Solution Thermodynamics And Its Application To Aqueous Solutions

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Solution Thermodynamics and its Application to Aqueous Solutions

Author : Yoshikata Koga
Publisher : Elsevier
ISBN 13 : 0080551874
Total Pages : 311 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Solution Thermodynamics and its Application to Aqueous Solutions by : Yoshikata Koga

Download or read book Solution Thermodynamics and its Application to Aqueous Solutions written by Yoshikata Koga and published by Elsevier. This book was released on 2007-11-12 with total page 311 pages. Available in PDF, EPUB and Kindle. Book excerpt: As the title suggests, we introduce a novel differential approach to solution thermodynamics and use it for the study of aqueous solutions. We evaluate the quantities of higher order derivative than the normal thermodynamic functions. We allow these higher derivative data speak for themselves without resorting to any model system. We thus elucidate the molecular processes in solution, (referred to in this book "mixing scheme), to the depth equal to, if not deeper, than that gained by spectroscopic and other methods. We show that there are three composition regions in aqueous solutions of non-electrolytes, each of which has a qualitatively distinct mixing scheme. The boundary between the adjacent regions is associated with an anomaly in the third derivatives of G. The loci of the anomalies in the temperature-composition field form the line sometimes referred as "Koga line. We then take advantage of the anomaly of a third derivative quantity of 1-propanol in the ternary aqueous solution, 1-propanol – sample species – H2O. We use its induced change as a probe of the effect of a sample species on H2O. In this way, we clarified what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. We also apply the same methodology to ions that have been ranked by the Hofmeister series. We show that the kosmotropes (salting out, or stabilizing agents) are either hydrophobes or hydration centres, and that chaotropes (salting in, or destablizing agents) are hydrophiles. - A new differential approach to solution thermodynamics - A particularly clear elucidation of the mixing schemes in aqueous solutions - A clear understandings on the effects of hydrophobes, hydrophiles, and amphiphiles to H2O - A clear understandings on the effects of ions on H2O in relation to the Hofmeister effect - A new differential approach to studies in muti-component aqueous solutions

Solution Thermodynamics and Its Application to Aqueous Solutions

Author : Yoshikata Koga
Publisher : Elsevier
ISBN 13 : 0444636307
Total Pages : 448 pages
Book Rating : 4.4/5 (446 download)

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Book Synopsis Solution Thermodynamics and Its Application to Aqueous Solutions by : Yoshikata Koga

Download or read book Solution Thermodynamics and Its Application to Aqueous Solutions written by Yoshikata Koga and published by Elsevier. This book was released on 2017-03-28 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solution Thermodynamics and its Application to Aqueous Solutions: A Differential Approach, Second Edition introduces a differential approach to solution thermodynamics, applying it to the study of aqueous solutions. This valuable approach reveals the molecular processes in solutions in greater depth than that gained by spectroscopic and other methods. The book clarifies what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. By applying the same methodology to ions that have been ranked by the Hofmeister series, the author shows that the kosmotropes are either hydrophobes or hydration centers, and that chaotropes are hydrophiles. This unique approach and important updates make the new edition a must-have reference for those active in solution chemistry. - Unique differential approach to solution thermodynamics allows for experimental evaluation of the intermolecular interaction - Incorporates research findings from over 40 articles published since the previous edition - Numerical or graphical evaluation and direct experimental determination of third derivatives, enthalpic and volumetric AL-AL interactions and amphiphiles are new to this edition - Features new chapters on spectroscopic study in aqueous solutions as well as environmentally friendly and hostile water aqueous solutions

Handbook of Aqueous Electrolyte Thermodynamics

Author : Joseph F. Zemaitis, Jr.
Publisher : John Wiley & Sons
ISBN 13 : 0470938404
Total Pages : 876 pages
Book Rating : 4.4/5 (79 download)

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Book Synopsis Handbook of Aqueous Electrolyte Thermodynamics by : Joseph F. Zemaitis, Jr.

Download or read book Handbook of Aqueous Electrolyte Thermodynamics written by Joseph F. Zemaitis, Jr. and published by John Wiley & Sons. This book was released on 2010-09-16 with total page 876 pages. Available in PDF, EPUB and Kindle. Book excerpt: Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable "do-it-yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful research and application tool for the practicing process engineer, and as a textbook for the chemical engineering student.

Phase Diagrams and Thermodynamic Modeling of Solutions

Author : Arthur D. Pelton
Publisher : Academic Press
ISBN 13 : 0128016698
Total Pages : 404 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Phase Diagrams and Thermodynamic Modeling of Solutions by : Arthur D. Pelton

Download or read book Phase Diagrams and Thermodynamic Modeling of Solutions written by Arthur D. Pelton and published by Academic Press. This book was released on 2018-09-19 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phase Diagrams and Thermodynamic Modeling of Solutions provides readers with an understanding of thermodynamics and phase equilibria that is required to make full and efficient use of these tools. The book systematically discusses phase diagrams of all types, the thermodynamics behind them, their calculations from thermodynamic databases, and the structural models of solutions used in the development of these databases. Featuring examples from a wide range of systems including metals, salts, ceramics, refractories, and concentrated aqueous solutions, Phase Diagrams and Thermodynamic Modeling of Solutions is a vital resource for researchers and developers in materials science, metallurgy, combustion and energy, corrosion engineering, environmental engineering, geology, glass technology, nuclear engineering, and other fields of inorganic chemical and materials science and engineering. Additionally, experts involved in developing thermodynamic databases will find a comprehensive reference text of current solution models. - Presents a rigorous and complete development of thermodynamics for readers who already have a basic understanding of chemical thermodynamics - Provides an in-depth understanding of phase equilibria - Includes information that can be used as a text for graduate courses on thermodynamics and phase diagrams, or on solution modeling - Covers several types of phase diagrams (paraequilibrium, solidus projections, first-melting projections, Scheil diagrams, enthalpy diagrams), and more

Molecular Thermodynamics Of Electrolyte Solutions (Second Edition)

Author : Lloyd L Lee
Publisher : World Scientific
ISBN 13 : 9811233012
Total Pages : 295 pages
Book Rating : 4.8/5 (112 download)

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Book Synopsis Molecular Thermodynamics Of Electrolyte Solutions (Second Edition) by : Lloyd L Lee

Download or read book Molecular Thermodynamics Of Electrolyte Solutions (Second Edition) written by Lloyd L Lee and published by World Scientific. This book was released on 2021-01-07 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrolytes and salt solutions are ubiquitous in chemical industry, biology and nature. This unique compendium introduces the elements of the solution properties of ionic mixtures. In addition, it also serves as a bridge to the modern researches into the molecular aspects of uniform and non-uniform charged systems. Notable subjects include the Debye-Hückel limit, Pitzer's formulation, Setchenov salting-out, and McMillan-Mayer scale. Two new chapters on industrial applications — natural gas treating, and absorption refrigeration, are added to make the book current and relevant.This textbook is eminently suitable for undergraduate and graduate students. For practicing engineers without a background in salt solutions, this introductory volume can also be used as a self-study.

Aqueous Systems at Elevated Temperatures and Pressures

Author : Roberto Fernandez-Prini
Publisher : Elsevier
ISBN 13 : 0080471994
Total Pages : 767 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Aqueous Systems at Elevated Temperatures and Pressures by : Roberto Fernandez-Prini

Download or read book Aqueous Systems at Elevated Temperatures and Pressures written by Roberto Fernandez-Prini and published by Elsevier. This book was released on 2004-07-06 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: The International Association for the Properties of Water and Steam (IAPWS) has produced this book in order to provide an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures. These systems are central to many areas of scientific study and industrial application, including electric power generation, industrial steam systems, hydrothermal processing of materials, geochemistry, and environmental applications. The authors' goal is to present the material at a level that serves both the graduate student seeking to learn the state of the art, and also the industrial engineer or chemist seeking to develop additional expertise or to find the data needed to solve a specific problem. The wide range of people for whom this topic is important provides a challenge. Advanced work in this area is distributed among physical chemists, chemical engineers, geochemists, and other specialists, who may not be aware of parallel work by those outside their own specialty. The particular aspects of high-temperature aqueous physical chemistry of interest to one industry may be irrelevant to another; yet another industry might need the same basic information but in a very different form. To serve all these constituencies, the book includes several chapters that cover the foundational thermophysical properties (such as gas solubility, phase behavior, thermodynamic properties of solutes, and transport properties) that are of interest across numerous applications. The presentation of these topics is intended to be accessible to readers from a variety of backgrounds. Other chapters address fundamental areas of more specialized interest, such as critical phenomena and molecular-level solution structure. Several chapters are more application-oriented, addressing areas such as power-cycle chemistry and hydrothermal synthesis. As befits the variety of interests addressed, some chapters provide more theoretical guidance while others, such as those on acid/base equilibria and the solubilities of metal oxides and hydroxides, emphasize experimental techniques and data analysis.- Covers both the theory and applications of all Hydrothermal solutions - Provides an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures- The presentation of the book is understandable to readers from a variety of backgrounds

Molecular Theory Of Water And Aqueous Solutions - Part 1: Understanding Water

Author : Arieh Ben-naim
Publisher : World Scientific
ISBN 13 : 9814469033
Total Pages : 660 pages
Book Rating : 4.8/5 (144 download)

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Book Synopsis Molecular Theory Of Water And Aqueous Solutions - Part 1: Understanding Water by : Arieh Ben-naim

Download or read book Molecular Theory Of Water And Aqueous Solutions - Part 1: Understanding Water written by Arieh Ben-naim and published by World Scientific. This book was released on 2009-07-17 with total page 660 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this book is to explain the unusual properties of both pure liquid water and simple aqueous solutions, in terms of the properties of single molecules and interactions among small numbers of water molecules. It is mostly the result of the author's own research spanning over 40 years in the field of aqueous solutions. An understanding of the properties of liquid water is a prelude to the understanding of the role of water in biological systems and for the evolvement of life.The book is targeted at anyone who is interested in the outstanding properties of water and its role in biological systems. It is addressed to both students and researchers in chemistry, physics and biology.

Engineering and Chemical Thermodynamics

Author : Milo D. Koretsky
Publisher : John Wiley & Sons
ISBN 13 : 0470259612
Total Pages : 724 pages
Book Rating : 4.4/5 (72 download)

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Book Synopsis Engineering and Chemical Thermodynamics by : Milo D. Koretsky

Download or read book Engineering and Chemical Thermodynamics written by Milo D. Koretsky and published by John Wiley & Sons. This book was released on 2012-12-17 with total page 724 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical engineers face the challenge of learning the difficult concept and application of entropy and the 2nd Law of Thermodynamics. By following a visual approach and offering qualitative discussions of the role of molecular interactions, Koretsky helps them understand and visualize thermodynamics. Highlighted examples show how the material is applied in the real world. Expanded coverage includes biological content and examples, the Equation of State approach for both liquid and vapor phases in VLE, and the practical side of the 2nd Law. Engineers will then be able to use this resource as the basis for more advanced concepts.

Metal Complexes in Aqueous Solutions

Author : Arthur E. Martell
Publisher : Springer Science & Business Media
ISBN 13 : 1489914862
Total Pages : 259 pages
Book Rating : 4.4/5 (899 download)

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Book Synopsis Metal Complexes in Aqueous Solutions by : Arthur E. Martell

Download or read book Metal Complexes in Aqueous Solutions written by Arthur E. Martell and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 259 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stability constants are fundamental to understanding the behavior of metal ions in aqueous solution. Such understanding is important in a wide variety of areas, such as metal ions in biology, biomedical applications, metal ions in the environment, extraction metallurgy, food chemistry, and metal ions in many industrial processes. In spite of this importance, it appears that many inorganic chemists have lost an appreciation for the importance of stability constants, and the thermodynamic aspects of complex formation, with attention focused over the last thirty years on newer areas, such as organometallic chemistry. This book is an attempt to show the richness of chemistry that can be revealed by stability constants, when measured as part of an overall strategy aimed at understanding the complexing properties of a particular ligand or metal ion. Thus, for example, there are numerous crystal structures of the Li+ ion with crown ethers. What do these indicate to us about the chemistry of Li+ with crown ethers? In fact, most of these crystal structures are in a sense misleading, in that the Li+ ion forms no complexes, or at best very weak complexes, with familiar crown ethers such as l2-crown-4, in any known solvent. Thus, without the stability constants, our understanding of the chemistry of a metal ion with any particular ligand must be regarded as incomplete. In this book we attempt to show how stability constants can reveal factors in ligand design which could not readily be deduced from any other physical technique.

Fundamentals of Chemical Engineering Thermodynamics

Author : Themis Matsoukas
Publisher : Pearson Education
ISBN 13 : 0132693062
Total Pages : 719 pages
Book Rating : 4.1/5 (326 download)

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Book Synopsis Fundamentals of Chemical Engineering Thermodynamics by : Themis Matsoukas

Download or read book Fundamentals of Chemical Engineering Thermodynamics written by Themis Matsoukas and published by Pearson Education. This book was released on 2013 with total page 719 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fundamentals of Chemical Engineering Thermodynamics is the clearest and most well-organized introduction to thermodynamics theory and calculations for all chemical engineering undergraduates. This brand-new text makes thermodynamics far easier to teach and learn. Drawing on his award-winning courses at Penn State, Dr. Themis Matsoukas organizes the text for more effective learning, focuses on "why" as well as "how," offers imagery that helps students conceptualize the equations, and illuminates thermodynamics with relevant examples from within and beyond the chemical engineering discipline. Matsoukas presents solved problems in every chapter, ranging from basic calculations to realistic safety and environmental applications.

Inorganic Chemistry in Aqueous Solution

Author : Jack Barrett
Publisher : Royal Society of Chemistry
ISBN 13 : 9780854044719
Total Pages : 196 pages
Book Rating : 4.0/5 (447 download)

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Book Synopsis Inorganic Chemistry in Aqueous Solution by : Jack Barrett

Download or read book Inorganic Chemistry in Aqueous Solution written by Jack Barrett and published by Royal Society of Chemistry. This book was released on 2003 with total page 196 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inorganic Chemistry in Aqueous Solution reviews the chemistry of the elements in all their oxidation states in an aqueous environment. The nature of ions in solution is described in some detail and enthalpies and entropies of hydration of many ions are defined and recalculated from the best data available. These values are used to provide an understanding of the periodicities of standard reduction potentials. Standard reduction potential data for all of the elements, group-by-group, covering the s and p, d and f blocks of the Periodic Table is also included. Major sections are devoted to the acid/base behaviour and the solubilities of inorganic compounds in water. Inorganic Chemistry in Aqueous Solution is aimed at undergraduate chemistry students but will also be welcomed by geologists interested in this field. Ideal for the needs of undergraduate chemistry students, Tutorial Chemistry Texts is a major series consisting of short, single topic or modular texts concentrating on the fundamental areas of chemistry taught in undergraduate science courses. Each book provides a concise account of the basic principles underlying a given subject, embodying an independent-learning philosophy and including worked examples.

An Introduction to Aqueous Electrolyte Solutions

Author : Margaret Robson Wright
Publisher : John Wiley & Sons
ISBN 13 : 0470842938
Total Pages : 603 pages
Book Rating : 4.4/5 (78 download)

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Book Synopsis An Introduction to Aqueous Electrolyte Solutions by : Margaret Robson Wright

Download or read book An Introduction to Aqueous Electrolyte Solutions written by Margaret Robson Wright and published by John Wiley & Sons. This book was released on 2007-06-05 with total page 603 pages. Available in PDF, EPUB and Kindle. Book excerpt: An Introduction to Aqueous Electrolyte Solutions is a comprehensive coverage of the subject including the development of key concepts and theory that focus on the physical rather than the mathematical aspects. Important links are made between the study of electrolyte solutions and other branches of chemistry, biology, and biochemistry, making it a useful cross-reference tool for students studying this important area of electrochemistry. Carefully developed throughout, each chapter includes intended learning outcomes and worked problems and examples to encourage student understanding of this multidisciplinary subject. * a comprehensive introduction to aqueous electrolyte solutions including the development of key concepts and theories * emphasises the connection between observable macroscopic experimental properties and interpretations made at the molecular level * key developments in concepts and theory explained in a descriptive manner to encourage student understanding * includes worked problems and examples throughout An invaluable text for students taking courses in chemistry and chemical engineering, this book will also be useful for biology, biochemistry and biophysics students required to study electrochemistry.

Thermodynamics: Basic Principles and Engineering Applications

Author : Alan M. Whitman
Publisher : Springer Nature
ISBN 13 : 3030252213
Total Pages : 328 pages
Book Rating : 4.0/5 (32 download)

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Book Synopsis Thermodynamics: Basic Principles and Engineering Applications by : Alan M. Whitman

Download or read book Thermodynamics: Basic Principles and Engineering Applications written by Alan M. Whitman and published by Springer Nature. This book was released on 2019-12-04 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: This textbook is for a one semester introductory course in thermodynamics, primarily for use in a mechanical or aerospace engineering program, although it could also be used in an engineering science curriculum. The book contains a section on the geometry of curves and surfaces, in order to review those parts of calculus that are needed in thermodynamics for interpolation and in discussing thermodynamic equations of state of simple substances. It presents the First Law of Thermodynamics as an equation for the time rate of change of system energy, the same way that Newton’s Law of Motion, an equation for the time rate of change of system momentum, is presented in Dynamics. Moreover, this emphasis illustrates the importance of the equation to the study of heat transfer and fluid mechanics. New thermodynamic properties, such as internal energy and entropy, are introduced with a motivating discussion rather than by abstract postulation, and connection is made with kinetic theory. Thermodynamic properties of the vaporizable liquids needed for the solution of practical thermodynamic problems (e.g. water and various refrigerants) are presented in a unique tabular format that is both simple to understand and easy to use. All theoretical discussions throughout the book are accompanied by worked examples illustrating their use in practical devices. These examples of the solution of various kinds of thermodynamic problems are all structured in exactly the same way in order to make, as a result of the repetitions, the solution of new problems easier for students to follow, and ultimately, to produce themselves. Many additional problems are provided, half of them with answers, for students to do on their own.

Chemical Thermodynamics of Selenium

Author :
Publisher : Elsevier
ISBN 13 : 0080457517
Total Pages : 896 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Chemical Thermodynamics of Selenium by :

Download or read book Chemical Thermodynamics of Selenium written by and published by Elsevier. This book was released on 2005-04-16 with total page 896 pages. Available in PDF, EPUB and Kindle. Book excerpt: In order to quantitatively predict the chemical reactions that hazardous materials may undergo in the environment, it is necessary to know the relative stabilities of the compounds and complexes that may be found under certain conditions. This type of calculations may be done using consistent chemical thermodynamic data, such as those contained in this book for inorganic compounds and complexes of selenium.* Fully detailed authoritative critical review of literature.* Integrated into a comprehensive and consistent database for waste management applications.* CD ROM version.

The Notion of Activity in Chemistry

Author : Jean-Louis Burgot
Publisher : Springer
ISBN 13 : 3319464019
Total Pages : 607 pages
Book Rating : 4.3/5 (194 download)

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Book Synopsis The Notion of Activity in Chemistry by : Jean-Louis Burgot

Download or read book The Notion of Activity in Chemistry written by Jean-Louis Burgot and published by Springer. This book was released on 2016-11-26 with total page 607 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides deep insight into the physical quantity known as chemical activity. The author probes deep into classical thermodynamics in Part I, and then into statistical thermodynamics in Part II, to provide the necessary background. The treatment has been streamlined by placing some background material in appendices. Chemical Activity is of interest not only to those in chemical thermodynamics, but also to chemical engineers working with mass transfer and its applications - for example, separation methods.

Applications of Adsorption and Ion Exchange Chromatography in Waste Water Treatment

Author : Inamuddin
Publisher : Materials Research Forum LLC
ISBN 13 : 1945291338
Total Pages : 311 pages
Book Rating : 4.9/5 (452 download)

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Book Synopsis Applications of Adsorption and Ion Exchange Chromatography in Waste Water Treatment by : Inamuddin

Download or read book Applications of Adsorption and Ion Exchange Chromatography in Waste Water Treatment written by Inamuddin and published by Materials Research Forum LLC. This book was released on 2017-06-01 with total page 311 pages. Available in PDF, EPUB and Kindle. Book excerpt: The ion-exchange process is a natural phenomenon and mankind has been using this technique since the early days of civilisation. With the progress of technologies and concepts, we got a better understanding of this technique and increased its application horizon. Like in other research areas, nanotechnology has also penetrated heavily into this field, and has helped develop smart materials with better properties for application in adsorption and ion-exchange chromatography. A large amount of research was carried out in this field in the last few decades, showing the importance of these materials and technologies. Water treatment is receiving great attention worldwide, due to the increasing demand of drinking water and hence the need to recycle polluted water sources. Keeping this importance in mind, this book “Applications of Adsorption and Ion Exchange Chromatography in Waste Water Treatment” has been edited with contributions from well know experts in the field, who have been working on different ion-exchange materials and technologies for many years.

Chemical Engineering in the Pharmaceutical Industry

Author : David J. am Ende
Publisher : John Wiley & Sons
ISBN 13 : 1119285860
Total Pages : 1172 pages
Book Rating : 4.1/5 (192 download)

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Book Synopsis Chemical Engineering in the Pharmaceutical Industry by : David J. am Ende

Download or read book Chemical Engineering in the Pharmaceutical Industry written by David J. am Ende and published by John Wiley & Sons. This book was released on 2019-04-23 with total page 1172 pages. Available in PDF, EPUB and Kindle. Book excerpt: A guide to the development and manufacturing of pharmaceutical products written for professionals in the industry, revised second edition The revised and updated second edition of Chemical Engineering in the Pharmaceutical Industry is a practical book that highlights chemistry and chemical engineering. The book’s regulatory quality strategies target the development and manufacturing of pharmaceutically active ingredients of pharmaceutical products. The expanded second edition contains revised content with many new case studies and additional example calculations that are of interest to chemical engineers. The 2nd Edition is divided into two separate books: 1) Active Pharmaceutical Ingredients (API’s) and 2) Drug Product Design, Development and Modeling. The active pharmaceutical ingredients book puts the focus on the chemistry, chemical engineering, and unit operations specific to development and manufacturing of the active ingredients of the pharmaceutical product. The drug substance operations section includes information on chemical reactions, mixing, distillations, extractions, crystallizations, filtration, drying, and wet and dry milling. In addition, the book includes many applications of process modeling and modern software tools that are geared toward batch-scale and continuous drug substance pharmaceutical operations. This updated second edition: Contains 30new chapters or revised chapters specific to API, covering topics including: manufacturing quality by design, computational approaches, continuous manufacturing, crystallization and final form, process safety Expanded topics of scale-up, continuous processing, applications of thermodynamics and thermodynamic modeling, filtration and drying Presents updated and expanded example calculations Includes contributions from noted experts in the field Written for pharmaceutical engineers, chemical engineers, undergraduate and graduate students, and professionals in the field of pharmaceutical sciences and manufacturing, the second edition of Chemical Engineering in the Pharmaceutical Industryf ocuses on the development and chemical engineering as well as operations specific to the design, formulation, and manufacture of drug substance and products.