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Reactions Of Ruthenium Ii Para Substituted Tetraphenylporphyrin Complexes With Carbon Monoxide And Oxygen
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Book Synopsis Reactions of Ruthenium (II) Para-substituted Tetraphenylporphyrin Complexes with Carbon Monoxide and Oxygen by : Lloyd Barringer
Download or read book Reactions of Ruthenium (II) Para-substituted Tetraphenylporphyrin Complexes with Carbon Monoxide and Oxygen written by Lloyd Barringer and published by . This book was released on 1979 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy Research Abstracts written by and published by . This book was released on 1982 with total page 1696 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactivity of Compounds Containing Ruthenium-carbon, -nitrogen, and -oxygen Bonds by :
Download or read book Synthesis and Reactivity of Compounds Containing Ruthenium-carbon, -nitrogen, and -oxygen Bonds written by and published by . This book was released on 1990 with total page 417 pages. Available in PDF, EPUB and Kindle. Book excerpt: The products and mechanisms of the thermal reactions of several complexes of the general structure (PMe3)4Ru(X)(Y) and (DMPM)2Ru(X)(Y) where X and Y are hydride, aryl, and benzyl groups, have been investigated. The mechanism of decomposition depends critically on the structure of the complex and the medium in which the thermolysis is carried out. The alkyl hydride complexes are do not react with alkane solvent, but undergo C-H activation processes with aromatic solvents by several different mechanisms. Thermolysis of (PMe3)4Ru(Ph)(Me) or (PMe3)4Ru(Ph)2 leads to the ruthenium benzyne complex (PMe3)4Ru([eta]2-C6H4) (1) by a mechanism which involves reversible dissociation of phosphine. In many ways its chemistry is analogous to that of early rather than late organo transition metal complexes. The synthesis, structure, variable temperature NMR spectroscopy and reactivity of ruthenium complexes containing aryloxide or arylamide ligands are reported. These complexes undergo cleavage of a P-C bond in coordinated trimethylphosphine, insertion of CO and CO2 and hydrogenolysis. Mechanistic studies on these reactions are described. The generation of a series of reactive ruthenium complexes of the general formula (PMe3)4Ru(R)(enolate) is reported. Most of these enolates have been shown to bind to the ruthenium center through the oxygen atom. Two of the enolate complexes 8 and 9 exist in equilibrium between the O- and C-bound forms. The reactions of these compounds are reported, including reactions to form oxygen-containing metallacycles. The structure and reactivity of these ruthenium metallacycles is reported, including their thermal chemistry and reactivity toward protic acids, electrophiles, carbon monoxide, hydrogen and trimethylsilane. 243 refs., 10 tabs.
Download or read book Master's Theses Directories written by and published by . This book was released on 1992 with total page 688 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Mechanisms of Inorganic and Organometallic Reactions by : M.V. Twigg
Download or read book Mechanisms of Inorganic and Organometallic Reactions written by M.V. Twigg and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mechanisms of Inorganic and Organometallic Reactions provides an ongoing critical review of the primary literature concerned with mechanisms of inorganic and organometallic reactions. The main focus is on reactions in solution, although solid-state and gas-phase studies are included where they provide relevant mechanistic insight. Each volume covers an eighteen-month literature period, and this, the eighth volume in the series, includes papers published during January 1990 through June 1991. Where appropriate, references to earlier reports and to specific sections in previous volumes are given. Coverage spans the whole area as comprehensively as possible in each volume, and while it is impossible to be absolutely exhaustive, every effort is made to include all of the important published work that is relevant to the elucidation of reaction mechanisms. Numerical data are reported in the units used by the original authors, and they are converted to common units only when comparisons are being made. The successful format of earlier volumes is retained to facilitate tracing progress over several years in a particular topic, and the series now permits this to be done for a twelve-year period. The introduction three volumes ago of computerized techniques to improve cross-referencing in the Index brought positive reader comments, and their use is being continued.
Download or read book Cumulated Index Medicus written by and published by . This book was released on 1977 with total page 928 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Electrochemistry of N4 Macrocyclic Metal Complexes by : Jose H. Zagal
Download or read book Electrochemistry of N4 Macrocyclic Metal Complexes written by Jose H. Zagal and published by Springer. This book was released on 2016-05-03 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt: This new edition describes the state of the art regarding metal complexes of N4-ligands, such as porphyrins and phthalocyanines. Volume 2 focuses on the electro assisted use of N4 complexes as biomimetic models for studying several biological redox processes. It focuses on molecular oxygen transport and catalytic activation to mimic monooxygenase enzymes of the cytochrome P450 in particular. It also examines N4 complexes’ use as catalysts for the oxidative degradation of various types of pollutants (organo-halides, for example) and residual wastes. The remarkable activity of these complexes towards a large number of significantly relevant biological compounds makes them excellent candidates as electrode modifiers for electrochemical sensing. This volume also discusses applications of N4 Macrocyclic Metal Complexes to photoelectrochemistry and photocatalysis, and concludes with an exciting section on Electrosynthesis of N4.
Book Synopsis Dissertation Abstracts International by :
Download or read book Dissertation Abstracts International written by and published by . This book was released on 2004 with total page 858 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Journal of the American Chemical Society by : American Chemical Society
Download or read book Journal of the American Chemical Society written by American Chemical Society and published by . This book was released on 1975 with total page 1062 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the Society are included in v. 1-59, 1879-1937.
Book Synopsis Mechanisms of Inorganic and Organometallic Reactions Volume 7 by : M.V. Twigg
Download or read book Mechanisms of Inorganic and Organometallic Reactions Volume 7 written by M.V. Twigg and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of Mechanisms of Inorganic and Organometallic Reactions is to provide an ongoing critical review of the literature concerned with the mechanisms of reactions of inorganic and organometallic compounds. The main focus is on reactions in solution, although solid state and gas phase studies are included where they provide relevant mechanistic insight. Each volume covers an eighteen month literature period, and this, the seventh volume in the series, deals with papers published during July 1988 through December 1989. Where appropriate, there are references to earlier work, and also to specific sections in previous volumes. Coverage continues to span the whole area as comprehensively as possible in each volume, and although it is impossible be absolutely complete, every effort is made to include all the important for it to published work that is relevant to the elucidation of reaction mechanisms. Numerical data are reported in the units used by the original authors, and they are only converted to common units when making comparisons. The basic format of earlier volumes is retained to facilitate tracing progress over several years in a particular topic; this can now be done for more than a decade worth of research. In the last volume, ligand reactivity of both coordination and organometallic compounds were brought together in Chapter 12, and, in response to numerous positive comments from readers, this arrangement has been maintained. There have been some similar suggestions about oscillating reactions, and this topic may have a separate section in the next volume.
Book Synopsis Organic Reaction Mechanisms 2004 by : A. C. Knipe
Download or read book Organic Reaction Mechanisms 2004 written by A. C. Knipe and published by John Wiley & Sons. This book was released on 2008-05-23 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt: The 40th annual volume in this highly successful and unique series surveying the advances in the understanding of organic reaction mechanisms. In every volume the content is divided in the different classes of organic reaction mechanisms, including: Reaction of Aldehydes and Ketones and their Derivatives Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives Oxidation and Reduction Carbenes and Nitrenes Elimination Reactions Radical Reactions Molecular Rearrangements An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation. As a new service to the reader all reaction mechanisms leading to stereospecific products are highlighted. This reflects the needs of the organic synthetic community with leads to chiral reactions.
Download or read book Research Awards Index written by and published by . This book was released on 1988 with total page 874 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Mechanisms of Inorganic and Organometallic Reactions by :
Download or read book Mechanisms of Inorganic and Organometallic Reactions written by and published by . This book was released on 1983 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Publications of the National Institute of Standards and Technology ... Catalog by : National Institute of Standards and Technology (U.S.)
Download or read book Publications of the National Institute of Standards and Technology ... Catalog written by National Institute of Standards and Technology (U.S.) and published by . This book was released on 1991 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Applied Science & Technology Index by :
Download or read book Applied Science & Technology Index written by and published by . This book was released on 1997 with total page 2948 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Aromatic and Heteroaromatic Chemistry by : C W Bird
Download or read book Aromatic and Heteroaromatic Chemistry written by C W Bird and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 530 pages. Available in PDF, EPUB and Kindle. Book excerpt: Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.
Book Synopsis American Doctoral Dissertations by :
Download or read book American Doctoral Dissertations written by and published by . This book was released on 1985 with total page 696 pages. Available in PDF, EPUB and Kindle. Book excerpt:
