Study Of Intermediates From Transition Metal Excited State Electron Transfer Reactions Final Report August 4 1986 August 31 1997

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Study of Intermediates from Transition Metal Excited-state Electron-transfer Reactions. Final Report, August 4, 1986--August 31, 1997

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ISBN 13 :
Total Pages : 31 pages
Book Rating : 4.:/5 (684 download)

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Download or read book Study of Intermediates from Transition Metal Excited-state Electron-transfer Reactions. Final Report, August 4, 1986--August 31, 1997 written by and published by . This book was released on 1997 with total page 31 pages. Available in PDF, EPUB and Kindle. Book excerpt: The techniques of continuous photolysis and pulsed laser flash photolysis, continuous and pulse radiolysis, fast-scan cyclic voltammetry, and time-resolved fluorimetry have been used to examine intramolecular electron transfer within the solvent quenching cage, photodynamics of quenching of the excited states of transition-metal photosensitizers, the properties of excites states and one-electron reduced forms, ground- and excited-state interactions with solutes, and photoinduced oxidations of organic solutes in aqueous solution. The following specific areas were examined: (1) the parameters that govern the yields of redox products from excited-state electron-transfer quenching reactions; (2) the mediation of the properties of excited states and one-electron reduced forms by the ligands and the solution medium; (3) the effect of the interactions between the ground state of the complex and the solution components on the behavior of the excited state; (4) the yields of singlet oxygen from excited-state energy-transfer quenching by O2; and (5) the oxidations of solutes by singlet oxygen, excited-state electron-transfer quenching, and free radicals. This report contains the abstracts of 50 publications describing the studies.

Study of Intermediates from Transition Metal Excited-state Electron-transfer Reactions. [Annual] Progress Report, August 1, 1989--July 31, 1992

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ISBN 13 :
Total Pages : 19 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Study of Intermediates from Transition Metal Excited-state Electron-transfer Reactions. [Annual] Progress Report, August 1, 1989--July 31, 1992 by :

Download or read book Study of Intermediates from Transition Metal Excited-state Electron-transfer Reactions. [Annual] Progress Report, August 1, 1989--July 31, 1992 written by and published by . This book was released on 1992 with total page 19 pages. Available in PDF, EPUB and Kindle. Book excerpt: Conventional and fast-kinetics techniques of photochemistry, photophysics, radiation chemistry, and electrochemistry were used to study the intermediates involved in transition metal excited-state electron-transfer reactions. These intermediates were excited state of Ru(II) and Cr(III) photosensitizers, their reduced forms, and species formed in reactions of redox quenchers and electron-transfer agents. Of particular concern was the back electron-transfer reaction between the geminate pair formed in the redox quenching of the photosensitizers, and the dependence of its rate on solution medium and temperature in competition with transformation and cage escape processes. (DLC).

Study of Intermediates from Transition Metal Excited-state Electron-transfer Reactions. Progress Report, August 1, 1989--December 31, 1991

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Total Pages : 19 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Study of Intermediates from Transition Metal Excited-state Electron-transfer Reactions. Progress Report, August 1, 1989--December 31, 1991 by :

Download or read book Study of Intermediates from Transition Metal Excited-state Electron-transfer Reactions. Progress Report, August 1, 1989--December 31, 1991 written by and published by . This book was released on 1991 with total page 19 pages. Available in PDF, EPUB and Kindle. Book excerpt: During this period, conventional and fast-kinetics techniques of photochemistry, photophysics, radiation chemistry, and electrochemistry were used for the characterization of the intermediates that are involved in transition metal excited-state electron-transfer reactions. The intermediates of interest were the excited states of Ru(II) and Cr(III) photosensitizers, their reduced forms, and the species formed in the reactions of redox quenchers and electron-transfer agents. Of particular concern has been the back electron-transfer reaction between the geminate pair formed in the redox quenching of the photosensitizers, and the dependence of its rate on solution medium and temperature in competition with transformation and cage escape processes.

Study of Intermediates from Transition Metal Excited-state Electron- Transfer Reactions. Progress Report, January 1, 1992--March 31, 1993

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ISBN 13 :
Total Pages : 5 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Study of Intermediates from Transition Metal Excited-state Electron- Transfer Reactions. Progress Report, January 1, 1992--March 31, 1993 by :

Download or read book Study of Intermediates from Transition Metal Excited-state Electron- Transfer Reactions. Progress Report, January 1, 1992--March 31, 1993 written by and published by . This book was released on 1993 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress on 6 projects is reported: excited state absorption spectrum of Ru(bpy)3{sup 2+}, solvent cage model for electron transfer quenching, reductive quenching of {sup *}Cr(III) complexes, solution medium effects in oxidative quenching of {sup *}Ru(II) complexes, photosensitized oxidation of phenol in aqueous solution, and quenching of Ru(II) complexes by oxygen.

Energy Research Abstracts

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ISBN 13 :
Total Pages : 716 pages
Book Rating : 4.:/5 (3 download)

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Download or read book Energy Research Abstracts written by and published by . This book was released on 1986 with total page 716 pages. Available in PDF, EPUB and Kindle. Book excerpt: Semiannual, with semiannual and annual indexes. References to all scientific and technical literature coming from DOE, its laboratories, energy centers, and contractors. Includes all works deriving from DOE, other related government-sponsored information, and foreign nonnuclear information. Arranged under 39 categories, e.g., Biomedical sciences, basic studies; Biomedical sciences, applied studies; Health and safety; and Fusion energy. Entry gives bibliographical information and abstract. Corporate, author, subject, report number indexes.

Study of Intermediates from Transition Metal Excited-state Electron-transfer Reactions

Author :
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ISBN 13 :
Total Pages : 19 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Study of Intermediates from Transition Metal Excited-state Electron-transfer Reactions by :

Download or read book Study of Intermediates from Transition Metal Excited-state Electron-transfer Reactions written by and published by . This book was released on 1992 with total page 19 pages. Available in PDF, EPUB and Kindle. Book excerpt: Conventional and fast-kinetics techniques of photochemistry, photophysics, radiation chemistry, and electrochemistry were used to study the intermediates involved in transition metal excited-state electron-transfer reactions. These intermediates were excited state of Ru(II) and Cr(III) photosensitizers, their reduced forms, and species formed in reactions of redox quenchers and electron-transfer agents. Of particular concern was the back electron-transfer reaction between the geminate pair formed in the redox quenching of the photosensitizers, and the dependence of its rate on solution medium and temperature in competition with transformation and cage escape processes. (DLC).

Substitution and Excited State Electron Transfer Reactions of Transition Metal Complexes in Organized Media

Author : Russell Hunter Schmehl
Publisher :
ISBN 13 :
Total Pages : 446 pages
Book Rating : 4.:/5 (823 download)

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Book Synopsis Substitution and Excited State Electron Transfer Reactions of Transition Metal Complexes in Organized Media by : Russell Hunter Schmehl

Download or read book Substitution and Excited State Electron Transfer Reactions of Transition Metal Complexes in Organized Media written by Russell Hunter Schmehl and published by . This book was released on 1980 with total page 446 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Excited-state Electron-transfer Reactions of Transition Metal Complexes

Author : David Gordon Taylor
Publisher :
ISBN 13 :
Total Pages : 232 pages
Book Rating : 4.:/5 (66 download)

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Book Synopsis Excited-state Electron-transfer Reactions of Transition Metal Complexes by : David Gordon Taylor

Download or read book Excited-state Electron-transfer Reactions of Transition Metal Complexes written by David Gordon Taylor and published by . This book was released on 1979 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Reversible excited-state electron-transfer reactions of transition metal complexes

Author : B. A. De Graff
Publisher :
ISBN 13 :
Total Pages : 14 pages
Book Rating : 4.:/5 (17 download)

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Book Synopsis Reversible excited-state electron-transfer reactions of transition metal complexes by : B. A. De Graff

Download or read book Reversible excited-state electron-transfer reactions of transition metal complexes written by B. A. De Graff and published by . This book was released on 1979 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Physics Briefs

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ISBN 13 :
Total Pages : 762 pages
Book Rating : 4.3/5 (91 download)

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Download or read book Physics Briefs written by and published by . This book was released on 1987 with total page 762 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Plates Illustrative of the Topography and Architecture of Japan

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (472 download)

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Download or read book Plates Illustrative of the Topography and Architecture of Japan written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Government Reports Announcements & Index

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ISBN 13 :
Total Pages : 648 pages
Book Rating : 4.:/5 (3 download)

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Download or read book Government Reports Announcements & Index written by and published by . This book was released on 1993-05 with total page 648 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Handbook of Synthetic Photochemistry

Author : Angelo Albini
Publisher : John Wiley & Sons
ISBN 13 : 3527323910
Total Pages : 498 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Handbook of Synthetic Photochemistry by : Angelo Albini

Download or read book Handbook of Synthetic Photochemistry written by Angelo Albini and published by John Wiley & Sons. This book was released on 2010-02-01 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: Unique in its focus on preparative impact rather than mechanistic details, this handbook provides an overview of photochemical reactions classed according to the structural feature that is built in the photochemical step, so as to facilitate use by synthetic chemists unfamiliar with this topic. An introductory section covers practical questions on how to run a photochemical reaction, while all classes of the most important photocatalytic reactions are also included. Perfect for organic synthetic chemists in academia and industry.

Bioinorganic Photochemistry

Author : Grazyna Stochel
Publisher : John Wiley & Sons
ISBN 13 : 9781405193276
Total Pages : 398 pages
Book Rating : 4.1/5 (932 download)

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Book Synopsis Bioinorganic Photochemistry by : Grazyna Stochel

Download or read book Bioinorganic Photochemistry written by Grazyna Stochel and published by John Wiley & Sons. This book was released on 2009-06-10 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioinorganic photochemistry is a rapidly evolving field integrating inorganic photochemistry with biological, medical and environmental sciences. The interactions of light with inorganic species in natural systems, and the applications in artificial systems of medical or environmental importance, form the basis of this challenging inter-disciplinary research area. Bioinorganic Photochemistry provides a comprehensive overview of the concepts and reactions fundamental to the field, illustrating important applications in biological, medical and environmental sciences. Topics covered include: Cosmic and environmental photochemistry Photochemistry of biologically relevant nanoassemblies Molecular aspects of photosynthesis Photoinduced electron transfer in biosystems Modern therapeutic strategies in photomedicine The book concludes with an outlook for the future of environmental protection, discussing emerging techniques in the field of pollution abatement, and the potential for bioinorganic photochemistry as a pathway to developing cheap, environmentally friendly sources of energy. Written as an authoritative guide for researchers involved in the development of bioinorganic photochemical processes, Bioinorganic Photochemistry is also accessible to scientists new to the field, and will be a key reference source for advanced courses in inorganic, and bioinorganic chemistry.

Report of the Presidential Commission on the Space Shuttle Challenger Accident

Author : DIANE Publishing Company
Publisher : DIANE Publishing
ISBN 13 : 0788119125
Total Pages : 267 pages
Book Rating : 4.7/5 (881 download)

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Book Synopsis Report of the Presidential Commission on the Space Shuttle Challenger Accident by : DIANE Publishing Company

Download or read book Report of the Presidential Commission on the Space Shuttle Challenger Accident written by DIANE Publishing Company and published by DIANE Publishing. This book was released on 1995-07 with total page 267 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Handbook of Photochemistry

Author : Marco Montalti
Publisher : CRC Press
ISBN 13 : 1420015192
Total Pages : 662 pages
Book Rating : 4.4/5 (2 download)

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Download or read book Handbook of Photochemistry written by Marco Montalti and published by CRC Press. This book was released on 2006-02-21 with total page 662 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the publication of the second edition of this handbook in 1993, the field of photochemical sciences has continued to expand across several disciplines including organic, inorganic, physical, analytical, and biological chemistries, and, most recently, nanosciences. Emphasizing the important role light-induced processes play in all of these fie

Applied Organic Chemistry

Author : Surya K. De
Publisher : John Wiley & Sons
ISBN 13 : 3527347852
Total Pages : 856 pages
Book Rating : 4.5/5 (273 download)

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Download or read book Applied Organic Chemistry written by Surya K. De and published by John Wiley & Sons. This book was released on 2021-03-08 with total page 856 pages. Available in PDF, EPUB and Kindle. Book excerpt: An indispensable guide for all synthetic chemists who want to learn about the most relevant reactions and reagents employed to synthesize important heterocycles and drugs! The synthesis of natural products, bioactive compounds, pharmaceuticals, and drugs is of fundamental interest in modern organic chemistry. New reagents and reaction methods towards these molecules are being constantly developed. By understanding the mechanisms involved and scope and limitations of each reaction applied, organic chemists can further improve existing reaction protocols and develop novel efficient synthetic routes towards frequently used drugs, such as Aspirin or Penicillin. Applied Organic Chemistry provides a summary of important (name) reactions and reagents applied in modern organic chemistry and drug synthesis. It covers rearrangement, condensation, olefination, metathesis, aromatic electrophilic substitutions, Pd-catalyzed C-C bond forming reactions, multi-component reactions, as well as oxidations and reductions. Each chapter is clearly structured, providing valuable information on reaction details, step-by-step mechanism, experimental procedures, applications, and (patent) references. By providing mechanistic information and representative experimental procedures, this book is an indispensable guide for researchers and professionals in organic chemistry, natural product synthesis, pharmaceutical, and medicinal chemistry, as well as post-graduates preparing themselves for a job in the pharmaceutical industry. Hot Topic: Reviews important classes of organic reactions (incl. name reactions) and reagents in medicinal chemistry. Useful: Provides information on reaction details, common reagents, and functional group transformations used to synthesize natural products, bioactive compounds, drugs, and pharmaceuticals, e.g. Aspirin, Penicillin. Unique: For every reaction the mechanism is explained step by step, and representative experimental procedures are given, unlike most books in this area. User-friendly: Chapters are clearly structured making it easy for the reader to compare different reactions. Applied Organic Chemistry is an indispensable guide for researchers and professionals in organic chemistry, natural product synthesis, pharmaceutical, and medicinal chemistry, as well as post-graduates preparing themselves for a job in the pharmaceutical industry.