Polymer Photodegradation

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Publisher : Springer Science & Business Media
ISBN 13 : 9401112746
Total Pages : 679 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Polymer Photodegradation by : J.F. Rabek

Download or read book Polymer Photodegradation written by J.F. Rabek and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 679 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the last two decades, the production of polymers and plastics has been increasing rapidly. In spite of developing new polymers and polymeric materials, only 40~60 are used commercially on a large scale. It has been estimated that half of the annual production of polymers is employed outdoors. The photochemical instability of most polymers limits their outdoor application as they are photodegraded quickly over periods from months to a few years. To the despair of technologists and consumers alike, photodegradation and environmental ageing of polymers occur much faster than can be expected from knowledge collected in laboratories. In order to improve polymer photostability there has been a very big effort during the last 30 years to understand the mechanisms involved in photodegradation and environmental ageing. This book represents the author's attempt, based on his 25 years' experience in research on photodegradation and photo stabilization, to collect and generalize a number of available data on the photodegradation of polymers. The space limitation and the tremendous number of publications in the past two decades have made a detailed presentation of all important results and data difficult. The author apologizes to those whose work has not been quoted or widely presented in this book. Because many published results are very often contradictory, it has been difficult to present a fully critical review of collected knowledge, without antagonizing authors. For that reason, all available theories, mechanisms and different suggestions have been presented together, and only practice can evaluate which of them are valid.

Photodegradation of Polymers

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3642800904
Total Pages : 222 pages
Book Rating : 4.6/5 (428 download)

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Book Synopsis Photodegradation of Polymers by : Jan F. Rabek

Download or read book Photodegradation of Polymers written by Jan F. Rabek and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book on physical characteristics and practical aspects of polymer photodegradation Rabek emphasizes the experimental work on the subject. The most important feature of the book is the physical interpretation of polymer degradation, e.g. mechanism of UV/light absorption, formation of excited states, energy transfer mechanism, kinetics, dependence on physical properties of macromolecules and polymer matrices, formation of mechanical defects, practics during environmental ageing. He includes also some aspects of polymer photodegradation in environmental and space condition.

Photostabilization of Polymers

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Publisher : Springer Science & Business Media
ISBN 13 : 9400907478
Total Pages : 607 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Photostabilization of Polymers by : J.F. Rabek

Download or read book Photostabilization of Polymers written by J.F. Rabek and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 607 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the last two decades, the production of polymers and plastics has been increasing rapidly. In spite of developing new polymers and polymeric materials, only 40-60 are used commercially on a large scale. It has been estimated that half of the annual production of polymers is employed outdoors. Increasing the stability of polymers and plastics towards heat, light, atmospheric oxygen and other environmental agents and weathering conditions has always been a very important problem. The photochemical instability of most of polymers limits them to outdoor application, where they are photo degraded fast over periods ranging from months to a few years. To the despair of technologists and consumers alike, photodegrada tion and environmental ageing of polymers occur much faster than can be expected from knowledge collected in laboratories. In many cases, improved methods of preparation and purification of both monomers and polymers yield products of better quality and higher resistance to heat and light. However, without stabilization of polymers by applica tion of antioxidants (to decrease thermal oxidative degradation) and photostabilizers (to decrease photo-oxidative degradation) it would be impossible to employ polymers and plastics in everyday use.

Photodegradation, photooxidation, and photostabilization of polymers

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Author :
Publisher :
ISBN 13 :
Total Pages : 588 pages
Book Rating : 4.:/5 (44 download)

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Book Synopsis Photodegradation, photooxidation, and photostabilization of polymers by : Bengt G. Ränby

Download or read book Photodegradation, photooxidation, and photostabilization of polymers written by Bengt G. Ränby and published by . This book was released on 1989 with total page 588 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Photodegradation and Light Stabilization of Heterochain Polymers

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Author :
Publisher : CRC Press
ISBN 13 : 9047410874
Total Pages : 195 pages
Book Rating : 4.0/5 (474 download)

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Book Synopsis Photodegradation and Light Stabilization of Heterochain Polymers by : Niyazi

Download or read book Photodegradation and Light Stabilization of Heterochain Polymers written by Niyazi and published by CRC Press. This book was released on 2006-11-14 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photodegradation and light stabilization are very important aspects of polymer aging. Polymer degradation includes different types of processes: thermodegradation, oxidation, acting of ozone, photodegradation, radiation, hydrolysis, mechanical degradation, and biodegradation. It is very important to know the mechanism of polymer degradation in orde

Photodegradation, Photo-oxidation, and Photostabilization of Polymers

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Author :
Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 600 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Photodegradation, Photo-oxidation, and Photostabilization of Polymers by : Bengt G. Rånby

Download or read book Photodegradation, Photo-oxidation, and Photostabilization of Polymers written by Bengt G. Rånby and published by John Wiley & Sons. This book was released on 1975 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Polymer Degradation and Stabilisation

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Author :
Publisher : CUP Archive
ISBN 13 : 9780521357975
Total Pages : 236 pages
Book Rating : 4.3/5 (579 download)

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Book Synopsis Polymer Degradation and Stabilisation by : Norman Grassie

Download or read book Polymer Degradation and Stabilisation written by Norman Grassie and published by CUP Archive. This book was released on 1988-04-14 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of polymer degradation and stabilisation is of considerable practical importance as the industrial uses of polymeric materials continue to expand. In this book, the authors lucidly relate technological phenomena to the chemistry and physics of degradation and stabilisation processes. Degradation embraces a variety of technologically important phenomena ranging from relatively low temperature processes such as 'weathering' of plastics, 'fatigue' of rubbers through the processing of polymers in shearing mixers to very high temperature processes such as flammability and ablation. All these technological phenomena have in common certain basic chemical reactions. Thus 'weathering' has its roots in photo-oxidation, 'fatigue' and melt-degradation in mechano-oxidation and flammability, and ablation in ablation in pyrolysis and vapour phase oxidation.

Degradation of Polymers

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Author :
Publisher : Elsevier
ISBN 13 : 0080868088
Total Pages : 579 pages
Book Rating : 4.0/5 (88 download)

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Book Synopsis Degradation of Polymers by : R.G. Compton

Download or read book Degradation of Polymers written by R.G. Compton and published by Elsevier. This book was released on 1975-01-01 with total page 579 pages. Available in PDF, EPUB and Kindle. Book excerpt: Degradation of Polymers

Polymer Photodegradation

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Author :
Publisher : Springer
ISBN 13 : 9789401045568
Total Pages : 664 pages
Book Rating : 4.0/5 (455 download)

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Book Synopsis Polymer Photodegradation by : Jan F. RABEK

Download or read book Polymer Photodegradation written by Jan F. RABEK and published by Springer. This book was released on 2012-09-19 with total page 664 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the last two decades, the production of polymers and plastics has been increasing rapidly. In spite of developing new polymers and polymeric materials, only 40~60 are used commercially on a large scale. It has been estimated that half of the annual production of polymers is employed outdoors. The photochemical instability of most polymers limits their outdoor application as they are photodegraded quickly over periods from months to a few years. To the despair of technologists and consumers alike, photodegradation and environmental ageing of polymers occur much faster than can be expected from knowledge collected in laboratories. In order to improve polymer photostability there has been a very big effort during the last 30 years to understand the mechanisms involved in photodegradation and environmental ageing. This book represents the author's attempt, based on his 25 years' experience in research on photodegradation and photo stabilization, to collect and generalize a number of available data on the photodegradation of polymers. The space limitation and the tremendous number of publications in the past two decades have made a detailed presentation of all important results and data difficult. The author apologizes to those whose work has not been quoted or widely presented in this book. Because many published results are very often contradictory, it has been difficult to present a fully critical review of collected knowledge, without antagonizing authors. For that reason, all available theories, mechanisms and different suggestions have been presented together, and only practice can evaluate which of them are valid.

Photodegradation of Polymers

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Author :
Publisher :
ISBN 13 : 9783642800917
Total Pages : 230 pages
Book Rating : 4.8/5 (9 download)

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Book Synopsis Photodegradation of Polymers by : Jan F Rabek

Download or read book Photodegradation of Polymers written by Jan F Rabek and published by . This book was released on 1996-07-04 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Degradation and Stabilisation of PVC

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Publisher : Springer Science & Business Media
ISBN 13 : 9400956185
Total Pages : 325 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Degradation and Stabilisation of PVC by : J. Owen

Download or read book Degradation and Stabilisation of PVC written by J. Owen and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 325 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyvinyl chloride has played a key role in the development of the plastics industry over the past 40 years and continues to be a polymer of major importance. The reasons for its enormous versatility and range of application derive from a combination of the basic structure which gives rise to a relatively tough and rigid material and its ability to accept a range of plasticisers and other additives which can modify its physical characteristics to produce a range of flexible products. Two major problems, however, have tested the skill and ingenuity of PVC technologists since earliest times. One is the thermal instability of the material at the temperatures required for melt processing and fabrication, and the second is the photochemical instability which until recently has limited the potentially large range of outdoor applications. Both problems have been handled in a commercially satisfactory way by the gradual development of a range of stabilisers, lubricants and other processing aids and the high quality material which has resulted has led to massive utilisation of PVC by industry. Totally adequate stabilisation requires a detailed understanding of the mechanisms by which degradation processes are initiated and propagated. Although great advances have been made in this respect in recent years the problem remains incompletely understood. This book presents an account of the present position and the problems which remain to be solved.

Photodegradation of Water Pollutants

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Author :
Publisher : CRC Press
ISBN 13 : 9780849324598
Total Pages : 322 pages
Book Rating : 4.3/5 (245 download)

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Book Synopsis Photodegradation of Water Pollutants by : Martin M. Halmann

Download or read book Photodegradation of Water Pollutants written by Martin M. Halmann and published by CRC Press. This book was released on 1995-12-05 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photodegradation of Water Pollutants, the only complete survey available of current photocatalytic methods for treating water pollutants, covers all aspects of light-stimulated detoxification. Ideal for researchers and students, this new book explains methods for pollution treatment that have proven more effective than conventional biodegradation. Photodegradation of Water Pollutants examines advanced oxidation processes that have been successful in treating the chemical substances produced by industrial effluents and intensive agriculture. These oxidation processes include irradiation with ultraviolet or visible light, the use of homogenous sensitizers, such as dyes, and the use of heterogeneous photocatalysts, such as dispersed semiconductors. In addition, Photodegradation of Water Pollutants addresses the naturally occurring self-cleaning of some pollutants in sunlit surface waters, as well as several alternative non-photochemical approaches to water treatment. Available treatment options are discussed for the main groups of water pollutants, including toxic inorganic ions (cyanides, heavy metals), hydrocarbon derivatives (oil spills, surfactants, pulp and paper wastes), halocarbons, organo-N, organo-P, and organo-S compounds. The text also contains a unique section on the economics of advanced oxidation pollution treatments.

Polymer Analysis Polymer Physics

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Author :
Publisher : Springer
ISBN 13 : 9783540612186
Total Pages : 0 pages
Book Rating : 4.6/5 (121 download)

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Book Synopsis Polymer Analysis Polymer Physics by :

Download or read book Polymer Analysis Polymer Physics written by and published by Springer. This book was released on 1996-11-04 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Fundamentals of Polymer Degradation and Stabilization

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 9781851667734
Total Pages : 218 pages
Book Rating : 4.6/5 (677 download)

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Book Synopsis Fundamentals of Polymer Degradation and Stabilization by : N.S. Allen

Download or read book Fundamentals of Polymer Degradation and Stabilization written by N.S. Allen and published by Springer Science & Business Media. This book was released on 1992-10-31 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the past decade, the field of polymer degradation and stabilization has become a subject of central importance in polymer science and technology. This book provides a fundamental source of information designed for those with only a basic understanding of the background of the field.

Polymer Degradation and Stabilization

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Publisher : Springer Science & Business Media
ISBN 13 : 3642693768
Total Pages : 129 pages
Book Rating : 4.6/5 (426 download)

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Book Synopsis Polymer Degradation and Stabilization by : W. L. Hawkins

Download or read book Polymer Degradation and Stabilization written by W. L. Hawkins and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 129 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of polymers as an important class of material was inhibited at the first by the premature failure of these versatile compounds in many applications. The deterioration of important properties of both natural and synthetic polymers is the result of irreversible changes in composition and structure of polymers molecules. As a result of these reactions, mechanical, electrical and/or aesthetic properties are degraded beyond acceptable limits. It is now generally recognized that stabilization against degradation is necessary if the useful life of polymers is to be extended sufficiently to meet design requirements for long-term applications. Polymers degrade by a wide variety of mechanisms, several of which affect all polymers through to varying degree. This monograph will concentrate on those degradation mechanisms which result from reactions of polymers with oxygen in its various forms and which are accelerated by heat and/or radiation. Those stabilization mechanisms are discussed which are based on an understanding of degradation reaction mechanisms that are reasonably well established. The stabilization of polymers is still undergoing a transition from an art to a science as mechanisms of degradation become more fully developed. A scientific approach to stabilization can only be approached when there is an understanding of the reactions that lead to degradation. Stabilization against biodegradation and burning will not be discussed since there is not a clear understanding of how polymers degrade under these conditions.

Modern Styrenic Polymers

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 9780471497523
Total Pages : 796 pages
Book Rating : 4.4/5 (975 download)

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Book Synopsis Modern Styrenic Polymers by : John Scheirs

Download or read book Modern Styrenic Polymers written by John Scheirs and published by John Wiley & Sons. This book was released on 2003-03-28 with total page 796 pages. Available in PDF, EPUB and Kindle. Book excerpt: This title addresses the latest developments in the field, covering the major advances that have occurred over the past five years in the polymerization and structure of new generation polystyrenes that are broadening its scope of application. It covers the advent of branched polystyrenes, syndiotactic polystyrene, high-molecular weight general purpose PS, styrenic interpolymers, and clear SBS copolymers Presents voluminous research previously only reported at conferences in one reference Unique coverage of a topic not found in the field

Degradation and Stabilization of Polymers

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Publisher :
ISBN 13 :
Total Pages : 742 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Degradation and Stabilization of Polymers by : Hans Helmut Gunter Jellinek

Download or read book Degradation and Stabilization of Polymers written by Hans Helmut Gunter Jellinek and published by . This book was released on 1983 with total page 742 pages. Available in PDF, EPUB and Kindle. Book excerpt: