Performance of Conductive Polymers as Binders for Lithium-Ion Batteries

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (134 download)

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Book Synopsis Performance of Conductive Polymers as Binders for Lithium-Ion Batteries by : Kuan Zhai

Download or read book Performance of Conductive Polymers as Binders for Lithium-Ion Batteries written by Kuan Zhai and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The growing market for energy storage devices raises the demand for lithium ion batteries (LIBs) with higher energy density and power density. Enhanced LIB performance requires the improvement of the electrode materials, so that the use of conductive polymer binders becomes an important option when the choice of active materials is limited. Compared to a traditional binder, such as PVDF, the advanced polymer binders exhibit not only electrochemical stability and adhesion strength, but also ionic/electronic conductivity for a thick electrode and/or a high-capacity electrode. Such considerations make the 3,4-propylenedioxythiophene-2,5-dicarboxylic acid family (ProDOT) and poly{[N,N'-bis(2-octyldodecyl)-naphthalene-1,4,5,8-bis (dicarboximide)-2,6-diyl]-alt-5,5'-(2,2'-bithiophene)} family (P(NDI2OD-T2)) of polymers attractive candidates for the LIB binders.Various experiments were designed and conducted on the selected binder candidates in order to evaluate different aspects of polymer behavior. The material properties are investigated based on thin film three-electrode systems, while the half-cell and full-cell experiments represent how the binder influences the electrodes and practical batteries, respectively. According to those experiments, the Hexyl-ProDOT polymer shows excellent mixed ionic/electronic conductivity and surface-controlled electrochemical reaction mechanism, which significantly enhances the performance of LiNi0.8Co0.15Al0.05O2 (NCA) electrode and improves the NCA-Nb2O5 battery. However, the effectiveness of P(NDI2OD-T2) is limited by its poor stability at low voltage.

Conductive Polymeric Binder for Lithium-ion Battery Anode

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ISBN 13 :
Total Pages : 35 pages
Book Rating : 4.:/5 (914 download)

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Book Synopsis Conductive Polymeric Binder for Lithium-ion Battery Anode by : Tianxiang Gao

Download or read book Conductive Polymeric Binder for Lithium-ion Battery Anode written by Tianxiang Gao and published by . This book was released on 2015 with total page 35 pages. Available in PDF, EPUB and Kindle. Book excerpt: Tin (Sn) has a high-specific capacity (993 mAhg-1) as an anode material for Li-ion batteries. To overcome the poor cycling performance issue caused by its large volume expansion and pulverization during the charging and discharging process, many researchers put efforts into it. Most of the strategies are through nanostructured material design and introducing conductive polymer binders that serve as matrix of the active material in anode. This thesis aims for developing a novel method for preparing the anode to improve the capacity retention rate. This would require the anode to have high electrical conductivity, high ionic conductivity, and good mechanical properties, especially elasticity. Here the incorporation of a conducting polymer and a conductive hydrogel in Sn-based anodes using a one-step electrochemical deposition via a 3-electrode cell method is reported: the Sn particles and conductive component can be electrochemically synthesized and simultaneously deposited into a hybrid thin film onto the working electrode directly forming the anode. A well-defined three dimensional network structure consisting of Sn nanoparticles coated by conducting polymers is achieved. Such a conductive polymer-hydrogel network has multiple advantageous features: meshporous polymeric structure can offer the pathway for lithium ion transfer between the anode and electrolyte; the continuous electrically conductive polypyrrole network, with the electrostatic interaction with elastic, porous hydrogel, poly (2-acrylamido-2-methyl-1-propanesulfonic acid-co-acrylonitrile) (PAMPS) as both the crosslinker and doping anion for polypyrrole (PPy) can decrease the volume expansion by creating porous scaffold and softening the system itself. Furthermore, by increasing the amount of PAMPS and creating an interval can improve the cycling performance, resulting in improved capacity retention about 80% after 20 cycles, compared with only 54% of that of the control sample without PAMPS. The cycle is performed under current of 0.1 C.

