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Startup And Operation Of A Metal Hydride Based Isotope Separation Process
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Book Synopsis Startup and Operation of a Metal Hydride Based Isotope Separation Process by :
Download or read book Startup and Operation of a Metal Hydride Based Isotope Separation Process written by and published by . This book was released on 1995 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: Production scale separation of tritium from other hydrogen isotopes at the Savannah River Site (SRS) in Aiken, SC, has been accomplished by several methods. These methods include thermal diffusion (1957--1986), fractional absorption (1964--1968), and cryogenic distillation (1967-present). Most recently, the Thermal Cycling Absorption Process (TCAP), a metal hydride based hydrogen isotope separation system, began production in the Replacement Tritium Facility (RTF) on April 9, 1994. TCAP has been in development at the Savannah River Technology Center since 1980. The production startup of this semi-continuous gas chromatographic separation process is a significant accomplishment for the Savannah River Site and was achieved after years of design, development, and testing.
Book Synopsis Metal Hydride Based Isotope Separation by :
Download or read book Metal Hydride Based Isotope Separation written by and published by . This book was released on 1991 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: A program to develop a metal hydride based hydrogen isotope separation process began at the Savannah River Laboratory in 1980. This semi-continuous gas chromatographic separation process will be used in new tritium facilities at the Savannah River Site. A tritium production unit is scheduled to start operation in 1993. An experimental, large-scale unit is currently being tested using protium and deuterium. Operation of the large-scale unit has demonstrated separation of mixed hydrogen isotopes (55% protium and 45% deuterium), resulting in protium and deuterium product streams with purities better than 99.5%. 3 refs., 4 figs.
Book Synopsis Hydrogen Isotope Exchange in Metal Hydride Columns by :
Download or read book Hydrogen Isotope Exchange in Metal Hydride Columns written by and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Several metal hydrides were shown to act as chromatographic media for hydrogen isotopes. The procedure was to equilibrate a column of hydride with flowing hydrogen, inject a small quantity of tritium tracer, and observe its elution behavior. Characteristic retention times were found. From these and the extent of widening of the tritium band, the heights equivalent to a theoretical plate could be calculated. Values of around 1 cm were obtained. The following are the metals whose hydrides were studied, together with the temperature ranges in which chromatographic behavior was observed: vanadium, 0 to 70°C; zirconium, 500 to 600°C; LaNi5, -78 to +30°C; Mg2Ni, 300 to 375°C; palladium, 0 to 70°C. A dual-temperature isotope separation process based on hydride chromatography was demonstrated. In this, a column was caused to cycle between two temperatures while being supplied with a constant stream of tritium-traced hydrogen. Each half-cycle was continued until ''breakthrough, '' i.e., until the tritium concentration in the effluent was the same as that in the feed. Up to that point, the effluent was enriched or depleted in tritium, by up to 20%.
Download or read book Energy Research Abstracts written by and published by . This book was released on 1992 with total page 752 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Proceedings of the Fourth Topical Meeting on Tritium Technology in Fission, Fusion, and Isotopic Applications by : James Anderson
Download or read book Proceedings of the Fourth Topical Meeting on Tritium Technology in Fission, Fusion, and Isotopic Applications written by James Anderson and published by . This book was released on 1992 with total page 1110 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Chemical Exchange as a Versatile Isotope Separation Process by : G. H. Clewett
Download or read book Chemical Exchange as a Versatile Isotope Separation Process written by G. H. Clewett and published by . This book was released on 1950 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Advanced Environmental, Chemical, and Biological Sensing Technologies ... by :
Download or read book Advanced Environmental, Chemical, and Biological Sensing Technologies ... written by and published by . This book was released on 2004 with total page 168 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Fusion Technology written by and published by . This book was released on 1995 with total page 1254 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Theory of Isotope Separation as Applied to the Large-scale Production of U235 by : Karl P. Cohen
Download or read book The Theory of Isotope Separation as Applied to the Large-scale Production of U235 written by Karl P. Cohen and published by . This book was released on 1951 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Theory of Isotope Separation as Applied to the Large Scale Production of U235 by : Karl Cohen
Download or read book The Theory of Isotope Separation as Applied to the Large Scale Production of U235 written by Karl Cohen and published by . This book was released on 2015-03-07 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: Isotope separation is the process of concentrating specific isotopes of a chemical element by removing other isotopes. The use of the nuclides produced is various. The largest variety is used in research (e.g. in chemistry where atoms of "marker" nuclide are used to figure out reaction mechanisms). By tonnage, separating natural uranium into enriched uranium and depleted uranium is the largest application. In the following text, mainly the uranium enrichment is considered. This process is a crucial one in the manufacture of uranium fuel for nuclear power stations, and is also required for the creation of uranium based nuclear weapons. Plutonium-based weapons use plutonium produced in a nuclear reactor, which must be operated in such a way as to produce plutonium already of suitable isotopic mix or grade. While different chemical elements can be purified through chemical processes, isotopes of the same element have nearly identical chemical properties, which makes this type of separation impractical, except for separation of deuterium. There are three types of isotope separation techniques: Those based directly on the atomic weight of the isotope. Those based on the small differences in chemical reaction rates produced by different atomic weights. Those based on properties not directly connected to atomic weight, such as nuclear resonances. The third type of separation is still experimental; practical separation techniques all depend in some way on the atomic mass. It is therefore generally easier to separate isotopes with a larger relative mass difference. For example deuterium has twice the mass of ordinary (light) hydrogen and it is generally easier to purify it than to separate uranium-235 from the more common uranium-238. On the other extreme, separation of fissile plutonium-239 from the common impurity plutonium-240, while desirable in that it would allow the creation of gun-type nuclear weapons from plutonium, is generally agreed to be impractical.
Download or read book INIS Atomindex written by and published by . This book was released on 1996 with total page 794 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Cascades for Hydrogen Isotope Separation Using Metal Hydrides by :
Download or read book Cascades for Hydrogen Isotope Separation Using Metal Hydrides written by and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Designs are presented for continuous countercurrent hydrogen isotope separation cascades based on the use of metal hydrides. The cascades are made up of pressure swing adsorption (PSA) or temperature swing adsorption (TSA) stages. The designs were evolved from consideration of previously conducted studies of the separation performance of four types of PSA and TSA processes.
Download or read book Fusion Science and Technology written by and published by . This book was released on 2002 with total page 1108 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Studies of Hydrogen Isotope Separation Using Vanadium Hydride in a Temperature Cycling Process by :
Download or read book Studies of Hydrogen Isotope Separation Using Vanadium Hydride in a Temperature Cycling Process written by and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Separations of gaseous HT-H2 mixtures on vanadium monohydride were carried out using a two-column temperature cycling process similar to parametric pumping. An equilibrium theory of process operation is presented which was in qualitative agreement with experimental results. Failure to achieve complete removal of HT from the cold column effluent as predicted was ascribed to the finite rates of the exchange reaction and to the presence and operation of an isotope effect in the rate of hydrogen absorption.
Book Synopsis Government Reports Announcements & Index by :
Download or read book Government Reports Announcements & Index written by and published by . This book was released on 1995 with total page 604 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Metal Hydride Compacts for Hydrogen Isotope Separation by :
Download or read book Metal Hydride Compacts for Hydrogen Isotope Separation written by and published by . This book was released on 1990 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt: A column packed with pellets of copper plated LaNi{sub 4.25}Al{sub 0.75} has been evaluated for its separation efficiency using a displacement method. Deuterium breakthrough curves were produced experimentally and compared with those calculated with a stage model. The height equivalent to a theoretical plate was attained and its dependence on temperature and gas flow rate was established. 6 refs., 4 figs.
Download or read book Energy written by and published by . This book was released on 1977 with total page 990 pages. Available in PDF, EPUB and Kindle. Book excerpt: