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Protic Salt Polymer Membranes
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Download or read book Protic Salt Polymer Membranes written by and published by . This book was released on 2010 with total page 35 pages. Available in PDF, EPUB and Kindle. Book excerpt: This research on proton-containing (protic) salts directly addresses proton conduction at high and low temperatures. This research is unique, because no water is used for proton ionization nor conduction, so the properties of water do not limit proton fuel cells. A protic salt is all that is needed to give rise to ionized proton and to support proton mobility. A protic salt forms when proton transfers from an acid to a base. Protic salts were found to have proton conductivities that are as high as or higher than the best aqueous electrolytes at ambient pressures and comparable temperatures without or with water present. Proton conductivity of the protic salts occurs providing two conditions exist: i) the energy difference is about 0.8 eV between the protic-salt state versus the state in which the acid and base are separated and 2) the chemical constituents rotate freely. The physical state of these proton-conducting salts can be liquid, plastic crystal as well as solid organic and inorganic polymer membranes and their mixtures. Many acids and bases can be used to make a protic salt which allows tailoring of proton conductivity, as well as other properties that affect their use as electrolytes in fuel cells, such as, stability, adsorption on catalysts, environmental impact, etc. During this project, highly proton conducting (~ 0.1S/cm) protic salts were made that are stable under fuel-cell operating conditions and that gave highly efficient fuel cells. The high efficiency is attributed to an improved oxygen electroreduction process on Pt which was found to be virtually reversible in a number of liquid protic salts with low water activity (1% water). Solid flexible non-porous composite membranes, made from inorganic polymer (e.g., 10%indium 90%tin pyrophosphate, ITP) and organic polymer (e.g., polyvinyl pyridinium phosphate, PVPP), were found that give conductivity and fuel cell performances similar to phosphoric acid electrolyte with no need for hydration at ambient pressures. Synthesis and processing of these protic salts into proton-conducting membrane is far from optimized. This protic salt approach has great promise for more improvements in proton conducting membranes for making practical compact, lightweight and inexpensive fuel cells with uses ranging from small electronics (Power = 1 to 100 Watts) to transportation (kiloWatts) to stationary applications (100 kiloWatts). This work clearly showed that proton can be conducted without water using protoic ionic liquids which are Bronsted salts which contain a proton and whose acid and base moieties have pK separated by more than 4 units and less than 14. A key finding is that the base used should be significantly different than the basicity of water or else water displaces the base and an ordinary acid membrane is left behind. This is the case where the acid moiety is sulfonic acid found on perfluorinated polymeric membranes. This PI suggests that a fruitful route for attaining highly proton-conductive stable protic salt membranes is to use the STABLE poly-phosphazene ( -P=N- ) polymer backbone with electrochemically STABLE pendant acid or base units on the phosphorous of poly-phosphazene and with suitable pK so the base is NOT the same pK as water. From this work this should give stable water-free proton conductors which should allow for stable fuel cells with Pt catalysts and possible with non-platinum catalyst for the hydrogen anode and oxygen cathode.
Download or read book Fuel Cells written by Klaus-Dieter Kreuer and published by Springer Science & Business Media. This book was released on 2012-12-14 with total page 795 pages. Available in PDF, EPUB and Kindle. Book excerpt: The expected end of the “oil age” will lead to increasing focus and reliance on alternative energy conversion devices, among which fuel cells have the potential to play an important role. Not only can phosphoric acid and solid oxide fuel cells already efficiently convert today’s fossil fuels, including methane, into electricity, but other types of fuel cells, such as polymer electrolyte membrane fuel cells, have the potential to become the cornerstones of a possible future hydrogen economy. Featuring 21 peer-reviewed entries from the Encyclopedia of Sustainability Science and Technology, Fuel Cells offers concise yet comprehensive coverage of the current state of research and identifies key areas for future investigation. Internationally renowned specialists provide authoritative introductions to a wide variety of fuel cell types, and discuss materials, components, and systems for these technologies. The entries also cover sustainability and marketing considerations, including comparisons of fuel cells with alternative technologies.
Book Synopsis Nanostructured Polymer Membranes, Volume 1 by : Visakh P. M.
Download or read book Nanostructured Polymer Membranes, Volume 1 written by Visakh P. M. and published by John Wiley & Sons. This book was released on 2016-11-18 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is intended to serve as a "one-stop" reference resource for important research accomplishments in the area of nanostructured polymer membranes and their processing and characterizations. It will be a very valuable reference source for university and college faculties, professionals, post-doctoral research fellows, senior graduate students, and researchers from R&D laboratories working in the area of polymer nanobased membranes. The various chapters are contributed by prominent researchers from industry, academia and government/private research laboratories across the globe and comprise an up-to-date record on the major findings and observations in the field.
Book Synopsis Fuel Cell Science by : Andrzej Wieckowski
Download or read book Fuel Cell Science written by Andrzej Wieckowski and published by John Wiley & Sons. This book was released on 2011-02-14 with total page 652 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive survey of theoretical andexperimental concepts in fuel cell chemistry Fuel cell science is undergoing significant development, thanks, in part, to a spectacular evolution of the electrocatalysis concepts, and both new theoretical and experimental methods. Responding to the need for a definitive guide to the field, Fuel Cell Science provides an up-to-date, comprehensive compendium of both theoretical and experimental aspects of the field. Designed to inspire scientists to think about the future of fuel cell technology, Fuel Cell Science addresses the emerging field of bio-electrocatalysis and the theory of heterogeneous reactions in fuel cell science and proposes potential applications for electrochemical energy production. The book is thorough in its coverage of the electron transfer process and structure of the electric double layer, as well as the development of operando measurements. Among other subjects, chapters describe: Recently developed strategies for the design, preparation, and characterization of catalytic materials for fuel cell electrodes, especially for new fuel cell cathodes A wide spectrum of theoretical and computational methods, with?the aim of?developing?new fuel cell catalysis concepts and improving existing designs to increase their performance.? Edited by two leading faculty, the book: Addresses the emerging fields of bio-electrocatalysis for fuel cells and theory of heterogeneous reactions for use in fuel cell catalysis Provides a survey of experimental and theoretical concepts in these new fields Shows the evolution of electrocatalysis concepts Describes the chemical physics of fuel cell reactions Forecasts future developments in electrochemical energy production and conversion Written for electrochemists and electrochemistry graduate students, electrocatalysis researchers, surface and physical chemists, chemical engineers, automotive engineers, and fuel cell and energy-related researchers, this modern compendium can help today's best minds meet the challenges in fuel science technology.
Book Synopsis Polymer Membranes by : T. deV. Naylor
Download or read book Polymer Membranes written by T. deV. Naylor and published by iSmithers Rapra Publishing. This book was released on 1996 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report describes the constitution and application of polymeric membranes in separation processes. The separation processes covered are reverse osmosis and nanofiltration, ultrafiltration, gas separation, pervaporation and ion exchange. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database provides useful references for further reading.
Book Synopsis Prediction of Polymeric Membrane Separation and Purification Performances by : Alexander Anim-Mensah
Download or read book Prediction of Polymeric Membrane Separation and Purification Performances written by Alexander Anim-Mensah and published by Springer. This book was released on 2014-11-21 with total page 64 pages. Available in PDF, EPUB and Kindle. Book excerpt: This brief describes the development of a new model for realistically characterizing solution-diffusion transport mechanisms in polymeric membranes that are used for separation and purification of organic solvents. Polymeric membranes used in these environments, if not selected appropriately, undergo excessive swelling and compaction resulting in lowered performance or membrane destruction in the long-term. This brief describes the relationship between key parameters from a chemical, mechanical and thermodynamic perspective. Moreover, the authors show how this new model points membrane manufacturers, scientists, and engineers towards an understanding of how these key parameters are considered in (1) designing and manufacturing membranes for the right application, (2) designing the right test experiments to determine the long-term membrane behavior in a short time, (3) minimizing the number of experiments to determine a reliable membrane for an application and (4) selecting the right membrane with higher level of certainty. The overall benefits of the model includes saving money and time. A simplified version of the model is included to assist the reader.
Book Synopsis Present Trends in Fuel Cell Technology Development by : N. Rajalakshmi
Download or read book Present Trends in Fuel Cell Technology Development written by N. Rajalakshmi and published by Nova Publishers. This book was released on 2008 with total page 154 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book the authors assess the technology for fuel cells in terms of processes and basic science, materials, applications and infrastructure. Each section is devoted to a particular type of fuel cell technology covering all the aspects of processes, materials, application, technology, challenges and present trends.
Book Synopsis Polymer Membranes in Biotechnology by : Seeram Ramakrishna
Download or read book Polymer Membranes in Biotechnology written by Seeram Ramakrishna and published by World Scientific. This book was released on 2011 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Following an introduction to the general concept of membrane separation in Chapter 1, preparation of polymeric membranes is discussed in Chapter 2. The book then describes in Chapter 3 membrane surface activation, which is a key step in ligand immobilizations. Chapter 4 focuses on ligand immobilization techniques and the organic chemistries behind them. Chapter 5 introduces the application of affinity membrane chromatography Finally, in Chapter 6, membranes used in biosensors and gas sensors, enzymatic membranes used as biosensor, and membrane biosensor for waste water treatment will be discussed. --
Book Synopsis Water and Salt Transport Structure/property Relationships in Polymer Membranes for Desalination and Power Generation Applications by : Geoffrey Matthew Geise
Download or read book Water and Salt Transport Structure/property Relationships in Polymer Membranes for Desalination and Power Generation Applications written by Geoffrey Matthew Geise and published by . This book was released on 2012 with total page 768 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing sustainable supplies of water and energy is a critical global challenge. Polymer membranes dominate desalination and could be crucial to power generation applications, which include reverse osmosis (RO), nanofiltration (NF), forward osmosis (FO), pressure-retarded osmosis (PRO), electrodialysis (ED), membrane capacitive deionization (CDI), and reverse electrodialysis (RED). Improved membranes with tailored water and salt transport properties are required to extend and optimize these technologies. Water and salt transport structure/property relationships provide the fundamental framework for optimizing polymer materials for membrane applications. The water and salt transport and free volume properties of a series of sulfonated styrenic pentablock copolymers were characterized. The polymers' water uptake and water permeability increase with degree of sulfonation, and the block molecular weights could be used to tune water uptake, permeability, and selectivity properties. The presence of fixed charge groups, i.e., sulfonate groups, on the polymer backbone influence the material's salt transport properties. Specifically, the salt permeability increases strongly with increasing salt concentration, and this increase is a result of increases in both salt sorption and diffusivity with salt concentration. The data for the sulfonated polymers, including a sulfonated polysulfone random copolymer, are compared to those for an uncharged polymer to determine the influence of polymer charge on salt transport properties. The sulfonated styrenic pentablock copolymer permeability data are compared to literature data using the water permeability and water/salt selectivity tradeoff relationship. Fundamental transport property comparisons can be made using this relationship. The effect of osmotic de-swelling on the polymers and the transport properties of composite membranes made from sulfonated styrenic pentablock copolymers are also discussed. The sulfonated styrenic pentablock copolymers were exposed to multi-valent ions to determine their effect on the polymer's salt transport properties. Magnesium chloride permeability depends less on upstream salt concentration than sodium chloride permeability, presumably due to stronger association between the sulfonate groups and magnesium compared to sodium ions. Triethylaluminum was used to neutralize the polymer's sulfonic acid functionality and presumably cross-link the polymer. The mechanical, transport, and free volume properties of these aluminum neutralized polymers were studied.
Book Synopsis High Temperature Polymer Electrolyte Membrane Fuel Cells by : Qingfeng Li
Download or read book High Temperature Polymer Electrolyte Membrane Fuel Cells written by Qingfeng Li and published by Springer. This book was released on 2015-10-15 with total page 561 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a comprehensive review of high-temperature polymer electrolyte membrane fuel cells (PEMFCs). PEMFCs are the preferred fuel cells for a variety of applications such as automobiles, cogeneration of heat and power units, emergency power and portable electronics. The first 5 chapters of the book describe rationalization and illustration of approaches to high temperature PEM systems. Chapters 6 - 13 are devoted to fabrication, optimization and characterization of phosphoric acid-doped polybenzimidazole membranes, the very first electrolyte system that has demonstrated the concept of and motivated extensive research activity in the field. The last 11 chapters summarize the state-of-the-art of technological development of high temperature-PEMFCs based on acid doped PBI membranes including catalysts, electrodes, MEAs, bipolar plates, modelling, stacking, diagnostics and applications.
Book Synopsis Proton Exchange Membrane Fuel Cells 7 by :
Download or read book Proton Exchange Membrane Fuel Cells 7 written by and published by The Electrochemical Society. This book was released on 2007 with total page 1581 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Membrane Technologies and Applications by : Kaustubha Mohanty
Download or read book Membrane Technologies and Applications written by Kaustubha Mohanty and published by CRC Press. This book was released on 2011-12-19 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt: Membrane technologies play an increasingly important role in unit operations for resource recovery, pollution prevention, and energy production, as well as environmental monitoring and quality control. They are also key component technologies of fuel cells and bioseparation applications. Membrane Technologies and Applications provides essential data and background information on various dimensions of membrane technologies, with a major focus on their practical application. Membranes of inorganic materials offer cost-effective solutions for simple to complex separation problems. This book is designed for anyone interested in water and wastewater treatment, membrane suppliers, as well as students and academics studying the field.
Book Synopsis Synthetic Polymeric Membranes by : Robert E. Kesting
Download or read book Synthetic Polymeric Membranes written by Robert E. Kesting and published by Wiley-Interscience. This book was released on 1985-10-16 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subject of this book is synthetic polymeric membranes, the thin polymer films in either solid or liquid states which act as semipermeable barriers for gaseous, liquid, or solid permeants.
Book Synopsis Organic-Inorganic Composite Polymer Electrolyte Membranes by : Dr Inamuddin
Download or read book Organic-Inorganic Composite Polymer Electrolyte Membranes written by Dr Inamuddin and published by Springer. This book was released on 2017-05-10 with total page 474 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume explores the latest developments in the area of polymer electrolyte membranes (PEMs) used for high-temperature fuel cells. Featuring contributions from an international array of researchers, it presents a unified viewpoint on the operating principles of fuel cells, various methodologies used for the fabrication of PEMs, and issues related to the chemical and mechanical stabilities of the membranes. Special attention is given to the fabrication of electrospun nanocomposite membranes. The editors have consciously placed an emphasis on developments in the area of fast-growing and promising PEM materials obtained via hygroscopic inorganic fillers, solid proton conductors, heterocyclic solvents, ionic liquids, anhydrous H3PO4 blends, and heteropolyacids. This book is intended for fuel cell researchers and students who are interested in a deeper understanding of the organic–inorganic membranes used in fuel cells, membrane fabrication methodologies, properties and clean energy applications.
Book Synopsis Smart Polymers by : Asit Baran Samui
Download or read book Smart Polymers written by Asit Baran Samui and published by CRC Press. This book was released on 2022-04-26 with total page 323 pages. Available in PDF, EPUB and Kindle. Book excerpt: Smart materials have been produced by conceiving of the idea of materials/systems having a fourth dimension. To match advances in instrumentation, efforts are being made to develop materials, resulting in smart materials with enhanced performance. In nature, the action of stimuli-responsive materials is reversible; this idea has attracted interest for its potential research and industrial applications. The challenge remains how to couple these applications with environmental consciousness. This book presents the basics of smart polymers and describes their current and future applications. This book is different from other books on the subject in that it explores polymer materials’ smart behavior in more depth, covering vibration damping, thermal and electrochemical energy, sensing at trace level, biotechnology, and so on. The 14 chapters in this book cover diverse areas, including: • Photoresponsive polymers that can be manipulated using a specific frequency of light • Designing polymers for vibration damping • Smart manipulations of hydrophobic and super-hydrophobic polymers • Biopolymers, including hydrogels for smart application, drug delivery, and other uses • Smart paints • Self-healing and shape memory polymers • Holography for data storage • Phase change polymers and solid polymer electrolytes for thermal and electrochemical energy • Molecular imprinting polymers for sub-ppm sensing and removal of unwanted materials • Smart textiles, and the concept of advanced textiles This book will be of particular interest to researchers, postgraduates, and industry experts. It offers an extensive introduction to the basics of smart polymers and their possible applications.
Book Synopsis Nanocarbons for Energy Conversion: Supramolecular Approaches by : Naotoshi Nakashima
Download or read book Nanocarbons for Energy Conversion: Supramolecular Approaches written by Naotoshi Nakashima and published by Springer. This book was released on 2018-08-13 with total page 564 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on nanocarbons (carbon nanotubes, graphene, nanoporous carbon, and carbon black) and related materials for energy conversion, including fuel cells (predominately proton exchange membrane fuel cells [PEMFC]), Li-ion batteries, and supercapacitors. Written by a group of internationally recognized researchers, it offers an in-depth review of the structure, properties, and functions of nanocarbons, and summarizes recent advances in the design, fabrication and characterization of nanocarbon-based catalysts for energy applications. As such, it is an invaluable resource for graduate students, academics and industrial scientists interested in the areas of nanocarbons, energy materials for fuel cells, batteries and supercapacitors as well as materials design, and supramolecular science.
Book Synopsis Separators and Membranes for Batteries, Capacitors, Fuel Cells, and Other Electrochemical Systems by : J. Weidner
Download or read book Separators and Membranes for Batteries, Capacitors, Fuel Cells, and Other Electrochemical Systems written by J. Weidner and published by The Electrochemical Society. This book was released on 2009-11 with total page 109 pages. Available in PDF, EPUB and Kindle. Book excerpt: The papers included in this issue of ECS Transactions were originally presented in the symposium ¿Separators and Membranes for Batteries, Capacitors, Fuel Cells, and Other Electrochemical Systems¿, held during the 215th meeting of The Electrochemical Society, in San Francisco, CA from May 24 to 29, 2009.
