Quantum Dynamics and Magneto-structural Correlations in Molecule Based Magnets

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Publisher :
ISBN 13 : 9781124330099
Total Pages : 890 pages
Book Rating : 4.3/5 (3 download)

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Book Synopsis Quantum Dynamics and Magneto-structural Correlations in Molecule Based Magnets by : Christopher Craig Beedle

Download or read book Quantum Dynamics and Magneto-structural Correlations in Molecule Based Magnets written by Christopher Craig Beedle and published by . This book was released on 2010 with total page 890 pages. Available in PDF, EPUB and Kindle. Book excerpt: The synthesis and study of magnetic nanostructures is of both intense scientific and technological interest. A single-molecule magnet (SMM) is a molecular nanomagnet that can be magnetized as a result of having a large spin ground state that experiences appreciable magnetoanisotropy, which leads to a thermodynamic barrier between "spin-up" and "spin-down" orientations. The monodisperse nature (same size, shape and anisotropy) of SMMs permits detailed studies of the magnetization and quantum dynamics of nanomagnets. The discovery of SMMs permitted, for the first time, detailed study of quantum effects associated with nanomagnets. The magnetic and quantum properties of these complexes is heavily dictated by molecular and crystal symmetry, and paramount to employing these systems as devices is a need to thoroughly understand and control environmental factors that govern their magnetization and quantum dynamics. To some extent this can be achieved by changing or eliminating co-crystallized solvate molecules and interchanging coordinated peripheral ligands. Magnetic and thermodynamic studies were carried out on a high symmetry system that exhibits a large spin ground state (S =51/2), a preferred orientation in an applied magnetic field, and slow magnetization relaxation dynamics. Strong competing magnetic exchange coupling between paramagnetic copper and manganese ions, in conjunction with high symmetry, gives rise to appreciable spin-frustration and geometric-frustration. These correlated effects lead to slow magnetization relaxation behavior. Detailed magnetization and thermodynamic studies were performed on a series of tetranuclear nickel complexes that exhibit fast magnetization tunneling and magnetic ordering. Magnetic ordering is a collective process that should drastically suppress or terminate quantum tunneling processes. It is revealed that even in an ordered state, the molecules within the crystal lattice act as single domains, thus, molecules quickly switch between magnetic ordering and single-domain quantum tunneling. A series/family of multifunctional tetranuclear manganese SMMs (magnetic and photoluminescent) were synthesized that systematically differ in co-crystallized solvate molecules and peripheral organic ligands to study magneto-structural correlation effects and quantum tunneling of magnetization. The goal is to couple emissive excited states to the magnetic moment of the SMM, which may allow, for the first time, detailed study of quantum dynamics on a 10−9-10−12s time scale.

Magneto-Structural Correlations in Exchange Coupled Systems

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Publisher : Springer
ISBN 13 :
Total Pages : 632 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Magneto-Structural Correlations in Exchange Coupled Systems by : R.D. Willett

Download or read book Magneto-Structural Correlations in Exchange Coupled Systems written by R.D. Willett and published by Springer. This book was released on 1985 with total page 632 pages. Available in PDF, EPUB and Kindle. Book excerpt: The area of magnetic interactions in solids has been of technical importance and academic interest for several decades. The concept of superexchange was introduced in solid state physics in order to correlate observed magnetic behavior with electronic and crystal structure in simple inorganic systems like ferrites. These ideas were usually cast in terms of valence bond arguments and applied to high synmetry situations. In the past decade, inorganic chemists have been active in the characterization of the magnetic behavior of a wide range of transition metal polymers and clusters. In a few instances, it has been possible to deduce simple magnetic-structural correla tions for structural changes involving variation of a structural parameter over a rather limited range. Simul taneously, superexchange arguments have been recast in the language of chemistry and have provided the basis for the interpretation of these correlations on a molecular level. However, as of yet, the range of successful application of these principles has been quite limited. Thus, there was a timely need to bring together the people active in this area to discuss approaches and ideas that can help bring this area of research to maturity.

