Structural Chemistry of Inorganic Actinide Compounds

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Publisher : Elsevier
ISBN 13 : 9780080467917
Total Pages : 504 pages
Book Rating : 4.4/5 (679 download)

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Book Synopsis Structural Chemistry of Inorganic Actinide Compounds by : Sergey Krivovichev

Download or read book Structural Chemistry of Inorganic Actinide Compounds written by Sergey Krivovichev and published by Elsevier. This book was released on 2006-12-08 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: Structural Chemistry of Inorganic Actinide Compounds is a collection of 13 reviews on structural and coordination chemistry of actinide compounds. Within the last decade, these compounds have attracted considerable attention because of their importance for radioactive waste management, catalysis, ion-exchange and absorption applications, etc. Synthetic and natural actinide compounds are also of great environmental concern as they form as a result of alteration of spent nuclear fuel and radioactive waste under Earth surface conditions, during burn-up of nuclear fuel in reactors, represent oxidation products of uranium miles and mine tailings, etc. The actinide compounds are also of considerable interest to material scientists due to the unique electronic properties of actinides that give rise to interesting physical properties controlled by the structural architecture of respective compounds. The book provides both general overview and review of recent developments in the field, including such emergent topics as nanomaterials and nanoparticles and their relevance to the transfer of actinides under environmental conditions. * Covers over 2,000 actinide compounds including materials, minerals and coordination polymers * Summarizes recent achievements in the field * Some chapters reveal (secret) advances made by the Soviet Union during the 'Cold war'

The Chemistry of the Actinides

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Publisher : Elsevier
ISBN 13 : 1483159345
Total Pages : 656 pages
Book Rating : 4.4/5 (831 download)

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Book Synopsis The Chemistry of the Actinides by : S. Ahrland

Download or read book The Chemistry of the Actinides written by S. Ahrland and published by Elsevier. This book was released on 2016-06-07 with total page 656 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of the Actinides contains selected chapters from the Comprehensive Inorganic Chemistry to meet the needs of certain specialists in this field. The book describes the 14 elements after actinium in the Periodic Table, known as the actinide elements or the 5f transition series. The book notes the occurrence, separation, chemical properties, chemical structures, and preparation of the metals. In a discussion of analytical chemistry, the radioactive properties of the actinides and the lanthanides are compared. The text then describes the nuclear or radiochemical records and chemical properties of the different members of the actinide series such as thorium, uranium, plutonium, and einsteinium. The book also explains the differences between the 5f shell and the 4f shell. One paper then discusses the groups of alloy compounds, including rare earths and intra-actinides. Another paper examines the general properties of actinide ions as to their electronic structure and oxidation states; the stability and preparation of the different oxidation states; and the applicability of solvent extraction in separating and purifying various substances. The text is suitable for researchers in organic chemistry, nuclear and atomic physicists, scientists, and academicians whose work involves radioactive materials.

Synthesis of Lanthanide and Actinide Compounds

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 9401137587
Total Pages : 377 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Synthesis of Lanthanide and Actinide Compounds by : G. Meyer

Download or read book Synthesis of Lanthanide and Actinide Compounds written by G. Meyer and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 377 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Structural Chemistry across the Periodic Table

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Author :
Publisher : Oxford University Press
ISBN 13 : 0198872968
Total Pages : 593 pages
Book Rating : 4.1/5 (988 download)

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Book Synopsis Structural Chemistry across the Periodic Table by : Thomas CW Mak

Download or read book Structural Chemistry across the Periodic Table written by Thomas CW Mak and published by Oxford University Press. This book was released on 2023-10-12 with total page 593 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is an expanded and updated version of Part III of the authors' previous work, Advanced Structural Inorganic Chemistry (OUP 2008). The original part deals with main-group elements, the rare-earth elements, transition-metal clusters, and supramolecular systems. In this new book, selected material from significant advances in the past decade has been added, with particular emphasis on compounds that exemplify new types of bonds such as sigma-hole, triel bond, tetrel bond, pnictogen bond, chalcogen bond, halogen bond, halogen-halogen interaction, aerogen bond, as well as quintuple and sextuple metal-metal bonds. Other new topics include actinide compounds, metallophilicity, heterometallic macrocycles and cages, com- and dis-proportionation reactions, hydrogen-bonded organic frameworks (HOFs), halogen-bonded organic frameworks, halogen-halogen interactions in supramolecular frameworks, covalent organic frameworks (COFs), and metal-organic frameworks (MOFs).

Lanthanide and Actinide Chemistry

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 1118681363
Total Pages : 308 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis Lanthanide and Actinide Chemistry by : Simon Cotton

Download or read book Lanthanide and Actinide Chemistry written by Simon Cotton and published by John Wiley & Sons. This book was released on 2013-03-15 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt: The only introduction into the exciting chemistry of Lanthanides and Actinides. The book is based on a number of courses on "f elements" The author has a long experience in teaching this field of chemistry Lanthanides have become very common elements in research and technology applications; this book offers the basic knowledge The book offers insights into a vast range of applications, from lasers to synthesis The Inorganic Chemistry: A Textbook series reflects the pivotal role of modern inorganic and physical chemistry in a whole range of emerging areas, such as materials chemistry, green chemistry and bioinorganic chemistry, as well as providing a solid grounding in established areas such as solid state chemistry, coordination chemistry, main group chemistry and physical inorganic chemistry. Lanthanide and Actinide Chemistry is a one-volume account of the Lanthanides (including scandium and yttrium), the Actinides and the Transactinide elements, intended as an introductory treatment for undergraduate and postgraduate students. The principal features of these elements are set out in detail, enabling clear comparison and contrast with the Transition Elements and Main Group metals. The book covers the extraction of the elements from their ores and their purification, as well as the synthesis of the man-made elements; the properties of the elements and principal binary compounds; detailed accounts of their coordination chemistry and organometallic chemistry, from both preparative and structural viewpoints, with a clear explanation of the factors responsible for the adoption of particular coordination numbers; spectroscopy and magnetism, especially for the lanthanides, with case studies and accounts of applications in areas like magnetic resonance imaging, lasers and luminescence; nuclear separations and problems in waste disposal for the radioactive elements, particularly in the context of plutonium. Latest developments are covered in areas like the synthesis of the latest man-made elements, whilst there is a whole chapter on the application of lanthanide compounds in synthetic organic chemistry. End-of-chapter questions suitable for tutorial discussions are provided, whilst there is a very comprehensive bibliography providing ready access to further reading on all topics.

Elements of Inorganic Structural Chemistry

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Publisher :
ISBN 13 :
Total Pages : 200 pages
Book Rating : 4.E/5 ( download)

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Book Synopsis Elements of Inorganic Structural Chemistry by : Erwin Parthé

Download or read book Elements of Inorganic Structural Chemistry written by Erwin Parthé and published by . This book was released on 1996 with total page 200 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Actinide Nanoparticle Research

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Publisher : Springer Science & Business Media
ISBN 13 : 3642114326
Total Pages : 448 pages
Book Rating : 4.6/5 (421 download)

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Book Synopsis Actinide Nanoparticle Research by : Stepan N. Kalmykov

Download or read book Actinide Nanoparticle Research written by Stepan N. Kalmykov and published by Springer Science & Business Media. This book was released on 2011-06-17 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the first book to cover actinide nano research. It is of interest both for fundamental research into the chemistry and physics of f-block elements as well as for applied researchers such as those studying the long-term safety of nuclear waste disposal and developing remediation strategies. The authors cover important issues of the formation of actinide nano-particles, their properties and structure, environmental behavior of colloids and nanoparticles related to the safe disposal of nuclear wastes, modeling and advanced methods of characterization at the nano-scale.

The Chemistry of the Actinide Elements

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Publisher : Springer Science & Business Media
ISBN 13 : 9400931557
Total Pages : 905 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis The Chemistry of the Actinide Elements by : G.T. Seaborg

Download or read book The Chemistry of the Actinide Elements written by G.T. Seaborg and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 905 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first edition of this work appeared almost thirty years ago, when, as we can see in retrospect, the study of the actinide elements was in its first bloom. Although the broad features of the chemistry of the actinide elements were by then quite well delineated, the treatment of the subject in the first edition was of necessity largely descriptive in nature. A detailed understanding of the chemical consequences of the characteristic presence of Sf electrons in most of the members of the actinide series was still for the future, and many of the systematic features of the actinide elements were only dimly apprehended. In the past thirty years all this has changed. The application of new spectroscopic techniques, which came into general use during this period, and new theoretical insights, which came from a better understanding of chemical bonding, inorganic chemistry, and solid state phenomena, were among the important factors that led to a great expansion and maturation in actinide element research and a large number of new and important findings. The first edition consisted of a serial description of the individual actinide elements, with a single chapter devoted to the six heaviest elements (lawrencium, the heaviest actinide, was yet to be discovered). Less than 15 % of the text was devoted to a consideration of the systematics of the actinide elements.

The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5)

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 1402035985
Total Pages : 698 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5) by : L.R. Morss

Download or read book The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5) written by L.R. Morss and published by Springer Science & Business Media. This book was released on 2007-12-31 with total page 698 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of the Actinide and Transactinide Elements is a contemporary and definitive compilation of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ion, and compound from atomic number 89 (actinium) through to 109 (meitnerium), this multi-volume work has specialized and definitive chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, and trace analysis. Several chapters deal with environmental science, safe handling, and biological interactions of the actinide elements. The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavoured to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work encompasses five volumes, each of which groups chapters on related topics. All chapters represent the current state of research in the chemistry of these elements and related fields.

Modern Inorganic Synthetic Chemistry

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Publisher : Elsevier
ISBN 13 : 0444635955
Total Pages : 808 pages
Book Rating : 4.4/5 (446 download)

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Book Synopsis Modern Inorganic Synthetic Chemistry by : Ruren Xu

Download or read book Modern Inorganic Synthetic Chemistry written by Ruren Xu and published by Elsevier. This book was released on 2017-02-11 with total page 808 pages. Available in PDF, EPUB and Kindle. Book excerpt: Modern Inorganic Synthetic Chemistry, Second Edition captures, in five distinct sections, the latest advancements in inorganic synthetic chemistry, providing materials chemists, chemical engineers, and materials scientists with a valuable reference source to help them advance their research efforts and achieve breakthroughs. Section one includes six chapters centering on synthetic chemistry under specific conditions, such as high-temperature, low-temperature and cryogenic, hydrothermal and solvothermal, high-pressure, photochemical and fusion conditions. Section two focuses on the synthesis and related chemistry problems of highly distinct categories of inorganic compounds, including superheavy elements, coordination compounds and coordination polymers, cluster compounds, organometallic compounds, inorganic polymers, and nonstoichiometric compounds. Section three elaborates on the synthetic chemistry of five important classes of inorganic functional materials, namely, ordered porous materials, carbon materials, advanced ceramic materials, host-guest materials, and hierarchically structured materials. Section four consists of four chapters where the synthesis of functional inorganic aggregates is discussed, giving special attention to the growth of single crystals, assembly of nanomaterials, and preparation of amorphous materials and membranes. The new edition’s biggest highlight is Section five where the frontier in inorganic synthetic chemistry is reviewed by focusing on biomimetic synthesis and rationally designed synthesis. Focuses on the chemistry of inorganic synthesis, assembly, and organization of wide-ranging inorganic systems Covers all major methodologies of inorganic synthesis Provides state-of-the-art synthetic methods Includes real examples in the organization of complex inorganic functional materials Contains more than 4000 references that are all highly reflective of the latest advancement in inorganic synthetic chemistry Presents a comprehensive coverage of the key issues involved in modern inorganic synthetic chemistry as written by experts in the field

Structural Crystallography of Inorganic Oxysalts

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Author :
Publisher : Oxford University Press
ISBN 13 : 0199213208
Total Pages : 323 pages
Book Rating : 4.1/5 (992 download)

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Book Synopsis Structural Crystallography of Inorganic Oxysalts by : Sergey V. Krivovichev

Download or read book Structural Crystallography of Inorganic Oxysalts written by Sergey V. Krivovichev and published by Oxford University Press. This book was released on 2009 with total page 323 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inorganic oxysalts are chemical compounds that contain oxygen - the most abundant element in the Earth's core. This book is the first systematic survey of structures of inorganic oxysalts considered from the viewpoint of modern scientific methods of description and visualization of complex atomic arrangements.

Structural Chemistry Across the Periodic Table

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Publisher : Oxford University Press
ISBN 13 : 019887295X
Total Pages : 593 pages
Book Rating : 4.1/5 (988 download)

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Book Synopsis Structural Chemistry Across the Periodic Table by : Emeritus Professor and Wei Lun Research Professor Thomas Cw Mak

Download or read book Structural Chemistry Across the Periodic Table written by Emeritus Professor and Wei Lun Research Professor Thomas Cw Mak and published by Oxford University Press. This book was released on 2023-10-12 with total page 593 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is an expanded and updated version of Part III of the authors' previous work, Advanced Structural Inorganic Chemistry (OUP 2008). The original part deals with main-group elements, the rare-earth elements, transition-metal clusters, and supramolecular systems. In this new book, selected material from significant advances in the past decade has been added, with particular emphasis on compounds that exemplify new types of bonds such as sigma-hole, triel bond, tetrel bond, pnictogen bond, chalcogen bond, halogen bond, halogen-halogen interaction, aerogen bond, as well as quintuple and sextuple metal-metal bonds. Other new topics include actinide compounds, metallophilicity, heterometallic macrocycles and cages, com- and dis-proportionation reactions, hydrogen-bonded organic frameworks (HOFs), halogen-bonded organic frameworks, halogen-halogen interactions in supramolecular frameworks, covalent organic frameworks (COFs), and metal-organic frameworks (MOFs).

Inorganic 3D Structures

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Publisher : Springer Science & Business Media
ISBN 13 : 364220340X
Total Pages : 215 pages
Book Rating : 4.6/5 (422 download)

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Book Synopsis Inorganic 3D Structures by : Angel Vegas

Download or read book Inorganic 3D Structures written by Angel Vegas and published by Springer Science & Business Media. This book was released on 2011-06-17 with total page 215 pages. Available in PDF, EPUB and Kindle. Book excerpt: D. Santamaría-Pérez and F. Liebau : Structural relationships between intermetallic clathrates, porous tectosilicates and clathrates hydrates Vladislav A. Blatov: Crystal structures of inorganic oxoacid salts perceived as cation arrays: a periodic graph approach Ángel Vegas: FeLiPO4: Dissection of a crystal structure. The parts and the whole D. J. M. Bevan, R. L. Martin, Ángel Vegas: Rationalisation of the substructures derived from the three fluorite-related [Li6(MVLi)N4] polymorphs: An analysis in terms of the “Bärnighausen Trees” and of the “Extended Zintl-Klemm Concept” Ángel Vegas: Concurrent pathways in the phase transitions of alloys and oxides: Towards an Unified Vision of Inorganic Solids

The Chemistry of the Actinide Elements

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Publisher : Springer
ISBN 13 :
Total Pages : 1014 pages
Book Rating : 4.:/5 (51 download)

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Book Synopsis The Chemistry of the Actinide Elements by : J.J. Katz

Download or read book The Chemistry of the Actinide Elements written by J.J. Katz and published by Springer. This book was released on 1986-10 with total page 1014 pages. Available in PDF, EPUB and Kindle. Book excerpt: The. first edition of this work appeared almost thirty years ago, when, as we can see in retrospect, the study of the actinide elements was in its first bloom. Although the broad features of the chemistry of the actinide elements were by then quite weil delineated, the treatment of the subject in the first edition was of necessity largely descriptive in nature. A detailed understanding ofthe chemical consequences of the characteristic presence of 5f electrons in most of the members ofthe actinide se ries was still for the future, and many ofthe systematic features ofthe actinide elements were only dimly apprehended. In the past thirty years all this has changed. The application of new spectroscopic techniques, which came into general use during this period, and new theoretical insights, which came from a better understanding of chemical bonding, inorganic chemistry, and solid state phenomena, were among the important factors that led to a great expansion and maturation in actinide element research and a large number of new and important findings. The first edition consisted of aserial description of the individual actinide elements, with a single chapter devoted to the six heaviest elements (lawrencium, the heaviest actinide, was yet to be discovered). Less than 15 % of the text was devoted to a consideration of the systematics of the actinide elements.

Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment

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Publisher : Elsevier
ISBN 13 : 0857092278
Total Pages : 512 pages
Book Rating : 4.8/5 (57 download)

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Book Synopsis Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment by : Kenneth L Nash

Download or read book Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment written by Kenneth L Nash and published by Elsevier. This book was released on 2011-03-15 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced separations technology is key to closing the nuclear fuel cycle and relieving future generations from the burden of radioactive waste produced by the nuclear power industry. Nuclear fuel reprocessing techniques not only allow for recycling of useful fuel components for further power generation, but by also separating out the actinides, lanthanides and other fission products produced by the nuclear reaction, the residual radioactive waste can be minimised. Indeed, the future of the industry relies on the advancement of separation and transmutation technology to ensure environmental protection, criticality-safety and non-proliferation (i.e., security) of radioactive materials by reducing their long-term radiological hazard. Advanced separation techniques for nuclear fuel reprocessing and radioactive waste treatment provides a comprehensive and timely reference on nuclear fuel reprocessing and radioactive waste treatment. Part one covers the fundamental chemistry, engineering and safety of radioactive materials separations processes in the nuclear fuel cycle, including coverage of advanced aqueous separations engineering, as well as on-line monitoring for process control and safeguards technology. Part two critically reviews the development and application of separation and extraction processes for nuclear fuel reprocessing and radioactive waste treatment. The section includes discussions of advanced PUREX processes, the UREX+ concept, fission product separations, and combined systems for simultaneous radionuclide extraction. Part three details emerging and innovative treatment techniques, initially reviewing pyrochemical processes and engineering, highly selective compounds for solvent extraction, and developments in partitioning and transmutation processes that aim to close the nuclear fuel cycle. The book concludes with other advanced techniques such as solid phase extraction, supercritical fluid and ionic liquid extraction, and biological treatment processes. With its distinguished international team of contributors, Advanced separation techniques for nuclear fuel reprocessing and radioactive waste treatment is a standard reference for all nuclear waste management and nuclear safety professionals, radiochemists, academics and researchers in this field. A comprehensive and timely reference on nuclear fuel reprocessing and radioactive waste treatment Details emerging and innovative treatment techniques, reviewing pyrochemical processes and engineering, as well as highly selective compounds for solvent extraction Discusses the development and application of separation and extraction processes for nuclear fuel reprocessing and radioactive waste treatment

The Chemistry of the Actinide and Transactinide Elements (Set Vol.1-6)

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 9400702116
Total Pages : 4503 pages
Book Rating : 4.4/5 (7 download)

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Book Synopsis The Chemistry of the Actinide and Transactinide Elements (Set Vol.1-6) by : L.R. Morss

Download or read book The Chemistry of the Actinide and Transactinide Elements (Set Vol.1-6) written by L.R. Morss and published by Springer Science & Business Media. This book was released on 2010-10-21 with total page 4503 pages. Available in PDF, EPUB and Kindle. Book excerpt: The fourth edition of "The Chemistry of the Actinide and Transactinide Elements" comprises all chapters in volumes 1 through 5 of the third edition (published in 2006) plus a new volume 6. To remain consistent with the plan of the first edition, “ ... to provide a comprehensive and uniform treatment of the chemistry of the actinide [and transactinide] elements for both the nuclear technologist and the inorganic and physical chemist,” and to be consistent with the maturity of the field, the fourth edition is organized in three parts. The first group of chapters follows the format of the first and second editions with chapters on individual elements or groups of elements that describe and interpret their chemical properties. A chapter on the chemical properties of the transactinide elements follows. The second group, chapters 15-26, summarizes and correlates physical and chemical properties that are in general unique to the actinide elements, because most of these elements contain partially-filled shells of 5f electrons whether present as isolated atoms or ions, as metals, as compounds, or as ions in solution. The third group, chapters 27-39, focuses on specialized topics that encompass contemporary fields related to actinides in the environment, in the human body, and in storage or wastes. Two appendices at the end of volume 5 tabulate important nuclear properties of all actinide and transactinide isotopes. Volume 6 (Chapters 32 through 39) consists of new chapters that focus on actinide species in the environment, actinide waste forms, nuclear fuels, analytical chemistry of plutonium, actinide chalcogenide and hydrothermal synthesis of actinide compounds. The subject and author indices and list of contributors encompass all six volumes.

Structural Methods in Molecular Inorganic Chemistry

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 0470972785
Total Pages : 0 pages
Book Rating : 4.4/5 (79 download)

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Book Synopsis Structural Methods in Molecular Inorganic Chemistry by : D. W. H. Rankin

Download or read book Structural Methods in Molecular Inorganic Chemistry written by D. W. H. Rankin and published by John Wiley & Sons. This book was released on 2013-04-01 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Determining the structure of molecules is a fundamental skill that all chemists must learn. Structural Methods in Molecular Inorganic Chemistry is designed to help readers interpret experimental data, understand the material published in modern journals of inorganic chemistry, and make decisions about what techniques will be the most useful in solving particular structural problems. Following a general introduction to the tools and concepts in structural chemistry, the following topics are covered in detail: • computational chemistry • nuclear magnetic resonance spectroscopy • electron paramagnetic resonance spectroscopy • Mössbauer spectroscopy • rotational spectra and rotational structure • vibrational spectroscopy • electronic characterization techniques • diffraction methods • mass spectrometry The final chapter presents a series of case histories, illustrating how chemists have applied a broad range of structural techniques to interpret and understand chemical systems. Throughout the textbook a strong connection is made between theoretical topics and the real world of practicing chemists. Each chapter concludes with problems and discussion questions, and a supporting website contains additional advanced material. Structural Methods in Molecular Inorganic Chemistry is an extensive update and sequel to the successful textbook Structural Methods in Inorganic Chemistry by Ebsworth, Rankin and Cradock. It is essential reading for all advanced students of chemistry, and a handy reference source for the professional chemist.