Conducting Polymers as Functional Binders for Lithium Ion Battery Positive Electrodes

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (954 download)

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Book Synopsis Conducting Polymers as Functional Binders for Lithium Ion Battery Positive Electrodes by : Pratik Ranjan Das

Download or read book Conducting Polymers as Functional Binders for Lithium Ion Battery Positive Electrodes written by Pratik Ranjan Das and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Lithium ion batteries have been successfully used in portable electronics applications. Their application areas are growing continuously. For their commercial application in electromobility and stationary storage, high energy density, high rate capability and long cycle life is required. This work demonstrates the improvement in energy density and rate capability of LiFePO4 composite positive electrodes by replacing conventional binders with conducting polymers such as polyaniline (PANI), poly-o-methoxy aniline (POMA), poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS). Conducting polymers act in a dual role as binder and conducting additive in the positive composite electrode. The capacity and charging rate capability of the electrodes are improved by using PANI and POMA. However, due to their inherent lower conductivity in the emeraldine state, complete replacement of carbon additive is not possible. On the other hand in this work it is shown that PEDOT:PSS is stable and highly conducting in the working potential window of LiFePO4 electrodes (2.8-4 V). Hence composite electrodes free of any carbon additive are prepared with PEDOT:PSS and LiFePO4. In order to understand the flow behaviour of composite slurries with different solid content; rheological measurements is performed with rheometer. All slurries show solid-like behavior due to formation of a network structure of LiFePO4 bridged by PEDOT:PSS chains. However, the solid loading of the slurries influences the distribution of the agglomerates and the binder affecting also the thickness, the adhesion and the electrical conductivity of the coatings casted from the different slurries under the same conditions. The optimum electrochemical performance is achieved with slurries containing 40 % solid loading. The electrochemical performance and the cycling stability of the composite electrodes are compared to the behaviour of conventional positive electrodes with carbon additives and PVDF binder. With increasing PEDOT:PSS content a decrease in the overvoltage and correspondingly an improvement in the rate capability is observed. Composite electrodes containing 8% PEDOT:PSS show comparable electrode capacity and better cycling stability as compared to conventional PVDF based system. engl.

Printed Batteries

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Publisher : John Wiley & Sons
ISBN 13 : 1119287421
Total Pages : 270 pages
Book Rating : 4.1/5 (192 download)

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Book Synopsis Printed Batteries by : Senentxu Lanceros-Méndez

Download or read book Printed Batteries written by Senentxu Lanceros-Méndez and published by John Wiley & Sons. This book was released on 2018-04-23 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offers the first comprehensive account of this interesting and growing research field Printed Batteries: Materials, Technologies and Applications reviews the current state of the art for printed batteries, discussing the different types and materials, and describing the printing techniques. It addresses the main applications that are being developed for printed batteries as well as the major advantages and remaining challenges that exist in this rapidly evolving area of research. It is the first book on printed batteries that seeks to promote a deeper understanding of this increasingly relevant research and application area. It is written in a way so as to interest and motivate readers to tackle the many challenges that lie ahead so that the entire research community can provide the world with a bright, innovative future in the area of printed batteries. Topics covered in Printed Batteries include, Printed Batteries: Definition, Types and Advantages; Printing Techniques for Batteries, Including 3D Printing; Inks Formulation and Properties for Printing Techniques; Rheological Properties for Electrode Slurry; Solid Polymer Electrolytes for Printed Batteries; Printed Battery Design; and Printed Battery Applications. Covers everything readers need to know about the materials and techniques required for printed batteries Informs on the applications for printed batteries and what the benefits are Discusses the challenges that lie ahead as innovators continue with their research Printed Batteries: Materials, Technologies and Applications is a unique and informative book that will appeal to academic researchers, industrial scientists, and engineers working in the areas of sensors, actuators, energy storage, and printed electronics.

Electronically Conductive Polymer Binder for Lithium-ion Battery Electrode

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (925 download)

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Book Synopsis Electronically Conductive Polymer Binder for Lithium-ion Battery Electrode by :

Download or read book Electronically Conductive Polymer Binder for Lithium-ion Battery Electrode written by and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A family of carboxylic acid group containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

Quantifying the Effect of Conductive Polymer Binders on Li-O2 Battery Performance

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ISBN 13 :
Total Pages : 53 pages
Book Rating : 4.:/5 (112 download)

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Book Synopsis Quantifying the Effect of Conductive Polymer Binders on Li-O2 Battery Performance by : Amy J. LeBar

Download or read book Quantifying the Effect of Conductive Polymer Binders on Li-O2 Battery Performance written by Amy J. LeBar and published by . This book was released on 2019 with total page 53 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Conducting Polymers-Based Energy Storage Materials

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Publisher : CRC Press
ISBN 13 : 0429510888
Total Pages : 353 pages
Book Rating : 4.4/5 (295 download)

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Book Synopsis Conducting Polymers-Based Energy Storage Materials by : Dr Inamuddin

Download or read book Conducting Polymers-Based Energy Storage Materials written by Dr Inamuddin and published by CRC Press. This book was released on 2019-12-10 with total page 353 pages. Available in PDF, EPUB and Kindle. Book excerpt: Conducting polymers are organic polymers which contain conjugation along the polymer backbone that conduct electricity. Conducting polymers are promising materials for energy storage applications because of their fast charge–discharge kinetics, high charge density, fast redox reaction, low-cost, ease of synthesis, tunable morphology, high power capability and excellent intrinsic conductivity compared with inorganic-based materials. Conducting Polymers-Based Energy Storage Materials surveys recent advances in conducting polymers and their composites addressing the execution of these materials as electrodes in electrochemical power sources. Key Features: Provides an overview on the conducting polymer material properties, fundamentals and their role in energy storage applications. Deliberates cutting-edge energy storage technology based on synthetic metals (conducting polymers) Covers current applications in next-generation energy storage devices. Explores the new aspects of conducting polymers with processing, tunable properties, nanostructures and engineering strategies of conducting polymers for energy storage. Presents up-to-date coverage of a large, rapidly growing and complex conducting polymer literature on all-types electrochemical power sources. This book is an invaluable guide for students, professors, scientists, and R&D industrial specialists working in the field of advanced science, nanodevices, flexible electronics, and energy science.

Functional Polymers for Metal-ion Batteries

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Publisher : John Wiley & Sons
ISBN 13 : 3527350683
Total Pages : 229 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Functional Polymers for Metal-ion Batteries by : Shanqing Zhang

Download or read book Functional Polymers for Metal-ion Batteries written by Shanqing Zhang and published by John Wiley & Sons. This book was released on 2023-05-22 with total page 229 pages. Available in PDF, EPUB and Kindle. Book excerpt: Functional Polymers for Metal-Ion Batteries Unique and useful book covering fundamental knowledge and practical applications of polymer materials in energy storage systems In Functional Polymers for Metal-Ion Batteries, the recent development and achievements of polymer-based materials are comprehensively analyzed in four directions, including electrode materials, binders, separators, and solid electrolytes, highlighting the working mechanisms, classification, design strategies, and practical applications of these polymer materials in mental-ion batteries. Specific sample topics covered in Functional Polymers for Metal-Ion Batteries include: Prominent advantages of various solid-state electrolytes, such as low flammability, easy processability, more tolerance to vibration, shock, and mechanical deformation Why and how functional polymers present opportunities to maximize energy density and pursue the sustainability of the battery industry How the application of functional polymers in metal-ion batteries helps enhance the high energy density of energy storage devices and reduce carbon footprint during production How development of functional separators could significantly lower the cost of battery manufacturing Providing a comprehensive understanding of the role of polymers in the whole configuration of metal-ion batteries from electrodes to electrolytes, Functional Polymers for Metal-Ion Batteries is an ideal resource for materials scientists, electrochemists, and polymer, solid state, and physical chemists who wish to understand the latest developments of this technology.

Conjugated Polymer Nanostructures for Energy Conversion and Storage Applications

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Publisher : John Wiley & Sons
ISBN 13 : 3527345574
Total Pages : 38 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Conjugated Polymer Nanostructures for Energy Conversion and Storage Applications by : Srabanti Ghosh

Download or read book Conjugated Polymer Nanostructures for Energy Conversion and Storage Applications written by Srabanti Ghosh and published by John Wiley & Sons. This book was released on 2021-06-01 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt: A timely overview of fundamental and advanced topics of conjugated polymer nanostructures Conjugated Polymer Nanostructures for Energy Conversion and Storage Applications is a comprehensive reference on conjugated polymers for energy applications. Distinguished academic and editor Srabanti Ghosh offers readers a broad overview of the synthesis, characterization, and energy-related applications of nanostructures based on conjugated polymers. The book includes novel approaches and presents an interdisciplinary perspective rooted in the interfacing of polymer and synthetic chemistry, materials science, organic chemistry, and analytical chemistry. This book provides complete descriptions of conjugated polymer nanostructures and polymer-based hybrid materials for energy conversion, water splitting, and the degradation of organic pollutants. Photovoltaics, solar cells, and energy storage devices such as supercapacitors, lithium ion battery electrodes, and their associated technologies are discussed, as well. Conjugated Polymer Nanostructures for Energy Conversion and Storage Applications covers both the fundamental topics and the most recent advances in this rapidly developing area, including: The design and characterization of conjugated polymer nanostructures, including the template-free and chemical synthesis of polymer nanostructures Conjugated polymer nanostructures for solar energy conversion and environmental protection, including the use of conjugated polymer-based nanocomposites as photocatalysts Conjugated polymer nanostructures for energy storage, including the use of nanocomposites as electrode materials The presentation of different and novel methods of utilizing conjugated polymer nanostructures for energy applications Perfect for materials scientists, polymer chemists, and physical chemists, Conjugated Polymer Nanostructures for Energy Conversion and Storage Applications also belongs on the bookshelves of organic chemists and any other practicing researchers, academics, or professionals whose work touches on these highly versatile and useful structures.

The Effects of Various Conductive Additive and Polymeric Binder Contents on the Performance of a Lithium-ion Composite

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis The Effects of Various Conductive Additive and Polymeric Binder Contents on the Performance of a Lithium-ion Composite by :

Download or read book The Effects of Various Conductive Additive and Polymeric Binder Contents on the Performance of a Lithium-ion Composite written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Fundamental electrochemical methods, cell performance tests, and physical characterization tests such as electron microscopy were used to study the effects of levels of the inert materials (acetylene black (AB), a nano-conductive additive, and polyvinylidene difluoride (PVDF), a polymer binder) on the power performance of lithium-ion composite cathodes. The electronic conductivity of the AB/PVDF composites at different compositions was measured with a four-point probe direct current method. The electronic conductivity was found to increase rapidly and plateau at a AB:PVDF ratio 0.2:1 (by weight), with 0.8:1 being the highest conductivity composition. AB:PVDF compositions along the plateau of 0.2:1, 0.4:1, 0.6:1 and 0.8:1 were investigated. Electrodes of each of those compositions were fabricated with different fractions of AB/PVDF to active material. It was found that at the 0.8:1 AB:PVDF, the rate performance improved with increases in the AB/PVDF loading, whereas at the 0.2:1 AB:PVDF, the rate performance improved with decreases in the AB/PVDF loading. The impedance of electrodes made with 0.6:1 AB:PVDF was low and relatively invariant.

Conductive Polymer-based Binders for Si Anode Electrodes in Lithium Ion Batteries

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ISBN 13 :
Total Pages : 64 pages
Book Rating : 4.:/5 (11 download)

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Book Synopsis Conductive Polymer-based Binders for Si Anode Electrodes in Lithium Ion Batteries by : Yuze Yao

Download or read book Conductive Polymer-based Binders for Si Anode Electrodes in Lithium Ion Batteries written by Yuze Yao and published by . This book was released on 2017 with total page 64 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Conducting Polymers as Functional Binders for Lithium Ion Battery

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ISBN 13 : 9783330009134
Total Pages : 132 pages
Book Rating : 4.0/5 (91 download)

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Book Synopsis Conducting Polymers as Functional Binders for Lithium Ion Battery by : Pratik Ranjan Das

Download or read book Conducting Polymers as Functional Binders for Lithium Ion Battery written by Pratik Ranjan Das and published by . This book was released on 2016-12-13 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Silicon Anode Systems for Lithium-Ion Batteries

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Publisher : Elsevier
ISBN 13 : 0323851819
Total Pages : 536 pages
Book Rating : 4.3/5 (238 download)

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Book Synopsis Silicon Anode Systems for Lithium-Ion Batteries by : Prashant N. Kumta

Download or read book Silicon Anode Systems for Lithium-Ion Batteries written by Prashant N. Kumta and published by Elsevier. This book was released on 2021-09-10 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt: Silicon Anode Systems for Lithium-Ion Batteries is an introduction to silicon anodes as an alternative to traditional graphite-based anodes. The book provides a comprehensive overview including abundance, system voltage, and capacity. It provides key insights into the basic challenges faced by the materials system such as new configurations and concepts for overcoming the expansion and contraction related problems. This book has been written for the practitioner, researcher or developer of commercial technologies. Provides a thorough explanation of the advantages, challenge, materials science, and commercial prospects of silicon and related anode materials for lithium-ion batteries Provides insights into practical issues including processing and performance of advanced Si-based materials in battery-relevant materials systems Discusses suppressants in electrolytes to minimize adverse effects of solid electrolyte interphase (SEI) formation and safety limitations associated with this technology

Conducting Polymers for Advanced Energy Applications

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Publisher : CRC Press
ISBN 13 : 1000513475
Total Pages : 517 pages
Book Rating : 4.0/5 (5 download)

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Book Synopsis Conducting Polymers for Advanced Energy Applications by : Ram K. Gupta

Download or read book Conducting Polymers for Advanced Energy Applications written by Ram K. Gupta and published by CRC Press. This book was released on 2021-12-23 with total page 517 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book details the use of conducting polymers and their composites in supercapacitors, batteries, photovoltaics, and fuel cells, nearly covering the entire spectrum of energy area under one title. Conducting Polymers for Advanced Energy Applications covers a range of advanced materials based on conducting polymers, the fundamentals, and the chemistry behind these materials for energy applications. FEATURES Covers materials, chemistry, various synthesis approaches, and the properties of conducting polymers and their composites Discusses commercialization and markets and elaborates on advanced applications Presents an overview and the advantages of using conducting polymers and their composites for advanced energy applications Describes a variety of nanocomposites, including metal oxides, chalcogenides, graphene, and materials beyond graphene Offers the fundamentals of electrochemical behavior This book provides a new direction for scientists, researchers, and students in materials science and polymer chemistry who seek to better understand the chemistry behind conducting polymers and improve their performance for use in advanced energy applications.

Lithium-ion Batteries

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Publisher : Nova Science Publishers
ISBN 13 : 9781536168464
Total Pages : 0 pages
Book Rating : 4.1/5 (684 download)

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Book Synopsis Lithium-ion Batteries by : Chappell Morneau

Download or read book Lithium-ion Batteries written by Chappell Morneau and published by Nova Science Publishers. This book was released on 2020 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Lithium-Ion Batteries: Properties, Advantages and Limitations summarizes research progress in anode and cathode binders of lithium ion batteries in the past 20 years. So far, the binders reported in the literature involve polymers, natural extracts, conductive binders and self-healing binders. Additionally, the authors provide a comprehensive review of state-of-the-art progress in graphite-silicon anodes, from novel structure design to electrode fabrication, from half-coin-cell testing to pouch-full-cell evaluation, and from fundamental mechanistic studies to applied research. High-performance polymeric separators, which serve as an important component in lithium-ion batteries, are also attracting increased attention. The requirements for the separators, their types, preparation methods and latest developments are summarized. Following this, recent advancements in ab initio screening of electrode materials for lithium-ion batteries by the construction of activity-stability Volcano plots are summarized. The underlying approach may also be applied in the investigation of catalytic reactions. In closing, the authors examine the diffusion equation in curvilinear coordinates by using the method of characteristics. This method is commonly applied to solve first order partial differential equations"--

NEXAFS Spectroscopy

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Publisher : Springer Science & Business Media
ISBN 13 : 3662028530
Total Pages : 415 pages
Book Rating : 4.6/5 (62 download)

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Book Synopsis NEXAFS Spectroscopy by : Joachim Stöhr

Download or read book NEXAFS Spectroscopy written by Joachim Stöhr and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 415 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the first ever comprehensive treatment of NEXAFS spectroscopy. It is suitable for novice researchers as an introduction to the field, while experts will welcome the detailed description of state-of-the-art instrumentation and analysis techniques, along with the latest experimental and theoretical results.

Materials for Advanced Batteries

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Publisher : Springer Science & Business Media
ISBN 13 : 1468438514
Total Pages : 366 pages
Book Rating : 4.4/5 (684 download)

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Book Synopsis Materials for Advanced Batteries by : D. Murphy

Download or read book Materials for Advanced Batteries written by D. Murphy and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: The idea of a NATO Science Committee Institute on "Materials for Advanced Batteries" was suggested to JB and DWM by Dr. A. G. Chynoweth. His idea was to bring together experts in the field over the entire spectrum of pure research to applied research in order to familiarize everyone with potentially interesting new systems and the problems involved in their development. Dr. M. C. B. Hotz and Professor M. N. Ozdas were instrumental in helping organize this meeting as a NATO Advanced Science Institute. An organlzlng committee consisting of the three of us along with W. A. Adams, U. v Alpen, J. Casey and J. Rouxel organized the program. The program consisted of plenary talks and poster papers which are included in this volume. Nearly half the time of the conference was spent in study groups. The aim of these groups was to assess the status of several key aspects of batteries and prospects for research opportunities in each. The study groups and their chairmen were: Current status and new systems J. Broadhead High temperature systems W. A. Adams Interface problems B. C. H. Steele Electrolytes U. v Alpen Electrode materials J. Rouxel These discussions are summarized in this volume. We and all the conference participants are most grateful to Professor J. Rouxel for suggesting the Aussois conference site, and to both he and Dr. M. Armand for handling local arrangements.