distributions, pressure drop across the filter, and to determine the kinetics of NO2 assisted PM oxidation under loading conditions and compare it with kinetics under passive oxidation conditions. The NO2 assisted passive oxidation performance of the SCRF℗ʼ was experimentally studied by running the engine at 2400 RPM and four different loads at nominal and reduced rail pressure for 5.5 hours in two stages of loading. These conditions were intended to span the SCRF℗ʼ inlet temperatures in the range of 264-364oC and inlet NO2 concentrations in the range of 52-120 ppm. Four conditions out of these eight conditions were repeated with the injection of urea in the form of diesel exhaust fluid at a target ammonia to NOx ratio of 1.0 to investigate both the NOx reduction performance, as well as the effect of urea on the NO2 assisted passive oxidation performance. From the conclusions of the study based on the experimental data, it was found that the cumulative percentage of PM oxidized in the SCRF℗ʼ increases with the increase in engine load due to higher SCRF℗ʼ temperatures and NO2 concentrations. On average, the reactions rates with urea injection during loading conditions in the SCRF℗ʼ are 25% lower compared to the reaction rates without urea injection. The reactivity of PM under loading conditions with and without urea injection is higher compared to the reactivity of PM under passive oxidation with and without urea injection. For a lumped PM oxidation model, a higher pre-exponential for NO2 assisted oxidation is needed for loading as compared to passive oxidation conditions. It was not possible to determine the kinetics of NO2 assisted oxidation of PM under loading conditions from the experimental data using a standard Arrhenius model which lead to the development of a different model for PM oxidation. A PM oxidation model was developed based on the shrinking core model which keeps the identity of the incoming PM masses in the SCRF℗ʼ as compared to SCR-F model being developed at MTU which is lumped model for PM oxidation. The PM oxidation model was calibrated to simulate PM oxidation in the SCRF℗ʼ with a single set of kinetics under wide range of conditions including loading and passive oxidation conditions. The reaction rate results from the PM oxidation model were then applied to the SCR-F model to simulate the pressure drop across SCRF℗ʼ and the PM retained in the SCRF℗ʼ for the loading conditions used in this study. The SCR-F model was calibrated using experimental data from Loading Tests w/o Urea to simulate the PM retained within ℗ł2 g and pressure drop across SCRF℗ʼ within ℗ł0.5 kPa of the experimental data at the end of the test. The calibrated SCR-F model was also used to estimate the cake, wall and channel pressure drop and the PM retained in the cake and wall for the Loading Tests w/o Urea to check the integrity of experimental data and the consistency of the model. The NO2 assisted kinetics for PM oxidation in the SCRF℗ʼ without urea injection using the SCR-F model resulted in an activation energy of 96 kJ/gmol and pre-exponential factor of 2.6 m/K-s for the cake and 1.8 m/K-s for the wall. An analysis of the results from the SCR-F model suggests that for all the conditions, 84-92% of the total PM retained was in the PM cake layer and the oxidation in the PM cake layer accounted for 72-84% of the total PM mass oxidized during loading.
Book Synopsis Catalysis and Automotive Pollution Control IV by : N. Kruse
Download or read book Catalysis and Automotive Pollution Control IV written by N. Kruse and published by Elsevier. This book was released on 1998-05-29 with total page 719 pages. Available in PDF, EPUB and Kindle. Book excerpt: In spite of the energy crises and the recession, there has been a global, explosive growth in the amount of motor vehicles. In the past 50 years, the amount has increased from 50 to 700 million vehicles. For economical reasons they will probably continue to be used for a considerable number of years, despite the poor yield of internal combustion engines resulting in the inevitable production of some gaseous pollutants. The subsequent increase of gaseous pollutants in our atmosphere caused by exhaust gas from automobiles has enhanced the problem of the elimination of these pollutants produced by internal combustion engines. Catalysis has proven to be the best solution to lower the content of exhaust gas in pollutants. As its predecessors, CAPoC4 proved to be a suitable platform for discussing technological improvements and developments along with future perspectives and challenges. In the light of new results and further legislative regulations, the following topics were intensely discussed: *low light-off behaviour based on improved catalysts and substrate formulations *efficient adsorber systems for storage of hydrocarbon emissions *electrically heated catalyst systems ahead the main catalyst or, alternatively, close coupled catalysts (at the manifold of the engine) • lean DeNOx catalysts allowing for decomposition of NOx in the oxygen-rich exhaust of direct injection gasoline engines and high speed injection diesel engines or, alternatively, NOx trapping/reduction in a hybrid approach * collection and destruction of dry particulates or soot. There is no doubt that clean vehicle technology is a vital part of improving air quality. Challenges remain and call for technological answers. Catalytic air pollution control is still an area providing a considerable incentive for innovative work.
