Reagents, Auxiliaries, and Catalysts for C-C Bond Formation

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 0471979244
Total Pages : 772 pages
Book Rating : 4.4/5 (719 download)

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Book Synopsis Reagents, Auxiliaries, and Catalysts for C-C Bond Formation by : Robert M. Coates

Download or read book Reagents, Auxiliaries, and Catalysts for C-C Bond Formation written by Robert M. Coates and published by John Wiley & Sons. This book was released on 1999-07-09 with total page 772 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Reagents for Organic Synthesis Reagents, Auxiliaries and Catalysts for C-C Bond Formation Robert M. Coates and Scott E. Denmark The University of Illinois, Urbana, USA Recognising the critical need for bringing a handy reference work that deals with the most popular reagents in synthesis to the laboratory of practising organic chemists, the Editors, of the acclaimed Encyclopedia of Reagents for Organic Synthesis (EROS) have selected the most important and useful reagents employed in contemporary organic synthesis. The Handbook of Reagents for Organic Synthesis; Reagents Auxiliaries and Catalysts for C-C Bond Formation, provides practical and concise information on a diverse group of reagents. To familiarise the user with the spectrum of reagents contained within this volume, the editors have subdivided more than 200 entries into 22 classes based on their chemical structures and function. The articles, arranged alphabetically, contain all of the information found in EROS as well as expanded reagents listings. In addition, new listings of recently published review articles and monographs are included, as well as relevant Organic Syntheses procedures that deal with either the preparations or reactions of the featured reagents. This comprehensive and well referenced handbook will prove of great value to all practitioners in the field of organic chemistry.

Grignard Reagents and Transition Metal Catalysts

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Author :
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110352729
Total Pages : 295 pages
Book Rating : 4.1/5 (13 download)

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Book Synopsis Grignard Reagents and Transition Metal Catalysts by : Janine Cossy

Download or read book Grignard Reagents and Transition Metal Catalysts written by Janine Cossy and published by Walter de Gruyter GmbH & Co KG. This book was released on 2016-04-25 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1912, the Chemistry Nobel Prize was awarded for the discovery of the so-called Grignard reagents. Nowadays, many transition metal variants are developed to modify reactivity and selectivity of the C–C bond formation reaction. The Grignard reaction is one of the fundamental organometallic reactions, often used in alcohol syntheses. With transition metals like iron, cobalt and nickel or with noble metals like copper, silver and palladium, modern Grignard reagents can be designed in reactivity, selectivity and functional group tolerance. This book, written by international experts, presents an overview on timely Grignard chemistry involving transition metals.

Organozinc Derivatives and Transition Metal Catalysts

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Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 311072894X
Total Pages : 305 pages
Book Rating : 4.1/5 (17 download)

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Book Synopsis Organozinc Derivatives and Transition Metal Catalysts by : Janine Cossy

Download or read book Organozinc Derivatives and Transition Metal Catalysts written by Janine Cossy and published by Walter de Gruyter GmbH & Co KG. This book was released on 2023-05-22 with total page 305 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organozinc reagents are less reactive than Grignard reagents but they are much more chemoselective. Since the Negishi cross-coupling reaction developed by Ei-ichi Negishi, who was awarded the Nobel Price in chemistry in 2010, a number of cross-coupling reactions involving organozinc derivatives and transition metal catalysts (Pd, Ni, Fe, Co, Cu, ...) has been tuned up to form C-C bonds. This book on "Organozinc derivatives and transition metal catalysts" has been written by experts in the field and is a complement to the book entitled "Grignard reagents and transition metal catalysts" (a De Gruyter book, edited by J. Cossy). Grignard reagents or organozinc reagents, that is the question? From a given substrate, what is the best organometallic reagent and the best transition metal to form a C-C bond by using a cross-coupling reaction? The solution might be found in these two books.

Enantioselective C-C Bond Forming Reactions

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Author :
Publisher : Elsevier
ISBN 13 : 044323700X
Total Pages : 338 pages
Book Rating : 4.4/5 (432 download)

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Book Synopsis Enantioselective C-C Bond Forming Reactions by :

Download or read book Enantioselective C-C Bond Forming Reactions written by and published by Elsevier. This book was released on 2023-12-01 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: Enantioselective C-C Bond Forming Reactions: From Metal Complex-, Organo-, and Bio-catalyzed Perspectives, Volume 73 in the Advances in Catalysis series, highlights new advances in the field, with this new volume presenting interesting chapters on topics such as An introduction to Chirality, Metal-catalyzed stereoselective C-C-bond forming reactions, Enantioselective C-C bond forming reactions promoted by organocatalysts based on unnatural amino acid derivatives, Enantioselective C-C bond formation in complex multicatalytic system, Gold-based multicatalytic systems for enantioselective C-C Bond forming reactions, Novel enzymatic tools for C-C bond formation through the development of new-to-nature biocatalysis, and more. Provides the authority and expertise of leading contributors from an international board of authors Presents the latest release in Advances in Catalysis serials Updated release includes the latest information in the field

Chiral Reagents for Asymmetric Synthesis

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 9780470856253
Total Pages : 618 pages
Book Rating : 4.8/5 (562 download)

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Book Synopsis Chiral Reagents for Asymmetric Synthesis by : Leo A. Paquette

Download or read book Chiral Reagents for Asymmetric Synthesis written by Leo A. Paquette and published by John Wiley & Sons. This book was released on 2003-08-01 with total page 618 pages. Available in PDF, EPUB and Kindle. Book excerpt: Derived from the renowned, Encyclopedia of Reagents for Organic Synthesis (EROS), the related editors have created a new handbook which focuses on chiral reagents used in asymmetric synthesis and is designed for the chemist at the bench. This new handbook follows the same format as the Encyclopedia, including an introduction and an alphabetical arrangement of the reagents. As chiral reagents are the key for the successful asymmetric synthesis, choosing the right reagents is essential, in this handy reference the editors give details on how to prepare, store and use the reagents as well as providing key reactions to demonstrate where reagents have been successfully used. Comprehensive information on 226 reagents Covers 64 reagents which were not included in EROS All information in one easy to use volume – at an affordable price All reagents included will be added to e-EROS – please visit the site where you can gain access to over 50,000 reactions and 3,800 of the most frequently consulted reagents. Visit: www.interscience.wiley.com/eros

Metal Catalyzed Reductive C-C Bond Formation

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3540728791
Total Pages : 272 pages
Book Rating : 4.5/5 (47 download)

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Book Synopsis Metal Catalyzed Reductive C-C Bond Formation by : Michael J Krische

Download or read book Metal Catalyzed Reductive C-C Bond Formation written by Michael J Krische and published by Springer Science & Business Media. This book was released on 2007-10-05 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by numerous experts

Oxidative Cross-Coupling Reactions

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Publisher : John Wiley & Sons
ISBN 13 : 3527336885
Total Pages : 243 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Oxidative Cross-Coupling Reactions by : Aiwen Lei

Download or read book Oxidative Cross-Coupling Reactions written by Aiwen Lei and published by John Wiley & Sons. This book was released on 2016-11-14 with total page 243 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first handbook on this emerging field provides a comprehensive overview of transition metal-catalyzed coupling reactions in the presence of an oxidant. Following an introduction to the general concept and mechanism of this reaction class, the team of authors presents chapters on C-C cross-coupling reactions using organometallic partners, C-Heteroatom bond forming reactions via oxidative couplings, and C-H couplings via C-H activation. The text also covers such groundbreaking topics as recent achievements in the fields of C-C and C-X bond formation reactions as well as C-H activation involving oxidative couplings. With its novel and concise approach towards important building blocks in organic chemistry and its focus on synthetic applications, this handbook is of great interest to all synthetic chemists in academia and industry alike.

Solvents as Reagents in Organic Synthesis

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 352734196X
Total Pages : 552 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Solvents as Reagents in Organic Synthesis by : Xiao-Feng Wu

Download or read book Solvents as Reagents in Organic Synthesis written by Xiao-Feng Wu and published by John Wiley & Sons. This book was released on 2018-01-03 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by highly renowned and experienced authors, this is the only reference on the application of solvents as reagents. Clearly structured, the text describes various methods for the activation and reaction of these small molecules, highlighting the synthetic opportunities as well as process-oriented advantages. To this end, all relevant types of solvents are covered separately and emphasized with numerous synthetic examples, while taking care to explain applications so as to avoid undesired side reactions. The result is a unique resource for every synthetic chemist and reaction engineer in industry and academia working on the methodical optimization of synthetic transformations.

Cross-Coupling Reactions

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Author :
Publisher : Springer
ISBN 13 : 354045313X
Total Pages : 248 pages
Book Rating : 4.5/5 (44 download)

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Book Synopsis Cross-Coupling Reactions by : Norio Miyaura

Download or read book Cross-Coupling Reactions written by Norio Miyaura and published by Springer. This book was released on 2003-07-01 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1972, a very powerful catalytic cycle for carbon-carbon bond formation was 2 first discovered by the coupling reaction of Grignard reagents at the sp -carbon. Over the past 30 years, the protocol has been substantially improved and expanded to other coupling reactions of Li,B,N,O,Al,Si,P,S,Cu,Mn,Zn,In,Sn, and Hg compounds. These reactions provided an indispensable and simple methodology for preparative organic chemists. Due to the simplicity and rel- bility in the carbon-carbon, carbon-heteroatom, and carbon-metalloid bo- formations,as well as high efficiency of the catalytic process,the reactions have been widely employed by organic chemists in various fields. Application of the protocol ranges from various syntheses of complex natural products to the preparation of biologically relevant molecules including drugs, and of sup- molecules, and to functional materials. The reactions on solid surfaces allow robot synthesis and combinatorial synthesis. Now, many organic chemists do not hesitate to use transition metal complexes for the transformation of org- ic molecules. Indeed, innumerable organic syntheses have been realized by the catalyzed reactions of transition metal complexes that are not achievable by t- ditional synthetic methods. Among these, the metal-catalyzed cross-coupling reactions have undoubtedly contributed greatly to the development of such a new area of “metal-catalyzed organic syntheses”. An excellent monograph for the cross-coupling reactions and other met- catalyzed C-C bond-forming reactions recently appeared in Metal-catalyzed Cross-coupling Reactions (Wiley-VCH,1998).

C-X Bond Formation

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Author :
Publisher : Springer
ISBN 13 : 3642120733
Total Pages : 187 pages
Book Rating : 4.6/5 (421 download)

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Book Synopsis C-X Bond Formation by : Arkadi Vigalok

Download or read book C-X Bond Formation written by Arkadi Vigalok and published by Springer. This book was released on 2010-06-30 with total page 187 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: Kilian Muñiz: Transition Metal Catalyzed Electrophilic Halogenation of C-H bonds in alpha-Position to Carbonyl Groups; Arkadi Vigalok * and Ariela W Kaspi: Late Transition Metal-Mediated Formation of Carbon-Halogen Bonds; Paul Bichler and Jennifer A. Love*: Organometallic Approaches to Carbon-Sulfur Bond Formation; David S. Glueck: Recent Advances in Metal-Catalyzed C-P Bond Formation; Andrei N. Vedernikov: C-O Reductive Elimination from High Valent Pt and Pd Centers; Lukas Hintermann: Recent Developments in Metal-Catalyzed Additions of Oxygen Nucleophiles to Alkenes and Alkynes; Moris S. Eisen: Catalytic C-N, C-O and C-S bond formation promoted by organoactinide complexes.

Copper-Mediated Cross-Coupling Reactions

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 1118690478
Total Pages : 682 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis Copper-Mediated Cross-Coupling Reactions by : Gwilherm Evano

Download or read book Copper-Mediated Cross-Coupling Reactions written by Gwilherm Evano and published by John Wiley & Sons. This book was released on 2013-09-23 with total page 682 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing comprehensive insight into the use of copper in cross-coupling reactions, Copper-Mediated Cross-Coupling Reactions provides a complete up-to-date collection of the available reactions and catalytic systems for the formation of carbon-heteroatom and carbon-carbon bonds. This essential reference covers a broad scope of copper-mediated reactions, their variations, key advances, improvements, and an array of academic and industrial applications that have revolutionized the field of organic synthesis. The text also discusses the mechanism of these transformations, the use of copper as cost-efficient alternative to palladium, as well as recently developed methods for conducting copper-mediated reactions with supported catalysts.

Homogeneous Catalysis for Unreactive Bond Activation

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Publisher : John Wiley & Sons
ISBN 13 : 1118788990
Total Pages : 648 pages
Book Rating : 4.1/5 (187 download)

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Book Synopsis Homogeneous Catalysis for Unreactive Bond Activation by : Zhang-Jie Shi

Download or read book Homogeneous Catalysis for Unreactive Bond Activation written by Zhang-Jie Shi and published by John Wiley & Sons. This book was released on 2014-10-17 with total page 648 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive overview of different catalytic reactions applied to the activation of chemical bonds. Each of the seven chapters covers key C-X classes where carbon is combined with another element: chlorine, fluorine, nitrogen, sulfur, oxygen, hydrogen, and carbon. The first part of the book discusses homogeneous catalysis in the activation and transformation of C-Cl and C-F, highlighting their basic activation modes, cross-coupling, and intensive mechanisms. The second part of the book focuses on C-N, C-S, and C-O bonds, mentioning their catalytic pathways. Finally, C-H and C-C bonds, their activation, chemical transformations, and applicability are covered. Overall, the book presents methodologies that can be applied to the efficient synthesis of drug molecules and fine chemicals. Through their presentation, the authors show that synthetic chemistry can be done in greener ways that limit hazards and pollution.

Chiral Reagents for Asymmetric Synthesis

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Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 616 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Chiral Reagents for Asymmetric Synthesis by : Leo A. Paquette

Download or read book Chiral Reagents for Asymmetric Synthesis written by Leo A. Paquette and published by John Wiley & Sons. This book was released on 1999 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt: [1] Reagents, auxiliaries, and catalysts for C-C bond formation / edited by Robert M. Coates and Scott E. Denmark -- [2] Oxidizing and reducing agents / edited by Steven D. Burke and Rick L. Danheiser -- [3] Acidic and basic reagents / edited by Hans J. Reich and James H. Rigby -- [4] Activating agents and protecting groups / edited by Anthony J. Pearson and William R. Roush -- [5] Chiral reagents for asymmetric synthesis / edited by Leo A. Paquette -- [6] Reagents for high-throughput solid-phase and solution-phase organic synthesis / edited by Peter Wipf -- [7] Reagents for glycosides, nucleotide and peptide synthesis / edited by David Crich -- [8] Reagents for direct functionalization of C-H bonds /edited by Philip L. Fuchs -- [9] Fluorine-containing reagents / edited by Leo A. Paquette -- [10] Catalyst components for coupling reactions / edited by Gary Molander -- [11] Reagents for radical and radical ion chemistry / edited by David Crich -- [12] Sulfur-containing reagents.

C-H and C-X Bond Functionalization

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Author :
Publisher : Royal Society of Chemistry
ISBN 13 : 1849737169
Total Pages : 350 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis C-H and C-X Bond Functionalization by : Xavi Ribas

Download or read book C-H and C-X Bond Functionalization written by Xavi Ribas and published by Royal Society of Chemistry. This book was released on 2013-05-24 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cross-coupling reactions involving C-H and C-X bond functionalisation are commonplace in natural product synthesis and natural products, therapeutic agents, biological probes, and advanced materials. Much attention has been given to understanding the mechanistic strategies used to achieve this, making this a hot topic in recent years. In this edited book, contributions from across the globe examine these strategies, with a particular focus on palladium and copper, as well as iron – an emerging element in this field. Reviewing the recent literature, the book presents an in-depth understanding of the field, guiding the reader to achieving the best synthetic strategies for aromatic functionalisation. Organic and Organometallic chemists, as well as natural product and pharmaceutical scientists, will find this an essential guide to a major transformation currently underway in synthetic chemistry.

Group 4 Metallocene Compounds: Reagents and Catalysts in Carbon-carbon Bond Forming Reactions

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Author :
Publisher :
ISBN 13 :
Total Pages : 366 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Group 4 Metallocene Compounds: Reagents and Catalysts in Carbon-carbon Bond Forming Reactions by : Dan Bergen Millward

Download or read book Group 4 Metallocene Compounds: Reagents and Catalysts in Carbon-carbon Bond Forming Reactions written by Dan Bergen Millward and published by . This book was released on 1999 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Fieser and Fieser's Reagents for Organic Synthesis

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 9788126515127
Total Pages : 614 pages
Book Rating : 4.5/5 (151 download)

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Book Synopsis Fieser and Fieser's Reagents for Organic Synthesis by : Mary Fieser

Download or read book Fieser and Fieser's Reagents for Organic Synthesis written by Mary Fieser and published by John Wiley & Sons. This book was released on 1986 with total page 614 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Amination and Formation of sp2 C-N Bonds

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Author :
Publisher : Springer
ISBN 13 : 3642405460
Total Pages : 233 pages
Book Rating : 4.6/5 (424 download)

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Book Synopsis Amination and Formation of sp2 C-N Bonds by : Marc Taillefer

Download or read book Amination and Formation of sp2 C-N Bonds written by Marc Taillefer and published by Springer. This book was released on 2013-12-12 with total page 233 pages. Available in PDF, EPUB and Kindle. Book excerpt: Palladium-Catalyzed sp2C–N Bond Forming Reactions: Recent Developments and Applications. Metal-catalyzed C(sp2)-N bond formation.- Recent Developments in Recyclable Copper Catalyst Systems for C−N Bond Forming Cross-Coupling Reactions Using Aryl Halides and Arylboronic Acids. Assembly of N-containing heterocycles via Pd and Cu-catalyzed C-N bond formation reactions. Copper-Catalyzed C(aryl)-N Bond Formation.