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Studies And Prevention Of Carbon Steel Corrosion And Solvent Degradation During Amine Based Co2 Capture From Industrial Gas Streams
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Book Synopsis Studies and Prevention of Carbon Steel Corrosion and Solvent Degradation During Amine-Based CO2 Capture from Industrial Gas Streams by : Pathamaporn Wattanaphan
Download or read book Studies and Prevention of Carbon Steel Corrosion and Solvent Degradation During Amine-Based CO2 Capture from Industrial Gas Streams written by Pathamaporn Wattanaphan and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Post-combustion CO2 Capture Technology by : Helei Liu
Download or read book Post-combustion CO2 Capture Technology written by Helei Liu and published by Springer. This book was released on 2018-09-25 with total page 55 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a comprehensive review of the latest information on all aspects of the post-combustion carbon capture process. It provides designers and operators of amine solvent-based CO2 capture plants with an in-depth understanding of the most up-to-date fundamental chemistry and physics of the CO2 absorption technologies using amine-based reactive solvents. Topics covered include the physical properties, chemical analysis, reaction kinetics, CO2 solubility, and innovative configurations of absorption and stripping columns as well as information on technology applications. This book also examines the post-build operational issues of corrosion prevention and control, solvent management, solvent stability, solvent recycling and reclaiming, intelligent monitoring and plant control including process automation. In addition, the authors discuss the recent insights into the theoretical basis of plant operation in terms of thermodynamics, transport phenomena, chemical reaction kinetics/engineering, interfacial phenomena, and materials. The insights provided help engineers, scientists, and decision makers working in academia, industry and government gain a better understanding of post-combustion carbon capture technologies.
Book Synopsis Corrosion of Stainless and Carbon Steel in Aqueous Piperazine for CO2 Capture by : Ching-Ting Liu
Download or read book Corrosion of Stainless and Carbon Steel in Aqueous Piperazine for CO2 Capture written by Ching-Ting Liu and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Current obstacles that prevent commercial implementation of amine-scrubbing CO2 capture are the high costs. Reducing capital costs by appropriate selection of construction materials, which requires knowledge of material corrosion performance for the process, will improve the economic feasibility of this technology. Corrosion was evaluated in three pilot plant campaigns using aqueous piperazine with the Advanced Stripper (PZAS). 316L stainless steel (SS) experienced higher corrosion than 304 SS and 2205 duplex SS, and the corrosion rate showed strong dependence on the temperature. 304 and 2205 performed well at all locations and should be good construction materials for PZAS. Degraded PZ exacerbated 316L corrosion, and removal of PZ degradation products using a carbon adsorption bed significantly reduced corrosion. Carbon steel (CS) corrosion showed a weak temperature effect because the corrosion was more dependent on the protective siderite film. The protectiveness of the films was related to fluid velocity. Ni-based alloys corroded in PZ, and the rate increased with temperature. Corrosion of C1010 CS and SS (304, 316L, 430) was measured at absorber and water wash conditions on the bench-scale. Corrosion rate decreases with increasing PZ. With more than 0.003 m PZ in solution, CS has acceptable corrosion performance. Corrosion of CS increases with increasing partial pressure of CO2, suggesting loading is another dominant parameter for carbon steel corrosion. Temperature has a less significant effect than PZ concentration and loading. CS corrosion increases with increasing flow velocity at both absorber and water wash conditions. SS had little corrosion at this lower temperature. Performance of siderite (FeCO3) protective films on CS was studied at representative stripper conditions on the bench-scale. Siderite films can deposit on the surface of CS in CO2-loaded PZ solution at temperatures >100 °C and protect CS from corrosion. The protection may fail in degraded PZ. Ethylenediamine (EDA) is one of the major contributors for the loss of film protectiveness or can be the surrogate for the effect of PZ degradation on siderite film protection. A link between protectiveness and the apparent density of siderite films was discovered. The apparent density of siderite films decreases with increasing flow velocity and decreasing CO2 loading, resulting in higher corrosion of CS
Book Synopsis Energy Efficient Solvents for CO2 Capture by Gas-Liquid Absorption by : Wojciech M. Budzianowski
Download or read book Energy Efficient Solvents for CO2 Capture by Gas-Liquid Absorption written by Wojciech M. Budzianowski and published by Springer. This book was released on 2016-12-01 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reviews and characterises promising single-compound solvents, solvent blends and advanced solvent systems suitable for CO2 capture applications using gas-liquid absorption. Focusing on energy efficient solvents with minimal adverse environmental impact, the contributions included analyse the major technological advantages, as well as research and development challenges of promising solvents and solvent systems in various sustainable CO2 capture applications. It provides a valuable source of information for undergraduate and postgraduate students, as well as for chemical engineers and energy specialists.
Book Synopsis Carbon Dioxide Chemistry, Capture and Oil Recovery by : Iyad Karamé
Download or read book Carbon Dioxide Chemistry, Capture and Oil Recovery written by Iyad Karamé and published by BoD – Books on Demand. This book was released on 2018-08-16 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fossil fuels still need to meet the growing demand of global economic development, yet they are often considered as one of the main sources of the CO2 release in the atmosphere. CO2, which is the primary greenhouse gas (GHG), is periodically exchanged among the land surface, ocean, and atmosphere where various creatures absorb and produce it daily. However, the balanced processes of producing and consuming the CO2 by nature are unfortunately faced by the anthropogenic release of CO2. Decreasing the emissions of these greenhouse gases is becoming more urgent. Therefore, carbon sequestration and storage (CSS) of CO2, its utilization in oil recovery, as well as its conversion into fuels and chemicals emerge as active options and potential strategies to mitigate CO2 emissions and climate change, energy crises, and challenges in the storage of energy.
Book Synopsis First-principles Studies on Degradation of Aqueous Amines for Carbon Dioxide Capture by : Bohak Yoon
Download or read book First-principles Studies on Degradation of Aqueous Amines for Carbon Dioxide Capture written by Bohak Yoon and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical absorption with aqueous amine-based solvents has been the most promising incumbent technology for post-combustion CO2 capture from flue gas. However, its extensive operation is severely limited by the large cost attributed to the enormous energy requirement for solvent regeneration and degradation issues leading to makeup of amine solvent loss. First-principles atomistic modeling can provide key insights into elucidating chemical phenomena pertinent to degradation behavior in CO2-loaded aqueous amine solution, which is often extremely challenging to be experimentally characterized. In this dissertation, our first-principles works on illuminating the molecular mechanisms governing solvent degradation of aqueous amine during CO2 capture are presented. Using density functional theory based ab initio molecular dynamics with enhanced sampling techniques, we identify elementary reactions governing CO2 capture and degradation. Molecular mechanisms of thermal and oxidative degradation of aqueous amine solvents are discussed in perspective of both thermodynamics and kinetics. We systematically investigate on the factors prevailing key reaction rates, such as amine functional groups, the steric hindrances, classes of amines (primary and secondary), concentration of amines, solvation nature, and temperature conditions. These factors may largely affect relative strengths of both inter- and intramolecular hydrogen bond interactions in CO2-loaded aqueous amine solution. Our theoretical studies further illustrate the importance of an atomistic-level description of solvation structure and dynamics that may primarily govern CO2 reaction with aqueous amine solvents and associated degradation mechanisms. This dissertation highlights the key role of first-principles computational modelling in accurately describing mechanistic understandings on CO2 capture by aqueous amine solvents and associated degradation processes. The enhanced atomisticlevel descriptions will provide more complete explanations for experimental characterizations and valuable suggestions on how to optimize existing solvents and design more cost-efficient solvents for carbon capture processes
Book Synopsis Absorption-Based Post-Combustion Capture of Carbon Dioxide by : Paul Feron
Download or read book Absorption-Based Post-Combustion Capture of Carbon Dioxide written by Paul Feron and published by Woodhead Publishing. This book was released on 2016-05-27 with total page 816 pages. Available in PDF, EPUB and Kindle. Book excerpt: Absorption-Based Post-Combustion Capture of Carbon Dioxide provides a comprehensive and authoritative review of the use of absorbents for post-combustion capture of carbon dioxide. As fossil fuel-based power generation technologies are likely to remain key in the future, at least in the short- and medium-term, carbon capture and storage will be a critical greenhouse gas reduction technique. Post-combustion capture involves the removal of carbon dioxide from flue gases after fuel combustion, meaning that carbon dioxide can then be compressed and cooled to form a safely transportable liquid that can be stored underground. Provides researchers in academia and industry with an authoritative overview of the amine-based methods for carbon dioxide capture from flue gases and related processes Editors and contributors are well known experts in the field Presents the first book on this specific topic
Book Synopsis Corrosion in CO2 Capture, Transportation, Geological Utilization and Storage by : Liwei Zhang
Download or read book Corrosion in CO2 Capture, Transportation, Geological Utilization and Storage written by Liwei Zhang and published by Springer Nature. This book was released on 2023-07-21 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book systematically discusses the operational stages with high risk of CO2-induced corrosion in CCUS projects, and related measures for corrosion control. CO2 capture, utilization, and storage (CCUS) is a key technology to mitigate climate change and substantially reduce greenhouse gas emissions from fossil fuels. CCUS deals with high concentration CO2, which is very corrosive in a humid environment. Therefore, it is very important to characterize, monitor, and mitigate CO2-induced corrosion in all processes of the CCUS operation chain. Some corrosion control techniques included in this book (e.g., CO2-resisting wellbore cement additives) are beneficial for corrosion control research and engineering practices. This book belongs to the field of corrosion science and engineering, and the expected readership is researchers and engineers working on CCUS.
Book Synopsis Corrosion in CO2 Absorption Process Using Aqueous Monoethanolamine/piperazine Solution by : Manjula Nainar
Download or read book Corrosion in CO2 Absorption Process Using Aqueous Monoethanolamine/piperazine Solution written by Manjula Nainar and published by . This book was released on 2007 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work explores the promise of aqueous solutions of blended monoethanolamine (MEA) and piperazine (PZ) as a cost-effective solvent for carbon dioxide (CO2) capture from industrial flue gas streams with respect to addressing corrosion, which is regarded as one of the most severe operational problems in typical CO2 capture plants. Two types of corrosion experiments were carried out in bench-scale setups, electrochemical tests for short-term exposure and weight loss tests for long-term exposure. The results show that the blended MEA/PZ solutions are more corrosive than the MEA solutions. The corrosion rate of carbon steel increases with concentration of PZ, total amine concentration, CO2 loading of solution, solution temperature, the presence of heat stable salts, and the presence of the proprietary oxidative degradation inhibitor (Inhibitor A provided by the University of Texas at Austin). Among the tested heat-stable salts, formate is the most corrosive salt, followed by acetate, oxalate, and thiosulfate in the absence of oxygen (O2), while acetate is the most corrosive salt followed by formate, oxalate, and thiosulfate in the presence of O2. Based on the level of corrosion rate found in the MEA/PZ system, corrosion control is required during plant operation to suppress the corrosion rate of carbon steel to below an acceptable level. Sodium metavanadate (NaVO3) and copper carbonate (CuCO3) were proven to be effective corrosion inhibitors with inhibition performance of up to 94-98%. Dissolved O2 is required in the solution to maintain active Cu2 or V5+, which, thus, prevents the metallic copper (Cu) from plating out or the formation of other oxidative states of vanadate. The performance of these two inhibitors can be deteriorated by the presence of heat-stable salts in the solutions.
Book Synopsis Corrosion Evaluation for Absorption - Based CO2 Capture Process Using Single and Blended Amines by : Prakashpathi Gunasekaran
Download or read book Corrosion Evaluation for Absorption - Based CO2 Capture Process Using Single and Blended Amines written by Prakashpathi Gunasekaran and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Advances in Natural Gas: Formation, Processing, and Applications. Volume 2: Natural Gas Sweetening by : Mohammad Reza Rahimpour
Download or read book Advances in Natural Gas: Formation, Processing, and Applications. Volume 2: Natural Gas Sweetening written by Mohammad Reza Rahimpour and published by Elsevier. This book was released on 2024-02-16 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Natural Gas: Formation, Processing, and Applications is a comprehensive eight-volume set of books that discusses in detail the theoretical basics and practical methods of various aspects of natural gas from exploration and extraction, to synthesizing, processing and purifying, producing valuable chemicals and energy. The volumes introduce transportation and storage challenges as well as hydrates formation, extraction, and prevention. Volume 2 titled Natural Gas Sweetening introduces in detail different natural gas sweetening methods. The book covers absorption with different solvents such as alkalis, amin blends, ionic liquids, etc. which is one of the important sweetening techniques, as well as natural gas sweetening with adsorption-based technologies utilizing various materials including zeolites, carbonaceous sorbents, metal oxides, etc. Is also discusses membrane-based processes with various types (such as ionic liquid, polymeric, MOF mixed matrix, dense metal membranes) and includes novel technologies for sweetening natural gas by using plasma and supersonic separators. Introduces natural gas sweetening concepts and challenges Describes various absorption and adsorption processes for natural gas sweetening Includes various membrane technologies for natural gas sweetening
Book Synopsis Corrosion of Stainless and Carbon Steel in Aqueous Amine for CO2 Capture by : Kent Billington Fischer
Download or read book Corrosion of Stainless and Carbon Steel in Aqueous Amine for CO2 Capture written by Kent Billington Fischer and published by . This book was released on 2019 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Post-combustion carbon capture and storage with amine absorbents is a key technology needed to provide low-cost decarbonized electricity. Improving understanding of corrosion by amines may reveal a solvent system compatible with carbon steel, which would reduce plant capital costs. Corrosion of stainless and carbon steel in aqueous monoethanolamine (MEA) and piperazine (PZ) has been measured. High temperature amine corrosion was measured in a bench-scale pressure vessel and iron solubility in amines was screened in stirred reactors. Corrosion was measured at two PZ pilot plants and one MEA pilot plant, using coupons and electrical resistance probes. Corrosion products were characterized by SEM and powder X-ray diffraction. Carbon steel (C1010) often performs well in 5 molal PZ up to 150 °C due to the formation of a passivating FeCO3 layer. This layer is promoted at high temperature, high CO2 loading, low solution velocity, and in amines with low Fe2+ solubility. FeCO3 formation is favorable at high temperature because Fe2+ solubility decreases and the kinetics of FeCO3 formation are faster. This also means that FeCO3 is not observed at low temperature. Despite this, carbon steel performs well at low temperature due to slower kinetics of metal oxidation. Depassivation and high corrosion of stainless steel (316L) can occur in amine solutions at high temperature (150 °C) when conditions are relatively anoxic and reducing. Performance of stainless at high temperature in PZ suggests that it can be pushed into and out of the passive state by small process changes, such as different flue gas O2 concentrations. However, stainless performs well in both MEA and PZ in pilot plants at ≈120 °C. Fe3+ corrosion products are generated in the absorber, then reduced to Fe2+ in the high temperature, anoxic conditions of the stripper. In this way, carried-over Fe3+ is responsible for oxidation of amine and corrosion at high temperature. Certain highly corrosive amines also have high Fe2+ solubility. Ethylamines like MEA are likely the correct chain length to form stable complexes with Fe2+ in solution. Stable Fe2+-amine complexes cause high Fe2+ solubility, which prevents FeCO3 formation and leads to high corrosion
Book Synopsis Advanced CO2 Capture Technologies by : Shin-ichi Nakao
Download or read book Advanced CO2 Capture Technologies written by Shin-ichi Nakao and published by Springer. This book was released on 2019-05-07 with total page 83 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book summarises the advanced CO2 capture technologies that can be used to reduce greenhouse gas emissions, especially those from large-scale sources, such as power-generation and steel-making plants. Focusing on the fundamental chemistry and chemical processes, as well as advanced technologies, including absorption and adsorption, it also discusses other aspects of the major CO2 capture methods: membrane separation; the basic chemistry and process for CO2 capture; the development of materials and processes; and practical applications, based on the authors’ R&D experience. This book serves as a valuable reference resource for researchers, teachers and students interested in CO2 problems, providing essential information on how to capture CO2 from various types of gases efficiently. It is also of interest to practitioners and academics, as it discusses the performance of the latest technologies applied in large-scale emission sources.
Book Synopsis Contamination Control in the Natural Gas Industry by : Thomas H. Wines
Download or read book Contamination Control in the Natural Gas Industry written by Thomas H. Wines and published by Gulf Professional Publishing. This book was released on 2021-11-25 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contamination Control in the Natural Gas Industry delivers the separation fundamentals and technology applications utilized by natural gas producers and processors. This reference covers principles and practices for better design and operation of a wide range of media, filters and systems to remove contaminants from liquids and gases, enabling gas industry professionals to fulfill diverse fluid purification requirements. Packed to cover practical technologies, diagnostics and troubleshooting methods, this book provides gas engineers and technologists with a critical first-ever reference geared to contamination control. Covers contamination control methods and equipment specific to the natural gas industry Includes guidelines on fundamentals and real-world technologies used today Gives engineers better design and operation with rating methods, standards and case histories
Book Synopsis Amine Oxidation in Carbon Dioxide Capture by Aqueous Scrubbing by : Alexander Karl Voice
Download or read book Amine Oxidation in Carbon Dioxide Capture by Aqueous Scrubbing written by Alexander Karl Voice and published by . This book was released on 2013 with total page 658 pages. Available in PDF, EPUB and Kindle. Book excerpt: Amine degradation in aqueous amine scrubbing systems for capturing CO2 from coal fired power plants is a major problem. Oxygen in the flue gas is the major cause of solvent deterioration, which increases the cost of CO2 capture due to reduced capacity, reduced rates, increased corrosion, solvent makeup, foaming, and reclaiming. Degradation also produces environmentally hazardous materials: ammonia, amides, aldehydes, nitramines, and nitrosamines. Thus it is important to understand and mitigate amine oxidation in industrial CO2 capture systems. A series of lab-scale experiments was conducted to better understand the causes of and solutions to amine oxidation. This work included determination of rates, products, catalysts, and inhibitors for various amines at various conditions. Special attention was paid to understanding monoethanolamine (MEA) oxidation, whereas oxidation of piperazine (PZ) and other amines was less thorough. The most important scientific contribution of this work has been to show that amine oxidation in real CO2 capture systems is much more complex than previously believed, and cannot be explained by mass transfer or reaction kinetics in the absorber by itself, or by dissolved oxygen kinetics in the cross exchanger. An accurate representation of MEA oxidation in real systems must take into account catalysts present (especially Mn and Fe), enhanced oxygen mass transfer in the absorber as a function of various process conditions, and possibly oxygen carriers other than dissolved oxygen in the cross exchanger and stripper. Strategies for mitigating oxidative degradation at low temperature, proposed in this and previous work are less effective or ineffective with high temperature cycling, which is more representative of real systems. In order of effectiveness, these strategies are: selecting an amine resistant to oxidation, reduction of dissolved metals in the system, reduction of the stripper temperature, reduction of the absorber temperature, and addition of a chemical inhibitor to the system. Intercooling in the absorber can reduce amine oxidation and improve energy efficiency, whereas amine oxidation should be considered in choosing the optimal stripper temperature. In real systems, 2-amino-2-methyl-1-propanol (AMP) is expected to be the most resistant to oxidation, followed by PZ and PZ derivatives, then methyldiethanolamine (MDEA), and then MEA. MEA oxidation with high temperature cycling is increased 70% by raising the cycling temperature from 100 to 120 °C, the proposed operational temperature range of the stripper. PZ oxidation is increased 100% by cycling to 150 °C as opposed to 120 °C. Metals are expected to increase oxidation in MEA and PZ with high temperature cycling by 40 - 80%. Inhibitor A is not expected to be effective in real systems with MEA or with PZ. MDEA is also not effective as an inhibitor in MEA, and chelating agents diethylenetriamine penta (acetic acid) (DTPA) and 2,5-dimercapto-1,3,4-thiadiazole (DMcT) are only mildly effective in MEA. Although MEA oxidation in real systems cannot be significantly reduced by any known additives, it can be accurately monitored on a continuous basis by measuring ammonia production from the absorber. Ammonia production was shown to account for two-thirds of nitrogen in degraded MEA at low temperature and with high temperature cycling, suggesting that it is a reliable indicator of MEA oxidation under a variety of process conditions. A proposed system, which minimizes amine oxidation while maintaining excellent rate and thermodynamic properties for CO2 capture would involve use of 4 m AMP + 2 m PZ as a capture solvent with the stripper at 135 °C, intercooling in the absorber, and use of a corrosion inhibitor or continuous metals removal system. Reducing (anaerobic) conditions should be avoided to prevent excessive corrosion from occurring and minimize the amount of dissolved metals. This system is expected to reduce amine oxidation by 90-95% compared with the base case 7 m MEA with the stripper at 120 °C.
Book Synopsis Beyond Current Research Trends in CO2 Utilization by : Michele Aresta
Download or read book Beyond Current Research Trends in CO2 Utilization written by Michele Aresta and published by Frontiers Media SA. This book was released on 2022-03-08 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Emerging Technologies and Biological Systems for Biogas Upgrading by : Nabin Aryal
Download or read book Emerging Technologies and Biological Systems for Biogas Upgrading written by Nabin Aryal and published by Academic Press. This book was released on 2021-03-31 with total page 530 pages. Available in PDF, EPUB and Kindle. Book excerpt: Emerging Technologies and Biological Systems for Biogas Upgrading systematically summarizes the fundamental principles and the state-of-the-art of biogas cleaning and upgrading technologies, with special emphasis on biological processes for carbon dioxide (CO2), hydrogen sulfide (H2S), siloxane, and hydrocarbon removal. After analyzing the global scenario of biogas production, upgrading and utilization, this book discusses the integration of methanation processes to power-to-gas systems for methane (CH4) production and physiochemical upgrading technologies, such as chemical absorption, water scrubbing, pressure swing adsorption and the use of membranes. It then explores more recent and sustainable upgrading technologies, such as photosynthetic processes using algae, hydrogen-mediated microbial techniques, electrochemical, bioelectrochemical, and cryogenic approaches. H2S removal with biofilters is also covered, as well as removal of siloxanes through polymerization, peroxidation, biological degradation and gas-liquid absorption. The authors also thoroughly consider issues of mass transfer limitation in biomethanation from waste gas, biogas upgrading and life cycle assessment of upgrading technologies, techno-economic aspects, challenges for upscaling, and future trends. Providing specific information on biogas upgrading technology, and focusing on the most recent developments, Emerging Technologies and Biological Systems for Biogas Upgrading is a unique resource for researchers, engineers, and graduate students in the field of biogas production and utilization, including waste-to-energy and power-to-gas. It is also useful for entrepreneurs, consultants, and decision-makers in governmental agencies in the fields of sustainable energy, environmental protection, greenhouse gas emissions and climate change, and strategic planning. Explores all major technologies for biogas upgrading through physiochemical, biological, and electrochemical processes Discusses CO2, H2S, and siloxane removal techniques Provides a systematical approach to discuss technologies, including challenges to gas–liquid mass transfer, life cycle assessment, technoeconomic implications, upscaling and systems integration
