Spin Crossover Materials

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Spin-Crossover Materials

Author : Malcolm A. Halcrow
Publisher : John Wiley & Sons
ISBN 13 : 1118519310
Total Pages : 729 pages
Book Rating : 4.1/5 (185 download)

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Book Synopsis Spin-Crossover Materials by : Malcolm A. Halcrow

Download or read book Spin-Crossover Materials written by Malcolm A. Halcrow and published by John Wiley & Sons. This book was released on 2013-01-07 with total page 729 pages. Available in PDF, EPUB and Kindle. Book excerpt: The phenomenon of spin-crossover has a large impact on the physical properties of a solid material, including its colour, magnetic moment, and electrical resistance. Some materials also show a structural phase change during the transition. Several practical applications of spin-crossover materials have been demonstrated including display and memory devices, electrical and electroluminescent devices, and MRI contrast agents. Switchable liquid crystals, nanoparticles, and thin films of spin-crossover materials have also been achieved. Spin-Crossover Materials: Properties and Applications presents a comprehensivesurvey of recent developments in spin-crossover research, highlighting the multidisciplinary nature of this rapidly expanding field. Following an introductory chapter which describes the spin-crossover phenomenon and historical development of the field, the book goes on to cover a wide range of topics including Spin-crossover in mononuclear, polynuclear and polymeric complexes Structure: function relationships in molecular spin-crossover materials Charge-transfer-induced spin-transitions Reversible spin-pairing in crystalline organic radicals Spin-state switching in solution Spin-crossover compounds in multifunctional switchable materials and nanotechnology Physical and theoretical methods for studying spin-crossover materials Spin-Crossover Materials: Properties and Applications is a valuable resource for academic researchers working in the field of spin-crossover materials and topics related to crystal engineering, solid state chemistry and physics, and molecular materials. Postgraduate students will also find this book useful as a comprehensive introduction to the field.

Spin Crossover in Transition Metal Compounds I

Author : Philipp Gütlich
Publisher : Springer Science & Business Media
ISBN 13 : 9783540403944
Total Pages : 640 pages
Book Rating : 4.4/5 (39 download)

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Book Synopsis Spin Crossover in Transition Metal Compounds I by : Philipp Gütlich

Download or read book Spin Crossover in Transition Metal Compounds I written by Philipp Gütlich and published by Springer Science & Business Media. This book was released on 2004-05-12 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by numerous experts

Spin Crossover in Transition Metal Compounds II

Author : Philipp Gütlich
Publisher : Springer
ISBN 13 : 9783642073281
Total Pages : 295 pages
Book Rating : 4.0/5 (732 download)

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Book Synopsis Spin Crossover in Transition Metal Compounds II by : Philipp Gütlich

Download or read book Spin Crossover in Transition Metal Compounds II written by Philipp Gütlich and published by Springer. This book was released on 2010-12-01 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Spin-Crossover Complexes

Author : Kazuyuki Takahashi MDPI
Publisher : MDPI
ISBN 13 : 3038428256
Total Pages : 207 pages
Book Rating : 4.0/5 (384 download)

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Book Synopsis Spin-Crossover Complexes by : Kazuyuki Takahashi MDPI

Download or read book Spin-Crossover Complexes written by Kazuyuki Takahashi MDPI and published by MDPI. This book was released on 2018-06-26 with total page 207 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a printed edition of the Special Issue "Spin-Crossover Complexes" that was published in Inorganics

Functional Molecular Materials

Author : Matteo Atzori
Publisher : CRC Press
ISBN 13 : 1351233645
Total Pages : 372 pages
Book Rating : 4.3/5 (512 download)

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Book Synopsis Functional Molecular Materials by : Matteo Atzori

Download or read book Functional Molecular Materials written by Matteo Atzori and published by CRC Press. This book was released on 2018-04-17 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of molecular materials represents an exciting playground for the design, tailoring, and combination of chemical building blocks as carriers of physical properties and aims at the understanding and development of novel functional molecular devices. Within this extraordinarily widespread framework, the realization of materials with the desired functionalities can only be achieved through a rational design strategy based on a solid understanding of the chemical and physical features of each constituting building block. This book provides a general overview of molecular materials, discussing their key features in a simple and organic way by focusing more on basic concepts rather than on specialized descriptions, in order to supply the non-expert reader with the immediate fundamental tools and hints to understand and develop research in this field. With this view, it is a step-by-step guide toward the preparation of functional molecular materials, where the knowledge and understanding so far attained by the scientific community through the investigation of significant archetypical examples is deconstructed down to the fundamental basis and then presented in reverse, from the base to the top.

Transition Metals in Coordination Environments

Author : Ewa Broclawik
Publisher : Springer
ISBN 13 : 3030117146
Total Pages : 532 pages
Book Rating : 4.0/5 (31 download)

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Book Synopsis Transition Metals in Coordination Environments by : Ewa Broclawik

Download or read book Transition Metals in Coordination Environments written by Ewa Broclawik and published by Springer. This book was released on 2019-03-16 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on the electronic properties of transition metals in coordination environments. These properties are responsible for the unique and intricate activity of transition metal sites in bio- and inorganic catalysis, but also pose challenges for both theoretical and experimental studies. Written by an international group of recognized experts, the book reviews recent advances in computational modeling and discusses their interplay using experiments. It covers a broad range of topics, including advanced computational methods for transition metal systems; spectroscopic, electrochemical and catalytic properties of transition metals in coordination environments; metalloenzymes and biomimetic compounds; and spin-related phenomena. As such, the book offers an invaluable resource for all researchers and postgraduate students interested in both fundamental and application-oriented research in the field of transition metal systems.

Multifunctional Molecular Materials

Author : Lahcene Ouahab
Publisher : CRC Press
ISBN 13 : 9814364304
Total Pages : 314 pages
Book Rating : 4.8/5 (143 download)

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Book Synopsis Multifunctional Molecular Materials by : Lahcene Ouahab

Download or read book Multifunctional Molecular Materials written by Lahcene Ouahab and published by CRC Press. This book was released on 2013-01-24 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive overview on multifunctional molecular materials that involve coexistence or interplay or synergy between multiple physical properties focusing on electrical conductivity, magnetism, single-molecule magnets behavior, chirality, spin crossover, and luminescence. The book’s coverage ranges from transition metals and lanthanide coordination complexes to genuine organic materials. The book also discusses some potentialities of applications of these materials in molecule-based devices.

The Molecule-Metal Interface

Author : Norbert Koch
Publisher : John Wiley & Sons
ISBN 13 : 3527653198
Total Pages : 257 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis The Molecule-Metal Interface by : Norbert Koch

Download or read book The Molecule-Metal Interface written by Norbert Koch and published by John Wiley & Sons. This book was released on 2013-02-08 with total page 257 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reviewing recent progress in the fundamental understanding of the molecule-metal interface, this useful addition to the literature focuses on experimental studies and introduces the latest analytical techniques as applied to this interface. The first part covers basic theory and initial principle studies, while the second part introduces readers to photoemission, STM, and synchrotron techniques to examine the atomic structure of the interfaces. The third part presents photoelectron spectroscopy, high-resolution UV photoelectron spectroscopy and electron spin resonance to study the electronic structure of the molecule-metal interface. In the closing chapter the editors discuss future perspectives. Written as a senior graduate or senior undergraduate textbook for students in physics, chemistry, materials science or engineering, the book's interdisciplinary approach makes it equally relevant for researchers working in the field of organic and molecular electronics.

A Textbook of Inorganic Chemistry – Volume 1

Author : Mandeep Dalal
Publisher : Dalal Institute
ISBN 13 : 8193872002
Total Pages : 480 pages
Book Rating : 4.1/5 (938 download)

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Book Synopsis A Textbook of Inorganic Chemistry – Volume 1 by : Mandeep Dalal

Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.

Functional Metallosupramolecular Materials

Author : John Hardy
Publisher : Royal Society of Chemistry
ISBN 13 : 1782620222
Total Pages : 416 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Functional Metallosupramolecular Materials by : John Hardy

Download or read book Functional Metallosupramolecular Materials written by John Hardy and published by Royal Society of Chemistry. This book was released on 2015-07-17 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is great interest in metallosupramolecular materials because of their use in magnetic, photonic and electronic materials. Functional Metallosupramolecular Materials focuses on the applications of these materials covering the chemistry underlying the synthesis of a variety of ligands to coordinate various metal ions and the generation of 2D and 3D materials based on these constructs. The book starts by looking at different metallosupramolecular systems including naturally occurring functional metallosupramolecular materials; DNA-based metallosupramolecular materials; metallopolymers; metallogels as well as functional materials based on MOFs. Subsequent chapters then systematically cover the different applications such as molecular computation, spin-crossover, light harvesting and as photocatalysts for the production of solar fuels. The book provides an overview of functional metallosupramolecular materials that will be of interest to graduate students, academics and industrial chemists interested in supramolecular chemistry, materials science and the materials applications. Priced at £159.00, US$260.00, €198.75

Molecular Magnetic Materials

Author : Barbara Sieklucka
Publisher : John Wiley & Sons
ISBN 13 : 3527339531
Total Pages : 508 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Molecular Magnetic Materials by : Barbara Sieklucka

Download or read book Molecular Magnetic Materials written by Barbara Sieklucka and published by John Wiley & Sons. This book was released on 2017-01-17 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive overview of this rapidly expanding interdisciplinary field of research. After a short introduction to the basics of magnetism and molecular magnetism, the text goes on to cover specific properties of molecular magnetic materials as well as their current and future applications. Design strategies for acquiring molecular magnetic materials with desired physical properties are discussed, as are such multifunctional materials as high Tc magnets, chiral and luminescent magnets, magnetic sponges as well as photo- and piezo-switching magnets. The result is an excellent resource for materials scientists, chemists, physicists and crystal engineers either entering or already working in the field.

Essentials of Inorganic Materials Synthesis

Author : C. N. R. Rao
Publisher : John Wiley & Sons
ISBN 13 : 111883254X
Total Pages : 231 pages
Book Rating : 4.1/5 (188 download)

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Book Synopsis Essentials of Inorganic Materials Synthesis by : C. N. R. Rao

Download or read book Essentials of Inorganic Materials Synthesis written by C. N. R. Rao and published by John Wiley & Sons. This book was released on 2015-04-06 with total page 231 pages. Available in PDF, EPUB and Kindle. Book excerpt: This compact handbook describes all the important methods of synthesis employed today for synthesizing inorganic materials. Some features: Focuses on modern inorganic materials with applications in nanotechnology, energy materials, and sustainability Synthesis is a crucial component of materials science and technology; this book provides a simple introduction as well as an updated description of methods Written in a very simple style, providing references to the literature to get details of the methods of preparation when required

Chemistry in Action: Making Molecular Movies with Ultrafast Electron Diffraction and Data Science

$Download Chemistry in Action: Making Molecular Movies with Ultrafast Electron Diffraction and Data Science PDF Online Free$

Author : Lai Chung Liu
Publisher : Springer Nature
ISBN 13 : 3030548511
Total Pages : 249 pages
Book Rating : 4.0/5 (35 download)

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Book Synopsis Chemistry in Action: Making Molecular Movies with Ultrafast Electron Diffraction and Data Science by : Lai Chung Liu

Download or read book Chemistry in Action: Making Molecular Movies with Ultrafast Electron Diffraction and Data Science written by Lai Chung Liu and published by Springer Nature. This book was released on 2020-09-10 with total page 249 pages. Available in PDF, EPUB and Kindle. Book excerpt: The thesis provides the necessary experimental and analytical tools to unambiguously observe the atomically resolved chemical reactions. A great challenge of modern science has been to directly observe atomic motions during structural transitions, and while this was first achieved through a major advance in electron source brightness, the information content was still limited and new methods for image reconstruction using femtosecond electron diffraction methods were needed. One particular challenge lay in reconciling the innumerable possible nuclear configurations with the observation of chemical reaction mechanisms that reproducibly give the same kind of chemistry for large classes of molecules. The author shows that there is a simple solution that occurs during barrier crossing in which the highly anharmonic potential at that point in nuclear rearrangements couples high- and low-frequency vibrational modes to give highly localized nuclear motions, reducing hundreds of potential degrees of freedom to just a few key modes. Specific examples are given in this thesis, including two photoinduced phase transitions in an organic system, a ring closure reaction, and two direct observations of nuclear reorganization driven by spin transitions. The emerging field of structural dynamics promises to change the way we think about the physics of chemistry and this thesis provides tools to make it happen.

Molecular Materials

Author : Duncan W. Bruce
Publisher : John Wiley & Sons
ISBN 13 : 1119972957
Total Pages : 455 pages
Book Rating : 4.1/5 (199 download)

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Book Synopsis Molecular Materials by : Duncan W. Bruce

Download or read book Molecular Materials written by Duncan W. Bruce and published by John Wiley & Sons. This book was released on 2011-04-04 with total page 455 pages. Available in PDF, EPUB and Kindle. Book excerpt: “... the book does an excellent job of putting together several different classes of materials. Many common points emerge, and the book may facilitate the development of hybrids in which the qualities of the “parents” are enhanced.” –Angew. Chem. Int. Ed. 2011 With applications in optoelectronics and photonics, quantum information processing, nanotechnology and data storage, molecular materials enrich our daily lives in countless ways. These materials have properties that depend on their exact structure, the degree of order in the way the molecules are aligned and their crystalline nature. Small, delicate changes in molecular structure can totally alter the properties of the material in bulk. There has been increasing emphasis on functional metal complexes that demonstrate a wide range of physical phenomena. Molecular Materials represents the diversity of the area, encapsulating magnetic, optical and electrical properties, with chapters on: Metal-Based Quadratic Nonlinear Optical Materials Physical Properties of Metallomesogens Molecular Magnetic Materials Molecular Inorganic Conductors and Superconductors Molecular Nanomagnets Structured to include a clear introduction, a discussion of the basic concepts and up-to-date coverage of key aspects, each chapter provides a detailed review which conveys the excitement of work in that field. Additional volumes in the Inorganic Materials Series: Low-Dimensional Solids | Molecular Materials | Porous Materials | Energy Materials

Synthesis and Applications of New Spin Crossover Compounds

Author : Takafumi Kitazawa
Publisher : MDPI
ISBN 13 : 303921361X
Total Pages : 254 pages
Book Rating : 4.0/5 (392 download)

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Book Synopsis Synthesis and Applications of New Spin Crossover Compounds by : Takafumi Kitazawa

Download or read book Synthesis and Applications of New Spin Crossover Compounds written by Takafumi Kitazawa and published by MDPI. This book was released on 2019-10-11 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: The crystal chemistry of spin crossover (SCO) behavior in coordination compounds can potentially be in association with smart materials—promising materials for applications as components of memory devices, displays, sensors and mechanical devices and, especially, actuators, such as artificial muscles. This Special Issue is devoted to various aspects of SCO and related research, comprising 18 interesting original papers on valuable and important SCO topics. Significant and fundamental scientific attention has been focused on the SCO phenomena in a wide research range of fields of fundamental chemical and physical and related sciences, containing the interdisciplinary regions of chemical and physical sciences related to the SCO phenomena. Coordination materials with bistable systems between the LS and the HS states are usually triggered by external stimuli, such as temperature, light, pressure, guest molecule inclusion, soft X-ray, and nuclear decay. Since the first Hofmann-like spin crossover (SCO) behavior in {Fe(py)2[Ni(CN)4]}n (py = pyridine) was demonstrated, this crystal chemistry motif has been frequently used to design Fe(II) SCO materials to enable determination of the correlations between structural features and magnetic properties.

Theoretical Foundations of Molecular Magnetism

Author : Roman Boča
Publisher : Elsevier
ISBN 13 : 9780080542713
Total Pages : 873 pages
Book Rating : 4.5/5 (427 download)

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Book Synopsis Theoretical Foundations of Molecular Magnetism by : Roman Boča

Download or read book Theoretical Foundations of Molecular Magnetism written by Roman Boča and published by Elsevier. This book was released on 1999-09-29 with total page 873 pages. Available in PDF, EPUB and Kindle. Book excerpt: Magnetochemistry is a highly interdisciplinary field that attracts the interest of chemists, physicists and material scientists. Although the general strategy of theoretical molecular magnetism has been in place for decades, its performance for extended systems of interacting magnetic units can be very complicated. Professor Boca's book treats the "mosaic" of the theoretical approaches currently used in the field. This book presents a review of the theoretical concepts of molecular magnetism. The first chapter of the book recapitulates the necessary mathematical background. An overview of macroscopic magnetic properties is then presented. Formulation of magnetic parameters and methods of their calculation are given, followed by a brief summary of magnetic behaviour. The core of the book deals with the temperature dependence of magnetic susceptibility for mononuclear complexes, dimers, and exchange-coupled clusters. This book will be particularly useful for those scientists and students working in the field of molecular magnetism who need to refer to a complete and systematic treatment of the mathematics of magneto-chemical theory.

Smart Inorganic Polymers

Author : Evamarie Hey-Hawkins
Publisher : John Wiley & Sons
ISBN 13 : 3527819134
Total Pages : 421 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Smart Inorganic Polymers by : Evamarie Hey-Hawkins

Download or read book Smart Inorganic Polymers written by Evamarie Hey-Hawkins and published by John Wiley & Sons. This book was released on 2019-02-07 with total page 421 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides complete and undiluted knowledge on making inorganic polymers functional. This comprehensive book reflects the state of the art in the field of inorganic polymers, based on research conducted by a number of internationally leading research groups working in this area. It covers the synthesis aspects of synthetic inorganic polymers and looks at multiple inorganic monomers as building blocks, which exhibit unprecedented electronic, redox, photo-emissive, magnetic, self-healing and catalytic properties. It also looks at the applications of inorganic polymers in areas such as optoelectronics, energy storage, industrial chemistry, and biology. Beginning with an overview of the use of smart inorganic polymers in daily life, Smart Inorganic Polymers: Synthesis, Properties and Emerging Applications in Materials and Life Sciences goes on to study the synthesis, properties, and applications of polymers incorporating different heteroelements such as boron, phosphorus, silicon, germanium, and tin. The book also examines inorganic polymers in flame-retardants, as functional materials, and in biology. An excellent addition to the polymer scientists' and synthetic chemists' toolbox Summarizes the state of the art on how to make and use functional inorganic polymers, from synthesis to applications Edited by the coordinator of a highly funded European community research program (COST action) that focuses specifically on the exploration of inorganic polymers Features contributions from top experts in the field Aimed at academics and industrial researchers in this field, Smart Inorganic Polymers: Synthesis, Properties and Emerging Applications in Materials and Life Sciences will also benefit scientists who want to get a better overview on the state-of-the-art of this rapidly advancing area.