Boron Hydride Chemistry

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Publisher : Elsevier
ISBN 13 : 032314649X
Total Pages : 545 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Boron Hydride Chemistry by : Earl Muetterties

Download or read book Boron Hydride Chemistry written by Earl Muetterties and published by Elsevier. This book was released on 2012-12-02 with total page 545 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron Hydride Chemistry covers the significant contributions of boron hydride research in the subjects of bonding, structure, and stereochemistry. This book contains 12 chapters that illustrate the merging of certain areas of boron hydride chemistry with other disciplines, such as organic, organometallic, and transition metal chemistry. After providing an overview of the general geometric, stereochemical, and dynamic stereochemical features of boron hydrides, this book goes on exploring the bonding theory and theoretical research on boron hydrides, with an emphasis on boron hydrides that have open polyhedral structures. These topics are followed by discussions on gas phase and solution reactions of borane and substituted boranes. A chapter focuses on the chemistry of cations containing boron atoms bonded to hydrogen. The remaining chapters examine the syntheses, structures, bonding, spectral properties, and chemistry of specific boron hydrides, including borazines, closo-boron hydrides, carboranes, icosahedral carboranes, and close- and nido-heteroboranes. Inorganic chemists and researchers, teachers, and undergraduate inorganic chemistry students will find this book invaluable.

Boron Hydrides

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Publisher : Courier Corporation
ISBN 13 : 0486271986
Total Pages : 347 pages
Book Rating : 4.4/5 (862 download)

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Book Synopsis Boron Hydrides by : William N. Lipscomb

Download or read book Boron Hydrides written by William N. Lipscomb and published by Courier Corporation. This book was released on 2013-05-13 with total page 347 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this classic monograph, Nobel Prize–winning chemist William N. Lipscomb elucidates his area of expertise: the general structural principles and reactions of boron hydrides and related compounds. Lipscomb's work appeared only a decade after the structures of boron hydrides were first elucidated and their chemistry formulated into a widely applicable framework. His observations led to a major reconsideration of how atoms bond to form stable molecules. A concise treatment of the many separate parts of the structural theory and its relation to chemistry, this volume begins with an overview of boron hydrides and related structures, progressing to three-center bonds and their applications, molecular orbitals, nuclear magnetic resonance studies of boron hydrides and related compounds, and reactions of the boron hydrides. More than 120 diagrams and figures illustrate a variety of structures.

Reaction Chemistry of Boron Hydrides

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Publisher :
ISBN 13 :
Total Pages : 5 pages
Book Rating : 4.:/5 (227 download)

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Book Synopsis Reaction Chemistry of Boron Hydrides by : H. H. Nelson

Download or read book Reaction Chemistry of Boron Hydrides written by H. H. Nelson and published by . This book was released on 1988 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: We have recently begun a program of boron chemistry in the chemistry division at NRL. Our initial efforts have involved investigations with the room temperature reactions of BH3 and BH with various oxidants and hydrocarbons. In conjunction with the gas phase experimental work, we are pursuing a computational study of the heats of formation of boron compounds and reaction energetics. In addition, there is a compound of the program emphasizing the heterogenous chemistry of boron oxides. (JES).

THE CHEMISTRY OF BORON HYDRIDES AND RELATED HYDRIDES

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Publisher :
ISBN 13 :
Total Pages : 122 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis THE CHEMISTRY OF BORON HYDRIDES AND RELATED HYDRIDES by :

Download or read book THE CHEMISTRY OF BORON HYDRIDES AND RELATED HYDRIDES written by and published by . This book was released on 1960 with total page 122 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Boron Chemistry — 3

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Publisher : Elsevier
ISBN 13 : 1483157903
Total Pages : 128 pages
Book Rating : 4.4/5 (831 download)

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Book Synopsis Boron Chemistry — 3 by : H. Nöth

Download or read book Boron Chemistry — 3 written by H. Nöth and published by Elsevier. This book was released on 2013-10-22 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron Chemistry contains the selected lectures presented at the Third International Meeting on Boron Chemistry held at Munich & Ettal, FRG on July 5-9, 1976. Separating nine papers as chapters, this book discusses effects of orbital vacancies in boron compounds, the aminoboronation reaction, and the cyclic coordination of boron compounds. This text also explores the organoboranes in synthesis and analysis; the synthesis, structure, and chemical reactions of metalloboranes; and studies of the smaller boron hydrides and their derivatives.

Progress in Boron Chemistry

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Publisher : Elsevier
ISBN 13 : 1483224899
Total Pages : 499 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Progress in Boron Chemistry by : H. Steinberg

Download or read book Progress in Boron Chemistry written by H. Steinberg and published by Elsevier. This book was released on 2013-09-03 with total page 499 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress in Boron Chemistry, Volume I is a 10-chapter text that covers the advances in the chemistry of various boron compounds and their applications. The opening chapter deals with the chemistry of compounds containing boron-boron bonds, followed by a brief overview of some aspects of the coordination chemistry of boron. The subsequent chapters discuss the molecular structures of boron hydrides and the chemotherapeutic potential of boron compounds. Other chapters explore the chemistry of other boron compounds, including heteroaromatic boron compounds, organoperoxyboranes, organoboron heterocycles, and boronic acids. The concluding chapter describes the NMR studies of boron compounds. This book is of value to organic, inorganic, and analytical chemists.

THE CHEMISTRY OF BORON HYDRIDES AND RELATED HYDRIDES

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Publisher :
ISBN 13 :
Total Pages : 29 pages
Book Rating : 4.L/5 ( download)

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Book Synopsis THE CHEMISTRY OF BORON HYDRIDES AND RELATED HYDRIDES by : R. W. Parry; R. C. Taylor

Download or read book THE CHEMISTRY OF BORON HYDRIDES AND RELATED HYDRIDES written by R. W. Parry; R. C. Taylor and published by . This book was released on 1958 with total page 29 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Progress in Boron Chemistry

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Publisher : Elsevier
ISBN 13 : 1483146618
Total Pages : 314 pages
Book Rating : 4.4/5 (831 download)

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Book Synopsis Progress in Boron Chemistry by : R. J. Brotherton

Download or read book Progress in Boron Chemistry written by R. J. Brotherton and published by Elsevier. This book was released on 2016-10-12 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress in Boron Chemistry, Volume 2 presents the chemistry and applications of boron and its compounds. This book provides a critical treatment of six areas of boron chemistry, including polyhedral borane ions, carboranes, polymers, hydrogen, metal borides, and elemental boron. Organized into six chapters, this volume begins with an overview of the structures as well as the synthesis of polyhedral borane anions. This text then examines the various types of classes and series of the carboranes. Other chapters consider the relatively intramolecular rearrangements and intramolecular exchange reactions concerning the various closo-carboranes and nido-carboranes. This book discusses as well the formation and the historical significance of a higher boron hydride polymer. The final chapter deals with the structural utilization of boron filaments, which promises to be the first large-scale use for comparatively high purity elemental boron. This book is intended to be suitable for boron chemists, chemical engineers, scientists, and research workers.

Hydrides of Boron and Silicon

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Publisher :
ISBN 13 :
Total Pages : 272 pages
Book Rating : 4.:/5 (5 download)

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Book Synopsis Hydrides of Boron and Silicon by : Alfred Stock

Download or read book Hydrides of Boron and Silicon written by Alfred Stock and published by . This book was released on 1957 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organoborane Chemistry

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Publisher : Elsevier
ISBN 13 : 0323153615
Total Pages : 373 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Organoborane Chemistry by : Thomas Onak

Download or read book Organoborane Chemistry written by Thomas Onak and published by Elsevier. This book was released on 2012-12-02 with total page 373 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organoborane Chemistry deals with the chemistry of organoboranes, with emphasis on compounds containing a carbon-boron bond. The structure and physical properties of organoboranes are discussed, along with the reactions of three-coordinate and four-coordinate organoboranes, organodiboranes, and other organopolyboranes such as organotetraboranes and organopentaborane compounds. Comprised of seven chapters, this book begins with an overview of multistep synthetic or degradative reactions involving organoboron compounds, along with the nomenclature for such compounds. The next chapter examines the structure and physical properties of organoboranes, with emphasis on boron-carbon bond lengths, electronic transitions, and molecular orbital calculations. Subsequent chapters focus on three-coordinate and four-coordinate organoboranes, together with their synthesis, reactions, and properties; hydroboration and dehydroboration of organodiboranes; and the synthesis, reactions, and physical properties of other organopolyboranes such as organotetraboranes, organopentaborane compounds, and organodecaborane compounds. The final chapter is devoted to cyclic boron-carbon systems and the applications of organoboron compounds. This monograph should be of interest to organic chemists.

THE CHEMISTRY OF BORON HYDRIDES AND RELATED HYDRIDES

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Publisher :
ISBN 13 :
Total Pages : 38 pages
Book Rating : 4.L/5 ( download)

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Book Synopsis THE CHEMISTRY OF BORON HYDRIDES AND RELATED HYDRIDES by : R.W. PARRY, R.C. TAYLOR

Download or read book THE CHEMISTRY OF BORON HYDRIDES AND RELATED HYDRIDES written by R.W. PARRY, R.C. TAYLOR and published by . This book was released on 1957 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Final Report The Chemistry of Boron Hydrides and Related Hydrides

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Publisher :
ISBN 13 :
Total Pages : 192 pages
Book Rating : 4.L/5 ( download)

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Book Synopsis Final Report The Chemistry of Boron Hydrides and Related Hydrides by : R.W.Parry, R.C. Taylor, C.E.Nordman, C.Kodana,S.G.Shore,E.R.Alton,J.C.Carter,C.Cluff,A.E.Emery,C.W.Heitsch,C.R.Peters,C.Reimann,J.R.Weaver,M.Yamauchi

Download or read book Final Report The Chemistry of Boron Hydrides and Related Hydrides written by R.W.Parry, R.C. Taylor, C.E.Nordman, C.Kodana,S.G.Shore,E.R.Alton,J.C.Carter,C.Cluff,A.E.Emery,C.W.Heitsch,C.R.Peters,C.Reimann,J.R.Weaver,M.Yamauchi and published by . This book was released on 1959 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Basic Principles of Organic Chemistry

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Publisher :
ISBN 13 : 9780805383218
Total Pages : 1596 pages
Book Rating : 4.3/5 (832 download)

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Book Synopsis Basic Principles of Organic Chemistry by : John D. Roberts

Download or read book Basic Principles of Organic Chemistry written by John D. Roberts and published by . This book was released on 1977 with total page 1596 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.

The chemistry of boron hydrides and related hydrides

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4./5 ( download)

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Book Synopsis The chemistry of boron hydrides and related hydrides by : Robert Walter Parry

Download or read book The chemistry of boron hydrides and related hydrides written by Robert Walter Parry and published by . This book was released on 1957 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Chemistry of Boron and Its Compounds

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Publisher :
ISBN 13 :
Total Pages : 730 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis The Chemistry of Boron and Its Compounds by : Earl L. Muetterties

Download or read book The Chemistry of Boron and Its Compounds written by Earl L. Muetterties and published by . This book was released on 1967 with total page 730 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Electron Deficient Compounds

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Publisher : Springer Science & Business Media
ISBN 13 : 1468460544
Total Pages : 211 pages
Book Rating : 4.4/5 (684 download)

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Book Synopsis Electron Deficient Compounds by : K. Wade

Download or read book Electron Deficient Compounds written by K. Wade and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 211 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is about compounds such as the boron hydrides and associated metal hydrides and alkyls which acquired the label 'electron deficient' when they were thought to contain too few valence electrons to hold together. Though they are now recognized as containing the numbers of bonding electrons appropriate for their structures, the term 'electron deficient' is still commonly applied to many substances that contain too few valence electrons to provide a pair for every pair of atoms close enough to be regarded as covalently bonded. The study of such substances has contributed much to chemistry. Techniques for the vacuum manipulation of volatile substances were devised specifically for their study; developments in valence theory resulted from considerations of their bonding; and the reactivity of several (for example, diborane and complex metal hydrides, lithium and aluminium alkyls) has made them valuable reagents. The purpose of this book is to provide an introduction to the chemistry of these fascinating compounds. The experimental and spectroscopic methods by which they can be studied are outlined, the various types of structure they adopt are described and profusely illustrated, and the relative merits of extended valence bond and simple molecular orbital treatments of their bonding are discussed, with as liberal use of diagrams and as limited recourse to the Greek alphabet as possible. A recurring theme is the importance attached to considerations of molecular sym metry. Their reactions are treated in sufficient detail to show whether these reflect any deficiency of electrons.

A Textbook of Inorganic Chemistry – Volume 1

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Publisher : Dalal Institute
ISBN 13 : 8193872002
Total Pages : 480 pages
Book Rating : 4.1/5 (938 download)

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Book Synopsis A Textbook of Inorganic Chemistry – Volume 1 by : Mandeep Dalal

Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.