Research Frontiers in Magnetochemistry

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Publisher : World Scientific
ISBN 13 : 9789810212469
Total Pages : 428 pages
Book Rating : 4.2/5 (124 download)

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Book Synopsis Research Frontiers in Magnetochemistry by : Charles J. O'Connor

Download or read book Research Frontiers in Magnetochemistry written by Charles J. O'Connor and published by World Scientific. This book was released on 1993 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the past 25 years, there have been many advances in the understanding of magnetic phenomena in molecular systems. For example, a variety of low-dimensional materials, and many new ferromagnetic, antiferromagnetic, and ferrimagnetic systems have been synthesized and analyzed; metal cluster compounds that exhibit magnetic exchange have been examined; new orbital overlap theories have been proposed to explain magneto-structural correlations in exchange coupled systems; and efforts directed toward the preparation of an organic ferromagnetic material have produced new and interesting compounds. There have also been many advances in the use of magnetism as a probe of inorganic biomolecules.This volume brings together reviews of current research in magnetochemistry that are written by the world's leading researchers in the fields of chemistry, physics, materials science, and magnetism. It contains comprehensive and in-depth reviews that describe some of the current activities of these scientists and their research and lays the foundation for future research endeavors.

The controlled molecular magnetism of mono-, bi- and polynuclear complexes based on hydrazones, azomethenes and its analogues” (“Управляемый молекулярный магнетизм моно-, би- и полиядерных комплексов на основе гидразонов, азометинов и их аналогов”)

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Publisher : Litres
ISBN 13 : 5042345744
Total Pages : 240 pages
Book Rating : 4.0/5 (423 download)

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Book Synopsis The controlled molecular magnetism of mono-, bi- and polynuclear complexes based on hydrazones, azomethenes and its analogues” (“Управляемый молекулярный магнетизм моно-, би- и полиядерных комплексов на основе гидразонов, азометинов и их аналогов”) by : Владимир Луков

Download or read book The controlled molecular magnetism of mono-, bi- and polynuclear complexes based on hydrazones, azomethenes and its analogues” (“Управляемый молекулярный магнетизм моно-, би- и полиядерных комплексов на основе гидразонов, азометинов и их аналогов”) written by Владимир Луков and published by Litres. This book was released on 2022-01-29 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: The monography “The controlled molecular magnetism of mono-, bi-and polynuclear complexes based on hydrazones, azomethenes and its analogues” represents the encyclopedic edition reflecting the basic experimental – theoretical aspects concerning new scientific area- magnetochemistry of exchange-couple systems. Alongside with a statement of fundamental concepts of magnetism including features of isotropic and anisotropic exchange interaction, and the theory of spin transitions, the central part of the monography is devoted to the analysis of magnetochemistry’s opportunities at the description of a structure and properties of bi- and tetranuclear complexes as well as supramolecular architectures based mainly on hydrazones, azomethenes and their analogues. The interrelation between features of an electronic and geometrical structure of complexes and character of exchange effects is considered, the magneto-structural correlations in the important modelling objects for directed design of one, two and threedimensional magneto-ordered structures have been revealed.

Magneto-structural Correlations in Molecular Magnets Containing the S-N Motive

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (128 download)

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Book Synopsis Magneto-structural Correlations in Molecular Magnets Containing the S-N Motive by : Christina Legendre

Download or read book Magneto-structural Correlations in Molecular Magnets Containing the S-N Motive written by Christina Legendre and published by . This book was released on 2021 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The present work aims to investigate mono-metallic cobalt and dysprosium complexes containing the S-N motive and put their potential as competitive single-molecule magnets (SMMs) into perspective. To this purpose, experimental and computational methods are combined to study the best structural conditions that give optimal magnetic properties. The magneto-structural correlations unveiled in this work should help steer further studies towards better performing SMMs....

Magneto-structural Correlations in a Mixed Porphyrin(Cu2+)/trityl Spin System: Magnitude, Sign and Distribution of the Exchange Coupling Constant

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Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (137 download)

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Book Synopsis Magneto-structural Correlations in a Mixed Porphyrin(Cu2+)/trityl Spin System: Magnitude, Sign and Distribution of the Exchange Coupling Constant by : Dinar Abdullin

Download or read book Magneto-structural Correlations in a Mixed Porphyrin(Cu2+)/trityl Spin System: Magnitude, Sign and Distribution of the Exchange Coupling Constant written by Dinar Abdullin and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: Tetrathiatriarylmethyl radicals (TAM or trityl) are receiving increasing attention in various fields of magnetic resonance such as imaging, dynamic nuclear polarization, spin labeling, and, more recently, molecular magnetism and quantum information technology. Here, a trityl radical attached via a phenyl bridge to a copper(II)tetraphenylporphyrin was synthesized, and its magnetic properties studied by multi-frequency continuous-wave electron paramagnetic resonance (EPR) spectroscopy and magnetic measurements. EPR revealed that the electron spin-spin coupling constant J between the trityl and Cu2+ spin centers is ferromagnetic with a magnitude of −2.3 GHz (−0.077 cm−1, urn:x-wiley:09476539:media:chem202203148:chem202203148-math-0001 convention) and a distribution width of 1.2 GHz (0.040 cm−1). With the help of density functional theory (DFT) calculations, the obtained ferromagnetic exchange coupling, which is unusual for para-substituted phenyl-bridged biradicals, could be related to the almost perpendicular orientation of the phenyl linker with respect to the porphyrin and trityl ring planes in the energy minimum, while the J distribution was rationalized by the temperature weighted rotation of the phenyl bridge about the molecular axis connecting both spin centers. This study exemplifies the importance of molecular dynamics for the homogeneity (or heterogeneity) of the magnetic properties of trityl-based systems

Magnetism

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Publisher : John Wiley & Sons
ISBN 13 : 3527604502
Total Pages : 395 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Magnetism by : Joel S. Miller

Download or read book Magnetism written by Joel S. Miller and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 395 pages. Available in PDF, EPUB and Kindle. Book excerpt: Combining the contemporary knowledge from widely scattered sources, this is a much-needed and comprehensive overview of the field. In maintaining a balance between theory and experiment, the book guides both advanced students and specialists to this research area. Topical reviews written by the foremost scientists explain recent trends and advances, focusing on the correlations between electronic structure and magnetic properties. The book spans recent trends in magnetism for molecules -- as well as inorganic-based materials, with an emphasis on new phenomena being explored from both experimental and theoretical viewpoints with the aim of understanding magnetism on the atomic scale. The volume helps readers evaluate their own experimental observations and serves as a basis for the design of new magnetic materials. Topics covered include: * Metallocenium Salts of Radical Anion Bis-(dichalcogenate) metalates * Chiral Molecule-Based Magnets * Cooperative Magnetic Behavior in Metal-Dicyanamide Complexes * Lanthanide Ions in Molecular Exchange Coupled Systems * Monte Carlo Simulation * Metallocene-Based Magnets * Magnetic Nanoporous Molecular Materials A unique reference work, indispensable for everyone concerned with the phenomena of magnetism.

Magnetism

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Publisher : John Wiley & Sons
ISBN 13 : 3527605401
Total Pages : 496 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Magnetism by : Joel S. Miller

Download or read book Magnetism written by Joel S. Miller and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: Magnetic phenomena and materials are everywhere. Our understanding of magnetic behavior, once thought to be mature, has enjoyed new impetus from contributions ranging from molecular chemistry, materials chemistry and sciences to solid state physics. New phenomena are explored that open promising perspectives for commercial applications in future - carrying out chemical reactions in magnetic fields is just one of those. The spectrum spans molecule-based - organic, (bio)inorganic, and hybrid - compounds, metallic materials as well as their oxides forming thin films, nanoparticles, wires etc. Reflecting contemporary knowledge, this open series of volumes provides a much-needed comprehensive overview of this growing interdisciplinary field. Topical reviews written by foremost scientists explain the trends and latest advances in a clear and detailed way. By maintaining the balance between theory and experiment, the book provides a guide for both advanced students and specialists to this research area. It will help evaluate their own experimental observations and serve as a basis for the design of new magnetic materials. A unique reference work, indispensable for everyone concerned with the phenomena of magnetism!

Comprehensive Inorganic Chemistry II

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Publisher : Newnes
ISBN 13 : 0080965296
Total Pages : 7694 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Comprehensive Inorganic Chemistry II by :

Download or read book Comprehensive Inorganic Chemistry II written by and published by Newnes. This book was released on 2013-07-23 with total page 7694 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973

Single-Molecule Magnets

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Publisher : John Wiley & Sons
ISBN 13 : 3527343210
Total Pages : 448 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Single-Molecule Magnets by : Malgorzata Holynska

Download or read book Single-Molecule Magnets written by Malgorzata Holynska and published by John Wiley & Sons. This book was released on 2019-02-11 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Concise overview of synthesis and characterization of single molecule magnets Molecular magnetism is explored as an alternative to conventional solid-state magnetism as the basis for ultrahigh-density memory materials with extremely fast processing speeds. In particular single-molecule magnets (SMM) are in the focus of current research, both because of their intrinsic magnetization properties, as well as because of their potential use in molecular spintronic devices. SMMs are fascinating objects on the example of which one can explain many concepts. Single-Molecule Magnets: Molecular Architectures and Building Blocks for Spintronics starts with a general introduction to single-molecule magnets (SMM), which helps readers to understand the evolution of the field and its future. The following chapters deal with the current synthetic methods leading to SMMs, their magnetic properties and their characterization by methods such as high-field electron paramagnetic resonance, paramagnetic nuclear magnetic resonance, and magnetic circular dichroism. The book closes with an overview of radical-bridged SMMs, which have shown application potential as building blocks for high-density memories. Covers a hot topic – single-molecule magnetism is one of the fastest growing research fields in inorganic chemistry and materials science Provides researchers and newcomers to the field with a solid foundation for their further work Single-Molecule Magnets: Molecular Architectures and Building Blocks for Spintronics will appeal to inorganic chemists, materials scientists, molecular physicists, and electronics engineers interested in the rapidly growing field of study.

A Themed Issue of Functional Molecule-based Magnets

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Publisher : MDPI
ISBN 13 : 3039289012
Total Pages : 134 pages
Book Rating : 4.0/5 (392 download)

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Book Synopsis A Themed Issue of Functional Molecule-based Magnets by : Keiichi Katoh

Download or read book A Themed Issue of Functional Molecule-based Magnets written by Keiichi Katoh and published by MDPI. This book was released on 2020-05-29 with total page 134 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research on molecule-based magnetic materials was systematized in the 1980s and expanded rapidly. A Special Issue focusing on molecule-based magnetic substances was published in Magnetochemistry. However, the functionalities of the substances increase daily; therefore, the researchers’ quest is not yet in decline. Research on molecule-based magnetism developed across many fields, including chemistry, physics, material chemistry, and applied physics, and the use of the various functionalities of these molecule-based magnetic substances has greatly influenced research on spin-based devices. In honor of Professor Masahiro Yamashita, who contributed greatly to this field, I have put together a Special Issue that highlights ten groundbreaking articles. The issue is entitled, “A Themed Issue of Functional Molecule-Based Magnets: Dedicated to Professor Masahiro Yamashita on the Occasion of his 65th Birthday”. I wish to thank the authors for their dedicated work, and the referees and editorial staff for the time they invested commenting on the articles.

Molecular Magnets Recent Highlights

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Publisher : Springer Science & Business Media
ISBN 13 : 9783211838914
Total Pages : 234 pages
Book Rating : 4.8/5 (389 download)

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Book Synopsis Molecular Magnets Recent Highlights by : Wolfgang Linert

Download or read book Molecular Magnets Recent Highlights written by Wolfgang Linert and published by Springer Science & Business Media. This book was released on 2003-03-12 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book deals with recent scientific highlights on molecular magnetism in Europe. Molecular magnetism is a new interdisciplinary discipline gathering together chemists and physicists, theoreticians and experimentalists. The book intends to provide the reader with documented answers to many current questions: How can chemists use soft conditions to transform molecules in light and transparent magnets. How does a molecular system can behave as a single molecule magnet. How to combine several functions in the same molecular system. How light can be used to switch molecular magnetic properties. How can molecules be used for ultimate high density information storage or in quantum computing. What kind of methods do physicists develop and use to explore these new properties of matter. What kind of concepts and calculations can be provided for theoreticians to design new objects and to better understand the field and to enlarge its exciting developments.

Introduction to Molecular Magnetism

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Publisher : John Wiley & Sons
ISBN 13 : 3527690565
Total Pages : 520 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Introduction to Molecular Magnetism by : Cristiano Benelli

Download or read book Introduction to Molecular Magnetism written by Cristiano Benelli and published by John Wiley & Sons. This book was released on 2015-04-16 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first introduction to the rapidly growing field of molecular magnetism is written with Masters and PhD students in mind, while postdocs and other newcomers will also find it an extremely useful guide. Adopting a clear didactic approach, the authors cover the fundamental concepts, providing many examples and give an overview of the most important techniques and key applications. Although the focus is one lanthanide ions, thus reflecting the current research in the field, the principles and the methods equally apply to other systems. The result is an excellent textbook from both a scientific and pedagogic point of view.

Single Molecule Toroics

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Publisher : Springer Nature
ISBN 13 : 3031117093
Total Pages : 242 pages
Book Rating : 4.0/5 (311 download)

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Book Synopsis Single Molecule Toroics by : Keith Murray

Download or read book Single Molecule Toroics written by Keith Murray and published by Springer Nature. This book was released on 2022-11-23 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book consists of chapters written by international experts on various aspects of single molecule toroics (SMTs).The chapters cover a broad range of relevant topics and highlight the latest advances performed in the field. An up-to-date overview of the emerging SMT architectures is presented while particular attention is given to not only the magnetism and relaxation effects involved but also to the respective applications in advanced electronics and memory devices. The role that lanthanides play -especially that of dysprosium- is discussed, while a thorough analysis using theoretical/ab initio calculations is provided. Since SMTs have grown out of single molecule magnetism (SMM), it is an expanding and topical subject and the present book will engender excitement and interest amongst chemists, physicists, theoreticians and materials scientists. The volume will be of great interest to researchers and graduates working on this topic and particularly those involved in lanthanide chemistry, magnetism and theory.

The fundamentals of molecular magnetism

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Publisher : Litres
ISBN 13 : 5041884986
Total Pages : pages
Book Rating : 4.0/5 (418 download)

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Book Synopsis The fundamentals of molecular magnetism by : Владимир Луков

Download or read book The fundamentals of molecular magnetism written by Владимир Луков and published by Litres. This book was released on 2019-09-10 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular magnetism occupies a crossing point between two fields of research-materials science and metal biochemistry – and plays an important role in the field of molecular electronics. The “Fundamentals of molecular magnetism” is the textbook to comprehensively address both the experimental and theoretical aspects of the relatively new field of research. It introduces the basic concepts concerning magnetization and magnetic susceptibility, establishes the fundamental equations of molecular magnetism and examines molecules containing a unique magnetic center, including the highspinlow- spin transition compounds. The textbook highlights polymetallic species, reviews the phenomenon of interaction between spin carriers from a theoretical point of view and includes numerous examples throughout to illustrate the topics discussed. An essential part of the textbook is devoted to novel class of magneto active materials- single molecular magnets (SMMs)

Multi Length-Scale Characterisation

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Publisher : John Wiley & Sons
ISBN 13 : 1118683587
Total Pages : 230 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis Multi Length-Scale Characterisation by : Duncan W. Bruce

Download or read book Multi Length-Scale Characterisation written by Duncan W. Bruce and published by John Wiley & Sons. This book was released on 2013-12-04 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume examines important experimental techniques needed to characterise inorganic materials in order to elucidate their properties for practical application. Addressing methods that examine the structures and properties of materials over length scales ranging from local atomic order to long-range order on the meso- and macro-scopic scales, Multi Length-Scale Characterisation contains five detailed chapters: Measurement of Bulk Magnetic Properties Thermal Methods Atomic Force Microscopy Gas Sorption in the Analysis of Nanoporous Solids Dynamic Light Scattering Ideal as a complementary reference work to other volumes in the series (Local Structural Characterisation and Structure from Diffraction Methods) or as an examination of the specific characterisation techniques in their own right, Multi Length-Scale Characterisation is a valuable addition to the Inorganic Materials Series.

Magnetism

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (748 download)

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Book Synopsis Magnetism by : Joel S. Miller

Download or read book Magnetism written by Joel S. Miller and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In the past few years our understanding of magnetic behavior, once thought to be mature, has enjoyed a new impetus from contributions ranging from molecular chemistry, materials chemistry and sciences to solid-state physics. The book spans recent trends in magnetism for molecule - as well as inorganic-based materials, with emphasis on new phenomena being explored from both experimental and theoretical points of view with the aim of understanding magnetism at the atomic scale. Reflecting contemporary knowledge, this is a much-needed and comprehensive overview of the field. Topical reviews written by foremost scientists explain the trends and latest advances in a clear and detailed way, focusing on the correlations between electronic structure and magnetic properties. By maintaining a balance between theory and experiment, the book provides a guide for both advanced students and specialists to this research area. It will help them evaluate their own experimental observations and serve as a basis for the design of new magnetic materials. A unique reference work, indispensable for everyone concerned with the phenomena of magnetism.