Preparation and Carbon Monoxide Oxidation Activity of Supported Copper Oxide Catalysts

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ISBN 13 :
Total Pages : 193 pages
Book Rating : 4.:/5 (256 download)

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Book Synopsis Preparation and Carbon Monoxide Oxidation Activity of Supported Copper Oxide Catalysts by : Johannes van der Meijden

Download or read book Preparation and Carbon Monoxide Oxidation Activity of Supported Copper Oxide Catalysts written by Johannes van der Meijden and published by . This book was released on 1981 with total page 193 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Preparation and Carbon Monoxide Oxidation Activity of Supported Copper(oxide) Catalysts

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ISBN 13 :
Total Pages : 193 pages
Book Rating : 4.:/5 (637 download)

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Book Synopsis Preparation and Carbon Monoxide Oxidation Activity of Supported Copper(oxide) Catalysts by : J. Vandermeijden

Download or read book Preparation and Carbon Monoxide Oxidation Activity of Supported Copper(oxide) Catalysts written by J. Vandermeijden and published by . This book was released on 1981 with total page 193 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Preparation and carbon monoxide oxidation activity of supported...

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Publisher :
ISBN 13 :
Total Pages : 210 pages
Book Rating : 4.:/5 (27 download)

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Book Synopsis Preparation and carbon monoxide oxidation activity of supported... by : Johannes Van Der Meijden

Download or read book Preparation and carbon monoxide oxidation activity of supported... written by Johannes Van Der Meijden and published by . This book was released on 1981 with total page 210 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Preparation and Carbon Monoxide Oxidation Activity of Supported Copper (oxide) Catalysts

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Publisher :
ISBN 13 :
Total Pages : 193 pages
Book Rating : 4.:/5 (17 download)

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Book Synopsis Preparation and Carbon Monoxide Oxidation Activity of Supported Copper (oxide) Catalysts by : P. van der Meijden

Download or read book Preparation and Carbon Monoxide Oxidation Activity of Supported Copper (oxide) Catalysts written by P. van der Meijden and published by . This book was released on 1981 with total page 193 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Low Temperature Carbon Monoxide Oxidation Over Gold Supported on Iron Oxide Catalysts

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Publisher :
ISBN 13 :
Total Pages : 310 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Low Temperature Carbon Monoxide Oxidation Over Gold Supported on Iron Oxide Catalysts by : Chien Sze

Download or read book Low Temperature Carbon Monoxide Oxidation Over Gold Supported on Iron Oxide Catalysts written by Chien Sze and published by . This book was released on 1995 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Perovskites and Related Mixed Oxides

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Publisher : John Wiley & Sons
ISBN 13 : 3527337636
Total Pages : 1050 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Perovskites and Related Mixed Oxides by : Pascal Granger

Download or read book Perovskites and Related Mixed Oxides written by Pascal Granger and published by John Wiley & Sons. This book was released on 2016-02-23 with total page 1050 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive handbook and ready reference details all the main achievements in the field of perovskite-based and related mixed-oxide materials. The authors discuss, in an unbiased manner, the potentials as well as the challenges related to their use, thus offering new perspectives for research and development on both an academic and industrial level. The first volume begins by summarizing the different synthesis routes from molten salts at high temperatures to colloidal crystal template methods, before going on to focus on the physical properties of the resulting materials and their related applications in the fields of electronics, energy harvesting, and storage as well as electromechanics and superconductivity. The second volume is dedicated to the catalytic applications of perovskites and related mixed oxides, including, but not limited to total oxidation of hydrocarbons, dry reforming of methane and denitrogenation. The concluding section deals with the development of chemical reactors and novel perovskite-based applications, such as fuel cells and high-performance ceramic membranes. Throughout, the contributions clearly point out the intimate links between structure, properties and applications of these materials, making this an invaluable tool for materials scientists and for catalytic and physical chemists.

Properties and Applications of Perovskite-Type Oxides

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Publisher : CRC Press
ISBN 13 : 9781439855225
Total Pages : 404 pages
Book Rating : 4.8/5 (552 download)

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Book Synopsis Properties and Applications of Perovskite-Type Oxides by : L.G. Tejuca

Download or read book Properties and Applications of Perovskite-Type Oxides written by L.G. Tejuca and published by CRC Press. This book was released on 2000-10-17 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference offers an overview of the bulk and surface properties of perovskite-like structures, and provides the latest discussions on the applications of these materials and processes. It also introduces ceramic methods for the processing of perovskite-derived high Tc cuprates.;Examining every available procedure for synthesizing high-surface-area perovskite oxides, this book: delineates processing techniques for preparing perovskite-derived high-critical-temperature superconductors; illustrates the relevance of physiochemical methods to investigate bulk and surface structures of perovskite compounds; explicates the importance of surface composition in the context of catalytic behaviour; summarizes methods of changing stoichiometry; shows how to design perovskite oxides for a given purpose; reviews key solid-state properties; and presents the major applications.

Novel Photodeposited Catalysts for Carbon Monoxide Oxidation and Preferential Oxidation of Carbon Monoxide in the Presence of Hydrogen (PROX)

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Publisher : ProQuest
ISBN 13 : 9780549925392
Total Pages : pages
Book Rating : 4.9/5 (253 download)

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Book Synopsis Novel Photodeposited Catalysts for Carbon Monoxide Oxidation and Preferential Oxidation of Carbon Monoxide in the Presence of Hydrogen (PROX) by : Sze Chi Chan

Download or read book Novel Photodeposited Catalysts for Carbon Monoxide Oxidation and Preferential Oxidation of Carbon Monoxide in the Presence of Hydrogen (PROX) written by Sze Chi Chan and published by ProQuest. This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: It has been shown that gold nanoparticles supported on metal oxides with sizes below 5 nm exhibit unique catalytic properties for CO oxidation, water-gas shift, and epoxidation of propylene. In particular, Au/TiO 2 exhibits CO oxidation activity at temperature as low as 90 K. Recent research reported that silver nanoparticles supported on TiO 2 are similar to Au nanoparticles supported on TiO 2 . Conventional methods for preparing Ag/TiO 2 and Au/TiO 2 supported catalysts include deposition-precipitation, wet impregnation and co-precipitation. Among these methods deposition-precipitation has shown the best results for these reactions due to the narrow size distribution of Ag and Au. The major disadvantage of the deposition-precipitation method is that Au and Ag particle sizes are very sensitive to precursor concentration. Preparation of Au particles less than 5 nm requires a low precursor concentration and low Au loading. In this work, a different approach, photodeposition, was used to prepare Ag and Au nanoparticles supported on TiO 2 . The main shortcoming of photodeposition is that its efficiency is very sensitive to both bulk and surface structural features. However, such problems can be overcome by reducing the size of TiO 2 particles to the nanoscale. Photodeposition of Ag nanoparticles on commercial TiO 2 particles and nanoparticles was performed on microscope grid-supported samples in order to provide direct visualization of the spatial distribution of photoactive sites on sub-micron-scale and nanoscale TiO 2 particle surfaces and to create materials for potential catalytic applications. HRTEM (high-resolution transmission electron microscopy) and HAADF-STEM (high-angle annular dark-field scanning transmission electron microscopy) were used to characterize these materials. The size and spatial distributions of the Ag nanoparticles on the commercial TiO 2 were not uniform; the concentration of Ag was higher on grain boundaries and at the edges of these submicrometer particles. In the case of TiO 2 nanoparticles, the size distribution of the Ag nanoparticles deposited was relatively uniform and independent of irradiation time and photon energy. The amount of Ag deposited on TiO 2 nanoparticles was at least 6 times higher than that on commercial samples for comparable irradiation conditions. Compared to the case of Ag photodeposition, the difference in the amount of Au photodeposited on TiO 2 particles and nanoparticles was even greater, especially at low precursor concentration. Photodeposition on TiO 2 nanoparticles is suggested as a potential method for the preparation of Ag/TiO 2 and Au/TiO 2 catalysts. The high photoreactivity of TiO 2 nanoparticles makes them an ideal material for preparation of supported metal catalysts when highly uniform nanoscale particle size is required. Extending the previous work, the Ag and Au photodeposition on TiO 2 nanoparticles were scaled-up from micro scale to laboratory scale to generate sample powders in sufficient quantity to be utilized in catalytic reactor. Most of the methods published for the preparation of metal-decorated TiO 2 by photodeposition involve suspended particles in a aqueous media. Our approach for the scale-up process was different, and was developed based on the sample preparation for metal photodeposition on microscope grids. A thin film of TiO 2 nanoparticle powders coated on a glass plate was obtained by using a spin-coating technique before metal photodeposition. Several commercial TiO 2 nanoparticles were used in this study, in order to choose appropriate samples for the scale-up experiments. Preliminary studies of the photoreactivity of commercial TiO 2 nanoparticles for Ag photodeposition on a microscope grid were carried out prior to the scale-up process. The effects of Ag photoreduction conditions, in particular the radiation source and the metal precursor solution concentration, on Ag photodeposition were investigated to determine the optimum conditions for the scale-up process. The size and spatial distribution of Ag nanoparticles, as well as the Ag loading on commercial TiO 2 nanoparticles for the scale up process under various conditions were determined using TEM and HAADF-STEM techniques. After the optimal conditions for the scale-up process were established, Ag/TiO 2 and Au/TiO 2 nanoparticles obtained from the scaled-up process were characterized by atomic absorption spectroscopy (AAS), X-ray diffraction (XRD), Xray photoelectron spectroscopy (XPS) and HAADF. In addition, Ag/TiO 2 and Au/TiO 2 nanoparticles were also prepared using traditional deposition-precipitation methods. The catalytic performance of Ag/TiO 2 and Au/TiO 2 nanoparticles prepared using two different methods for CO oxidation and preferential oxidation of CO in the presence of H 2 (PROX) were investigated using a high-throughput reactor. Results obtained from this study showed that the size of Ag particles, Ag loading, as well as preparation method contributed to the difference in activity of Ag/TiO 2 for CO oxidation and PROX. In the case of Au/TiO 2 the difference in activity for CO oxidation and PROX is mainly due to the preparation method and Au loading.

Kinetics of Catalytic Reactions

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Publisher : Springer Science & Business Media
ISBN 13 : 0387259724
Total Pages : 257 pages
Book Rating : 4.3/5 (872 download)

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Book Synopsis Kinetics of Catalytic Reactions by : M. Albert Vannice

Download or read book Kinetics of Catalytic Reactions written by M. Albert Vannice and published by Springer Science & Business Media. This book was released on 2006-04-09 with total page 257 pages. Available in PDF, EPUB and Kindle. Book excerpt: Describes how to conduct kinetic experiments with heterogeneous catalysts, analyze and model the results, and characterize the catalysts Detailed analysis of mass transfer in liquid phase reactions involving porous catalysts. Important to the fine chemicals and pharmaceutical industries so it has appeal to many researchers in both industry and academia (chemical engineering and chemistry departments

Calorimetry and Thermal Methods in Catalysis

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Publisher : Springer Science & Business Media
ISBN 13 : 3642119549
Total Pages : 569 pages
Book Rating : 4.6/5 (421 download)

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Book Synopsis Calorimetry and Thermal Methods in Catalysis by : Aline Auroux

Download or read book Calorimetry and Thermal Methods in Catalysis written by Aline Auroux and published by Springer Science & Business Media. This book was released on 2013-09-18 with total page 569 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book is about calorimetry and thermal analysis methods, alone or linked to other techniques, as applied to the characterization of catalysts, supports and adsorbents, and to the study of catalytic reactions in various domains: air and wastewater treatment, clean and renewable energies, refining of hydrocarbons, green chemistry, hydrogen production and storage. The book is intended to fill the gap between the basic thermodynamic and kinetics concepts acquired by students during their academic formation, and the use of experimental techniques such as thermal analysis and calorimetry to answer practical questions. Moreover, it supplies insights into the various thermal and calorimetric methods which can be employed in studies aimed at characterizing the physico-chemical properties of solid adsorbents, supports and catalysts, and the processes related to the adsorption desorption phenomena of the reactants and/or products of catalytic reactions. The book also covers the basic concepts for physico-chemical comprehension of the relevant phenomena. Thermodynamic and kinetic aspects of the catalytic reactions can be fruitfully investigated by means of thermal analysis and calorimetric methods, in order to better understand the sequence of the elemental steps in the catalysed reaction. So the fundamental theory behind the various thermal analysis and calorimetric techniques and methods also are illustrated.

Catalyst Preparation

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Publisher : CRC Press
ISBN 13 : 1420006509
Total Pages : 490 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Catalyst Preparation by : John Regalbuto

Download or read book Catalyst Preparation written by John Regalbuto and published by CRC Press. This book was released on 2016-04-19 with total page 490 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text explores the optimization of catalytic materials through traditional and novel methods of catalyst preparation, characterization, and monitoring for oxides, supported metals, zeolites, and heteropolyacids. It focuses on the synthesis of bulk materials and of heterogeneous materials, particularly at the nanoscale. The final chapters examine pretreatment, drying, finishing effects, and future applications involving catalyst preparation and the technological advances necessary for continued progress. Topics also include heat and mass transfer limitations, computation methods for predicting properties, and catalyst monitoring on laboratory and industrial scales.

Catalysis by Materials with Well-Defined Structures

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Publisher : Academic Press
ISBN 13 : 0128013400
Total Pages : 393 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Catalysis by Materials with Well-Defined Structures by : Zili Wu

Download or read book Catalysis by Materials with Well-Defined Structures written by Zili Wu and published by Academic Press. This book was released on 2015-03-26 with total page 393 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysis by Materials with Well-Defined Structures examines the latest developments in the use of model systems in fundamental catalytic science. A team of prominent experts provides authoritative, first-hand information, helping readers better understand heterogeneous catalysis by utilizing model catalysts based on uniformly nanostructured materials. The text addresses topics and issues related to material synthesis, characterization, catalytic reactions, surface chemistry, mechanism, and theoretical modeling, and features a comprehensive review of recent advances in catalytic studies on nanomaterials with well-defined structures, including nanoshaped metals and metal oxides, nanoclusters, and single sites in the areas of heterogeneous thermal catalysis, photocatalysis, and electrocatalysis. Users will find this book to be an invaluable, authoritative source of information for both the surface scientist and the catalysis practitioner Outlines the importance of nanomaterials and their potential as catalysts Provides detailed information on synthesis and characterization of nanomaterials with well-defined structures, relating surface activity to catalytic activity Details how to establish the structure-catalysis relationship and how to reveal the surface chemistry and surface structure of catalysts Offers examples on various in situ characterization instrumental techniques Includes in-depth theoretical modeling utilizing advanced Density Functional Theory (DFT) methods

Experimental Relations of Gold (and Other Metals) to Light

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Publisher :
ISBN 13 :
Total Pages : 42 pages
Book Rating : 4.B/5 (1 download)

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Book Synopsis Experimental Relations of Gold (and Other Metals) to Light by : Michael Faraday

Download or read book Experimental Relations of Gold (and Other Metals) to Light written by Michael Faraday and published by . This book was released on 1857 with total page 42 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Oxidation Catalysis in Environmental Applications

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ISBN 13 :
Total Pages : 228 pages
Book Rating : 4.:/5 (182 download)

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Book Synopsis Oxidation Catalysis in Environmental Applications by : Matthew Maurice Yung

Download or read book Oxidation Catalysis in Environmental Applications written by Matthew Maurice Yung and published by . This book was released on 2007 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: The environmental applications of oxidation catalysis were examined as part of a two-stage strategy for the reduction of nitrogen oxides (NOx) and also for the removal of carbon monoxide from hydrogen streams. Cobalt-based catalysts were examined. Reduction of NOx, Co/TiO2 and Co/ZrO2 were studied for the oxidation of NO to NO2 in excess oxygen. NO oxidation was studied as the first step in a two-step catalytic scheme where NO is oxidized to NO2 and, in turn, NO2 is reduced with CH4 to N2 under lean conditions. Catalysts were prepared by sol-gel and incipient-wetness impregnation techniques. It was found that increasing the calcination temperature had an adverse effect on the activity of the IWI catalysts. Catalyst characterization showed higher activity for NO oxidation on Co/ZrO2 than on Co/TiO2 which was observed to correlate with the formation of the Co3O4 phase. For the preferential oxidation of CO, cobalt on several metal oxide supports were investigated and showed the highest activity on Co/ZrO2. A variety of reaction experiments were performed to examine the effects of reactant concentrations, residence time, and temperature on the CO conversion and O2 selectivity to CO2.

Catalysis by Gold

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Publisher : World Scientific
ISBN 13 : 1860948952
Total Pages : 383 pages
Book Rating : 4.8/5 (69 download)

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Book Synopsis Catalysis by Gold by : Geoffrey Colin Bond

Download or read book Catalysis by Gold written by Geoffrey Colin Bond and published by World Scientific. This book was released on 2006 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: Gold has traditionally been regarded as inactive as a catalytic metal. However, the advent of nanoparticulate gold on high surface area oxide supports has demonstrated its high catalytic activity in many chemical reactions. Gold is active as a heterogeneous catalyst in both gas and liquid phases, and complexes catalyse reactions homogeneously in solution. Many of the reactions being studied will lead to new application areas for catalysis by gold in pollution control, chemical processing, sensors and fuel cell technology. This book describes the properties of gold, the methods for preparing gold catalysts and ways to characterise and use them effectively in reactions. The reaction mechanisms and reasons for the high activities are discussed and the applications for gold catalysis considered. Sample Chapter(s). Chapter 1: Introduction to Catalysis (892 KB). Contents: Introduction to Catalysis; The Physical and Chemical Properties of Gold; Physical Properties and Characterisation of Small Gold Particles; Preparation of Supported Gold Catalysts; Chemisorption of Simple Molecules on Gold; Oxidation of Carbon Monoxide; The Selective Oxidation of Carbon Monoxide; Selective Oxidation; Reactions Involving Hydrogen; The WaterOCoGas Shift; Reactions of Environmental Importance; Catalysis by Soluble and Supported Gold Compounds; Miscellaneous Reactions Catalysed by Gold; Commercial Applications. Readership: Postgraduate level researchers in academia and industry, as well as general readers."

Selective CO Oxidation Over Au Supported on Mixed Oxides

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (129 download)

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Book Synopsis Selective CO Oxidation Over Au Supported on Mixed Oxides by : Abhishek Jain

Download or read book Selective CO Oxidation Over Au Supported on Mixed Oxides written by Abhishek Jain and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Influence of Surface Structure on the Catalytic Activity of Alumina Supported Transition Metal Oxides

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Publisher :
ISBN 13 :
Total Pages : 430 pages
Book Rating : 4.3/5 (129 download)

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Book Synopsis The Influence of Surface Structure on the Catalytic Activity of Alumina Supported Transition Metal Oxides by : Paul Worn Park

Download or read book The Influence of Surface Structure on the Catalytic Activity of Alumina Supported Transition Metal Oxides written by Paul Worn Park and published by . This book was released on 1996 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt: