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Author : Bernd Giese
Publisher : C R C Press Reprints
ISBN 13 :
Total Pages : 316 pages
Book Rating : 4.3/5 (91 download)
Download or read book Radicals in Organic Synthesis written by Bernd Giese and published by C R C Press Reprints. This book was released on 1986 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Samir Z. Zard
Publisher : Oxford Chemistry Masters
ISBN 13 : 9780198502418
Total Pages : 280 pages
Book Rating : 4.5/5 (24 download)
Download or read book Radical Reactions in Organic Synthesis written by Samir Z. Zard and published by Oxford Chemistry Masters. This book was released on 2003 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt: Samir Zard provides a description of radical reactions and their applications in organic synthesis. This book shows that an with an elementary knowledge of kinetic and some common sense, it is possible to harness radicals into a tremendously powerful tool for solving synthetic problems.
Author : Hideo Togo
Publisher : Elsevier
ISBN 13 : 9780080524252
Total Pages : 270 pages
Book Rating : 4.5/5 (242 download)
Download or read book Advanced Free Radical Reactions for Organic Synthesis written by Hideo Togo and published by Elsevier. This book was released on 2004-01-14 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radical reactions have become increasingly important and a very attractive tool in organic synthesis in the last two decades, due to their powerful, selective, specific, and mild reaction abilities. Advanced Free Radical Reactions for Organic Synthesis reviews information on all types of practical radical reactions, e.g. cyclizations, additions, hydrogen-atom abstractions, decarboxylation reactions. The book usefully provides experimental details for the most important reactions as well as numerous references to the original literature. By covering both the fundamentals and synthetic applications it is therefore suitable for both new and experienced researchers, chemists, biochemists, natural product chemists and graduate students. This title is the definitive guide to radical chemistry for all scientists. Introduces and reviews the use of radicals to perform synthetic transformations Practical details are provided for the most important methods Numerous references to the original literature
Author : D. I. Davies
Publisher : Springer Science & Business Media
ISBN 13 : 3642669220
Total Pages : 181 pages
Book Rating : 4.6/5 (426 download)
Download or read book Free Radicals in Organic Synthesis written by D. I. Davies and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 181 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Jacques Fossey
Publisher :
ISBN 13 :
Total Pages : 328 pages
Book Rating : 4.:/5 (319 download)
Download or read book Free Radicals in Organic Chemistry written by Jacques Fossey and published by . This book was released on 1995-11-09 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radicals constitute the most frequently used class of reaction intermediates in organic chemistry. This study describes the structure and reactivity of free radicals, and explores their role in both natural phenomena and in the design of new reaction pathways.
Author : Derek H. R. Barton
Publisher : Cambridge University Press
ISBN 13 : 9780521445801
Total Pages : 180 pages
Book Rating : 4.4/5 (458 download)
Download or read book Half a Century of Free Radical Chemistry written by Derek H. R. Barton and published by Cambridge University Press. This book was released on 1993-04-15 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the experience over 25 years of the senior author with the chemistry of organic free radicals. It begins with a mechanistic study of industrial importance on the pyrolysis of chlorinated alkanes. It continues with a theory on the biosynthesis of phenolate derived alkaloids involving phenolate radical coupling. There follows 20 years of practical work to prove the theory correct, especially in the case of morphine alkaloids. The book then describes the work on nitrile photolysis (Barton reaction) which involved the invention of new radical chemistry leading to a simple synthesis of the important hormone, aldosterone. There follows a description of the invention of an important new method for the deoxygenation of biologically important molecules, especially sugars and nucleosides, using radical chemistry applied to thiocarbonyl derivatives. Some years later, in a logical extension to carboxylic acids, another new reaction was invented which provides carbon, nitrogen, oxygen and other radicals under mild conditions. A final chapter summarizes recent applications of thiocarbonyl group derived radical reactions by other authors.
Author : Andreas Gansäuer
Publisher : Springer
ISBN 13 : 9783642068416
Total Pages : 0 pages
Book Rating : 4.0/5 (684 download)
Download or read book Radicals in Synthesis I written by Andreas Gansäuer and published by Springer. This book was released on 2010-11-25 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This series presents critical reviews of the present position and future trends in modern chemical research. It contains short and concise reports on chemistry, each written by a world renowned expert. This publication is still valid and useful after five or ten years. Scientists and practitioners in the mentioned fields and in industry will benefit from this series. Further information as well as the electronic version of the whole content is available at: springerlink.com
Author : Dennis P. Curran
Publisher : John Wiley & Sons
ISBN 13 : 3527615229
Total Pages : 294 pages
Book Rating : 4.5/5 (276 download)
Download or read book Stereochemistry of Radical Reactions written by Dennis P. Curran and published by John Wiley & Sons. This book was released on 2008-09-26 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt: As little as a decade ago, radicals were regarded as interesting reactive intermediates with little synthetic use. However, recent results show that radicals have an enormous potential for applications in stereoselective reactions - it's all a matter of knowing what method to use and how to apply it. Three world experts in the field have combined their expertise and present the concepts to understand and even to predict the course of stereoselective radical reactions. In addition, guidelines are established which will enable the readers to plan and carry out their own stereoselective syntheses with radicals. A comprehensive list of references provides an easy access to the primary literature. The Stereochemistry of Radical Reactions is a highly topical introduction to this burgeoning field of research. Both advanced students and researchers active in the field will welcome this book as a source of concepts and ideas.
Author : V. Tamara Perchyonok
Publisher : Royal Society of Chemistry
ISBN 13 : 1849730008
Total Pages : 142 pages
Book Rating : 4.8/5 (497 download)
Download or read book Radical Reactions in Aqueous Media written by V. Tamara Perchyonok and published by Royal Society of Chemistry. This book was released on 2010 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radical Reactions in Aqueous Media provides a step-wise introduction, taking students from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes."--Jacket.
Author : L. Fensterbank
Publisher : Thieme
ISBN 13 : 3132442178
Total Pages : 708 pages
Book Rating : 4.1/5 (324 download)
Download or read book Science of Synthesis: Free Radicals: Fundamentals and Applications in Organic Synthesis 2 written by L. Fensterbank and published by Thieme. This book was released on 2020-12-17 with total page 708 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radically enhance your progress in organic synthesis Radical chemistry has undergone a renaissance in recent years. These two volumes will make the key developments accessible to a broad range of organic chemists. They cover both the generation of radicals and their use. The editors, Prof. Louis Fensterbank and Dr. Cyril Ollivier, are experts in radical chemistry and its application to organic synthesis. Find out all about the generation and use of radicals The two-volume set describes the fundamentals of radical chemistry and its application in organic synthesis. It includes practical examples of the generation of a variety of organic radicals. You will find critically reviewed, reliable and ready-to-use information on the use of radicals in: "single-electron transfer" "hydrogen-atom transfer" radical functionalization and cross-coupling processes. By understanding the fundamental reactivities of radicals, they can be harnessed for atom-efficient and green reactions.
Author : Robin Hicks
Publisher : John Wiley & Sons
ISBN 13 : 111995696X
Total Pages : 628 pages
Book Rating : 4.1/5 (199 download)
Download or read book Stable Radicals written by Robin Hicks and published by John Wiley & Sons. This book was released on 2011-08-02 with total page 628 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stable radicals - molecules with odd electrons which are sufficiently long lived to be studied or isolated using conventional techniques - have enjoyed a long history and are of current interest for a broad array of fundamental and applied reasons, for example to study and drive novel chemical reactions, in the development of rechargeable batteries or the study of free radical reactions in the body. In Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds a team of international experts provide a broad-based overview of stable radicals, from the fundamental aspects of specific classes of stable neutral radicals to their wide range of applications including synthesis, materials science and chemical biology. Topics covered include: triphenylmethyl and related radicals polychlorinated triphenylmethyl radicals: towards multifunctional molecular materials phenalenyls, cyclopentadienyls, and other carbon-centered radicals the nitrogen oxides: persistent radicals and van der Waals complex dimers nitroxide radicals: properties, synthesis and applications the only stable organic sigma radicals: di-tert-alkyliminoxyls. delocalized radicals containing the hydrazyl [R2N-NR] unit metal-coordinated phenoxyl radicals stable radicals containing the thiazyl unit: synthesis, chemical, and materials properties stable radicals of the heavy p-block elements application of stable radicals as mediators in living-radical polymerization nitroxide-catalyzed alcohol oxidations in organic synthesis metal-nitroxide complexes: synthesis and magneto-structural correlations rechargeable batteries using robust but redox-active organic radicals spin labeling: a modern perspective functional in vivo EPR spectroscopy and imaging using nitroxides and trityl radicals biologically relevant chemistry of nitroxides Stable Free Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds is an essential guide to this fascinating area of chemistry for researchers and students working in organic and physical chemistry and materials science.
Author : Michael John Perkins
Publisher : Oxford University Press, USA
ISBN 13 :
Total Pages : 108 pages
Book Rating : 4.F/5 ( download)
Download or read book Radical Chemistry written by Michael John Perkins and published by Oxford University Press, USA. This book was released on 2000 with total page 108 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aimed at students with a grounding in organic chemistry, this Primer presents radical chemistry in a modern context, where reactive radicals are recognized both as mediators of many disease conditions, and as key players in mechanisms of enzyme action.
Author : Philippe Renaud (Prof)
Publisher :
ISBN 13 :
Total Pages : 632 pages
Book Rating : 4.X/5 (4 download)
Download or read book Radicals in Organic Synthesis written by Philippe Renaud (Prof) and published by . This book was released on 2001 with total page 632 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Zory Vlad Todres
Publisher : CRC Press
ISBN 13 : 9781420008395
Total Pages : 496 pages
Book Rating : 4.0/5 (83 download)
Download or read book Ion-Radical Organic Chemistry written by Zory Vlad Todres and published by CRC Press. This book was released on 2008-10-20 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: Consolidating knowledge from a number of disciplines, Ion-Radical Organic Chemistry: Principles and Applications, Second Edition presents the recent changes that have occurred in the field since the publication of the first edition in 2003. This volume examines the formation, transformation, and application of ion-radicals in typical conditions of organic synthesis. Avoiding complex mathematics, the author explains the principles of ion-radical organic chemistry and presents an overview of organic ion-radical reactions. He reviews methods of determining ion-radical mechanisms and controlling ion-radical reactions. Wherever applicable, the text addresses issues relating to ecology and biomedical concerns as well as inorganic participants of the ion-radical organic reactions. After reviewing the nature of organic ion-radicals and their ground-state electronic structure, the book discusses their formation, the relationship between electronic structure and reactivity, mechanism and regulation of reactions, stereochemical aspects, synthetic opportunities, and practical applications. Additional topics include electronic and opto-electronic devices, organic magnets and conductors, lubricants, other materials, and reactions of industrial or biomedical importance. The book concludes by providing an outlook on possible future development in this field. Researchers and practitioners engaged in active work on synthetic or mechanistic organic chemistry and its practical applications will find this text to be invaluable in both its scope and its depth.
Author : Malcolm D. Forbes
Publisher : John Wiley & Sons
ISBN 13 : 9780470584101
Total Pages : 300 pages
Book Rating : 4.5/5 (841 download)
Download or read book Carbon-Centered Free Radicals and Radical Cations written by Malcolm D. Forbes and published by John Wiley & Sons. This book was released on 2010-01-22 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers the most advanced computational and experimental methods for studying carbon-centered radical intermediates With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare fine chemicals and pharmaceutical products. Moreover, it helps readers better understand their role in complex atmospheric reactions and biological systems. Thoroughly up to date, the book highlights the most advanced computational and experimental methods available for studying and using these critically important intermediates. Carbon-Centered Free Radicals and Radical Cations begins with a short history of the field of free radical chemistry, and then covers: A discussion of the relevant theory Mechanistic chemistry, with an emphasis on synthetic utility Molecular structure and mechanism, focusing on computational methods Spectroscopic investigations of radical structure and kinetics, including demonstrations of spin chemistry techniques such as CIDNP and magnetic field effects Free radical chemistry in macromolecules Each chapter, written by one or more leading experts, explains difficult concepts clearly and concisely, with references to facilitate further investigation of individual topics. The authors were selected in order to provide insight into a broad range of topics, including small molecule synthesis, polymer degradation, computational chemistry as well as highly detailed experimental work in the solid, liquid, and gaseous states. This volume is essential for students or researchers interested in building their understanding of the role of carbon-centered radical intermediates in complex systems and how they may be used to develop a broad range of useful products.
Author : Andrew F. Parsons
Publisher : Wiley-Blackwell
ISBN 13 : 9780632052929
Total Pages : 252 pages
Book Rating : 4.0/5 (529 download)
Download or read book An Introduction to Free Radical Chemistry written by Andrew F. Parsons and published by Wiley-Blackwell. This book was released on 2000-11-30 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: The past twenty years has seen an explosion of interest in free radicals, as their pivotal role in both chemistry and biology has come to light. This introductory textbook aims to capture this excitement for advanced level undergraduates, with particular emphasis on the importance of radical reactions in organic synthesis. The book provides a gentle, stepwise introduction to the subject, taking the student from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes, allowing the relevance of the subject to be grasped more easily. Suitable for advanced level undergraduates and postgraduates in chemistry and biochemistry, the book will also be invaluable for research level scientists requiring an update in the area.
Author : E. T. Denisov
Publisher : John Wiley & Sons
ISBN 13 : 0471281832
Total Pages : 904 pages
Book Rating : 4.4/5 (712 download)
Download or read book Handbook of Free Radical Initiators written by E. T. Denisov and published by John Wiley & Sons. This book was released on 2005-01-14 with total page 904 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radical initiators–chemical molecules which easilydecompose into free radicals–serve as reactive intermediatesin synthetic methodologies such as organic and polymer synthesis aswell as in technological processes, oligomerization, networkformation, and kinetic research. The Handbook of Free RadicalInitiators presents an up-to-date account of the physicochemicaldata on radical initiators and reactions of radical generation.Individual chapters include: Dialkyl Peroxides and Hydroperoxides Diacyl Peroxides, Peresters, and Organic Polyoxides Azo-Compounds Bimolecular Reactions of Free Radical Generation by Ozone,Dioxygen, Hydroperoxides, and Haloid Molecules Free Radical Abstraction Reactions Free Radical Addition Reactions Free Radical Recombination and DisproportoinationReactions Professionals and academic researchers in chemical engineering,pharmaceuticals, biotechnology, plastics, and rubbers will find theHandbook of Free Radical Initiators to be a distinguished, vitalresource.
