Author : Philippa H. McGuinness
Publisher : Springer Nature
ISBN 13 : 3031142446
Total Pages : 151 pages
Book Rating : 4.0/5 (311 download)
Book Synopsis Probing Unconventional Transport Regimes in Delafossite Metals by : Philippa H. McGuinness
Download or read book Probing Unconventional Transport Regimes in Delafossite Metals written by Philippa H. McGuinness and published by Springer Nature. This book was released on 2022-10-01 with total page 151 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis describes in-depth studies of the remarkable electronic transport within the ultrahigh conductivity delafossite metals PtCoO_2 and PdCoO_2 using the tool of focused ion beam (FIB) microstucturing. Despite being first synthesised over 50 years ago, important questions remain regarding both the origin of the unusually high conductivity of these compounds and the consequences of their unique properties for unconventional electronic transport, such as that within the ballistic regime. The thesis explores both these areas. High-energy electron irradiation is used to examine the effects of deliberately introducing point defects into PdCoO_2 and PtCoO_2, demonstrating that the extremely low resistivity of these materials stems from an extreme purity as high as 1 defect in 120,000 atoms, rather than a novel scattering suppression mechanism. In addition, studies of the electronic transport in micron-scale squares of these metals show that their broadly hexagonal Fermi surfaces lead not only to long range ballistic behaviour but novel ballistic regime phenomena which cannot be observed in materials with a higher-symmetry Fermi surface.