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Phosphorus Mobility And Speciation Under Dynamic Redox Conditions In Shallow Eutrophic Freshwater Systems
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Book Synopsis Phosphorus Mobility and Speciation Under Dynamic Redox Conditions in Shallow Eutrophic Freshwater Systems by : Austin E. Wilkes
Download or read book Phosphorus Mobility and Speciation Under Dynamic Redox Conditions in Shallow Eutrophic Freshwater Systems written by Austin E. Wilkes and published by . This book was released on 2019 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt: Internal loading of phosphorus (P) from lake sediments can delay the recovery of lakes from eutrophication for years to decades following decreases in external nutrient inputs. While internal P loading is a pervasive problem in freshwater systems, molecular speciation of P in benthic sediments of these systems remains poorly characterized. As different P species will exhibit different responses to changing sediment-water interface (SWI) geochemistry, quantifying P speciation in sediments is a critical step in understanding P dynamics in sediment-water systems. Here, various synchrotron-based techniques were employed to directly probe the bonding environments of P and iron (Fe) in natural and experimentally manipulated lake sediments in order to link chemical speciation to chemical behavior and to identify the geochemical drivers that mediate this linkage. We manipulated SWI redox conditions in mesocosm experiments to investigate the impacts of prolonged anoxia and redox oscillations on P mobility and speciation in sediments. Mesocosm experiments demonstrate that oscillating redox conditions near the SWI may drive accelerated P release from sediments relative to uninterrupted reducing conditions. Sediment P is found to be predominantly associated with Fe oxyhydroxides, calcium carbonate, and apatite minerals in three shallow hyper/eutrophic lakes in northern Vermont. In Missisquoi Bay and Lake Carmi, Fe redox cycling controls P mobility via precipitation and dissolution of Fe oxyhydroxides. In the hypereutrophic Shelburne Pond, the presence of Fe sulfides precludes redox-driven P cycling and P mobility is instead dominated by organic matter mineralization. Our results demonstrate that internal P loading can manifest differently in similar shallow lake systems due to differences in lake configuration, sediment P and Fe speciation, and organic content of sediments. This work demonstrates the potential utility, as well as the limitations, of P K- edge X-ray absorption near edge structure spectroscopy in determining sediment P speciation in freshwater lakes.
Book Synopsis Interactions of Phosphate and Silicate with Iron Oxides in Freshwater Environments by : Md Abdus Sabur
Download or read book Interactions of Phosphate and Silicate with Iron Oxides in Freshwater Environments written by Md Abdus Sabur and published by . This book was released on 2019 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt: Internal phosphorus loads, from bottom sediments to surface waters, are often comparable in magnitude to external phosphorus loads, particularly in water bodies with a history of high external phosphorus inputs from point and non-point sources. The benthic release of phosphorus can be influenced by several factors including pH, redox potential, temperature, microbial activity and the concentration of competitive anions at or near the sediment-water interface. Dissolved silicate occurs ubiquitously in natural waters and may act as a competitive ion to phosphate. Nonetheless, prior to the work in this thesis, the effect of silicate on internal phosphorus loading remained poorly understood. This thesis addresses several of the mechanisms through which silicate may influence the mobilization of aqueous phosphate from sediments in aquatic environments. The thesis starts with a thorough literature review of phosphorus biogeochemical cycling in relation to eutrophication, sediment-surface water interactions, mineralogy, competitive anions and microbial activity (Chapter 1). Next, adsorption/desorption of phosphate on/from goethite, a model ferric (hydr)oxide mineral, is investigated in the absence and presence of dissolved silicate. The influence of dissolved silicate on phosphate adsorption is evaluated through laboratory experiments and application of the CD-MUSIC model (Chapter 2). The results show that increasing concentrations of silicate decrease phosphate adsorption, leaving more phosphate in the aqueous phase. The competitive effect of dissolved silicate is more pronounced under alkaline conditions. Subsequently, phosphate desorption experiments were conducted under dynamic pH conditions in the presence and absence of silicate (Chapter 3). The experimental results show that the gradual transition from acidic to alkaline conditions induces the desorption of phosphate adsorbed to goethite under acidic conditions. The presence of silicate in the phosphate/goethite system does not affect phosphate desorption, because of the stronger surface complexation of phosphate to goethite. In addition to adsorption and desorption processes, the co-precipitation of phosphate with iron and the potential subsequent dissolution of these co-precipitates as a result of changing physico-chemical conditions may also control the mobility of phosphate in aquatic environments. The effects of dissolved silicate on the co-precipitation of phosphate with iron and the reactivity of the resulting solids are examined (Chapter 4). Ferric (co)-precipitates (i.e., Fe-P-Si) with variable Si:Fe ratios, were synthesized either via oxidation of Fe2+(aq) or by increasing the pH of Fe3+(aq) solution. The solids were characterized by a combination of chemical and spectroscopic techniques including attenuated total internal reflectance Fourier transform infrared spectroscopy (ATR-FTIR) and X-ray powder diffraction spectroscopy (XRD). Similar solid phase P:Fe ratios were found in co-precipitates formed from solutions with different dissolved silicate concentrations, regardless of the method of preparation. This suggests that the interactions between phosphate and iron during co-precipitation were not affected by dissolved silicate. The ferric (co)-precipitates were subsequently reductively dissolved abiotically in buffered ascorbate-citrate solution to determine their reactivity under reducing conditions. The kinetic data show that the co-precipitates with higher Si:Fe ratios were more recalcitrant to dissolution. For co-precipitates synthesized via oxidation of Fe2+(aq), reductive dissolution experiments were also conducted in the presence of the facultative anaerobic iron reducing bacteria Shewanella putrefaciens. XRD analyses of the residual solids imply that solids with the higher Si:Fe ratios may be more resistant to microbially mediated reductive dissolution. The relative reactivities of the co-precipitates obtained by the two synthesis methods are also addressed in Chapter 4. In Chapter 5, the effect of silicate on the mobility of phosphate in a natural sediment was evaluated via flow-through experiments. The results show that dissolved silicate enhances the mobility of phosphate at the sediment-water interface. Ferric (co)-precipitates were formed at the oxic surface of sediment columns via the oxidation of ferrous iron supplied with upflowing solutions containing variable silicate concentrations. The subsequent dissolution of these co-precipitates under imposed anoxic conditions at the sediment-water interface indicates that the co-precipitates formed at higher dissolved silicate concentrations were more reactive towards reductive dissolution. These results are therefore in apparent contradiction to those observed in Chapter 4. The ferric (co)-precipitates (i.e., Fe-P-Si) evaluated in Chapter 4 were prepared from solutions containing high concentrations of iron, phosphate and silicate, by imposing either rapid aeration or pH increase. These conditions were selected to maximize the yield from the syntheses. The synthesis methods in Chapter 4 are therefore most representative of aquatic environments where co-precipitation occurs rapidly (e.g., groundwater springs) and the concentrations of these dissolved constituents are fairly high. However, in many other aquatic environments, the diffusion-controlled release of Fe2+(aq) from the deeper sediments results in the gradual oxidation of Fe2+ at the sediment-water interface under oxic conditions. This process is typical in lake sediments with minimal advective exchange between surface water and groundwater. This gradual oxidation (at relatively low concentrations of Fe2+) results in the slow formation of ferric (co)-precipitates which may be dissimilar to those synthesized herein and discussed in Chapter 4. The ferric (co)-precipitates synthesized with the flow-through column system in Chapter 5 may be better analogues of slow forming co-precipitates in diffusion dominated or moderately advection influenced aquatic sediments than those synthesized in Chapter 4. Finally, to elucidate the likely importance of the various influences of dissolved silicate on phosphate mobility investigated in this thesis, concentrations of dissolved phosphate and silicate as well as pH data are extracted from the US National Water Information System (NWIS) network (data shown in Chapter 1 and Chapter 2). The NWIS data along with combined experimental and modeling results suggest that silicate-mediated phosphate mobilization is likely a commonly occurring process at the sediment-water interface of lakes and reservoirs. This thesis also demonstrates the multiple roles of silicate on the mobilization of phosphate in aquatic environments, and improves our fundamental knowledge of iron, phosphorus and silicon cycling in freshwater environments.
Book Synopsis Internal Phosphorus Loading in Lakes by : Bryan Spears
Download or read book Internal Phosphorus Loading in Lakes written by Bryan Spears and published by . This book was released on 2020 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nutrient enrichment of lakes is a ubiquitous problem, impacting ecological and human health on a global scale by accelerating the pace of eutrophication, often resulting in algal blooms, depleted dissolved oxygen concentrations, and economic harm to surrounding communities. In many lakes, bed sediments are a major but unrecognized source of phosphorus to the water, a process known as internal phosphorus loading. Internal loading is notoriously difficult to measure and manage given the need to access processes operating on and within the lakebed. In addition, climate change threatens to promote internal loading. For example, warming of lakes can increase the release of phosphorus from sediments due to 1) longer and stronger periods of lake stratification resulting in sediment anoxia and 2) enhanced microbial decomposition of organic matter. Degraded water quality not only impairs ecological health but also can influence social pride and community morale. This is the first book dedicated to the understanding of internal phosphorus loading in lakes and examines the causes, the ecological and societal impacts, and options for managing this complex phenomenon. With contributions from leading experts, this edited volume provides a broad view of internal phosphorus loading, methods for measurement, management practices for water quality improvement, case studies from around the world, and recommendations for addressing this growing concern. It is essential reading for environmental and engineering professionals involved in lake and reservoir management, students and faculty in limnology, state and federal authorities involved in water quality regulation, and lakefront homeowners and management boards interested in maintaining lake water quality and managing algal blooms. Key Features * First-ever comprehensive volume on internal phosphorous loading that clearly details what it is and why it occurs * Identifies and explores the drivers of internal phosphorus loading * Provi
Book Synopsis Phosphorus: Polluter and Resource of the Future by : Christian Schaum
Download or read book Phosphorus: Polluter and Resource of the Future written by Christian Schaum and published by IWA Publishing. This book was released on 2018-03-15 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive book provides an up-to-date and international approach that addresses the Motivations, Technologies and Assessment of the Elimination and Recovery of Phosphorus from Wastewater. This book is part of the Integrated Environmental Technology Series.
Download or read book Shallow Lakes ’95 written by Lech Kufel and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 405 pages. Available in PDF, EPUB and Kindle. Book excerpt: Shallow lakes differ from deep ones in many aspects of nutrient dynamics, biotic structure and interactions of various trophic levels. Though very common in European lowlands, shallow lakes attract inadequate attention from research teams. This book aims at filling gaps in our knowledge of the processes which take place in non-stratified lakes. It contains proceedings from the international conference `Shallow Lakes *95' held in Mikolajki, Poland, on 20-26 August 1995. In more than 50 original papers up-to-date views on eutrophication, degradation and recovery of shallow lakes are presented. The first four sections of the book (Nutrient fluxes, Biotic structure, Trophic interactions and Whole lake studies) deal with theoretical aspects of lake functioning while the fifth (Biomanipulation, restoration and management) is devoted to practical measures undertaken to improve water quality in shallow lakes. The book is therefore addressed to university biologists and ecologists and PhD students, as well as to managers involved in restoration of shallow lakes.
Book Synopsis The Structuring Role of Submerged Macrophytes in Lakes by : Erik Jeppesen
Download or read book The Structuring Role of Submerged Macrophytes in Lakes written by Erik Jeppesen and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt: The rapid growth of the discipline of aquatic ecology has been driven both by scientific interest in the complexities of aquatic ecosystems and by their enormous environmental importance and sensitivity. This book focuses on the remarkably diverse roles played by underwater plants, and is divided into three parts: 10 thematic chapters, followed by 18 case studies, and rounded off by three integrative chapters. The topics range from macrophytes as fish food to macrophytes as mollusc and microbe habitat, making this of interest to aquatic ecologists as well as limnologists, ecosystem ecologists, microbial ecologists, fish biologists, and environmental managers.
Book Synopsis Biogeochemistry of Wetlands by : K. Ramesh Reddy
Download or read book Biogeochemistry of Wetlands written by K. Ramesh Reddy and published by CRC Press. This book was released on 2022-09-10 with total page 926 pages. Available in PDF, EPUB and Kindle. Book excerpt: The globally important nature of wetland ecosystems has led to their increased protection and restoration as well as their use in engineered systems. Underpinning the beneficial functions of wetlands are a unique suite of physical, chemical, and biological processes that regulate elemental cycling in soils and the water column. This book provides an in-depth coverage of these wetland biogeochemical processes related to the cycling of macroelements including carbon, nitrogen, phosphorus, and sulfur, secondary and trace elements, and toxic organic compounds. In this synthesis, the authors combine more than 100 years of experience studying wetlands and biogeochemistry to look inside the black box of elemental transformations in wetland ecosystems. This new edition is updated throughout to include more topics and provide an integrated view of the coupled nature of biogeochemical cycles in wetland systems. The influence of the elemental cycles is discussed at a range of scales in the context of environmental change including climate, sea level rise, and water quality. Frequent examples of key methods and major case studies are also included to help the reader extend the basic theories for application in their own system. Some of the major topics discussed are: Flooded soil and sediment characteristics Aerobic-anaerobic interfaces Redox chemistry in flooded soil and sediment systems Anaerobic microbial metabolism Plant adaptations to reducing conditions Regulators of organic matter decomposition and accretion Major nutrient sources and sinks Greenhouse gas production and emission Elemental flux processes Remediation of contaminated soils and sediments Coupled C-N-P-S processes Consequences of environmental change in wetlands# The book provides the foundation for a basic understanding of key biogeochemical processes and its applications to solve real world problems. It is detailed, but also assists the reader with box inserts, artfully designed diagrams, and summary tables all supported by numerous current references. This book is an excellent resource for senior undergraduates and graduate students studying ecosystem biogeochemistry with a focus in wetlands and aquatic systems.
Download or read book Redox written by J. Schüring and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt: Few processes are as important for environmental geochemistry as the interplay between the oxidation and reduction of dissolved and solid species. The knowledge of the redox conditions is most important to predict the geochemical behaviour of a great number of components, the mobilities of which are directly or indirectly controlled by redox processes. The understanding of the chemical mechanisms responsible for the establishment of measurable potentials is the major key for the evaluation and sensitive interpretation of data. This book is suitable for advanced undergraduates as well as for all scientists dealing with the measurement and interpretation of redox conditions in the natural environment.
Book Synopsis Freshwater Microbiology by : David C. Sigee
Download or read book Freshwater Microbiology written by David C. Sigee and published by John Wiley & Sons. This book was released on 2005-09-27 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt: This unique textbook takes a broad look at the rapidly expanding field of freshwater microbiology. Concentrating on the interactions between viruses, bacteria, algae, fungi and micro-invertebrates, the book gives a wide biological appeal. Alongside conventional aspects such as phytoplankton characterisation, seasonal changes and nutrient cycles, the title focuses on the dynamic and applied aspects that are not covered within the current textbooks in the field. Complete coverage of all fresh water biota from viruses to invertebrates Unique focus on microbial interactions including coverage of biofilms, important communities on all exposed rivers and lakes. New information on molecular and microscopical techniques including a study of gene exchange between bacteria in the freshwater environment. Unique emphasis on the applied aspects of freshwater microbiology with particular emphasis on biodegradation and the causes and remediation of eutrophication and algal blooms.
Book Synopsis Water Quality for Ecosystem and Human Health by : Geneviève M. Carr
Download or read book Water Quality for Ecosystem and Human Health written by Geneviève M. Carr and published by UNEP/Earthprint. This book was released on 2008 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt: This document is intended to provide an overview of the major components of surface and ground water quality and how these relate to ecosystem and human health. Local, regional and global assessments of water quality monitoring data are used to illustrate key features of aquatic environments, and to demonstrate how human activities on the landscape can influence water quality in both positive and negative ways. Clear and concise background knowledge on water quality can serve to support other water assessments.
Book Synopsis Water Quality Assessments by : Deborah V Chapman
Download or read book Water Quality Assessments written by Deborah V Chapman and published by CRC Press. This book was released on 1996-08-22 with total page 658 pages. Available in PDF, EPUB and Kindle. Book excerpt: This guidebook, now thoroughly updated and revised in its second edition, gives comprehensive advice on the designing and setting up of monitoring programmes for the purpose of providing valid data for water quality assessments in all types of freshwater bodies. It is clearly and concisely written in order to provide the essential information for all agencies and individuals responsible for the water quality.
Book Synopsis Phosphorus Release from Lake Sediments by : Raymond E. Wildung
Download or read book Phosphorus Release from Lake Sediments written by Raymond E. Wildung and published by . This book was released on 1973 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Phosphorus in Environmental Technology by : E. Valsami-Jones
Download or read book Phosphorus in Environmental Technology written by E. Valsami-Jones and published by IWA Publishing. This book was released on 2004-05-31 with total page 681 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phosphorus in Environmental Technology: Principles and Applications, provides a definitive and detailed presentation of state-of-the-art knowledge on the environmental behaviour of phosphorus and its applications to the treatment of waters and soils. Special attention is given to phosphorus removal for recovery technologies, a concept that has emerged over the past 5-6 years. The book features an all-encompassing approach: the fundamental science of phosphorus (chemistry, geochemistry, mineralogy, biology), key aspects of its environmental behaviour and mobility, industrial applications (treatment, removal, recovery) and the principles behind such applications, novel biotechnologies and, importantly, it also addresses socio-economic issues which often influence implementation and the ultimate success of any new technology. A detailed subject index helps the reader to find their way through the different scientific and technological aspects covered, making it an invaluable reference work for students, professionals and consultants dealing with phosphorus-related environmental technologies. State-of-the-art knowledge on the behaviour of phosphorus and its applications to environmental science and technology. Covers all aspects of phosphorus in the environment, engineered and biological systems; an interdisciplinary text.
Book Synopsis Hydrodynamics and Water Quality by : Zhen-Gang Ji
Download or read book Hydrodynamics and Water Quality written by Zhen-Gang Ji and published by John Wiley & Sons. This book was released on 2017-07-05 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt: The primary reference for the modeling of hydrodynamics and water quality in rivers, lake, estuaries, coastal waters, and wetlands This comprehensive text perfectly illustrates the principles, basic processes, mathematical descriptions, case studies, and practical applications associated with surface waters. It focuses on solving practical problems in rivers, lakes, estuaries, coastal waters, and wetlands. Most of the theories and technical approaches presented within have been implemented in mathematical models and applied to solve practical problems. Throughout the book, case studies are presented to demonstrate how the basic theories and technical approaches are implemented into models, and how these models are applied to solve practical environmental/water resources problems. This new edition of Hydrodynamics and Water Quality: Modeling Rivers, Lakes, and Estuaries has been updated with more than 40% new information. It features several new chapters, including one devoted to shallow water processes in wetlands as well as another focused on extreme value theory and environmental risk analysis. It is also supplemented with a new website that provides files needed for sample applications, such as source codes, executable codes, input files, output files, model manuals, reports, technical notes, and utility programs. This new edition of the book: Includes more than 120 new/updated figures and 450 references Covers state-of-the-art hydrodynamics, sediment transport, toxics fate and transport, and water quality in surface waters Provides essential and updated information on mathematical models Focuses on how to solve practical problems in surface waters—presenting basic theories and technical approaches so that mathematical models can be understood and applied to simulate processes in surface waters Hailed as “a great addition to any university library” by the Journal of the American Water Resources Association (July 2009), Hydrodynamics and Water Quality, Second Edition is an essential reference for practicing engineers, scientists, and water resource managers worldwide.
Book Synopsis Diffusive Gradients in Thin-Films for Environmental Measurements by : William Davison
Download or read book Diffusive Gradients in Thin-Films for Environmental Measurements written by William Davison and published by Cambridge University Press. This book was released on 2016-09-15 with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt: An essential guide to the applications and usage of the diffusive gradients in thin-films (DGT) technique for students and professionals.
Book Synopsis Intermittent Rivers and Ephemeral Streams by : Thibault Datry
Download or read book Intermittent Rivers and Ephemeral Streams written by Thibault Datry and published by Academic Press. This book was released on 2017-07-11 with total page 624 pages. Available in PDF, EPUB and Kindle. Book excerpt: Intermittent Rivers and Ephemeral Streams: Ecology and Management takes an internationally broad approach, seeking to compare and contrast findings across multiple continents, climates, flow regimes, and land uses to provide a complete and integrated perspective on the ecology of these ecosystems. Coupled with this, users will find a discussion of management approaches applicable in different regions that are illustrated with relevant case studies. In a readable and technically accurate style, the book utilizes logically framed chapters authored by experts in the field, allowing managers and policymakers to readily grasp ecological concepts and their application to specific situations. - Provides up-to-date reviews of research findings and management strategies using international examples - Explores themes and parallels across diverse sub-disciplines in ecology and water resource management utilizing a multidisciplinary and integrative approach - Reveals the relevance of this scientific understanding to managers and policymakers
Book Synopsis Biogeochemistry of Estuaries by : Thomas S. Bianchi
Download or read book Biogeochemistry of Estuaries written by Thomas S. Bianchi and published by Oxford University Press. This book was released on 2007 with total page 721 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offering a comprehensive and interdisciplinary approach to the study of biochemical cycling in estuaries, this text utilises numerous illustrations and an extensive literature base in order to impart the current state-of-the-art knowledge in the field.