Book Synopsis Impact of Particulate Matter Composition on Catalyzed Diesel Particulate Filter Filtration and Regeneration on a Steady State Research Diesel Engine by : Matthew Bohm
Download or read book Impact of Particulate Matter Composition on Catalyzed Diesel Particulate Filter Filtration and Regeneration on a Steady State Research Diesel Engine written by Matthew Bohm and published by . This book was released on 2005 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis AN EXPERIMENTAL INVESTIGATION INTO THE EFFECT OF NO2 AND TEMPERATURE ON THE PASSIVE OXIDATION AND ACTIVE REGENERATION OF PARTICULATE MATTER IN A DIESEL PARTICULATE FILTER by :
Download or read book AN EXPERIMENTAL INVESTIGATION INTO THE EFFECT OF NO2 AND TEMPERATURE ON THE PASSIVE OXIDATION AND ACTIVE REGENERATION OF PARTICULATE MATTER IN A DIESEL PARTICULATE FILTER written by and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract : In this study the oxidation of particulate matter (PM) retained in a catalyzed particulate filter (CPF) is investigated to understand the kinetics of PM oxidation. Seven passive oxidation and four active regeneration experiments were performed on a Cummins ISB 2013 280 hp engine and the production aftertreatment system adapted to a lab setup, in order to study the NO2 assisted and thermal oxidation of the PM retained in the CPF. The CPF was loaded with PM produced by the engine and the PM was then oxidized in the CPF under various Passive Oxidation (PO) and Active Regeneration (AR) conditions. First, the engine was operated at an engine condition that produced PM at a greater rate than the production setting, in order to load the CPF to 3.0±0.4 g/L in a suitable time of 6 hours. To study the NO2 assisted oxidation, exhaust at pre-determined engine conditions with low PM concentration (2 concentration and temperature was flowed through the CPF. During the PO testing, the exhaust temperature into the CPF varied from 299 - 385°C, the NO2 concentration varied between 137 - 1013 ppm and the exhaust mass flowrate varied between 3.63 - 12.0 kg/min. Thermal oxidation was studied by operating the engine at a specific condition where the exhaust at the Diesel Oxidation Catalyst (DOC) inlet was at a higher temperature than the light-off temperature of hydrocarbon oxidation in the DOC (300 °C). Late combustion cycle fuel dosing was performed and the hydrocarbons in the dosed fuel were oxidized across the DOC. This created an exotherm and raised the exhaust temperature into the CPF to the required value between 498 - 575°C to oxidize the PM retained in the CPF at the end of loading, by reaction with O2. The O2 concentration into the CPF varied between 8.17 to 9.03%. It was found that the NO2 assisted kinetics could be represented using the standard Arrhenius equation. The activation energy obtained using the standard Arrhenius model, is 94 kJ/gmol and the pre-exponential factor obtained is 25.5 1/ppm/s. The thermal oxidation reaction rate could be similarly represented using the O2 concentration and temperature over the range of conditions studied. The activation energy for thermal oxidation was found to be 136 kJ/gmol and the pre-exponential factor obtained is 3.56 1/ppm/s. It was found that for two of the passive oxidation tests, the reaction rates were higher than that predicted using the Arrhenius representation. The Loading Engine Condition also showed higher reaction kinetics than the NO2assisted kinetics. The engine and exhaust conditions as well as reaction rates obtained as part of this study are intended to be compared to the corresponding values obtained for a SCR-in-DPF substrate that is currently being studied at Michigan Tech as the next phase of study. The purpose of this comparison is to understand the difference in performance of both aftertreatment systems in light of their respective weights and volumes. The data obtained during this study is also being used to calibrate the 1-D CPF model at MTU. An introduction to the model is provided in this thesis, and the important variables of the study that are also used for model calibration are presented in the appropriate sections.
Book Synopsis Influence of Engine Operating Condition and Aftertreatment Component Selection on Diesel Particulate Filter Operation by : Eric L. Schroeder
Download or read book Influence of Engine Operating Condition and Aftertreatment Component Selection on Diesel Particulate Filter Operation written by Eric L. Schroeder and published by . This book was released on 2006 with total page 394 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Particle Filter Retrofit for All Diesel Engines by : Andreas Mayer
Download or read book Particle Filter Retrofit for All Diesel Engines written by Andreas Mayer and published by expert verlag. This book was released on 2008 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Diesel Particulate Filter Technology by : Timothy V Johnson
Download or read book Diesel Particulate Filter Technology written by Timothy V Johnson and published by SAE International. This book was released on 2007-03-28 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt: Until recently, the complexity of the Diesel Particulate Filter (DPF) system has hindered its commercial success. Stringent regulations of diesel emissions has lead to advancements in this technology, therefore mainstreaming the use of DPFs in light- and heavy-duty diesel filtration applications. This book covers the latest and most important research in DPF systems, focusing mainly on the advancements of the years 2002-2006. Editor Timothy V. Johnson selected the top 29 SAE papers covering the most significant research in this technology.
Book Synopsis A Modeling Study of a Diesel Oxidation Catalyst and Catalyzed Particulate Filter During Loading and Active Regeneration by : Harsha Shankar Surenahalli
Download or read book A Modeling Study of a Diesel Oxidation Catalyst and Catalyzed Particulate Filter During Loading and Active Regeneration written by Harsha Shankar Surenahalli and published by . This book was released on 2010 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Effect of Lubricant Derived Ash on the Catalytic Activity of Diesel Particulate Filters by : Timothy Quinn Murray
Download or read book The Effect of Lubricant Derived Ash on the Catalytic Activity of Diesel Particulate Filters written by Timothy Quinn Murray and published by . This book was released on 2014 with total page 93 pages. Available in PDF, EPUB and Kindle. Book excerpt: A diesel particulate filter (DPF) is an aftertreatment device used to remove hazardous particulate matter (PM) from diesel engine exhaust. Modem emission restrictions have limited the acceptable amount of PM output by diesel engines to the extent that a filtration strategy, such as the use of a DPF, is necessary. Diesel PM is comprised primarily by black carbon soot. Once trapped in the filter, the soot can be oxidized into CO2 and pass out of the exhaust system during what is referred to as regeneration. Metallic lubricant additive derived compounds, which make up a small fraction of PM, cannot be oxidized and remain inside the DPF until regular maintenance calls for the removal and cleaning of the filter. The buildup of ash increases the pressure drop across the filter, resulting in a direct fuel penalty to the engine. The oxidation of soot can be carried out actively at high temperatures or passively at low temperatures with the aid of a catalyst. Active regeneration requires more energy than passive regeneration because the stream of exhaust gas must be heated to a higher temperature. However, catalysts are expensive, and therefore there is a significant additional capital cost associated with catalyzed filters. The purpose of this research was to investigate the impact of ash accumulation on the catalytic activity of DPFs. The impact was measured experimentally by comparing the ability of two ash loaded DPF samples to promote several chemical reactions (most importantly soot oxidation) to the ability of a previously unused (clean) filter. It was shown that ash accumulation results in a loss in the catalytic activity of a DPF, as evidenced by a reduced capacity to generate NO2, and promote the catalyzed passive oxidation of soot. Reduced soot oxidation performance will result in faster accumulation of soot, which increases the pressure drop across the filter and necessitates more frequent regenerations. Both of these results will negatively impact fuel economy.
Book Synopsis Effect of Particulate Matter and Exhaust Gas Composition on Diesel Particulate Filter Regenration by : Amy E. Fischer
Download or read book Effect of Particulate Matter and Exhaust Gas Composition on Diesel Particulate Filter Regenration written by Amy E. Fischer and published by . This book was released on 2009 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Controlling Diesel NO_x & PM Emissions Using Fuel Components and Enhanced Aftertreatment Techniques by : Simaranjit Singh Gill
Download or read book Controlling Diesel NO_x & PM Emissions Using Fuel Components and Enhanced Aftertreatment Techniques written by Simaranjit Singh Gill and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The following research thesis focuses on methods of controlling nitrogen oxides (NO_x) and particulate matter (PM) emissions emitted from a low temperature diesel exhaust. This involves studying the influence of hydrogen (H2) on various aftertreatment devices such as hydrocarbon selective catalytic reduction (HC-SCR) over silver-alumina (Ag-Al2O3) catalysts for lean NO_x reduction, platinum diesel oxidation catalysts (DOC) for nitrogen dioxide (NO2) production and passive regeneration methods for the diesel particulate filter (DPF). H2 was implemented on-board either through diesel exhaust gas fuel reforming or via the simulation of ammonia (NH3) dissociation. Both methods showed to be very effective in enhancing the activity of a silver HC-SCR catalyst for the reduction of NO_x with conversions reaching 90% with the aid of an upstream DPF. A combined DOC and catalysed DPF (cDPF) configuration proved promising for passive regeneration in the presence of reformed exhaust gas recirculation (REGR). The addition of H2 over the DOC led to an improved catalyst light-off temperature and increased rate of oxidation for NO2 production. Implementing filtered EGR (FEGR) removes the hydrocarbon (HC) and soot recirculation penalty, thus minimising particulate growth which results in a significantly reduced engine-out soot emission during exhaust gas recirculation (EGR) and hence, an improved NO_x/soot ratio. Introducing fuel components which enhance the cetane number and oxygenate the diesel fuel allow better control of the NO_x/soot trade-off with improved soot oxidation properties.
Book Synopsis Evaluation of Catalyzed Diesel Particulate Filters Used in an Underground Metal Mine by : John J. Baz-Dresch
Download or read book Evaluation of Catalyzed Diesel Particulate Filters Used in an Underground Metal Mine written by John J. Baz-Dresch and published by . This book was released on 1993 with total page 24 pages. Available in PDF, EPUB and Kindle. Book excerpt:
