Spectroscopy of Complex Oxide Interfaces

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Publisher : Springer
ISBN 13 : 3319749897
Total Pages : 326 pages
Book Rating : 4.3/5 (197 download)

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Book Synopsis Spectroscopy of Complex Oxide Interfaces by : Claudia Cancellieri

Download or read book Spectroscopy of Complex Oxide Interfaces written by Claudia Cancellieri and published by Springer. This book was released on 2018-04-09 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book summarizes the most recent and compelling experimental results for complex oxide interfaces. The results of this book were obtained with the cutting-edge photoemission technique at highest energy resolution. Due to their fascinating properties for new-generation electronic devices and the challenge of investigating buried regions, the book chiefly focuses on complex oxide interfaces. The crucial feature of exploring buried interfaces is the use of soft X-ray angle-resolved photoemission spectroscopy (ARPES) operating on the energy range of a few hundred eV to increase the photoelectron mean free path, enabling the photons to penetrate through the top layers – in contrast to conventional ultraviolet (UV)-ARPES techniques. The results presented here, achieved by different research groups around the world, are summarized in a clearly structured way and discussed in comparison with other photoemission spectroscopy techniques and other oxide materials. They are complemented and supported by the most recent theoretical calculations as well as results of complementary experimental techniques including electron transport and inelastic resonant X-ray scattering.

Hard X-ray Photoelectron Spectroscopy (HAXPES)

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Publisher : Springer
ISBN 13 : 3319240439
Total Pages : 576 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Hard X-ray Photoelectron Spectroscopy (HAXPES) by : Joseph Woicik

Download or read book Hard X-ray Photoelectron Spectroscopy (HAXPES) written by Joseph Woicik and published by Springer. This book was released on 2015-12-26 with total page 576 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides the first complete and up-to-date summary of the state of the art in HAXPES and motivates readers to harness its powerful capabilities in their own research. The chapters are written by experts. They include historical work, modern instrumentation, theory and applications. This book spans from physics to chemistry and materials science and engineering. In consideration of the rapid development of the technique, several chapters include highlights illustrating future opportunities as well.

INVESTIGATIONS OF STRONGLY-CORRELATED COMPLEX METAL OXIDES AND INTERFACES USING SYNCHROTRON X-RAY SPECTROSCOPY

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Publisher :
ISBN 13 :
Total Pages : 154 pages
Book Rating : 4.:/5 (128 download)

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Book Synopsis INVESTIGATIONS OF STRONGLY-CORRELATED COMPLEX METAL OXIDES AND INTERFACES USING SYNCHROTRON X-RAY SPECTROSCOPY by : Ravini Udeshika Chandrasena

Download or read book INVESTIGATIONS OF STRONGLY-CORRELATED COMPLEX METAL OXIDES AND INTERFACES USING SYNCHROTRON X-RAY SPECTROSCOPY written by Ravini Udeshika Chandrasena and published by . This book was released on 2019 with total page 154 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this dissertation, we used a combination of several synchrotron-based x-ray spectroscopic techniques to investigate the effects of strain, ionic defect formation, and heteroengineering in strongly-correlated electronic systems. First, we introduce a method to control and stabilize oxygen vacancies in complex transition-metal oxide thin films. In our approach, we utilized atomic layer-by-layer pulsed laser deposition (ALL laser PLD) from two separate targets to synthesize high-quality single crystalline CaMnO3 films under coherent tensile strain, varying systematically from +0.8% to +4%. An increase of the oxygen vacancy content in the single-crystalline CaMnO3 thin films with applied in-plane strain was experimentally observed using high-resolution soft x-ray absorption spectroscopy (XAS) in conjunction with bulk-sensitive hard x-ray photoelectron spectroscopy (HAXPES). Our experimental results were verified using first-principles theory and atomic core-hole multiplet calculations. Furthermore, our results highlight the importance of protecting the surfaces of CaMnO3 thin-films with thin Pt layers in-situ in order to stabilize the oxygen vacancy content. Next, we discuss the role of oxygen vacancies in driving the metal-insulator transition in LaNiO3 thin films. Here, we also use atomic layer-by-layer pulsed laser deposition (ALL laser PLD) from two separate targets to synthesize high-quality single-crystalline LaNiO3 films with systematically varying thicknesses, ranging from 1 u.c. to 50 u.c. An increase in the oxygen vacancy content was observed with the decreasing LaNiO3 film thickness using XAS. A higher concentration of oxygen vacancies was observed for the ultrathin insulating films (

An Essential Guide to Electronic Material Surfaces and Interfaces

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Publisher : John Wiley & Sons
ISBN 13 : 111902711X
Total Pages : 316 pages
Book Rating : 4.1/5 (19 download)

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Book Synopsis An Essential Guide to Electronic Material Surfaces and Interfaces by : Leonard J. Brillson

Download or read book An Essential Guide to Electronic Material Surfaces and Interfaces written by Leonard J. Brillson and published by John Wiley & Sons. This book was released on 2016-08-01 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: An Essential Guide to Electronic Material Surfaces and Interfaces is a streamlined yet comprehensive introduction that covers the basic physical properties of electronic materials, the experimental techniques used to measure them, and the theoretical methods used to understand, predict, and design them. Starting with the fundamental electronic properties of semiconductors and electrical measurements of semiconductor interfaces, this text introduces students to the importance of characterizing and controlling macroscopic electrical properties by atomic-scale techniques. The chapters that follow present the full range of surface and interface techniques now being used to characterize electronic, optical, chemical, and structural properties of electronic materials, including semiconductors, insulators, nanostructures, and organics. The essential physics and chemistry underlying each technique is described in sufficient depth for students to master the fundamental principles, with numerous examples to illustrate the strengths and limitations for specific applications. As well as references to the most authoritative sources for broader discussions, the text includes internet links to additional examples, mathematical derivations, tables, and literature references for the advanced student, as well as professionals in these fields. This textbook fills a gap in the existing literature for an entry-level course that provides the physical properties, experimental techniques, and theoretical methods essential for students and professionals to understand and participate in solid-state electronics, physics, and materials science research. An Essential Guide to Electronic Material Surfaces and Interfaces is an introductory-to-intermediate level textbook suitable for students of physics, electrical engineering, materials science, and other disciplines. It is essential reading for any student or professional engaged in surface and interface research, semiconductor processing, or electronic device design.

Internal Photoemission Spectroscopy

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Publisher : Elsevier
ISBN 13 : 0080555896
Total Pages : 312 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Internal Photoemission Spectroscopy by : Valeri V. Afanas'ev

Download or read book Internal Photoemission Spectroscopy written by Valeri V. Afanas'ev and published by Elsevier. This book was released on 2010-07-07 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: The monographic book addresses the basics of the charge carrier photoemission from one solid to another - the internal photoemission, (IPE) - and different spectroscopic applications of this phenomenon to solid state heterojunctions. This is the first book in the field of IPE, which complements the conventional external photoemission spectroscopy by analysing interfaces separated from the sample surface by a layer of a different solid or liquid. IPE is providing the most straightforward and, therefore, reliable information regarding the energy spectrum of electron states at interfaces. At the same time, the method provides the unique capability of analysing the heterostructures relevant to the modern micro- and nano-electronic devices as well as new materials involved in their design and fabrication. In addition to the discussion of fundamental physical and technical aspects of IPE spectroscopic applications, several “hot topics are addressed. These include development of new insulating materials for advances Si MOS technology (both high-k gate insulators and low-k dielectrics for interconnect insulation), metal gate materials, development of heterostructures based on high-mobility semiconductors, etc. Thanks to a considerable activity in this field over the last few years, the recent results concerning band structure of most important interfaces involving novel materials can now be documented. - First complete description of the internal photoemission phenomena - A practical guide to internal photoemission measurements - Describes reliable energy barrier determination procedures - Surveys trap spectroscopy methods applicable to thin insulating layers - Provides an overview of the most recent results on band structure of high-permittivity insulating materials and their interfaces - Contains a complete collection of reference data on interface band alignment for wide-bandgap insulating materials in contact with metals and semiconductors

Two-dimensional Electron Systems in Functional Oxides Studied by Photoemission Spectroscopy

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Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (958 download)

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Book Synopsis Two-dimensional Electron Systems in Functional Oxides Studied by Photoemission Spectroscopy by : Tobias Rödel

Download or read book Two-dimensional Electron Systems in Functional Oxides Studied by Photoemission Spectroscopy written by Tobias Rödel and published by . This book was released on 2016 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Many transition metal oxides (TMOs) show complex physics, ranging from ferroelectricity to magnetism, high-Tc superconductivity and colossal magnetoresistance. The existence of a variety of ground states often occurs as different degrees of freedom (e.g. lattice, charge, spin, orbital) interact to form different competing phases which are quite similar in energy. The capability to epitaxially grow heterostructures of TMOs increased the complexity even more as new phenomena can emerge at the interface. One typical example is the two-dimensional electron system (2DES) at the interface of two insulating oxides, namely LaAlO3/SrTiO3, which shows metal-to-insulator transitions, magnetism or gate-tunable superconductivity. The origin of this thesis was the discovery of a similar 2DES at the bare surface of SrTiO3 fractured in vacuum, making it possible to study its electronic structure by angle-resolved photoemission spectroscopy (ARPES).In this thesis, the study of well-prepared surfaces, instead of small fractured facets, results in spectroscopic data showing line widths approaching the intrinsic value. This approach allows a detailed analysis of many-body phenomena like the renormalization of the self-energy due to electron-phonon interaction.Additionally, the understanding of the electronic structure of the 2DES at the surface of SrTiO3(001) was given an additional turn by the surprising discovery of a complex spin texture measured by spin-ARPES. In this thesis data is presented which contradicts these conclusions and discusses possible reasons for the discrepancy.One major motivation of this thesis was the question if and how the electronic structure and the properties of the 2DES can be changed or controlled. In this context, the study of 2DESs at (110) and (111) surface revealed that the electronic band structure of the 2DES (orbital ordering, symmetry of the Fermi surface, effective masses) can be tuned by confining the electrons at different surface orientations of the same material, namely SrTiO3.A major achievement of this thesis is the generalization of the existence of a 2DES in SrTiO3 to many other surfaces and interfaces of TMOs (TiO2 anatase, CaTiO3, BaTiO3) and even simpler oxides already used in modern applications (ZnO). In all these oxides, we identify oxygen vacancies as the origin for the creation of the 2DESs.In anatase and other doped d0 TMOs, both localized and itinerant electrons (2DES) can exist due to oxygen vacancies. Which of the two cases is energetically favorable depends on subtle differences as demonstrated by studying two polymorphs of the same material (anatase and rutile).In CaTiO3, the oxygen octahedron around the Ti ion is slightly tilted. This symmetry breaking results in the mixing of different d-orbitals demonstrating again why and how the electronic structure of the 2DES can be altered.In BaTiO3, the creation of a 2DES results in the coexistence of the two, usually mutual exclusive, phenomena of ferroelectricity and metallicity in the same material by spatially separating the two.Moreover, this work demonstrates that the 2DES also exists in ZnO which is - compared to the Ti-based oxides - rather a conventional semiconductor as the orbital character of the itinerant electrons is of s and not d-type.The main result of this thesis is the demonstration of a simple and versatile technique for the creation of 2DESs by evaporating Al on oxide surfaces. A redox reaction between metal and oxide results in a 2DES at the interface of the oxidized metal and the reduced oxide. In this thesis the study of such interfacial 2DESs was limited to photoemission studies in ultra high vacuum. However, this technique opens up the possibility to study 2DESs in functional oxides in ambient conditions by e.g. transport techniques, and might be an important step towards cost-efficient mass production of 2DESs in oxides for future applications.

Metal Oxide Nanoparticles, 2 Volume Set

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Publisher : John Wiley & Sons
ISBN 13 : 1119436745
Total Pages : 903 pages
Book Rating : 4.1/5 (194 download)

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Book Synopsis Metal Oxide Nanoparticles, 2 Volume Set by : Oliver Diwald

Download or read book Metal Oxide Nanoparticles, 2 Volume Set written by Oliver Diwald and published by John Wiley & Sons. This book was released on 2021-09-14 with total page 903 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxide Nanoparticles A complete nanoparticle resource for chemists and industry professionals Metal oxide nanoparticles are integral to a wide range of natural and technological processes—from mineral transformation to electronics. Additionally, the fields of engineering, electronics, energy technology, and electronics all utilize metal oxide nanoparticle powders. Metal Oxide Nanoparticles: Formation, Functional Properties, and Interfaces presents readers with the most relevant synthesis and formulation approaches for using metal oxide nanoparticles as functional materials. It covers common processing routes and the assessment of physical and chemical particle properties through comprehensive and complementary characterization methods. This book will serve as an introduction to nanoparticle formulation, their interface chemistry and functional properties at the nanoscale. It will also act as an in-depth resource, sharing detailed information on advanced approaches to the physical, chemical, surface, and interface characterization of metal oxide nanoparticle powders and dispersions. Addresses the application of metal oxide nanoparticles and its economic impact Examines particle synthesis, including the principles of selected bottom-up strategies Explores nanoparticle formulation—a selection of processing and application routes Discusses the significance of particle surfaces and interfaces on structure formation, stability and functional materials properties Covers metal oxide nanoparticle characterization at different length scales With this valuable resource, academic researchers, industrial chemists, and PhD students can all gain insight into the synthesis, properties, and applications of metal oxide nanoparticles.

Electronic and Spin Reconstruction at Complex Oxide Interfaces

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Publisher :
ISBN 13 :
Total Pages : 138 pages
Book Rating : 4.:/5 (914 download)

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Book Synopsis Electronic and Spin Reconstruction at Complex Oxide Interfaces by :

Download or read book Electronic and Spin Reconstruction at Complex Oxide Interfaces written by and published by . This book was released on 2011 with total page 138 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Epitaxial Growth of Complex Metal Oxides

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Publisher : Woodhead Publishing
ISBN 13 : 0081029462
Total Pages : 534 pages
Book Rating : 4.0/5 (81 download)

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Book Synopsis Epitaxial Growth of Complex Metal Oxides by : Gertjan Koster

Download or read book Epitaxial Growth of Complex Metal Oxides written by Gertjan Koster and published by Woodhead Publishing. This book was released on 2022-04-22 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt: Epitaxial Growth of Complex Metal Oxides, Second Edition reviews techniques and recent developments in the fabrication quality of complex metal oxides, which are facilitating advances in electronic, magnetic and optical applications. Sections review the key techniques involved in the epitaxial growth of complex metal oxides and explore the effects of strain and stoichiometry on crystal structure and related properties in thin film oxides. Finally, the book concludes by discussing selected examples of important applications of complex metal oxide thin films, including optoelectronics, batteries, spintronics and neuromorphic applications. This new edition has been fully updated, with brand new chapters on topics such as atomic layer deposition, interfaces, STEM-EELs, and the epitaxial growth of multiferroics, ferroelectrics and nanocomposites. Examines the techniques used in epitaxial thin film growth for complex oxides, including atomic layer deposition, sputtering techniques, molecular beam epitaxy, and chemical solution deposition techniques Reviews materials design strategies and materials property analysis methods, including the impacts of defects, strain, interfaces and stoichiometry Describes key applications of epitaxially grown metal oxides, including optoelectronics, batteries, spintronics and neuromorphic applications

Nanomagnetic Materials

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Publisher : Elsevier
ISBN 13 : 0128223545
Total Pages : 814 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Nanomagnetic Materials by : Akinobu Yamaguchi

Download or read book Nanomagnetic Materials written by Akinobu Yamaguchi and published by Elsevier. This book was released on 2021-06-28 with total page 814 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanomagnetic Materials: Fabrication, Characterization and Application explores recent studies of conventional nanomagnetic materials in spintronics, data storage, magnetic sensors and biomedical applications. In addition, the book also reviews novel magnetic characteristics induced in two-dimensional materials, diamonds, and those induced by the artificial formation of lattice defect and heterojunction as novel nanomagnetic materials. Nanomagnetic materials are usually based on d- and f-electron systems. They are an important solution to the demand for higher density of information storage, arising from the emergence of novel technologies required for non-volatile memory systems. Advances in the understanding of magnetization dynamics and in the characteristics of nanoparticles or surface of nanomagnetic materials is resulting in greater expansion of applications of nanomagnetic materials, including in biotechnology, sensor devices, energy harvesting, and power generating systems. This book provides a cogent overview of the latest research on novel nanomagnetic materials, including spintronic nanomagnets, molecular nanomagnets, self-assembling magnetic nanomaterials, nanoparticles, multifunctional materials, and heterojunction-induced novel magnetism. Explains manufacturing principles and process for nanomagnetic materials Discusses physical and chemical properties and potential industrial applications, such as magnetic data storage, sensors, oscillator, permanent magnets, power generations, and biomedical applications Assesses the major challenges of using magnetic nanomaterials on a broad scale

Photoelectron Spectroscopy

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Publisher : Springer Science & Business Media
ISBN 13 : 3662031507
Total Pages : 525 pages
Book Rating : 4.6/5 (62 download)

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Book Synopsis Photoelectron Spectroscopy by : Stefan Hüfner

Download or read book Photoelectron Spectroscopy written by Stefan Hüfner and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 525 pages. Available in PDF, EPUB and Kindle. Book excerpt: An up-to-date introduction to the field, treating in depth the electronic structures of atoms, molecules, solids and surfaces, together with brief descriptions of inverse photoemission, spin-polarized photoemission and photoelectron diffraction. Experimental aspects are considered throughout and the results carefully interpreted by theory. A wealth of measured data is presented in tabullar for easy use by experimentalists.

Photon-assisted Spectroscopy of Electronic Interface States in Perovskite Oxide Heterostructures

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (652 download)

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Book Synopsis Photon-assisted Spectroscopy of Electronic Interface States in Perovskite Oxide Heterostructures by :

Download or read book Photon-assisted Spectroscopy of Electronic Interface States in Perovskite Oxide Heterostructures written by and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Complex oxides are an intriguing field of solid-state research, as they can exhibit a wide variety of functional properties, such as ferroelasticity, ferroelectricity, ferro- and antiferromagnetism or an even more complicated type of magnetic ordering, the combination or interaction of those ferroic properties (multiferroicity), high spin polarization, or high-temperature superconductivity. Thus they are prospective candidates for future materials in microelectronics. It is a matter of fact that the performance of such oxide-based devices depends mainly on transport properties, which in turn depend on the distribution and density of intrinsic or extrinsic electronic interface states across the device structure. The present thesis focuses on the identification and characterization of such electronic properties by two different photoassisted spectroscopy techniques: surface photovoltage spectroscopy and photoelectron spectroscopy. This work especially deals with perovskite oxides, namely with the model perovskite strontium titanate (SrTiO3) as a substrate and three differently doped lanthanum manganite thin films (10-15 nm thickness) grown by pulsed laser deposition (PLD) on the SrTiO3 substrate(La0.7Sr0.3MnO3, La0.7Ca0.3MnO3, La0.7Ce0.3MnO3). The first part aims at the identification of electronic surface and interface states at the free SrTiO3 surface as well as at the three different lanthanum manganite/SrTiO3 interfaces. For that purpose three different experimental realizations of the surface photovoltage spectroscopy technique were implemented and employed: photoelectron spectroscopy under additional optical excitation, the capacitive detection of the photoinduced displacement current in a parallel-plate capacitor geometry under modulated optical excitation, and the classical Kelvin probe technique. The methods are evaluated comparatively with respect to their suitability to analyze the given oxidic interfaces. The main result of this first part is a map of the.

Phononic and Electronic Excitations in Complex Oxides Studied with Advanced Infrared and Raman Spectroscopy Techniques

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Publisher :
ISBN 13 : 9783031118678
Total Pages : 0 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis Phononic and Electronic Excitations in Complex Oxides Studied with Advanced Infrared and Raman Spectroscopy Techniques by : Fryderyk Lyzwa

Download or read book Phononic and Electronic Excitations in Complex Oxides Studied with Advanced Infrared and Raman Spectroscopy Techniques written by Fryderyk Lyzwa and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This PhD thesis reports on investigations of several oxide-based materials using advanced infrared and Raman spectroscopy techniques and in combination with external stimuli such as high magnetic or electric field, sptial confinement in thin film heterostructures and the radiation with UV light. This leads to new results in the fields of superconductivity, electronic polarization states and nanoscale phenomena. Among these, the observation of anomalous polar moments is of great relevance for understanding the electric-field-induced metal-to-insulator transistion; and the demonstration that confocal Raman spectroscopy of backfolded acoustic photons in metal-oxide multilayers can be used as a powerful characterization tool for monitoring their interface properties and layer thickness is an important technical development for the engineering of such functional oxide heterostructures.

Fundamentals of Sum-Frequency Spectroscopy

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Publisher : Cambridge University Press
ISBN 13 : 131647304X
Total Pages : 570 pages
Book Rating : 4.3/5 (164 download)

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Book Synopsis Fundamentals of Sum-Frequency Spectroscopy by : Y. R. Shen

Download or read book Fundamentals of Sum-Frequency Spectroscopy written by Y. R. Shen and published by Cambridge University Press. This book was released on 2016-02-18 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first book on the topic, and written by the founder of the technique, this comprehensive resource provides a detailed overview of sum-frequency spectroscopy, its fundamental principles, and the wide range of applications for surfaces, interfaces, and bulk. Beginning with an overview of the historical context, and introductions to the basic theory of nonlinear optics and surface sum-frequency generation, topics covered include discussion of different experimental arrangements adopted by researchers, notes on proper data analysis, an up-to-date survey commenting on the wide range of successful applications of the tool, and a valuable insight into current unsolved problems and potential areas to be explored in the future. With the addition of chapter appendices that offer the opportunity for more in-depth theoretical discussion, this is an essential resource that integrates all aspects of the subject and is ideal for anyone using, or interested in using, sum-frequency spectroscopy.

Controlling the Interaction in Complex Oxide Interfaces

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (897 download)

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Book Synopsis Controlling the Interaction in Complex Oxide Interfaces by : Ying - Hao Chu

Download or read book Controlling the Interaction in Complex Oxide Interfaces written by Ying - Hao Chu and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Encyclopedia of Interfacial Chemistry

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Publisher : Elsevier
ISBN 13 : 0128098945
Total Pages : 5276 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Encyclopedia of Interfacial Chemistry by :

Download or read book Encyclopedia of Interfacial Chemistry written by and published by Elsevier. This book was released on 2018-03-29 with total page 5276 pages. Available in PDF, EPUB and Kindle. Book excerpt: Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry, Seven Volume Set summarizes current, fundamental knowledge of interfacial chemistry, bringing readers the latest developments in the field. As the chemical and physical properties and processes at solid and liquid interfaces are the scientific basis of so many technologies which enhance our lives and create new opportunities, its important to highlight how these technologies enable the design and optimization of functional materials for heterogeneous and electro-catalysts in food production, pollution control, energy conversion and storage, medical applications requiring biocompatibility, drug delivery, and more. This book provides an interdisciplinary view that lies at the intersection of these fields. Presents fundamental knowledge of interfacial chemistry, surface science and electrochemistry and provides cutting-edge research from academics and practitioners across various fields and global regions

The Study of Energy Levels and Reactions at Oxide-oxide Heterojunction Interfaces with Photoelectron Spectroscopy

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Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (133 download)

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Book Synopsis The Study of Energy Levels and Reactions at Oxide-oxide Heterojunction Interfaces with Photoelectron Spectroscopy by : Hao Ting Kung

Download or read book The Study of Energy Levels and Reactions at Oxide-oxide Heterojunction Interfaces with Photoelectron Spectroscopy written by Hao Ting Kung and published by . This book was released on 2020 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxide-oxide heterojunction interfaces (OHIs) play a crucial role in the development of next generation thin-film devices due to their high tunability. The formation of OHIs is complex as it can involve events such as charge transfer, interfacial diffusion, and chemical reactions. These events contribute to the electronic band structure at an OHI and its ability to perform an intended application. In this work, multiple transition-metal-oxide/oxide OHIs were formed and systematically studied with in-situ photoelectron spectroscopy. The chemical compositions and electronic band structures at the OHIs were found deviating from those of the bulk materials and the driving forces behind the observed phenomenon are discussed. Evidence of charge transfer such as band bending and interface dipoles were also observed at the OHIs and the results were found to be deviating from the existing energy level alignment rules. The findings of this thesis should be taken into consideration when designing OHIs.