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Response Of Unstable Chemical Systems To External Perturbations
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Book Synopsis Response of Unstable Chemical Systems to External Perturbations by : Peter J. Ortoleva
Download or read book Response of Unstable Chemical Systems to External Perturbations written by Peter J. Ortoleva and published by . This book was released on 1971 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt: For a system of coupled chemical reactions, with diffusion and in a homogeneous steady state near marginal stability, the response to a periodic external perturbation is derived in a linear analysis and shown to be a resonance phenomena. Responses to perturbations of external variables with small effects on the rate coefficients are amplified at resonance. Suggested applications of the theory are: Study of kinetic parameters and their dependence on external variables; Use of marginally stable systems as analogues of electronic devices; Use of marginally stable systems as sensors and receptors; Out-of-phase external perturbations as stabilization methods; and Double resonance experiments. (Author).
Book Synopsis Scientific and Technical Aerospace Reports by :
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1991 with total page 1460 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.
Book Synopsis Penetration of Boundary Perturbations in Unstable Chemical Systems by : Peter J. Ortoleva
Download or read book Penetration of Boundary Perturbations in Unstable Chemical Systems written by Peter J. Ortoleva and published by . This book was released on 1971 with total page 29 pages. Available in PDF, EPUB and Kindle. Book excerpt: The effects of boundary perturbations of chemical species is investigated in a linear analysis for systems of coupled chemical reactions, with diffusion, which have instabilities. At marginal stability of one of the harmonic modes of such a system the penetration depth of the chemical boundary perturbation coupled to that mode approaches infinity at resonance, that is at the frequency of boundary perturbation equal to the marginal oscillatory frequency of the mode. For the case of equal and diagonal diffusion coefficients for all chemical species the penetration of the perturbation is homogeneous at resonance; unattenuated inhomogeneous penetration occurs in association with symmetry breaking instabilities of the system. The propagation of an impulse boundary perturbation is derived. Some possible applications of the theory are suggested but not demonstrated: Analysis of chemical instabilities; analogies of electronic devices such as tuned amplifiers, transmitters and receivers (chemical radio); communication in aggregates of biological systems; and mechanism of pheromone emission and reception. (Author).
Book Synopsis Penetration of Boundary Perturbation in Unstable Chemical Systems by : Peter J. Ortoleva
Download or read book Penetration of Boundary Perturbation in Unstable Chemical Systems written by Peter J. Ortoleva and published by . This book was released on 1971 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Non-Equilibrium Dynamics in Chemical Systems by : C. Vidal
Download or read book Non-Equilibrium Dynamics in Chemical Systems written by C. Vidal and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Markedly apart from elementary particle physics, another current has been building up and cont i nuous ly growi ng within contemporary phys i cs for severa 1 decades, and even expanding into many other disciplines, especially chemistry, biology and, quite recently, economics. Several reasons account for this: presumably the most impor tant one lies in the fact that, whatever the specific problem, model or material concerned, the same basic mathematical features are always involved. In this way, a general phenomenology has emerged which, unlike thermodynamics, is no longer depen dent upon the details or specifics: what largely prevails is the nonlinear charac ter of the underlying dynamics. Perhaps we are witnessing the emergence of a "non linear physics"--In a way similar to the birth of "quantum physics" in the twen ties - a physics which deals with the general behaviour of systems, whatever they are or may be. Over the past fifteen years, chemical systems evolving sufficiently far from equilibrium have proved to be particularly well fitted to experimental research on nonlinear behaviour: oscillation, multistability, birhythmicity, chaotic evolution, spatial self-organization and hysteresis are displayed by chemical reactions whose number is growing each year. In this volume are collected the lectures, communica tions and posters (abstracts) presented at an international meeting entitled: "Non-Equilibrium Dynamics in Chemical Systems", held in Bordeaux (France), Septem ber 3 rd-lth, 1984.
Book Synopsis Statistical Mechanics for Chemistry and Materials Science by : Biman Bagchi
Download or read book Statistical Mechanics for Chemistry and Materials Science written by Biman Bagchi and published by CRC Press. This book was released on 2018-07-06 with total page 558 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the broad subject of equilibrium statistical mechanics along with many advanced and modern topics such as nucleation, spinodal decomposition, inherent structures of liquids and liquid crystals. Unlike other books on the market, this comprehensive text not only deals with the primary fundamental ideas of statistical mechanics but also covers contemporary topics in this broad and rapidly developing area of chemistry and materials science.
Book Synopsis Government Reports Announcements by :
Download or read book Government Reports Announcements written by and published by . This book was released on 1971 with total page 1360 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Chemical Reactivity in Quantum Mechanics and Information Theory by : Roman F Nalewajski
Download or read book Chemical Reactivity in Quantum Mechanics and Information Theory written by Roman F Nalewajski and published by Elsevier. This book was released on 2022-11-17 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Reactivity in Quantum Mechanics and Information Theory introduces a thermodynamic-like description of molecular systems and provides an objective treatment of their fragments. The book formulates adequate entropic tools for probing in chemical terms and the electronic structure of molecules and rationalizing reactivity principles. It covers the information origins of chemical bonds, covalent/ionic composition, trends in molecular stability and reactivity, equilibrium polarizations and charge-transfer reconstructions of reactive complexes, as well as the phase/current promotions of molecular substrates. In addition, the book introduces a precise descriptor of molecular fragments and clarifies mostly intuitive semantics of several chemical concepts. Readers will find a precise and unbiased description of chemical reactivity phenomena in Donor-Acceptor systems in terms of quantum states and generalized concepts of Information/Communication theories. Generates a new basis for understanding the rules governing molecular processes, information origins of chemical bonding, and its covalent/ionic composition Provides an objective approach to classical issues in modern reactivity theory Offers a unifying information-theoretic perspective on electronic states
Book Synopsis Chemical Complexity by : Alexander S. Mikhailov
Download or read book Chemical Complexity written by Alexander S. Mikhailov and published by Springer. This book was released on 2017-08-10 with total page 209 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an outline of theoretical concepts and their experimental verification in studies of self-organization phenomena in chemical systems, as they emerged in the mid-20th century and have evolved since. Presenting essays on selected topics, it was prepared by authors who have made profound contributions to the field. Traditionally, physical chemistry has been concerned with interactions between atoms and molecules that produce a variety of equilibrium structures - or the 'dead' order - in a stationary state. But biological cells exhibit a different 'living' kind of order, prompting E. Schrödinger to pose his famous question “What is life?” in 1943. Through an unprecedented theoretical and experimental development, it was later revealed that biological self-organization phenomena are in complete agreement with the laws of physics, once they are applied to a special class of thermodynamically open systems and non-equilibrium states. This knowledge has in turn led to the design and synthesis of simple inorganic systems capable of self-organization effects. These artificial 'living organisms' are able to operate on macroscopic to microscopic scales, even down to single-molecule machines. In the future, such research could provide a basis for a technological breakthrough, comparable in its impact with the invention of lasers and semiconductors. Its results can be used to control natural chemical processes, and to design artificial complex chemical processes with various functionalities. The book offers an extensive discussion of the history of research on complex chemical systems and its future prospects.
Book Synopsis Foundations of Complex Systems by : G. Nicolis
Download or read book Foundations of Complex Systems written by G. Nicolis and published by World Scientific. This book was released on 2012 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a self-contained presentation of the physical and mathematical laws governing complex systems. Complex systems arising in natural, engineering, environmental, life and social sciences are approached from a unifying point of view using an array of methodologies such as microscopic and macroscopic level formulations, deterministic and probabilistic tools, modeling and simulation. The book can be used as a textbook by graduate students, researchers and teachers in science, as well as non-experts who wish to have an overview of one of the most open, markedly interdisciplinary and fast-growing branches of present-day science.
Book Synopsis Foundations Of Complex Systems: Emergence, Information And Prediction (2nd Edition) by : Gregoire Nicolis
Download or read book Foundations Of Complex Systems: Emergence, Information And Prediction (2nd Edition) written by Gregoire Nicolis and published by World Scientific. This book was released on 2012-03-08 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a self-contained presentation of the physical and mathematical laws governing complex systems. Complex systems arising in natural, engineering, environmental, life and social sciences are approached from a unifying point of view using an array of methodologies such as microscopic and macroscopic level formulations, deterministic and probabilistic tools, modeling and simulation. The book can be used as a textbook by graduate students, researchers and teachers in science, as well as non-experts who wish to have an overview of one of the most open, markedly interdisciplinary and fast-growing branches of present-day science.
Book Synopsis An Introduction to Nonlinear Chemical Dynamics by : Irving R. Epstein
Download or read book An Introduction to Nonlinear Chemical Dynamics written by Irving R. Epstein and published by Oxford University Press. This book was released on 1998-10-22 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: Assuming no more than an undergraduate knowledge of chemistry, the authors take the reader through the necessary mathematical and theoretical background of oscillating reactions, chaos and chemical waves to advanced topics of current research interest in chemical systems.
Book Synopsis Determination of Complex Reaction Mechanisms by : John Ross
Download or read book Determination of Complex Reaction Mechanisms written by John Ross and published by Oxford University Press. This book was released on 2006 with total page 239 pages. Available in PDF, EPUB and Kindle. Book excerpt: In a chemical system with many chemical species several questions can be asked: what species react with other species: in what temporal order: and with what results? These questions have been asked for over one hundred years about simple and complex chemical systems, and the answers constitute the macroscopic reaction mechanism. In Determination of Complex Reaction Mechanisms authors John Ross, Igor Schreiber, and Marcel Vlad present several systematic approaches for obtaining information on the causal connectivity of chemical species, on correlations of chemical species, on the reaction pathway, and on the reaction mechanism.Basic pulse theory is demonstrated and tested in an experiment on glycolysis. In a second approach, measurements on time series of concentrations are used to construct correlation functions and a theory is developed which shows that from these functions information may be inferred on the reaction pathway, the reaction mechanism, and the centers of control in that mechanism. A third approach is based on application of genetic algorithm methods to the study of the evolutionary development of a reaction mechanism, to the attainment given goals in a mechanism, and to the determination of a reaction mechanism and rate coefficients by comparison with experiment. Responses of non-linear systems to pulses or other perturbations are analyzed, and mechanisms of oscillatory reactions are presented in detail. The concluding chapters give an introduction to bioinformatics and statistical methods for determining reaction mechanisms.
Author :Gustavo García Gómez-Tejedor Publisher :Springer Science & Business Media ISBN 13 :9400725647 Total Pages :508 pages Book Rating :4.4/5 (7 download)
Book Synopsis Radiation Damage in Biomolecular Systems by : Gustavo García Gómez-Tejedor
Download or read book Radiation Damage in Biomolecular Systems written by Gustavo García Gómez-Tejedor and published by Springer Science & Business Media. This book was released on 2012-01-04 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the discovery of X-rays and radioactivity, ionizing radiations have been widely applied in medicine both for diagnostic and therapeutic purposes. The risks associated with radiation exposure and handling led to the parallel development of the field of radiation protection. Pioneering experiments done by Sanche and co-workers in 2000 showed that low-energy secondary electrons, which are abundantly generated along radiation tracks, are primarily responsible for radiation damage through successive interactions with the molecular constituents of the medium. Apart from ionizing processes, which are usually related to radiation damage, below the ionization level low-energy electrons can induce molecular fragmentation via dissociative processes such as internal excitation and electron attachment. This prompted collaborative projects between different research groups from European countries together with other specialists from Canada, the USA and Australia. This book summarizes the advances achieved by these research groups after more than ten years of studies on radiation damage in biomolecular systems. An extensive Part I deals with recent experimental and theoretical findings on radiation induced damage at the molecular level. It includes many contributions on electron and positron collisions with biologically relevant molecules. X-ray and ion interactions are also covered. Part II addresses different approaches to radiation damage modelling. In Part III biomedical aspects of radiation effects are treated on different scales. After the physics-oriented focus of the previous parts, there is a gradual transition to biology and medicine with the increasing size of the object studied. Finally, Part IV is dedicated to current trends and novel techniques in radiation reserach and the applications hence arising. It includes new developments in radiotherapy and related cancer therapies, as well as technical optimizations of accelerators and totally new equipment designs, giving a glimpse of the near future of radiation-based medical treatments.
Book Synopsis Foundations of Complex Systems by : Gregoire Nicolis
Download or read book Foundations of Complex Systems written by Gregoire Nicolis and published by World Scientific. This book was released on 2007 with total page 343 pages. Available in PDF, EPUB and Kindle. Book excerpt: A geometric process is a simple monotone process that was first introduced by the author in 1988. It is a generalization of renewal process. This book captures the extensive research work on geometric processes that has been done since then in both probability and statistics theory and various applications. Some results are published for the first time. A reference book for researchers and a handbook for practioners, it is also a useful textbook for postgraduate or senior undergraduate students.
Book Synopsis TRAC: Trends in Analytical Chemistry by : U.A.Th. Brinkman
Download or read book TRAC: Trends in Analytical Chemistry written by U.A.Th. Brinkman and published by Elsevier. This book was released on 2016-06-13 with total page 411 pages. Available in PDF, EPUB and Kindle. Book excerpt: TRAC: Trends in Analytical Chemistry, Volume 11 presents relevant topics in global analytical chemistry research. This book discusses the fundamental principle of competitive immunoassays. Organized into 27 chapters, this volume begins with an overview of the general and important contributions relating to the presentation of forensic evidence to courts of law. This text then discusses the importance of the analysis of scanned measuring quantities. Other chapters consider the advantages as well as the drawbacks of coupled chromatographic methods. This book discusses as well the status of analytical chemistry within the broader scientific arena as a practical rather than fundamentally oriented discipline. The final chapter deals with the properly functioning process control system in manufacturing insulin by reversed-phase high-performance liquid chromatography (RP–HPLC). This book is a valuable resource for analytical, organic, clinical, and regulatory chemists. Electrochemists, scientists, students, engineers, researcher workers, and other practitioners will also find this book extremely useful.
Download or read book Active Materials written by Peter Fratzl and published by Walter de Gruyter GmbH & Co KG. This book was released on 2021-12-20 with total page 378 pages. Available in PDF, EPUB and Kindle. Book excerpt: What are active materials? This book aims to introduce and redefine conceptions of matter by considering materials as entities that ‘sense’ and respond to their environment. By examining the modeling of, the experiments on, and the construction of these materials, and by developing a theory of their structure, their collective activity, and their functionality, this volume identifies and develops a novel scientific approach to active materials. Moreover, essays on the history and philosophy of metallurgy, chemistry, biology, and materials science provide these various approaches to active materials with a historical and cultural context. The interviews with experts from the natural sciences included in this volume develop new understandings of ‘active matter’ and active materials in relation to a range of research objects and from the perspective of different scientific disciplines, including biology, physics, chemistry, and materials science. These insights are complemented by contributions on the activity of matter and materials from the humanities and the design field. Discusses the mechanisms of active materials and their various conceptualizations in materials science. Redefines conceptions of active materials through interviews with experts from the natural sciences. Contextualizes, historizes, and reflects on different notions of matter/materials and activity through contributions from the humanities. A highly interdisciplinary approach to a cutting-edge research topic, with contributions from both the sciences and the humanities.
