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Recent Developments In The Chemistry Of Free Radical Addition Reactions
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Author :J I G (John Ivan George) Cadogan Publisher :Hassell Street Press ISBN 13 :9781013669286 Total Pages :40 pages Book Rating :4.6/5 (692 download)
Book Synopsis Recent Developments in the Chemistry of Free-radical Addition Reactions by : J I G (John Ivan George) Cadogan
Download or read book Recent Developments in the Chemistry of Free-radical Addition Reactions written by J I G (John Ivan George) Cadogan and published by Hassell Street Press. This book was released on 2021-09-09 with total page 40 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work has been selected by scholars as being culturally important and is part of the knowledge base of civilization as we know it. This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. To ensure a quality reading experience, this work has been proofread and republished using a format that seamlessly blends the original graphical elements with text in an easy-to-read typeface. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.
Book Synopsis Recent Developments in the Chemistry of Free-radical Addition Reactions by : John Ivan George Cadogan
Download or read book Recent Developments in the Chemistry of Free-radical Addition Reactions written by John Ivan George Cadogan and published by . This book was released on 1961 with total page 40 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Recent Developments in the Chemistry of Free-radical Addition Recations by :
Download or read book Recent Developments in the Chemistry of Free-radical Addition Recations written by and published by . This book was released on 1960 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Radical Reactions in Aqueous Media by : V. Tamara Perchyonok
Download or read book Radical Reactions in Aqueous Media written by V. Tamara Perchyonok and published by Royal Society of Chemistry. This book was released on 2010 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radical Reactions in Aqueous Media provides a step-wise introduction, taking students from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes."--Jacket.
Book Synopsis Half a Century of Free Radical Chemistry by : Derek H. R. Barton
Download or read book Half a Century of Free Radical Chemistry written by Derek H. R. Barton and published by Cambridge University Press. This book was released on 1993-04-15 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the experience over 25 years of the senior author with the chemistry of organic free radicals. It begins with a mechanistic study of industrial importance on the pyrolysis of chlorinated alkanes. It continues with a theory on the biosynthesis of phenolate derived alkaloids involving phenolate radical coupling. There follows 20 years of practical work to prove the theory correct, especially in the case of morphine alkaloids. The book then describes the work on nitrile photolysis (Barton reaction) which involved the invention of new radical chemistry leading to a simple synthesis of the important hormone, aldosterone. There follows a description of the invention of an important new method for the deoxygenation of biologically important molecules, especially sugars and nucleosides, using radical chemistry applied to thiocarbonyl derivatives. Some years later, in a logical extension to carboxylic acids, another new reaction was invented which provides carbon, nitrogen, oxygen and other radicals under mild conditions. A final chapter summarizes recent applications of thiocarbonyl group derived radical reactions by other authors.
Book Synopsis Advances in Free Radical Chemistry by : S.Z. Zard
Download or read book Advances in Free Radical Chemistry written by S.Z. Zard and published by Elsevier. This book was released on 2000-01-31 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: This series is designed to provide a vehicle in which investigators, who have demonstrated a high degree of competence in some aspect of free radical chemistry, can present a particular area of interest. The series encompasses a wide variety of topics which are of current interest.
Book Synopsis Free Radicals in Organic Chemistry by : Jacques Fossey
Download or read book Free Radicals in Organic Chemistry written by Jacques Fossey and published by . This book was released on 1995-11-09 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radicals constitute the most frequently used class of reaction intermediates in organic chemistry. This study describes the structure and reactivity of free radicals, and explores their role in both natural phenomena and in the design of new reaction pathways.
Book Synopsis The Chemistry of Free Radicals by : Rayson L. Huang
Download or read book The Chemistry of Free Radicals written by Rayson L. Huang and published by Hodder Education. This book was released on 1974 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Free Radicals in Organic Synthesis by : D. I. Davies
Download or read book Free Radicals in Organic Synthesis written by D. I. Davies and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 181 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Free Radicals in Chemistry and Biology by : Milan Lazar
Download or read book Free Radicals in Chemistry and Biology written by Milan Lazar and published by CRC Press. This book was released on 1989-03-31 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Elementary radical reactions are described in terms of fundamental knowledge of organic chemistry and chemical physics in this valuable reference text. The complex radical processes of nonchain and chain mechanisms, such as dimerization, alkylation, polymerization, telomerization, halogenation pyrolysis, oxidation and combustion, are complemented by reactions in chemical lasers and in the cosmos, as well as by reactions in biological objects under normal or pathological metabolism. The text also provides the synthesis of facts from various fields of research and involves mechanisms where free radicals appear either as main or side intermediates in one of the several alternatives of the reaction pathway. Highlights include 38 tables and 39 figures.
Book Synopsis The Chemistry of Radical Polymerization by : Graeme Moad
Download or read book The Chemistry of Radical Polymerization written by Graeme Moad and published by Elsevier. This book was released on 2006 with total page 667 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book commences with a general introduction outlining the basic concepts of radical polymerization. This is followed by a chapter on radical reactions that is intended to lay the theoretical ground-work for the succeeding chapters on initiation, propagation and termination.
Book Synopsis Advanced Free Radical Reactions for Organic Synthesis by :
Download or read book Advanced Free Radical Reactions for Organic Synthesis written by and published by Elsevier. This book was released on 2004-01-14 with total page 271 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radical reactions have become increasingly important and a very attractive tool in organic synthesis in the last two decades, due to their powerful, selective, specific, and mild reaction abilities. Advanced Free Radical Reactions for Organic Synthesis reviews information on all types of practical radical reactions, e.g. cyclizations, additions, hydrogen-atom abstractions, decarboxylation reactions. The book usefully provides experimental details for the most important reactions as well as numerous references to the original literature. By covering both the fundamentals and synthetic applications it is therefore suitable for both new and experienced researchers, chemists, biochemists, natural product chemists and graduate students. This title is the definitive guide to radical chemistry for all scientists. Introduces and reviews the use of radicals to perform synthetic transformations Practical details are provided for the most important methods Numerous references to the original literature
Book Synopsis From Atoms to Molecules by : Colin A. Russell
Download or read book From Atoms to Molecules written by Colin A. Russell and published by Taylor & Francis. This book was released on 2024-08-01 with total page 331 pages. Available in PDF, EPUB and Kindle. Book excerpt: The focus of this volume by Professor Russell is the history of organic chemistry, which arose improbably out of early speculations about the construction of chemical compounds, and in particular their electrochemical nature. The rise of electrochemistry and the work of Berzelius were critical in this regard, and receive much attention in the first few chapters in this book. Aspects of the contributions of Frankland (fully explored elsewhere) and those of Kekulê and Hofmann are considered, together with the miscellaneous functions of organic synthesis and the origins of conformational analysis. Questions of chemical organisation are germane to the whole sequence of events and are briefly summarized before the whole last hundred years of organic chemistry are placed in historical perspective.
Book Synopsis Handbook of Free Radical Initiators by : E. T. Denisov
Download or read book Handbook of Free Radical Initiators written by E. T. Denisov and published by John Wiley & Sons. This book was released on 2005-01-14 with total page 903 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radical initiators–chemical molecules which easily decompose into free radicals–serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: Dialkyl Peroxides and Hydroperoxides Diacyl Peroxides, Peresters, and Organic Polyoxides Azo-Compounds Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules Free Radical Abstraction Reactions Free Radical Addition Reactions Free Radical Recombination and Disproportoination Reactions Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.
Book Synopsis The Investigation of Organic Reactions and Their Mechanisms by : Howard Maskill
Download or read book The Investigation of Organic Reactions and Their Mechanisms written by Howard Maskill and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: A range of alternative mechanisms can usually be postulated for most organic chemical reactions, and identification of the most likely requires detailed investigation. Investigation of Organic Reactions and their Mechanisms will serve as a guide for the trained chemist who needs to characterise an organic chemical reaction and investigate its mechanism, but who is not an expert in physical organic chemistry. Such an investigation will lead to an understanding of which bonds are broken, which are made, and the order in which these processes happen. This information and knowledge of the associated kinetic and thermodynamic parameters are central to the development of safe, efficient, and profitable industrial chemical processes, and to extending the synthetic utility of new chemical reactions in chemical and pharmaceutical manufacturing, and academic environments. Written as a coherent account of the principal methods currently used in mechanistic investigations, at a level accessible to academic researchers and graduate chemists in industry, the book is highly practical in approach. The contributing authors, an international group of expert practitioners of the techniques covered, illustrate their contributions by examples from their own research and from the relevant wider chemical literature. The book covers basic aspects such as product analysis, kinetics, catalysis, and investigation of reactive intermediates. It also includes material on significant recent developments, e.g. computational chemistry, calorimetry, and electrochemistry, in addition to topics of high current industrial relevance, e.g. reactions in multiphase systems, and synthetically useful reactions involving free radicals and catalysis by organometallic compounds.
Book Synopsis Free-Radical Synthesis and Functionalization of Heterocycles by : Yannick Landais
Download or read book Free-Radical Synthesis and Functionalization of Heterocycles written by Yannick Landais and published by Springer. This book was released on 2018-05-03 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume describes the recent developments in the free-radical mediated synthesis and elaboration of heterocycles. The first chapter, dealing with radical cascade processes illustrates the power and the beauty of radical chemistry with some striking examples of total synthesis of complex natural heterocycles. As organic chemists strive towards sustainability, radical chemistry has recently seen major advances and efforts in this direction, including C-H activation of arenes and unactivated alkyl groups. Photochemical activation, for a long time the preferred mode of activation in radical chemistry has also seen an unexpected revival with the advent of visible light metal- and organocatalyzed photoredox processes. A survey of these emerging areas is provided along with the concepts at the origin of these developments. The venerable Minisci reaction allows for direct access to functionalized heterocycles. This process has lately seen an interesting renaissance and is discussed in this volume. Addition of heteroatom-centered radicals onto unsaturated systems constitutes another powerful method to construct heterocycles. Examples of such a strategy are proposed along with the formation of various heterocycles relying on homolytic substitution at sulfur, phosphorus and selenium. Additionally free-radical functionalization of reactive functional groups including isonitriles, isothiocyanates and related unsaturated systems which offer a straightforward route towards useful aromatic and non-aromatic heterocycles are discussed. Finally, as metals are able to trigger single electron transfer both in reductive and oxidative modes this provides another possibility for the synthesis of heterocycles. Significant research efforts have focused on the use of samarium, copper and other metals to access a broad variety of heterocycles in a single pot process, starting from readily available raw material. Examples and mechanistic insights are discussed by experts in this area.
Book Synopsis Streamlining Free Radical Green Chemistry by : V. Tamara Perchyonok
Download or read book Streamlining Free Radical Green Chemistry written by V. Tamara Perchyonok and published by Royal Society of Chemistry. This book was released on 2012 with total page 804 pages. Available in PDF, EPUB and Kindle. Book excerpt: This practical, concise guide showcases the sustainable methods offered by green free radical chemistry and summarizes the fundamental science involved.
