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Pushing The Limits Of Acidity And Basicity Of Transition Metal Hydride Complexes Microform Studies Of Acidic Dicationic Dihydrogen Complexes Of Iron Ii And Basic Anionic Hydride Complexes Of Iridium Iii
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Author :Shaun Errick Landau Publisher :National Library of Canada = Bibliothèque nationale du Canada ISBN 13 :9780612459281 Total Pages : pages Book Rating :4.4/5 (592 download)
Book Synopsis Pushing the Limits of Acidity and Basicity of Transition Metal Hydride Complexes [microform]: Studies of Acidic Dicationic Dihydrogen Complexes of Iron (II) and Basic Anionic Hydride Complexes of Iridium (III) by : Shaun Errick Landau
Download or read book Pushing the Limits of Acidity and Basicity of Transition Metal Hydride Complexes [microform]: Studies of Acidic Dicationic Dihydrogen Complexes of Iron (II) and Basic Anionic Hydride Complexes of Iridium (III) written by Shaun Errick Landau and published by National Library of Canada = Bibliothèque nationale du Canada. This book was released on 1999 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Pushing the Limits of Acidity and Basicity of Transition Metal Hydride Complexes, Studies of Acidic Dicationic Dihydrogen Complexes of Iron (II) and Basic Anionic Hydride Complexes of Iridium (III). by :
Download or read book Pushing the Limits of Acidity and Basicity of Transition Metal Hydride Complexes, Studies of Acidic Dicationic Dihydrogen Complexes of Iron (II) and Basic Anionic Hydride Complexes of Iridium (III). written by and published by . This book was released on 1999 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Pushing the Limits of Acidity and Basicity of Transition Metal Hydride Complexes, Studies of Acidic Dicationic Dihydrogen Complexes of Iron (II) and Basic Anionic Hydride Complexes of Iridium (III). by : Shaun Errick Landau
Download or read book Pushing the Limits of Acidity and Basicity of Transition Metal Hydride Complexes, Studies of Acidic Dicationic Dihydrogen Complexes of Iron (II) and Basic Anionic Hydride Complexes of Iridium (III). written by Shaun Errick Landau and published by . This book was released on 1999 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: ['Trans'-Fe(H2)(CO)(dppe)2]2+ (pKa -5) was generated by protonation while [' trans'-Fe(H2)(CO)(depe)2]2+ (pK a -2) was generated using molecular H2. These complexes were characterized in solution but were not isolated. ['Trans'-Fe(BF 4)(CO)(depe)2][BF4] and ['Trans'-Fe(OTf)(CO)(depe) 2][OTf] were isolated and characterized. ['Trans'-FeF(CO)(depe) 2]+ was generated from ['trans'-Fe(BF 4)(CO)(depe)2]+ and characterized in solution but was not isolated. The compounds [K('Q')][IrH4(PR3) 2] ('Q' = 18-crown-6, R = Ph, iPr, Cy; ' Q' = aza-18-crown-6, R = iPr; 'Q' = diaza-18-crown-6, R = Ph, iPr, Cy) were formed in the reactions of IrH5(PR3)2 with KH and 'Q'. The PCy3 compounds were not isolated. In solution [IrH4(PR 3)2]- (R = Ph, Cy) are 'cis' but [IrH4(P'i'Pr3)2] - is a mixture of 'cis' and 'trans' isomers. There is evidence of solution proton-hydride bonding of the aza salts. In the solid state the anion in [K(18-crown-6)][IrH4(Pi Pr3)2] is 'cis' but it is ' trans' in [K(diaza-18-crown-6)][IrH4(PiPr3)2]. [K(diaza-18-crown-6)][IrH4(PR3)2] (R =Ph, iPr) form solid-state chains linked by proton-hydride bonds.
Book Synopsis Transition Metal Hydride Complexes from Protonation Reactions: Formation and Reactivity by : David Wayne Mosley
Download or read book Transition Metal Hydride Complexes from Protonation Reactions: Formation and Reactivity written by David Wayne Mosley and published by . This book was released on 1997 with total page 118 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Characterization and Reactivity of Transition-metal Dihydrogen Complexes of Fe, Ru, and W by : Lori Ruth Ann Stepan Van der Sluys
Download or read book Synthesis, Characterization and Reactivity of Transition-metal Dihydrogen Complexes of Fe, Ru, and W written by Lori Ruth Ann Stepan Van der Sluys and published by . This book was released on 1991 with total page 714 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Hydrides and Dihydrogen Complexes of Metalloporphyrins by : Paul Stephen Wagenknecht
Download or read book Hydrides and Dihydrogen Complexes of Metalloporphyrins written by Paul Stephen Wagenknecht and published by . This book was released on 1991 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transition Metal Hydride Complexes by : Jeffrey M. Sullivan
Download or read book Transition Metal Hydride Complexes written by Jeffrey M. Sullivan and published by . This book was released on 1986 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reduction with Complex Metal Hydrides by : Norman G. Gaylord
Download or read book Reduction with Complex Metal Hydrides written by Norman G. Gaylord and published by . This book was released on 1956 with total page 1076 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transition Metal Hydrides by : Maria Margaret Ludvig
Download or read book Transition Metal Hydrides written by Maria Margaret Ludvig and published by . This book was released on 1987 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Some Transition Metal Hydride Complexes as Catalysts by : P. J. Knowles
Download or read book Some Transition Metal Hydride Complexes as Catalysts written by P. J. Knowles and published by . This book was released on 1970 with total page 199 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Thermodynamic Studies of Hydride Transfer Reactions in Transition Metal Complexes by : Niladri Sarker
Download or read book Thermodynamic Studies of Hydride Transfer Reactions in Transition Metal Complexes written by Niladri Sarker and published by . This book was released on 2001 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Early Main Group Metal Catalysis by : Sjoerd Harder
Download or read book Early Main Group Metal Catalysis written by Sjoerd Harder and published by John Wiley & Sons. This book was released on 2020-04-06 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.
Book Synopsis Molecular Catalysts for Energy Conversion by : Tatsuhiro Okada
Download or read book Molecular Catalysts for Energy Conversion written by Tatsuhiro Okada and published by Springer. This book was released on 2010-11-22 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the past decade the topic of energy and environment has been ackno- edged among many people as a critical issue to be solved in 21st century since the Kyoto Protocol came into e?ect in 1997. Its political recognition was put forward especially at Heiligendamm in 2007, when the e?ect of carbon dioxide emission and its hazard in global climate were discussed and shared univ- sallyascommonknowledge.Controllingtheglobalwarmingintheeconomical framework of massive development worldwide through this new century is a very challenging problem not only among political, economical, or social c- cles but also among technological or scienti?c communities. As long as the humans depend on the combustion of fossil for energy resources, the waste heat exhaustion and CO emission are inevitable. 2 In order to establish a new era of energy saving and environment benign society, which is supported by technologies and with social consensus, it is important to seek for a framework where new clean energy system is inc- porated as infrastructure for industry and human activities. Such a society strongly needs innovative technologies of least CO emission and e?cient en- 2 ergy conversion and utilization from remaining fossil energies on the Earth. Energy recycling system utilizing natural renewable energies and their c- version to hydrogen may be the most desirable option of future clean energy society. Thus the society should strive to change its energy basis, from foss- consuming energy to clean and recycling energy.
Book Synopsis Catalytic Carbonylation Reactions by : Matthias Beller
Download or read book Catalytic Carbonylation Reactions written by Matthias Beller and published by Springer Science & Business Media. This book was released on 2006-09-14 with total page 289 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbonylation reactions are of major importance in both organic and industrial chemistry. Due to the availability, price and reactivity pattern, carbon monoxide is becoming a more and more important building block for fine and bulk chemicals. The major reaction types of carbon monoxide are comprehensively discussed by leading experts from academia and industry. The authors highlight important carbonylation reactions such as hydroformylation, alkoxy-carbonylations, co/olefin-copolymerization, Pauson-Khand reactions and others. They illustrate applications in organic synthesis and give industrial examples. This volume is designed to provide graduate students and researchers with essential information on the use of carbon monoxide in organic synthesis. Therefore, the reader will get a balanced view of this developing and complex subject.
Book Synopsis Biomass Valorization by : Davide Ravelli
Download or read book Biomass Valorization written by Davide Ravelli and published by John Wiley & Sons. This book was released on 2021-05-24 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explore the potential of biomass-based chemicals with this comprehensive new reference from leading voices in the field With the depletion of fossil raw materials a readily ascertainable inevitability, the exploitation of biomass-based renewable derivatives becomes ever more practical and realistic. In Biomass Valorization: Sustainable Methods for the Production of Chemicals, accomplished researchers and authors Davide Ravelli and Chiara Samori deliver a thorough compilation of state-of-the-art techniques and most advanced strategies used to convert biomass into useful building blocks and commodity chemicals. Each chapter in this collection of insightful papers begins by detailing the core components of the described technology, along with a fulsome description of its advantages and limitations, before moving on to a discussion of recent advancements in the field. The discussions are grouped by the processed biomass, such as terrestrial biomass, aquatic biomass, and biomass-deriving waste. Readers will also benefit from the inclusion of: A thorough introduction to the role of biomass in the production of chemicals An exploration of biomass processing via acid, base and metal catalysis, as well as biocatalysis A practical discussion of biomass processing via pyrolysis and thermochemical-biological hybrid processes A concise treatment of biomass processing assisted by ultrasound and via electrochemical, photochemical and mechanochemical means Perfect for chemical engineers, catalytic chemists, biotechnologists, and polymer chemists, Biomass Valorization: Sustainable Methods for the Production of Chemicals will also earn a place in the libraries of environmental chemists and professionals working with organometallics and natural products chemists.
Book Synopsis Alkaline-Earth Metal Compounds by : Sjoerd Harder
Download or read book Alkaline-Earth Metal Compounds written by Sjoerd Harder and published by Springer. This book was released on 2013-07-20 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.
Book Synopsis Metal Catalyzed Cascade Reactions by : Thomas J.J. Müller
Download or read book Metal Catalyzed Cascade Reactions written by Thomas J.J. Müller and published by Springer. This book was released on 2006-06-27 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights cyclization via carbopalladation and acylpalladation and Heck-pericyclic sequences. They discuss p-allyl palladium-based cascade reactions, Michael-type additions as an entry to transition-metal-promoted cyclizative transformations, and sequential or consecutive palladium-catalyzed processes, and show Pauson-Khand cascades, metal-catalyzed cyclizations of acyclic precursors, as well as cascade and sequential ruthenium-catalyzed transformations. This is a comprehensive overview of an exciting and highly dynamic, and innovative methodological concept.
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