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Spatially Resolved Immobilization Of Metallopolymers
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Book Synopsis Spatially resolved immobilization of metallopolymers by : Rouven Müller
Download or read book Spatially resolved immobilization of metallopolymers written by Rouven Müller and published by Cuvillier Verlag. This book was released on 2019-09-25 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the course of the present thesis, the first method for the spatially resolved surface immobilization of various metallopolymers on a single surface was developed, employing the versatile NITEC photochemistry. The in-depth analysis of the photoligation process identified crucial parameters for the successful immobilization of the metallopolymers, which are also valid for all other photo triggered surface ligation protocols. ToF-SIMS and spatially resolved XPS analysis of the prepared surfaces demonstrated the preserved chemical composition of the fabricated metallopolymer surfaces. In the second part of the thesis, the photochemistry of spiro(thio)pyrans was investigated for the formation of light-sensitive spiropyran-metal complexes, as well as the creation of a photoresist for the application in STED-inspired lithography. The irradiation of an NMR tube inside the NMR spectrometer in so-called LED-NMR experiments was introduced for the investigation of the prepared spiropyran-metal complexes. Finally, the photo triggered reaction of the spirothiopyran photoswitch with an electron deficient maleimide was used for the spatial encoding of surfaces for the first time. In addition, the preparation of a spirothiopyran-based photoresist enabled the writing of structures below the diffraction limit, with the thinnest lines written with STED-inspired lithography to date.
Book Synopsis Comprehensive Materials Processing by :
Download or read book Comprehensive Materials Processing written by and published by Newnes. This book was released on 2014-04-07 with total page 5485 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Materials Processing, Thirteen Volume Set provides students and professionals with a one-stop resource consolidating and enhancing the literature of the materials processing and manufacturing universe. It provides authoritative analysis of all processes, technologies, and techniques for converting industrial materials from a raw state into finished parts or products. Assisting scientists and engineers in the selection, design, and use of materials, whether in the lab or in industry, it matches the adaptive complexity of emergent materials and processing technologies. Extensive traditional article-level academic discussion of core theories and applications is supplemented by applied case studies and advanced multimedia features. Coverage encompasses the general categories of solidification, powder, deposition, and deformation processing, and includes discussion on plant and tool design, analysis and characterization of processing techniques, high-temperatures studies, and the influence of process scale on component characteristics and behavior. Authored and reviewed by world-class academic and industrial specialists in each subject field Practical tools such as integrated case studies, user-defined process schemata, and multimedia modeling and functionality Maximizes research efficiency by collating the most important and established information in one place with integrated applets linking to relevant outside sources
Book Synopsis Organometallic Chemistry and Catalysis by : Didier Astruc
Download or read book Organometallic Chemistry and Catalysis written by Didier Astruc and published by Springer Science & Business Media. This book was released on 2007-08-02 with total page 598 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title.
Book Synopsis Ruthenium-Containing Polymers by : Ulrich S. Schubert
Download or read book Ruthenium-Containing Polymers written by Ulrich S. Schubert and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the synthetic methodologies as well as the properties and potential usage of various ruthenium-containing materials. Starting from the first examples of 'ruthenopolymers' reported in the 1970s to the 3D architectures now synthesized, these materials have shown their importance far beyond fundamental polymer science. As well as highlighting the remarkable properties and versatile applications, this book also addresses a key question related to the applications of such heavy-metal-containing materials from the perspective of achieving a sustainable future. This book is of interest to both materials scientists and chemists in academia and industry.
Book Synopsis Metallo-Supramolecular Polymers by : Masayoshi Higuchi
Download or read book Metallo-Supramolecular Polymers written by Masayoshi Higuchi and published by . This book was released on 2019 with total page 92 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II). The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.
Book Synopsis Metallopolymer Nanocomposites by : A.D. Pomogailo
Download or read book Metallopolymer Nanocomposites written by A.D. Pomogailo and published by Springer Science & Business Media. This book was released on 2006-01-27 with total page 577 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents and analyzes the essential data on nanoscale metal clusters dispersed in, or chemically bonded with polymers. Special attention is paid to the in situ synthesis of the nanocomposites, their chemical interactions, and the size and distribution of the particles in the polymer matrix. Numerous novel nanocomposites are described with regard to their mechanical, electrophysical, optical, magnetic, catalytic and biological properties. Their applications, present and future, are outlined.
Book Synopsis Electropolymerization by : Serge Cosnier
Download or read book Electropolymerization written by Serge Cosnier and published by John Wiley & Sons. This book was released on 2011-08-04 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing extensive coverage, including conducting, insulating and electroactive films, this handbook and ready reference deals with introductory topics and fundamentals as well as advanced insights. Clearly structured, in the first part of the book readers learn the fundamentals of electropolymerizatoin for all important types of polymers, mechanisms of film formation and functionalization, while the second part covers a wide range of applications in biochemistry, analytics, photovoltaics, energy and the environment as well as actuators.
Book Synopsis Self-Healing Polymers by : Wolfgang H. Binder
Download or read book Self-Healing Polymers written by Wolfgang H. Binder and published by John Wiley & Sons. This book was released on 2013-03-29 with total page 638 pages. Available in PDF, EPUB and Kindle. Book excerpt: Self-healing is a well-known phenomenon in nature: a broken bone merges after some time and if skin is damaged, the wound will stop bleeding and heals again. This concept can be mimicked in order to create polymeric materials with the ability to regenerate after they have suffered degradation or wear. Already realized applications are used in aerospace engineering, and current research in this fascinating field shows how different self-healing mechanisms proven successful by nature can be adapted to produce even more versatile materials. The book combines the knowledge of an international panel of experts in the field and provides the reader with chemical and physical concepts for self-healing polymers, including aspects of biomimetic processes of healing in nature. It shows how to design self-healing polymers and explains the dynamics in these systems. Different self-healing concepts such as encapsulated systems and supramolecular systems are detailed. Chapters on analysis and friction detection in self-healing polymers and on applications round off the book.
Book Synopsis Active Protective Coatings by : Anthony E. Hughes
Download or read book Active Protective Coatings written by Anthony E. Hughes and published by Springer. This book was released on 2016-03-01 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers a broad range of materials science that has been brought to bear on providing solutions to the challenges of developing self-healing and protective coatings for a range of metals. The book has a strong emphasis on characterisation techniques, particularly new techniques that are beginning to be used in the coatings area. It features many contributions written by experts from various industrial sectors which examine the needs of the sectors and the state of the art. The development of self-healing and protective coatings has been an expanding field in recent years and applies a lot of new knowledge gained from other fields as well as other areas of materials science to the development of coatings. It has borrowed from fields such as the food and pharmaceutical industries who have used, polymer techniques, sol-gel science and colloidosome technology for a range encapsulation techniques. It has also borrowed from fields like hydrogen storage such as from the development of hierarchical and other materials based on organic templating as “nanocontainers” for the delivery of inhibitors. In materials science, recent developments in high throughput and other characterisation techniques, such as those available from synchrotrons, are being increasing used for novel characterisation – one only needs to look at the application of these techniques in self healing polymers to gauge wealth of new information that has been gained from these techniques. This work is largely driven by the need to replace environmental pollutants and hazardous chemicals that represent risk to humans such as chromate inhibitors which are still used in some applications.
Book Synopsis Immobilized Biocatalysts by : Peter Grunwald
Download or read book Immobilized Biocatalysts written by Peter Grunwald and published by MDPI. This book was released on 2018-11-14 with total page 511 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a printed edition of the Special Issue "Immobilized Biocatalysts" that was published in Catalysts
Book Synopsis Single-Chain Polymer Nanoparticles by : José A. Pomposo
Download or read book Single-Chain Polymer Nanoparticles written by José A. Pomposo and published by John Wiley & Sons. This book was released on 2017-08-18 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first book on this important and emerging topic presents an overview of the very latest results obtained in single-chain polymer nanoparticles obtained by folding synthetic single polymer chains, painting a complete picture from synthesis via characterization to everyday applications. The initial chapters describe the synthetics methods as well as the molecular simulation of these nanoparticles, while subsequent chapters discuss the analytical techniques that are applied to characterize them, including size and structural characterization as well as scattering techniques. The final chapters are then devoted to the practical applications in nanomedicine, sensing, catalysis and several other uses, concluding with a look at the future for such nanoparticles. Essential reading for polymer and materials scientists, materials engineers, biochemists as well as environmental chemists.
Download or read book Click Polymerization written by Anjun Qin and published by Royal Society of Chemistry. This book was released on 2018-08-28 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: Click chemistry describes organic reactions which are highly efficient, regioselective and allow for mild reaction conditions. The archetypal click reaction of Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC) is used in many diverse areas and has been extensively developed for polymer synthesis, leading to the term of click polymerization. This technique enables the preparation of functional polymers with linear and topological structures that have the potential to be used in optoelectronics and biological fields. Edited by world renowned experts, Click Polymerization is the first book to comprehensively summarize this approach to polymer synthesis consolidating all the different reaction types in one resource. From the basic knowledge through to the latest developments in synthesis, chapters include transition-metal catalysed and metal-free azide-alkyne click polymerizations as well as thiol-ene, thiol-yne and thiol-epoxy click polymerizations. The book provides an authoritative guide to click polymerization techniques for graduate students and researchers interested in polymer chemistry and materials science.
Author :Anatolii D. Pomogailo Publisher :Springer Science & Business Media ISBN 13 :3642105742 Total Pages :306 pages Book Rating :4.6/5 (421 download)
Book Synopsis Macromolecular Metal Carboxylates and Their Nanocomposites by : Anatolii D. Pomogailo
Download or read book Macromolecular Metal Carboxylates and Their Nanocomposites written by Anatolii D. Pomogailo and published by Springer Science & Business Media. This book was released on 2010-09-02 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: Data on the synthesis and physicochemical studies of salts of mono- or dibasic unsaturated carboxylic acids and macromolecular metal carboxylates are generalised and described systematically in this monograph. The structures and properties of the COO group in various compounds and characteristic features of the structures of carboxylate are analysed. The main routes and kinetics of polymerisation transformations of unsaturated metal carboxylates are considered. The attention is focused on the effect of the metal ion on the monomer reactivity and the polymer morphology and structure. The possibility of stereochemical control of radical polymerisation of unsaturated metal carboxylates is demonstrated. The electronic, magnetic, optical, absorption and thermal properties of metal (co)polymers and nanocomposites and their main applications are also considered.
Book Synopsis Hydrogen Bonded Polymers by : Wolfgang Binder
Download or read book Hydrogen Bonded Polymers written by Wolfgang Binder and published by Springer Science & Business Media. This book was released on 2007-03-16 with total page 215 pages. Available in PDF, EPUB and Kindle. Book excerpt: Control of polymeric structure is among the most important endeavours of modern macromolecular science. In particular, tailoring the positioning and strength of intermolecular forces within macromolecules by synthetic methods and thus gaining structural control over the final polymeric materials has become feasible, resulting in the field of supramolecular polymer science. Besides other intermolecular forces, hydrogen bonds are unique intermolecular forces enabling the tuning of material properties via self-assembly processes over a wide range of interactions strength ranging from several kJmol to several tens of kJmol . Central for the formation of these structures are precursor molecules of small molecular weight (usually lower than 10 000), which can assemble in solid or solution to aggregates of defined geometry.
Book Synopsis Bioelectrochemistry by : Richard C. Alkire
Download or read book Bioelectrochemistry written by Richard C. Alkire and published by John Wiley & Sons. This book was released on 2013-09-25 with total page 411 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioelectrochemistry is a fast growing field at the interface between electrochemistry and other sciences such as biochemistry, analytical chemistry and medicinal chemistry. In the recent years, the methods and the understanding of the fundamentals have seen significant progress, which has led to rapid development in the field. Here, the expert editors have carefully selected contributions to best reflect the latest developments in this hot and rapidly growing interdisciplinary topic. The resulting excellent and timely overview of this multifaceted field covers recent methodological advances, as well as a range of new applications for analytical detection, drug screening, tumor therapy, and for energy conversion in biofuel cells. This book is a must-have for all Electrochemists, Biochemists, Analytical Chemists, and Medicinal Chemists.
Book Synopsis Living and Controlled Polymerization by : Joseph Jagur-Grodzinski
Download or read book Living and Controlled Polymerization written by Joseph Jagur-Grodzinski and published by Nova Publishers. This book was released on 2006 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: The living/controlled polymerisation techniques opened new vistas in polymer chemistry. The leading authorities in this field and its pioneers contributed chapters to this collective volume. The controlled polymerisation techniques have enabled preparation of polymers, copolymers, and block copolymers with predetermined molecular weights and narrow polydispersity, in which functional groups or biologically active molecules could be placed at well defined locations. They have also enabled preparation of advanced polymeric structures with precisely determined architectures and improved properties. Moreover, they have provided opportunities for preparation of novel polymeric materials from monomers, which before have not been suitable or accessible for such purposes. Properties of some of these polymeric materials may be significantly different from those of the existing ones. They provide opportunities for new applications. Several patents have already been approved for such speciality applications as, drug delivery, biocompatible surfaces, thermoplastic elastomers, moisture curable sealants, and so on. Many more products, based on polymers fabricated by the living/ controlled polymerisation techniques, will certainly emerge in such specialised areas as, nanotechnology, medical devices, "smart polymers", sensors , smart separation technologies, optical fibres and other optical applications, various biomaterials, etc.
Book Synopsis Chemistry of Polymeric Metal Chelates by : Gulzhian I. Dzhardimalieva
Download or read book Chemistry of Polymeric Metal Chelates written by Gulzhian I. Dzhardimalieva and published by Springer. This book was released on 2018-02-13 with total page 1020 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with the chemistry of polymeric metal chelates. The main results and the production and chemical structure of polymers with chelate units as well as the specificity of metal complex binding of different structure are presented here. This book also reveals the transformations which components undergo in the course of chelation. Special attention is paid not only to synthetic but also to natural (including living) systems. The usage of polymeric metal chelates and their development are examined. The related research was performed for chelates with chain structure. This book is useful to researchers being active in synthesis and design of macromolecular metal chelates
