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Radical Reactions
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Book Synopsis Radical Reactions in Organic Synthesis by : Samir Z. Zard
Download or read book Radical Reactions in Organic Synthesis written by Samir Z. Zard and published by Oxford Chemistry Masters. This book was released on 2003 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt: Samir Zard provides a description of radical reactions and their applications in organic synthesis. This book shows that an with an elementary knowledge of kinetic and some common sense, it is possible to harness radicals into a tremendously powerful tool for solving synthetic problems.
Book Synopsis Stereochemistry of Radical Reactions by : Dennis P. Curran
Download or read book Stereochemistry of Radical Reactions written by Dennis P. Curran and published by John Wiley & Sons. This book was released on 2008-09-26 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt: As little as a decade ago, radicals were regarded as interesting reactive intermediates with little synthetic use. However, recent results show that radicals have an enormous potential for applications in stereoselective reactions - it's all a matter of knowing what method to use and how to apply it. Three world experts in the field have combined their expertise and present the concepts to understand and even to predict the course of stereoselective radical reactions. In addition, guidelines are established which will enable the readers to plan and carry out their own stereoselective syntheses with radicals. A comprehensive list of references provides an easy access to the primary literature. The Stereochemistry of Radical Reactions is a highly topical introduction to this burgeoning field of research. Both advanced students and researchers active in the field will welcome this book as a source of concepts and ideas.
Book Synopsis Advanced Free Radical Reactions for Organic Synthesis by :
Download or read book Advanced Free Radical Reactions for Organic Synthesis written by and published by Elsevier. This book was released on 2004-01-14 with total page 271 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radical reactions have become increasingly important and a very attractive tool in organic synthesis in the last two decades, due to their powerful, selective, specific, and mild reaction abilities. Advanced Free Radical Reactions for Organic Synthesis reviews information on all types of practical radical reactions, e.g. cyclizations, additions, hydrogen-atom abstractions, decarboxylation reactions. The book usefully provides experimental details for the most important reactions as well as numerous references to the original literature. By covering both the fundamentals and synthetic applications it is therefore suitable for both new and experienced researchers, chemists, biochemists, natural product chemists and graduate students. This title is the definitive guide to radical chemistry for all scientists. Introduces and reviews the use of radicals to perform synthetic transformations Practical details are provided for the most important methods Numerous references to the original literature
Book Synopsis Radicals in Organic Synthesis by : Bernd Giese
Download or read book Radicals in Organic Synthesis written by Bernd Giese and published by C R C Press Reprints. This book was released on 1986 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Radical Reactions written by Nathan Price and published by American Chemical Society. This book was released on 2023-03-31 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radical Reactions provides the reader a brief overview of radical reactions, an overview overlooked in most undergraduate chemistry curriculums. Most of the exciting developments in the field of radical and radical ion chemistry came about because someone understood the fundamentals and was able to design new chemistry based upon that understanding. The target audience is individuals who have had at least one semester of organic chemistry.
Book Synopsis Extreme Reactions by : Lenka Bustikova
Download or read book Extreme Reactions written by Lenka Bustikova and published by Cambridge University Press. This book was released on 2019-10-24 with total page 315 pages. Available in PDF, EPUB and Kindle. Book excerpt: Shows that the acquisition of political power and demand for rights by ascendant minority groups in Eastern Europe has precipitated a backlash of radical right mobilization.
Book Synopsis Radical Reactions in Aqueous Media by : V. Tamara Perchyonok
Download or read book Radical Reactions in Aqueous Media written by V. Tamara Perchyonok and published by Royal Society of Chemistry. This book was released on 2010 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radical Reactions in Aqueous Media provides a step-wise introduction, taking students from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes."--Jacket.
Book Synopsis Free Radical Reactions in Medicine by : Janos Feher
Download or read book Free Radical Reactions in Medicine written by Janos Feher and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book aims to provide a concise review of the medical aspects of free radical reactions. Until now, there have been extensive reviews of the subject in a physiological, pathophysiological and biochemical context. Here, however, the authors concentrate on the biology of free radical reactions as relevant to medical practice, emphasizing that the topic is not just a branch of basic science. Consequently, a short introduction on chemical and biological aspects is followed by a detailed discussion of the role played by free radical reactions in the pathogenesis and development of several human diseases and in therapeutic possibilities. The summary of data from the literature is supplemented by the authors' own experimental results. The presentation will help medical researchers to notice so far unknown connections among several diseases and to make them aware of the existance of the so-called "free radical diseases".
Book Synopsis Radical Reactions of Fullerenes and their Derivatives by : B.L. Tumanskii
Download or read book Radical Reactions of Fullerenes and their Derivatives written by B.L. Tumanskii and published by Springer Science & Business Media. This book was released on 2006-04-11 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt: The discovery of fullerenes, species belonging to the electronodeficient polyalkenes with weakly conjugated double bonds, has opened novel opportunities for the radical chemistry. Pioneering study in this field was performed by P. J. Krusic, E. Wasserman, P. N. Keizer, J. R. Morton, and K. F. Preston (Science, 1991, 254, 1184). The fullerenyl radical adducts formed via addition of atoms or free radicals to fullerenes have no analogs in organic chemistry. In fact, radicals in which the unpaired electrons are delocalized over the surface of a sphere or ellipsoid have never been studied before. The unusual character of the fullerenyl radicals is also due to the fact that they occupy a sort of intermediate position between the planar and tetrahedral radicals. Thus, the elucidation of the characteristic features of fullerenyl radicals and their reactivity by EPR spectroscopy, and the comparison of the results with those of quantum-chemical studies are of fundamental importance. Isolation of the products from homolytic reactions of fullerenes in bulk amounts opens the door to large-scale preparation of new organic and organoelement derivatives of including biologically active ones. Radical reactions of fullerenes find wide application in the synthesis of fullere- containing polymers with valuable photophysical characteristics. Ferromagnetism of the complex of with tetra(dimethylamino)ethylene found lends impetus to a search of novel methods for preparation of biradicals one unpaired electron of those is located on the fullerene cage while the other retained by the addend.
Book Synopsis Magnetic Isotope Effect in Radical Reactions by : Kev M. Salikhov
Download or read book Magnetic Isotope Effect in Radical Reactions written by Kev M. Salikhov and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 155 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last two decades it was demonstrated that, in addition to masses and charges, magnetic moments of nuclei are able to influence remarkably chemical reactions. This book presents the physical background (both theoretical and experimental) of the magnetic isotope effects in radical reactions in solutions. Special attention has been paid to the quantitative interpretation of the available experimental data. This book will be useful for physicists, chemists and biologists employing the isotope effect in their investigations as well as for those involved in isotope separation and isotope enrichment projects. Additionally, the magnetic isotope effect appears to be important in geochemistry and cosmochemistry. The book can be recommended for postgraduates and senior undergraduate students.
Book Synopsis Practical Synthetic Organic Chemistry by : Stéphane Caron
Download or read book Practical Synthetic Organic Chemistry written by Stéphane Caron and published by John Wiley & Sons. This book was released on 2020-02-05 with total page 850 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a hands-on guide for the organic chemist. Focusing on the most reliable and useful reactions, the chapter authors provide the information necessary for a chemist to strategically plan a synthesis, as well as repeat the procedures in the laboratory. Consolidates all the key advances/concepts in one book, covering the most important reactions in organic chemistry, including substitutions, additions, eliminations, rearrangements, oxidations, reductions Highlights the most important reactions, addressing basic principles, advantages/disadvantages of the methodology, mechanism, and techniques for achieving laboratory success Features new content on recent advances in CH activation, photoredox and electrochemistry, continuous chemistry, and application of biocatalysis in synthesis Revamps chapters to include new and additional examples of chemistry that have been demonstrated at a practical scale
Book Synopsis Handbook of Free Radical Initiators by : E. T. Denisov
Download or read book Handbook of Free Radical Initiators written by E. T. Denisov and published by John Wiley & Sons. This book was released on 2005-01-14 with total page 903 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radical initiators–chemical molecules which easily decompose into free radicals–serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: Dialkyl Peroxides and Hydroperoxides Diacyl Peroxides, Peresters, and Organic Polyoxides Azo-Compounds Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules Free Radical Abstraction Reactions Free Radical Addition Reactions Free Radical Recombination and Disproportoination Reactions Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.
Book Synopsis Carbon-Centered Free Radicals and Radical Cations by : Malcolm D. Forbes
Download or read book Carbon-Centered Free Radicals and Radical Cations written by Malcolm D. Forbes and published by John Wiley & Sons. This book was released on 2010-01-22 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers the most advanced computational and experimental methods for studying carbon-centered radical intermediates With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare fine chemicals and pharmaceutical products. Moreover, it helps readers better understand their role in complex atmospheric reactions and biological systems. Thoroughly up to date, the book highlights the most advanced computational and experimental methods available for studying and using these critically important intermediates. Carbon-Centered Free Radicals and Radical Cations begins with a short history of the field of free radical chemistry, and then covers: A discussion of the relevant theory Mechanistic chemistry, with an emphasis on synthetic utility Molecular structure and mechanism, focusing on computational methods Spectroscopic investigations of radical structure and kinetics, including demonstrations of spin chemistry techniques such as CIDNP and magnetic field effects Free radical chemistry in macromolecules Each chapter, written by one or more leading experts, explains difficult concepts clearly and concisely, with references to facilitate further investigation of individual topics. The authors were selected in order to provide insight into a broad range of topics, including small molecule synthesis, polymer degradation, computational chemistry as well as highly detailed experimental work in the solid, liquid, and gaseous states. This volume is essential for students or researchers interested in building their understanding of the role of carbon-centered radical intermediates in complex systems and how they may be used to develop a broad range of useful products.
Book Synopsis Liquid-Phase Reaction Rate Constants by : E. T. Denisov
Download or read book Liquid-Phase Reaction Rate Constants written by E. T. Denisov and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 782 pages. Available in PDF, EPUB and Kindle. Book excerpt: The past 25 years in chemical kinetics have seen major advances in studyiqg the mechanisms of complex chemical re actions, in particular free radical reactions. Many differ ent methods have been developed for quantitative studies of elementary chemical reactions. Thousands of rate constants have been measured, for hundreds of diverse chemical reac tions. It is becoming more and more difficult for the chemist to orient himself in the voluminous and rapidly growing liter ature of chemical reaction kinetics. This leads to major expenditures of time in searching out, collecting. and eval uating quantitative kinetic data; to unnecessary repetition (duplication) of research; and to a situation in which the rich material already accumulated in the field of chemical kinetics is very often not fully utilized in comparing, interpreting, and analyzing new experimental data. There is a pressing need for the creation of a series of handbooks on reaction rate constants. Such work was begun several years ago at the initiative of V. N. Kondrat'ev, and is now going forward under his direction at the Institute of Chemical Physics of the USSR Academy of Sciences. This book is devoted to liquid-phase, homolytic reactions. Part One contains data on monomolecular reactions in which molecules decompose to form radicals, as well as data on bi molecular and trimolecular reactions that form free radicals.
Book Synopsis Handbook of Radical Polymerization by : Krzysztof Matyjaszewski
Download or read book Handbook of Radical Polymerization written by Krzysztof Matyjaszewski and published by John Wiley & Sons. This book was released on 2002-08-08 with total page 934 pages. Available in PDF, EPUB and Kindle. Book excerpt: * Provides a concise source of information on synthetic techniques, purification, and characterization methods for free-radical polymers. * Presents information on future trends in the synthesis of free-radical polymers.
Book Synopsis Half a Century of Free Radical Chemistry by : Derek H. R. Barton
Download or read book Half a Century of Free Radical Chemistry written by Derek H. R. Barton and published by Cambridge University Press. This book was released on 1993-04-15 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the experience over 25 years of the senior author with the chemistry of organic free radicals. It begins with a mechanistic study of industrial importance on the pyrolysis of chlorinated alkanes. It continues with a theory on the biosynthesis of phenolate derived alkaloids involving phenolate radical coupling. There follows 20 years of practical work to prove the theory correct, especially in the case of morphine alkaloids. The book then describes the work on nitrile photolysis (Barton reaction) which involved the invention of new radical chemistry leading to a simple synthesis of the important hormone, aldosterone. There follows a description of the invention of an important new method for the deoxygenation of biologically important molecules, especially sugars and nucleosides, using radical chemistry applied to thiocarbonyl derivatives. Some years later, in a logical extension to carboxylic acids, another new reaction was invented which provides carbon, nitrogen, oxygen and other radicals under mild conditions. A final chapter summarizes recent applications of thiocarbonyl group derived radical reactions by other authors.
Book Synopsis Reactive Intermediate Chemistry by : Robert A. Moss
Download or read book Reactive Intermediate Chemistry written by Robert A. Moss and published by John Wiley & Sons. This book was released on 2004-01-07 with total page 1088 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactive Intermediate Chemistry presents a detailed and timely examination of key intermediates central to the mechanisms of numerous organic chemical transformations. Spectroscopy, kinetics, and computational studies are integrated in chapters dealing with the chemistry of carbocations, carbanions, radicals, radical ions, carbenes, nitrenes, arynes, nitrenium ions, diradicals, etc. Nanosecond, picosecond, and femtosecond kinetic realms are explored, and applications of current dynamics and electronic structure calculations are examined. Reactive Intermediate Chemistry provides a deeper understanding of contemporary physical organic chemistry, and will assist chemists in the design of new reactions for the efficient synthesis of pharmaceuticals, fine chemicals, and agricultural products. Among its features, this authoritative volume is: Edited and authored by world-renowned leaders in physical organic chemistry. Ideal for use as a primary or supplemental graduate textbook for courses in mechanistic organic chemistry or physical chemistry. Enhanced by supplemental reading lists and summary overviews in each chapter.
