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Small Molecule Activation By Cooperative Transition Metal Amido Complexes
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Book Synopsis Small Molecule Activation by Cooperative Transition Metal Amido Complexes by : Sven Schneider
Download or read book Small Molecule Activation by Cooperative Transition Metal Amido Complexes written by Sven Schneider and published by . This book was released on 2010 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transition Metal Complexes in Cooperative Lewis Pairs for Small Molecule Activation by : Krishna Mistry
Download or read book Transition Metal Complexes in Cooperative Lewis Pairs for Small Molecule Activation written by Krishna Mistry and published by . This book was released on 2019 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Bifunctional Transition Metal Amido Complexes by : Anja Friedrich
Download or read book Bifunctional Transition Metal Amido Complexes written by Anja Friedrich and published by . This book was released on 2010 with total page 237 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Catalytic Activation of Small Molecules by Transition Metal Complexes by : Edward Mason Gordon
Download or read book The Catalytic Activation of Small Molecules by Transition Metal Complexes written by Edward Mason Gordon and published by . This book was released on 1987 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Bio-inspired First-row Transition Metal Complexes for Small Molecule Activation by : Yun Ji Park
Download or read book Bio-inspired First-row Transition Metal Complexes for Small Molecule Activation written by Yun Ji Park and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Transition Metal Complexes with Bulky Tin Ligands for Application in Small Molecule Activation by : Veeranna Yempally
Download or read book Synthesis and Characterization of Transition Metal Complexes with Bulky Tin Ligands for Application in Small Molecule Activation written by Veeranna Yempally and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The role of bulky tin ligands in the stabilization of transition metal complexes with electronic unsaturation has been studied to understand the mode of binding of small molecules at an unsaturated metal center. We were able to isolate electronically unsaturated Pt-Sn bimetallic complexes effective in the reversible activation of small molecules including CO, H2, C2H4, and NH3 at room temperature. We have examined the effect of the modification of ligands in Pt-Sn bimetallic complexes for the activation of small molecules and have observed that the Pt(SnBut3)2(CNBut)2 bimetallic complex reversibly activates hydrogen at room temperature both in the solid state and in solution. Similarly, we have also prepared bimetallic Pt-Sn complexes with an NHC carbine ligand which were also shown to activate hydrogen and alkenes reversibly. A bimetallic Fe-Sn cluster complex, Fe2 ([mu]-SnBut2)2(CO)8, was synthesized from the reaction of But3SnH with the Fe2(CO)9 and shown to be selective at activating the benzylic C-H bond of alkylaromatic solvent molecules. The new complexes containing tin have been characterized spectroscopically to gain an insight into the reaction mechanism involved in small molecule activation.
Book Synopsis A Computational Study of Small Molecule Activation in Transition Metal Complexes by : Gemma Joy Christian
Download or read book A Computational Study of Small Molecule Activation in Transition Metal Complexes written by Gemma Joy Christian and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Computational Study of Small Molecule Activation Via Low-coordinate Late First-row Transition Metal Complexes by : Aaron Pierpont
Download or read book Computational Study of Small Molecule Activation Via Low-coordinate Late First-row Transition Metal Complexes written by Aaron Pierpont and published by . This book was released on 2010 with total page 116 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Activation of Small Molecules by Transition Metal Complexes Via Computational Methods by : Ahmad Najafian
Download or read book Activation of Small Molecules by Transition Metal Complexes Via Computational Methods written by Ahmad Najafian and published by . This book was released on 2020 with total page 113 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Activation of Small Molecules by Some Transition Metal Complexes by : Philip Vasil Yaneff
Download or read book The Activation of Small Molecules by Some Transition Metal Complexes written by Philip Vasil Yaneff and published by . This book was released on 1976 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Activation of Small Molecules by Multidentate Diphosphino Late Transition Metal Complexes by : Junghee Seo
Download or read book Activation of Small Molecules by Multidentate Diphosphino Late Transition Metal Complexes written by Junghee Seo and published by . This book was released on 2015 with total page 202 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Small Molecule Activation Mediated by Metal-ligand Cooperation Via a Dearomatization/rearomatization Reaction Sequence Using Redox Active Pyridine Based Ligand-systems in Transition Metal Complexes by : Rasmus Stichauer
Download or read book Small Molecule Activation Mediated by Metal-ligand Cooperation Via a Dearomatization/rearomatization Reaction Sequence Using Redox Active Pyridine Based Ligand-systems in Transition Metal Complexes written by Rasmus Stichauer and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transition Metals in the Synthesis of Complex Organic Molecules by : Louis S. Hegedus
Download or read book Transition Metals in the Synthesis of Complex Organic Molecules written by Louis S. Hegedus and published by University Science Books. This book was released on 1999 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.
Book Synopsis Catalytic Small Molecule Reduction Using Late Transition Metal Complexes of Carbon and Nitrogen Donor Chelates by : Sopheavy Siek
Download or read book Catalytic Small Molecule Reduction Using Late Transition Metal Complexes of Carbon and Nitrogen Donor Chelates written by Sopheavy Siek and published by . This book was released on 2017 with total page 772 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogenation reactions can be used to store energy in chemical bonds, and if these reactions are reversible that energy can be released on demand. A new bidentate chelating ligand was designed and synthesized for this project, using an N-heterocyclic carbene ring bound directly to a pyridinol ring (NHC-pyOR). This new ligand was used to make iridium complexes that were studied as catalysts for the hydrogenation of CO2 and dehydrogenation of formic acid. For comparison, analogous bipy derived iridium and ruthenium complexes were also tested. In general, the NHC-pyOR complexes demonstrated modest activity, where hydroxyl-pyridines found in the bipy derived systems are more active for CO2 hydrogenation under basic conditions. However, the trends were quite different for formic acid dehydrogenation reaction which will be discussed in Chapter 2. Other ruthenium (II) and iridium (III) complexes of the NHC-pyOR ligand with difference counter anions from above complexes were also synthesized. The ruthenium complexes were tested for their ability to accelerate CO2 (de)hydrogenation, but our studies show that these complexes all undergo transformations in solution and thus they are not true catalysts, but rather pre-catalysts. The use of new tridentate pincer ligands derived from NHC and pyridinol is also described. A new ligand containing (NHC-pyOR-NHC) rings binding to a metal with the pyridinol derivative were synthesized. A series of metal complexes of the type LnM were synthesized (n = 1 and 2; M = Fe2+, Co3+, and Ru2+). Preliminary results of photocatalytic reduction of CO2 to CO show that ruthenium complexes are the most active catalysts followed by cobalt and iron, respectively. The activation of carbon dioxide and nitrite utilizing bio-inspired and proton responsive catalysts were also studied with tris(triazolyl)hydroborate (Ttz) complexes of zinc(II) and copper(II). For the biomimetic zinc complexes for CO2 activation, the synthetic result was found to be greatly depend on the steric bulk of Ttz ligand which will be discussed in detail in Chapter 6. Moreover, the electrochemical reduction of Ttz-Cu(II) complexes in the presence and absence of a proton source shows processes that are relevant to enzymatic nitrite reduction which also will be studied in Chapter 7.
Book Synopsis Organometallic Pincer Chemistry by : Gerard van Koten
Download or read book Organometallic Pincer Chemistry written by Gerard van Koten and published by Springer. This book was released on 2012-09-17 with total page 363 pages. Available in PDF, EPUB and Kindle. Book excerpt: Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a Versatile Privileged Ligand Platform: General Considerations.- Elena Poverenov, David Milstein: Non-Innocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand Electronic and Steric Properties.- Gemma R. Freeman, J. A. Gareth Williams: Metal Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence.- Davit Zargarian, Annie Castonguay, Denis M. Spasyuk: ECE-Type Pincer Complexes of Nickel.- Roman Jambor and Libor Dostál: The Chemistry of Pincer Complexes of 13 - 15 Main Group Elements.- Kálmán J. Szabo: Pincer Complexes as Catalysts in Organic Chemistry.- Jun-ichi Ito and Hisao Nishiyama: Optically Active Bis(oxazolinyl)phenyl Metal Complexes as Multi-potent Catalysts.- Anthony St. John, Karen I. Goldberg, and D. Michael Heinekey: Pincer Complexes as Catalysts for Amine Borane Dehydrogenation.- Dmitri Gelman and Ronit Romm: PC(sp3)P Transition Metal Pincer Complexes: Properties and Catalytic Applications.- Jennifer Hawk and Steve Craig: Physical Applications of Pincer Complexes.
Book Synopsis NHC Supported CuI Amido and Sulfido Complexes: Synthesis, Characterization, and Applications in Small Molecule Activation by :
Download or read book NHC Supported CuI Amido and Sulfido Complexes: Synthesis, Characterization, and Applications in Small Molecule Activation written by and published by . This book was released on 2015 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis presents the synthesis and characterization of several new Cu(I) amido and sulfido complexes supported by N-Heterocyclic Carbene (NHC) ligand and discusses their applications in small molecule activation, e.g. CO2 activation, etc.
Book Synopsis Foundations for Small Molecule Activation at Reduced Metal-metal Bonded Complexes by : Tristan Robert Brown
Download or read book Foundations for Small Molecule Activation at Reduced Metal-metal Bonded Complexes written by Tristan Robert Brown and published by . This book was released on 2017 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: