Results from Boiling Temperature Measurements for Saturated Solutions in the Systems NaCl + KNO3 + H2O, NaNO3 + KNO3 + H2O, and NaCl + NaNO3 + KNO3 + H2O.

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Book Synopsis Results from Boiling Temperature Measurements for Saturated Solutions in the Systems NaCl + KNO3 + H2O, NaNO3 + KNO3 + H2O, and NaCl + NaNO3 + KNO3 + H2O. by :

Download or read book Results from Boiling Temperature Measurements for Saturated Solutions in the Systems NaCl + KNO3 + H2O, NaNO3 + KNO3 + H2O, and NaCl + NaNO3 + KNO3 + H2O. written by and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Boiling temperature measurements have been made for saturated ternary solutions of NaCl + KNO3 + H2O and NaNO3 + KNO3 + H2O over the full solute mole fraction range, along with the limiting binary solutions NaCl + H2O, NaNO3 + H2O, and KNO3 + H2O. Boiling temperatures have also been measured for the quaternary NaCl + NaNO3 + KNO3 + H2O mixtures with KNO3:NaNO3 mole ratios of 1.01 and 1.19, which corresponding to the eutectic ratio and a near-eutectic ratio for the NaNO3 + KNO3 + H2O subsystem. The maximum boiling temperature found for the NaCl + KNO3 + H2O system is 134 C and for the NaNO3 + KNO3 + H2O system is 160 C, but boiling temperatures as high as 196 C were measured the NaCl + NaNO3 + KNO3 + H2O system. These mixture compositions correspond to the major mineral assemblages that are predicted to control the deliquescence relative humidity of salts found by leaching dust samples from the proposed nuclear repository at Yucca Mountain, Nevada.

Results from Boiling Temperature Measurements for Saturated Solutions in the Systems NaCl + Ca(NO3)2 + H2O, NaNO3 + KNO3 + H2O, and NaCl + KNO3 + H2O, and Dry Out Temperatures for NaCl + NaNO3 + KNO3 + Ca(NO3)2 + H2O.

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Total Pages : 33 pages
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Book Synopsis Results from Boiling Temperature Measurements for Saturated Solutions in the Systems NaCl + Ca(NO3)2 + H2O, NaNO3 + KNO3 + H2O, and NaCl + KNO3 + H2O, and Dry Out Temperatures for NaCl + NaNO3 + KNO3 + Ca(NO3)2 + H2O. by : J. A. Rard

Download or read book Results from Boiling Temperature Measurements for Saturated Solutions in the Systems NaCl + Ca(NO3)2 + H2O, NaNO3 + KNO3 + H2O, and NaCl + KNO3 + H2O, and Dry Out Temperatures for NaCl + NaNO3 + KNO3 + Ca(NO3)2 + H2O. written by J. A. Rard and published by . This book was released on 2005 with total page 33 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boiling temperature measurements have been made for saturated ternary solutions of NaCl + KNO{sub 3} + H{sub 2}O and NaNO{sub 3} + KNO{sub 3} + H{sub 2}O at three selected salt ratios and for NaCl + Ca(NO{sub 3}){sub 2} + H{sub 2}O over the full composition range. The maximum boiling temperature found for the NaCl + Ca(NO{sub 3}){sub 2} + H{sub 2}O system is 164.7 {+-} 0.6 C, and the composition is estimated to occur at x(Ca(NO{sub 3}){sub 2}) {approx} 0.25. Experiments were also performed for the five component NaCl + NaNO{sub 3} + KNO{sub 3} + Ca(NO{sub 3}){sub 2} + H{sub 2}O mixtures with the molar ratio of NaCl:NaNO{sub 3}:KNO{sub 3} held essentially constant at 1:0.9780:1.1468 as the solute mole fraction of Ca(NO{sub 3}){sub 2}, x(Ca(NO{sub 3}){sub 2}), was varied between 0 and 0.25. The NaCl + NaNO{sub 3} + KNO{sub 3} + Ca(NO{sub 3}){sub 2} + H{sub 2}O system forms low melting mixtures and thus boiling temperatures for saturated were not determined. Instead, the temperatures corresponding to the cessation of boiling (i.e., dry out temperatures) of these liquid mixtures were determined. These dry out temperatures range from {approx} 300 C when x(Ca(NO{sub 3}){sub 2}) = 0 to {ge} 400 C when x(Ca(NO{sub 3}){sub 2}) = 0.20 and 0.25. The investigated mixture compositions correspond to some of the major mineral assemblages that are predicted to control the deliquescence relative humidity of salts formed by leaching dust samples from the proposed nuclear repository at Yucca Mountain, Nevada.

Boiling Temperature and Reversed Deliquescence Relative Humidity Measurements for Mineral Assemblages in the NaCl + NaNO3 + KNO3 + Ca(NO3)2 + H2O System

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Book Synopsis Boiling Temperature and Reversed Deliquescence Relative Humidity Measurements for Mineral Assemblages in the NaCl + NaNO3 + KNO3 + Ca(NO3)2 + H2O System by :

Download or read book Boiling Temperature and Reversed Deliquescence Relative Humidity Measurements for Mineral Assemblages in the NaCl + NaNO3 + KNO3 + Ca(NO3)2 + H2O System written by and published by . This book was released on 2005 with total page 58 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boiling temperature measurements have been made at ambient pressure for saturated ternary solutions of NaCl + KNO3 + H2O, NaNO3 + KNO3 + H2O, and NaCl + Ca(NO3)2 + H2O over the full composition range, along with those of the single salt systems. Boiling temperatures were also measured for the four component NaCl + NaNO3 + KNO3 + H2O and five component NaCl + NaNO3 + KNO3 + Ca(NO3)2 + H2O mixtures, where the solute mole fraction of Ca(NO3)2, x(Ca(NO3)2), was varied between 0 and 0.25. The maximum boiling temperature found for the NaCl + KNO3 + H2O system is ≈ 134.9 C; for the NaNO3 + KNO3 + H2O system is ≈ 165.1 C at x(NaNO3) ≈ 0.46 and x(KNO3) ≈ 0.54; and for the NaCl + Ca(NO3)2 + H2O system is 164.7 ± 0.6 C at x(NaCl) ≈ 0.25 and x(Ca(NO3)2) ≈ 0.75. The NaCl + NaNO3 + KNO3 + Ca(NO3)2 + H2O system forms molten salts below their maximum boiling temperatures, and the temperatures corresponding to the cessation of boiling (dry out temperatures) of these liquid mixtures were determined. These dry out temperatures range from ≈ 300 C when x(Ca(NO3)2) = 0 to ≥ 400 C when x(Ca(NO3)2) = 0.20 and 0.25. Mutual deliquescence/efflorescence relative humidity (MDRH/MERH) measurements were also made for the NaNO3 + KNO3 and NaCl + NaNO3 + KNO3 salt mixture from 120 to 180 C at ambient pressure. The NaNO3 and NaCl + NaNO3 + KNO3 salt mixture has a MDRH of 26.4% at 120 C and 20.0% at 150 C. This salt mixture also absorbs water at 180 C, which is higher than expected from the boiling temperature experiments. The NaCl + NaNO3 + KNO3 salt mixture was found to have a MDRH of 25.9% at 120 C and 10.5% at 180 C. The investigated mixture compositions correspond to some of the major mineral assemblages that are predicted to control brine composition due to the deliquescence of salts formed in dust deposited on waste canisters in the proposed nuclear repository at Yucca Mountain, Nevada.

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Scientific Basis for Nuclear Waste Management

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Results from Boiling Temperature Measurements for Saturated Solutions in the Systems NaCl + KNO{sub 3} + H{sub 2}O, NaNO{sub 3} + KNO{sub 3} + H{sub 2}O, and NaCl + NaNO{sub 3} + KNO{sub 3} + H{sub 2}O.

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Book Synopsis Results from Boiling Temperature Measurements for Saturated Solutions in the Systems NaCl + KNO{sub 3} + H{sub 2}O, NaNO{sub 3} + KNO{sub 3} + H{sub 2}O, and NaCl + NaNO{sub 3} + KNO{sub 3} + H{sub 2}O. by : J. A. Rard

Download or read book Results from Boiling Temperature Measurements for Saturated Solutions in the Systems NaCl + KNO{sub 3} + H{sub 2}O, NaNO{sub 3} + KNO{sub 3} + H{sub 2}O, and NaCl + NaNO{sub 3} + KNO{sub 3} + H{sub 2}O. written by J. A. Rard and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Boiling temperature measurements have been made for saturated ternary solutions of NaCl + KNO{sub 3} + H{sub 2}O and NaNO{sub 3} + KNO{sub 3} + H{sub 2}O over the full solute mole fraction range, along with the limiting binary solutions NaCl + H{sub 2}O, NaNO{sub 3} + H{sub 2}O, and KNO{sub 3} + H{sub 2}O. Boiling temperatures have also been measured for the quaternary NaCl + NaNO{sub 3} + KNO{sub 3} + H{sub 2}O mixtures with KNO{sub 3}:NaNO{sub 3} mole ratios of 1.01 and 1.19, which corresponding to the eutectic ratio and a near-eutectic ratio for the NaNO{sub 3} + KNO{sub 3} + H{sub 2}O subsystem. The maximum boiling temperature found for the NaCl + KNO{sub 3} + H{sub 2}O system is 134 C and for the NaNO{sub 3} + KNO{sub 3} + H{sub 2}O system is 160 C, but boiling temperatures as high as 196 C were measured the NaCl + NaNO{sub 3} + KNO{sub 3} + H{sub 2}O system. These mixture compositions correspond to the major mineral assemblages that are predicted to control the deliquescence relative humidity of salts found by leaching dust samples from the proposed nuclear repository at Yucca Mountain, Nevada.

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