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Polyoxometalate Chemistry
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Book Synopsis Polyoxometalate Molecular Science by : Juan J. Borrás-Almenar
Download or read book Polyoxometalate Molecular Science written by Juan J. Borrás-Almenar and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 473 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyoxometalates (POMs) form a large, distinctive class of molecular inorganic compounds of unrivaled electronic versatility and structural variation, with impacts ranging from chemistry, catalysis, and materials science to biology, and medicine. This book covers the basic principles governing the structure, bonding and reactivity of these metal-oxygen cluster anions and the major developments in their molecular science. The book comprises three sections. The first covers areas ranging from topological principles via synthesis and stability to reactivity in solution. It also focuses on the physical methods currently used to extract information on the molecular and electronic structures as well as the physical properties of these clusters. The second part reviews different types of POMs, focusing on those systems that currently impact other areas of interest, such as supramolecular chemistry, nanochemistry and molecular magnetism. The third section is devoted to POM-based materials and their applications and prospects in catalysis and materials science.
Book Synopsis Polyoxometalate Chemistry by : Francis Secheresse
Download or read book Polyoxometalate Chemistry written by Francis Secheresse and published by World Scientific. This book was released on 2013 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book highlights recent prominent results in the domain of the synthesis of new polyoxometalates with a specific attention to polyoxothioanions, and provides some novelties and perspectives in selected domains such as magnetism, luminescence and nanochemistry, and macroions self-assembly in solutions. The case of OC one-potOCO syntheses often used and reported in POMs synthesis is studied in terms of more complex solution speciation processes related to highly dynamical situation connected to factors such as pH, ionic strength, reaction time, temperature, counterion nature, concentration of starting materials, presence of electron donors and redox potentials. The behavior of macroions (2nm-6nm size range) in solution is shown to be quite different from the simple ionic solution or colloidal systems (DebyeOCoHuckel model). Their self-assembling into a single-layered, spherical, hollow vesicle structure, namely the OC blackberryOCO structure, is clearly described. Examples of spin clusters with tunable interactions are given and single molecule magnets based on POMs are specifically tackled. Besides paramagnetic transition metal centres and lanthanoid ions encapsulated in archetypal lacunary polyoxoanions, magnetically functionalized Kleperates are described, their discovery tracing back nearly 15 years.
Download or read book Polyoxometalate Chemistry written by and published by Academic Press. This book was released on 2017-02-17 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyoxometalate Chemistry continues a long-running series that describes recent advances in scientific research, in particular, in the field of inorganic chemistry. Several highly regarded experts, mostly from academia, contribute on specific topics. The current issue focuses on recent advances in the development and application of polyoxometalate complexes in areas such as solution chemistry, self-organization, solar fuels, non-aqueous chemistry, spintronics, nanoscience and catalysis. Presents a single monograph on recent developments in polyoxometalate chemistry as written by scientific leaders in this field Concise and informative presentations cover a wide range of topics in this field of chemistry Contains detailed literature references, enabling the reader to move on to the source of the reported work where more details can be found Provides a solid presentation of a hard-cover book of excellent technical quality
Book Synopsis Polyoxometalate Chemistry From Topology via Self-Assembly to Applications by : M.T. Pope
Download or read book Polyoxometalate Chemistry From Topology via Self-Assembly to Applications written by M.T. Pope and published by Springer Science & Business Media. This book was released on 2001-06-30 with total page 421 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyoxometalates constitute an extensive class of compounds with an unmatched range of structures, properties and applications. This is an authoritative, up-to-date summary of the chemistry and applications of polyoxometalates.
Book Synopsis Polyoxometalate Chemistry for Nano-Composite Design by : Toshihiro Yamase
Download or read book Polyoxometalate Chemistry for Nano-Composite Design written by Toshihiro Yamase and published by Springer Science & Business Media. This book was released on 2006-04-28 with total page 235 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Chemists from several international polyoxometalate research groups discussed recent results, including: controlled self-organization processes for the preparation of nano-composites; electronic interactions in magnetic mixed-valence cryptands and coronands; synthesis of the novel polyoxometalates with topological or biological significance; systematic investigations in acid-base and/or redox catalysis for organic transformations; and electronic properties in materials science."--Page v
Book Synopsis Polyoxometalate Chemistry by : Francis Sécheresse
Download or read book Polyoxometalate Chemistry written by Francis Sécheresse and published by World Scientific. This book was released on 2013-06-11 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book highlights recent prominent results in the domain of the synthesis of new polyoxometalates with a specific attention to polyoxothioanions, and provides some novelties and perspectives in selected domains such as magnetism, luminescence and nanochemistry, and macroions self-assembly in solutions. The case of “one-pot” syntheses often used and reported in POMs synthesis is studied in terms of more complex solution speciation processes related to highly dynamical situation connected to factors such as pH, ionic strength, reaction time, temperature, counterion nature, concentration of starting materials, presence of electron donors and redox potentials. The behavior of macroions (2nm-6nm size range) in solution is shown to be quite different from the simple ionic solution or colloidal systems (Debye–Huckel model). Their self-assembling into a single-layered, spherical, hollow vesicle structure, namely the “blackberry” structure, is clearly described. Examples of spin clusters with tunable interactions are given and single molecule magnets based on POMs are specifically tackled. Besides paramagnetic transition metal centres and lanthanoid ions encapsulated in archetypal lacunary polyoxoanions, magnetically functionalized Kleperates are described, their discovery tracing back nearly 15 years. Contents:Polyoxometalate-Protected Metal Nanoparticles: Synthesis, Structure and Catalysis (Yifeng Wang and Ira A Weinstock)When Giants Meet Dwarves in the Same Pond — Unique Solution Physical Chemistry Opportunities Offered by Polyoxometalate Macroions (Dong Li, Panchao Yin and Tianbo Liu)Directed Assembly of Polyoxometalates Across Length Scales: From Macro-Molecules to Microsystems and iChells (Antoine G Boulay, Geoffrey J T Cooper and Leroy Cronin)Magnetic Polyoxometalates (Juan M Clemente-Juan, Eugenio Coronado and Alejandro Gaita-Ariño)Magnetism of Keplerates (Paul Kögerler)Polyoxometalates as Ligands for Functional Lanthanoid Complexes (Chris Ritchie and Colette Boskovic)Polyoxothiometalates POTM (Francis Sécheresse and Emmanuel Cadot) Readership: Graduate students and researchers of nanoscience and nanotechnology and chemistry (physical and inorganic) — inter-disciplinary. Keywords:Polyoxometalates;Magnetic Polyoxometalates;Polyoxometalate Assembling;Giant Polyoxometalates;Lanthanoid Complexes;Metal Nanoparticles;Polyxothiometalates;BlackberrysKey Features:Limited number of subjects on really modern aspects of POM chemistryYoung and upcoming authors representing the future of POM chemistryLinks between chemistry and nanochemistry
Book Synopsis Polyoxometalate-Based Hybrids and their Applications by : Majid M. Heravi
Download or read book Polyoxometalate-Based Hybrids and their Applications written by Majid M. Heravi and published by Elsevier. This book was released on 2023-03-14 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyoxometalate-Based Hybrids and their Applications focuses on recent progress in polyoxometalate-based hybrids materials. Chapters present the structure, composition, classification and properties of POMs such as isopolyaions, heteropolyanions, giant and lacunary polyoxometalates and then cover polyoxometalate-based open-frameworks (POM-OFs), include a historical introduction to these compounds, and present their synthetic strategies. The structural diversity and relative applications of POM-OFs is also covered. Other sections delve into synthetic strategies, structural diversity and relative applications of porous polyoxometalate-based metal-organic frameworks. Polyoxometalate-based coordination polymers (POMCPs) and polyoxometalate-based host-guest framework materials are highlighted in final sections. This book is an essential reference for inorganic chemists, biochemists, and material scientists working in academia and industry. Discusses polyoxometalate-based host-guest framework materials Includes coverage of polyoxometalates and their environmental applications Reviews transition metal substituted lacunary polyoxometalates
Book Synopsis Polyoxometalate-Based Assemblies and Functional Materials by : Yu-Fei Song
Download or read book Polyoxometalate-Based Assemblies and Functional Materials written by Yu-Fei Song and published by Springer. This book was released on 2018-03-24 with total page 167 pages. Available in PDF, EPUB and Kindle. Book excerpt: The authors of this volume concentrate on the recent progress of novel polyoxometalate (POM) syntheses, as well as advances made in catalytic, electrochemical, and sensing systems. The state-of-the-art techniques such as flow system and gel-electrophoresis for the discovery of POMs are covered with a detailed discussion. Of particular importance, the application of POM-based materials in photo-sensing, heterogeneous catalysis, energy conservation and storage, and gas separation is reviewed. Over the past few years, POM chemistry has witnessed a remarkable progress with more than 1500 papers published each year. Due to their intrinsic structural features, POMs are considered as versatile building blocks for the construction of sophisticated complex assemblies and advanced multi-functional materials. Various strategies, methods, and techniques have been adopted to develop POM-based materials with intriguing properties and excellent performance. All the contributors to this volume are young, vibrant chemists in this research field and all the works are carefully collected from the authors’ years of experience. This volume serves as an essential reference for every POM chemist and is of great interest to new researchers who wish to learn more about this area.
Book Synopsis Supramolecular Chemistry of Biomimetic Systems by : Junbai Li
Download or read book Supramolecular Chemistry of Biomimetic Systems written by Junbai Li and published by Springer. This book was released on 2017-10-10 with total page 394 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book investigates the latest developments in supramolecular assembly systems for mimicking biological structures and functions. Consisting of 14 chapters, it covers various assembly systems, such as polysaccharides, peptides, proteins, biopolymers, natural materials and various hybrid systems. Further, it focuses on different types of supramolecular systems with particular functions or structures that are relevant to living systems. A number of modern techniques used to study the supramolecular systems, such as total internal reflection fluorescence microscopy (TIRFM) and two-photon confocal microscopy, are also introduced in detail. Unlike conventional books on supramolecular assemblies, this book highlights the functions of the assembly systems, particularly their biological applications. As such, it offers a valuable resource for experienced researchers, as well as graduate students working in the field of supramolecular chemistry and biomimetic systems.
Book Synopsis Polyoxometalate Chemistry From Topology via Self-Assembly to Applications by : M.T. Pope
Download or read book Polyoxometalate Chemistry From Topology via Self-Assembly to Applications written by M.T. Pope and published by Springer Science & Business Media. This book was released on 2007-05-08 with total page 427 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work incorporates contributions from polyoxometalate scientists, and presents a summary of research developments in this field. Topics discussed include synthetic strategies leading to functionalized organic polyoxometalate derivatives, oxothioanions, and supramolecular assemblies.
Book Synopsis Comprehensive Coordination Chemistry II by : J. A. McCleverty
Download or read book Comprehensive Coordination Chemistry II written by J. A. McCleverty and published by Newnes. This book was released on 2003-12-03 with total page 17046 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
Book Synopsis Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity by : M.T. Pope
Download or read book Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity written by M.T. Pope and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 409 pages. Available in PDF, EPUB and Kindle. Book excerpt: MICHAEL T. POPE AND ACHIM MULLER Department of Chemistry, Georgetown University, Washington, DC 20057-2222, U.S.A.; Department of Chemistry, University of Bielefeld, D-4BOO Bielefeld 1, F.R.G. Polyoxometalates, from their discovery and early development in the final decades of the 19th century to their current significance in disciplines as diverse as chemistry, mathematics, and medicine, continue to display surprisingly novel structures, unexpected reactivities and applications, and to attract increasing attention worldwide. Most of the contributors to the present volume participated in the workshop held at the Center for Interdisciplinary Research at the University of Bielefeld, July 15-17, 1992. The choice of topics illustrates some of the variety of directions and fields in which polyoxometalates can play an important role. Although many of the leading polyoxometalate research groups are represented here, we regret that time constraints, financial limitations, and in some cases difficulties of communication did not allow us to include significant and imp- tant work from other groups outside Europe and North America. In the following we briefly review the current status of the field of po- oxometalates.
Book Synopsis The Aqueous Chemistry of Oxides by : Bruce C. Bunker
Download or read book The Aqueous Chemistry of Oxides written by Bruce C. Bunker and published by Oxford University Press. This book was released on 2016-02-02 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Aqueous Chemistry of Oxides is a single-volume text that encapsulates all of the critical issues associated with how oxide materials interact with aqueous solutions. It serves as a central reference for academics working with oxides in the contexts of geology, various types of inorganic chemistry, and materials science. The text also has utility for professionals working with industrial applications in which oxides are either prepared or must perform in aqueous environments. The volume is organized into five key sections. Part One features two introductory chapters, intended to introduce the mutual interests of engineers, chemists, geologists, and industrial scientists in the physical and chemical properties of oxide materials. Part Two provides the essential and fundamental principles that are critical to understanding most of the major reactions between water and oxides. Part Three deals with the synthesis of oxide materials in aqueous media. Part Four deals with oxide-water reactions and their environmental and technological impacts, and Part Five is devoted to other types of relevant reactions. The Aqueous Chemistry of Oxides is the first book that provides a comprehensive summary of all of the critical reactions between oxides and water in a single volume. As such, it ties together a wide range of existing books and literature into a central location that provides a key reference for understanding and accessing a broad range of more specialized topics. The book contain over 300 figures and tables.
Book Synopsis Polyoxometalates in Catalysis, Biology, Energy and Materials Science by : Soumyajit Roy
Download or read book Polyoxometalates in Catalysis, Biology, Energy and Materials Science written by Soumyajit Roy and published by Frontiers Media SA. This book was released on 2019-12-05 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Advances in Inorganic Chemistry by : Rudi van Eldik
Download or read book Advances in Inorganic Chemistry written by Rudi van Eldik and published by Elsevier. This book was released on 2006-12-01 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thematic issue devoted to 'Template Effects and Molecular Organization' is based on a special symposium recently organized by the American Chemical Society in Philadelphia. The authors contributed oral presentations and are experts in their fields. Each chapter is fully referenced Contains comprehensive reviews written by leading experts in the field Includes new information on the important advances in inorganic and bioinorganic chemistry
Book Synopsis Chemical Synergies by : Nuno A.G. Bandeira
Download or read book Chemical Synergies written by Nuno A.G. Bandeira and published by Walter de Gruyter GmbH & Co KG. This book was released on 2018-05-07 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book gives an overview of recent integrated and inter-disciplinary approaches between chemical experiment and theory in a variety of fields, from polymer science to materials chemistry and ranging from the design of tailored properties to catalysis and reactivity, building on the well-established success of Density Functional Theory as the foremost quantum chemical method to provide qualitative and quantitative interpretation of results from the chemical laboratory. The combination of several characterization techniques with an understanding at the molecular level of chemical and physical phenomena are the main focal point of the subject matter.
Book Synopsis Trends in Polyoxometalates Research by : Laurent Ruhlmann
Download or read book Trends in Polyoxometalates Research written by Laurent Ruhlmann and published by Nova Science Publishers. This book was released on 2015 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book attempts to make available the recent developments in polyoxometalate (POM) synthesis. The focus centralises on the functionalisation of POMs with covalently organic moiety (for instance, the use of exogenous ligands such as carboxylate or bisphosphonate). It also delves into the development of lanthanide POMs, or the formation of blackberry-like assemblies. Likewise, the properties (redox properties, magnetism, etc...), and its applications (homogeneous and heterogeneous catalysis, photocatalysis, photoelectrocatalysis and photovoltaic cell development, etc.) are also analysed. This application concerns also the catalysis of H2O oxidation, photodegradation of pollutants, and reduction of cationic metal to form original nanoparticles. The use of polyoxometalates as catalysts for biologically relevant reactions is also considered. One of the other aims of the book is to highlight some recent developments and perspectives in the domain of materials and their applications. For instance, the use of POM-organic photosensitiser hybrids can also be achieved for application in the generation of photocurrent and the development of new types of solar cells. By combining POMs with electrically active materials, a variety of applications have been explored and several examples of POM-based electronic materials are presented in this book.
