Polynuclear Complexes

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An Introduction to the Chemistry of Complex Compounds

Author : Aleksander Abramovich Grinberg
Publisher : Elsevier
ISBN 13 : 1483184668
Total Pages : 388 pages
Book Rating : 4.4/5 (831 download)

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Book Synopsis An Introduction to the Chemistry of Complex Compounds by : Aleksander Abramovich Grinberg

Download or read book An Introduction to the Chemistry of Complex Compounds written by Aleksander Abramovich Grinberg and published by Elsevier. This book was released on 2013-10-22 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: An Introduction to the Chemistry of Complex Compounds discusses the fundamental concepts that are essential in understanding the underlying principles of complex compounds. The coverage of the book includes the compounds of the hexa, penta, and tetrammine type; compounds of the tri, dl, monoamine and hexacido types for the coordination number of 6; and complex compounds with a coordination number of 4. The text also covers the effects and chemical properties of complex compounds, such as the nature of the force of complex formation; the mutual effects of coordinated groups; and acid-base properties, oxidation-reduction properties, and solution equilibriums of complex compounds. The book will be of great use to chemists and chemical engineers.

Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory

Author : E. Kochanski
Publisher : Springer Science & Business Media
ISBN 13 : 9401126984
Total Pages : 448 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory by : E. Kochanski

Download or read book Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory written by E. Kochanski and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: The scope of this paper is to recall fundamental notions of the molecular spectroscopy and dynamics, necessary for discussion of photophysical and photochemical processes in condensed phases. We will thus treat in a more detailed way the specific features which are important for molecular systems strongly interacting with their environment. Other aspects such as the time evolution of isolated molecules, single-level excitation and state-to-state chemistry, important for the gas-phase photophysics are omitted. We start (Sec.2) with a brief description of radiative processes (light absorption and emission) in molecules. In the quantum-mechanical treatment of this problem, the appropriate basis is that of so-called zero-order states, corresponding to the traditional scheme of electronic states (singlets, doublets, triplets etc.) and vibrational levels belonging to each state. The important point will be deduction of selection rules for most radiative transitions. At this stage all molecular states are considered as stationary states. In order to treat the breakdown of simple selection rules and non-radiative transitions between individual molecular states, it is necessary to take into account the mechanisms coupling the zero-order states (Sec.3). We will first focus on intramolecular coupling effects and then discuss the solvent effects on intramolecular relaxation processes. The problem of the non-radiative transfer of the electronic energy between different molecules - closely related to that of the energy dissipation within a single molecule will be treated in Sec.4.

Modern Aspects of Rare Earths and their Complexes

Author : Vinny R. Sastri
Publisher : Elsevier
ISBN 13 : 0080536689
Total Pages : 1005 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Modern Aspects of Rare Earths and their Complexes by : Vinny R. Sastri

Download or read book Modern Aspects of Rare Earths and their Complexes written by Vinny R. Sastri and published by Elsevier. This book was released on 2003-12-09 with total page 1005 pages. Available in PDF, EPUB and Kindle. Book excerpt: In order to use rare earths successfully in various applications, a good understanding of the chemistry of these elements is of paramount importance. Nearly three to four decades have passed since titles such as The Rare Earths edited by F.H. Spedding and A.H. Daane, The chemistry of the Rare Earth Elements by N.E. Topp and Complexes of the Rare Earths by S.P. Sinha were published. There have been many international conferences and symposia on rare earths, as well as the series of volumes entitled Handbook of Physics and Chemistry of Rare Earths edited by K.A. Gschneidner and L. Eyring. Thus, there is a need for a new title covering modern aspects of rare earth complexes along with the applications. The present title consists of twelve chapters. 1. Introduction2. General aspects3. Stability of complexes4. Lanthanide complexes5. Structural chemistry of lanthanide compounds6. Organometallic complexes7. Kinetics and mechanisms of rare earths complexation8. Spectroscopy of lanthanide complexes9. Photoelectron spectroscopy of rare earths10. Lanthanide NMR shift reagents11. Environmental ecological biological aspects12. Applications The authors studied in schools headed by pioneers in rare earth chemistry, have a combined experience of one hundred and fifty years in inorganic chemistry, rare earth complex chemistry, nuclear and radiochemistry of rare earths and supramolecular chemistry. The present monograph is a product of this rich experience.

Metal And Non-Metal Biguanide Complexes

Author : Ranajit Kumar Ray
Publisher : New Age International
ISBN 13 : 9788122410389
Total Pages : 180 pages
Book Rating : 4.4/5 (13 download)

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Book Synopsis Metal And Non-Metal Biguanide Complexes by : Ranajit Kumar Ray

Download or read book Metal And Non-Metal Biguanide Complexes written by Ranajit Kumar Ray and published by New Age International. This book was released on 1999 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: In This Short But Authoritative Book, Drs. Ray And Kauffman Succinctly Review All Important Studies On Complexes Of Biguanide And Its Derivatives Published Since Priyadaranjan Rays Classical Chemical Review Article By Giving Special Attention To Synthesis, Properties, Magnetism, Spectroscopy, Reactions, Kinetics, Structures And Applications. This Book Is The Only One Of Its Kind. The Structures Of The Ligands And Their Complexes As Revealed By Magnetic Moments, Electronic Spectra, Epr And X-Ray Crystallography Have Been Considered.The Books References Which Number More Than Four Hundred Should Give Practising Scientists Ready Access To The Crucial Details Needed For Research And Development On These Theoretically And Practically Significant Compounds. As Such, It Provides Data That Widely Scattered Is In Scientific Literatures In A Single Handy Source Book. This Book Is Heartily Recommend To Inorganic, Organic, Medical And Pharmaceutical Chemists, As Well As To Anyone Concerned With This Unique Class Of Ligands And Their Complexes With A Wide Variety Of Elements Of Varying Oxidation States And Coordination Numbers.

Homogeneous Catalysis with Metal Complexes

Author : Oleg N. Temkin
Publisher : John Wiley & Sons
ISBN 13 : 1119966825
Total Pages : 963 pages
Book Rating : 4.1/5 (199 download)

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Book Synopsis Homogeneous Catalysis with Metal Complexes by : Oleg N. Temkin

Download or read book Homogeneous Catalysis with Metal Complexes written by Oleg N. Temkin and published by John Wiley & Sons. This book was released on 2012-02-08 with total page 963 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous catalysis by soluble metal complexes has gained considerable attention due to its unique applications and features such as high activity and selectivity. Catalysis of this type has demonstrated impressive achievements in synthetic organic chemistry and commercial chemical technology. Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms presents a comprehensive summary of the results obtained over the last sixty years in the field of the kinetics and mechanisms of organic and inorganic reactions catalyzed with metal complexes. Topics covered include: Specific features of catalytic reaction kinetics in the presence of various mono- and polynuclear metal complexes and nanoclusters Multi-route mechanisms and the methods of their identification, as well as approaches to the kinetics of polyfunctional catalytic systems Principles and features of the dynamic behavior of nonlinear kinetic models The potential, achievements, and limitations of applying the kinetic approach to the identification of complex reaction mechanisms The development of a rational strategy for designing kinetic models The kinetic models and mechanisms of many homogeneous catalytic processes employed in synthetic and commercial chemistry Written for specialists in the field of kinetics and catalysis, this book is also relevant for post-graduates engaged in the study

Macromolecule-Metal Complexes

Author : Francesco Ciardelli
Publisher : Springer Science & Business Media
ISBN 13 : 3642609864
Total Pages : 333 pages
Book Rating : 4.6/5 (426 download)

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Book Synopsis Macromolecule-Metal Complexes by : Francesco Ciardelli

Download or read book Macromolecule-Metal Complexes written by Francesco Ciardelli and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 333 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first concise overview on the topic, spanning the spectrum from fundamentals to new application areas. The synthesis, kinetics and thermodynamics of these complexes are covered in detail, while much emphasis is placed on special properties such as gas transport, charge transport, catalysis and light-induced processes. Furthermore, the authors treat the actual working areas for new application methods. In all, a very helpful tool for polymer and materials scientists, as well as organic and physical chemists working in these fields.

Metallo-Drugs: Development and Action of Anticancer Agents

Author : Astrid Sigel
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 311047073X
Total Pages : 588 pages
Book Rating : 4.1/5 (14 download)

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Book Synopsis Metallo-Drugs: Development and Action of Anticancer Agents by : Astrid Sigel

Download or read book Metallo-Drugs: Development and Action of Anticancer Agents written by Astrid Sigel and published by Walter de Gruyter GmbH & Co KG. This book was released on 2018-02-05 with total page 588 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 18, entitled Metallo-Drugs: Development and Action of Anticancer Agents of the series Metal Ions in Life Sciences centers on biological, medicinal inorganic chemistry. The serendipitous discovery of the antitumor activity of cis-diamminodichloroplatinum(II) (cisplatin) by Barnett Rosenberg in the 1960s is a landmark in metallodrug-based chemotherapy. The success of cisplatin in the clinic, followed by oxaliplatin and carboplatin, along with their drawbacks relating mainly to resistance development and severe toxicity, initiated research on polynuclear platinum complexes and on Pt(IV) complexes as prodrugs. Furthermore, the indicated shortcomings led to the exploration of other transition and main group metal ions, among them Ru(II/III), Au(I/III), Ti(IV), V(IV/V), and Ga(III) including also the essential metal ions Fe(II/III), Cu(I/II), and Zn(II). Ionic as well as covalent and non-covalent interactions between structurally very different complexes and biomolecules like nucleic acids, proteins, and carbohydrates are studied and discussed with regard to their possible anticancer actions. Hence, MILS-18 summarizes the research at the forefront of medicinal inorganic chemistry, including studies on the next-generation, tailor-made anticancer drugs. All this and more is treated in an authoritative and timely manner in the 17 stimulating chapters of this book, written by 39 internationally recognized experts from 10 nations (from the US via Europe to China and Australia). The impact of this vibrant research area is manifested by more than 2700 references, nearly 150 illustrations (more than half in color) and several comprehensive tables. Metallo-Drugs: Development and Action of Anticancer Agents is an essential resource for scientists working in the wide range from enzymology, material sciences, analytical, organic, and inorganic biochemistry all the way through to medicine including the clinic ... not forgetting that it also provides excellent information for teaching.

Nomenclature of Inorganic Chemistry II

Author : International Union of Pure and Applied Chemistry. Commission on the Nomenclature of Inorganic Chemistry
Publisher : Royal Society of Chemistry
ISBN 13 : 9780854044870
Total Pages : 144 pages
Book Rating : 4.0/5 (448 download)

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Book Synopsis Nomenclature of Inorganic Chemistry II by : International Union of Pure and Applied Chemistry. Commission on the Nomenclature of Inorganic Chemistry

Download or read book Nomenclature of Inorganic Chemistry II written by International Union of Pure and Applied Chemistry. Commission on the Nomenclature of Inorganic Chemistry and published by Royal Society of Chemistry. This book was released on 2001 with total page 144 pages. Available in PDF, EPUB and Kindle. Book excerpt: A thoroughly revised edition of the 'Red Book'.

New Ideas on Inorganic Chemistry

Author : Alfred Werner
Publisher :
ISBN 13 :
Total Pages : 296 pages
Book Rating : 4.:/5 (89 download)

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Book Synopsis New Ideas on Inorganic Chemistry by : Alfred Werner

Download or read book New Ideas on Inorganic Chemistry written by Alfred Werner and published by . This book was released on 1911 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Chemical Thermodynamics of Compounds and Complexes of U, Np, Pu, Am, Tc, Se, Ni and Zr With Selected Organic Ligands

Author :
Publisher : Elsevier
ISBN 13 : 0080457525
Total Pages : 1133 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Chemical Thermodynamics of Compounds and Complexes of U, Np, Pu, Am, Tc, Se, Ni and Zr With Selected Organic Ligands by :

Download or read book Chemical Thermodynamics of Compounds and Complexes of U, Np, Pu, Am, Tc, Se, Ni and Zr With Selected Organic Ligands written by and published by Elsevier. This book was released on 2005-11-04 with total page 1133 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency. It contains a critical review of the literature on thermodynamic data for compounds of complexes of oxalate, citrate, EDTA and iso-saccharinate with uranium, neptunium, plutonium, americium, technetium, selenium, nickel and zirconium. A review team, composed of five internationally recognized experts, has critically reviewed all the scientific literature containing chemical thermodynamic information for the above mentioned systems. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography. Contributed by: Wolfgang Hummel (Chairman), Paul Scherrer Institute, Switzerland, Giorgio Anderegg, Swiss Federal Institute of Technology (ETH), Switzerland, Linfeng Rao, Lawrence Berkeley National Laboratory, U.S.A., Ignasi Puigdomènech, Swedish Nuclear Fuel and Waste Management Co. (SKB), Sweden, and Osamu Tochiyama, Tohoku University, Japan. * Critical review of all literature on chemical thermodynamics for compounds and complexes of oxalate, citrate, EDTA and iso-saccharinate with U, Np, Pu, Am, Tc and Se, Ni and Zr. * Tables of recommended Selected Values for thermochemical properties * Documented review procedure * Exhaustive bibliography * Intended to meet requirements of radioactive waste management community * Valuable reference source for the physical, analytical and environmental chemist.

Computational Modelling of Molecular Nanomagnets

Author : Gopalan Rajaraman
Publisher : Springer Nature
ISBN 13 : 3031310381
Total Pages : 507 pages
Book Rating : 4.0/5 (313 download)

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Book Synopsis Computational Modelling of Molecular Nanomagnets by : Gopalan Rajaraman

Download or read book Computational Modelling of Molecular Nanomagnets written by Gopalan Rajaraman and published by Springer Nature. This book was released on with total page 507 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Advances in Inorganic Chemistry

Author :
Publisher : Academic Press
ISBN 13 : 0080578969
Total Pages : 385 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Advances in Inorganic Chemistry by :

Download or read book Advances in Inorganic Chemistry written by and published by Academic Press. This book was released on 1999-11-23 with total page 385 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bioinorganic to solid state. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.

Homogeneous and Heterogeneous Catalysis

Author :
Publisher : VSP
ISBN 13 : 9789067640732
Total Pages : 1206 pages
Book Rating : 4.6/5 (47 download)

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Book Synopsis Homogeneous and Heterogeneous Catalysis by :

Download or read book Homogeneous and Heterogeneous Catalysis written by and published by VSP. This book was released on 1986-06 with total page 1206 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Proceedings contains plenary lectures and selected poster communications spanning the entire field of catalysis --- from catalysis by protons to catalysis by multinuclear clusters and ultra-disperse particles. It includes discussion of the recent results of fundamental research conducted at the juncture between homogeneous and heterogeneous catalysis. New ideas, based on modern physical and quantum-chemical methods, and concerning the mechanism of formation and functioning of active sites of catalysts are suggested. It is shown how the cyclic change of atomic distribution in the active site occurs during catalytic transformations. In addition, the Proceedings report new data on methods of ''assembling'' molecularly organized catalytic systems and on the mechanisms of their action. The various problems such as the effect of strong metal--support interaction, migration of atoms in active sites, and design of catalytic properties of substances are also widely discussed. Similarities and differences in mechanisms of action of homogeneous and heterogeneous catalysts are considered, using as examples CO hydrogenation, hydrogenolysis of saturated hydrocarbons, selective hydrogenation and oxidation of olefins, metathesis and polymerization of olefins, hydrosilylation and hydroformylation of olefins, etc.

Progress in Inorganic Chemistry, Volume 21

Author : Stephen J. Lippard
Publisher : John Wiley & Sons
ISBN 13 : 047016672X
Total Pages : 306 pages
Book Rating : 4.4/5 (71 download)

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Book Synopsis Progress in Inorganic Chemistry, Volume 21 by : Stephen J. Lippard

Download or read book Progress in Inorganic Chemistry, Volume 21 written by Stephen J. Lippard and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive series of volumes on inorganic chemistry provides inorganic chemists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Every volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. Each volume features a complete subject index and the series includes a cumulative index as well.

Principles and Applications of Density Functional Theory in Inorganic Chemistry II

Author : Nikolas Kaltsoyannis
Publisher : Springer Science & Business Media
ISBN 13 : 9783540218616
Total Pages : 264 pages
Book Rating : 4.2/5 (186 download)

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Book Synopsis Principles and Applications of Density Functional Theory in Inorganic Chemistry II by : Nikolas Kaltsoyannis

Download or read book Principles and Applications of Density Functional Theory in Inorganic Chemistry II written by Nikolas Kaltsoyannis and published by Springer Science & Business Media. This book was released on 2004 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt: E. Clot, O. Eisenstein: Agostic Interactions from a Computational Perspective: One Name, many Interpretations.- Robert J. Deet: Recent Developments in Computational Bioinorganic Chemistry.- E. Ruiz: Theoretical Study of the Exchange Coupling in Large Polynuclear Transition Metal Complexes Using DFT Methods.- D. Sánches-Portal, P. Ordejón, E. Canadell: Computing the Properties of Materials from First Principles with SIESTA.- F. Corà, M. Alfredsson, G. Mallia, D.S. Middlemiss, W.C. Mackrodt, R. Dovesi, R. Orlando: The Performance of Hybrid Density Functionals in Solid State Chemistry

Molecular Magnetic Materials

Author : Barbara Sieklucka
Publisher : John Wiley & Sons
ISBN 13 : 3527339531
Total Pages : 508 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Molecular Magnetic Materials by : Barbara Sieklucka

Download or read book Molecular Magnetic Materials written by Barbara Sieklucka and published by John Wiley & Sons. This book was released on 2017-01-17 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive overview of this rapidly expanding interdisciplinary field of research. After a short introduction to the basics of magnetism and molecular magnetism, the text goes on to cover specific properties of molecular magnetic materials as well as their current and future applications. Design strategies for acquiring molecular magnetic materials with desired physical properties are discussed, as are such multifunctional materials as high Tc magnets, chiral and luminescent magnets, magnetic sponges as well as photo- and piezo-switching magnets. The result is an excellent resource for materials scientists, chemists, physicists and crystal engineers either entering or already working in the field.

Structural Nanocrystalline Materials

Author : Carl C. Koch
Publisher : Cambridge University Press
ISBN 13 : 1139464019
Total Pages : 362 pages
Book Rating : 4.1/5 (394 download)

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Book Synopsis Structural Nanocrystalline Materials by : Carl C. Koch

Download or read book Structural Nanocrystalline Materials written by Carl C. Koch and published by Cambridge University Press. This book was released on 2007-05-31 with total page 362 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanocrystalline materials exhibit exceptional mechanical properties, representing an exciting new class of structural materials for technological applications. The advancement of this important field depends on the development of new fabrication methods, and an appreciation of the underlying nano-scale and interface effects. This authored book addresses these essential issues, presenting for the first time a fundamental, coherent and current account at the theoretical and practical level of nanocrystalline and nanocomposite bulk materials and coatings. The subject is approached systematically, covering processing methods, key structural and mechanical properties, and a wealth of applications. This is a valuable resource for graduate students studying nanomaterials science and nanotechnologies, as well as researchers and practitioners in materials science and engineering.