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Organometallic And Surface Chemistry Of Mixed Metal Systems
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Book Synopsis Organometallic and Surface Chemistry of Mixed-metal Systems by :
Download or read book Organometallic and Surface Chemistry of Mixed-metal Systems written by and published by . This book was released on 1993 with total page 4 pages. Available in PDF, EPUB and Kindle. Book excerpt: Three new SO[sub 2] complexes of metal cluster compounds were prepared: [PPN][HFe[sub 3](CO)[sub 9]SO[sub 2]], and [PPN][sub 2][Ru[sub 3]CO[sub 9]SO[sub 2]] and [PPN][sub 2][Ru[sub 3](CO)[sub 7](SO[sub 2])[sub 3]]. The x-ray structures were determined for two of these and the transformation of bound SO[sub 2] to duster bound SO and S ligands was investigated.
Book Synopsis Organometallic and Surface Chemistry of Mixed-metal Systems. Progress Report, March 15, 1992--March 14, 1993 by :
Download or read book Organometallic and Surface Chemistry of Mixed-metal Systems. Progress Report, March 15, 1992--March 14, 1993 written by and published by . This book was released on 1993 with total page 4 pages. Available in PDF, EPUB and Kindle. Book excerpt: Three new SO2 complexes of metal cluster compounds were prepared: [PPN][HFe3(CO)9SO2], and [PPN]2[Ru3CO9SO2] and [PPN]2[Ru3(CO)--(SO2)3]. The x-ray structures were determined for two of these and the transformation of bound SO2 to duster bound SO and S ligands was investigated.
Book Synopsis Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis by : Jean-Marie Basset
Download or read book Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis written by Jean-Marie Basset and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt: Surface organometallic chemistry is a new field bringing together researchers from organometallic, inorganic, and surface chemistry and catalysis. Topics ranging from reaction mechanisms to catalyst preparation are considered from a molecular basis, according to which the "active site" on a catalyst surface has a supra-molecular character. This. the first book on the subject, is the outcome of a NATO Workshop held in Le Rouret. France, in May. 1986. It is our hope that the following chapters and the concluding summary of recommendations for research may help to provide a definition of surface organometallic chemistry. Besides catalysis. the central theme of the Workshop, four main topics are considered: 1) Reactions of organometallics with surfaces of metal oxides, metals. and zeolites; 2) Molecular models of surfaces, metal oxides, and metals; 3) Molecular approaches to the mechanisms of surface reactions; 4) Synthesis and modification of zeolites and related microporous solids. Most surface organometallic chemistry has been carried out on amorphous high-surf ace-area metal oxides such as silica. alumina. magnesia, and titania. The first chapter. contributed by KNOZINGER. gives a short summary of the structure and reactivity of metal oxide surfaces. Most of our understanding of these surfaces is based on acid base and redox chemistry; this chemistry has developed from X-ray and spectroscopic data, and much has been inferred from the structures and reactivities of adsorbed organic probe molecules. There are major opportunities for extending this understanding by use of well-defined (single crystal) oxide surfaces and organometallic probe molecules.
Book Synopsis Modern Surface Organometallic Chemistry by : Jean-Marie Basset
Download or read book Modern Surface Organometallic Chemistry written by Jean-Marie Basset and published by John Wiley & Sons. This book was released on 2009-07-10 with total page 725 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covering everything from the basics to recent applications, this monograph represents an advanced overview of the field. Edited by internationally acclaimed experts respected throughout the community, the book is clearly divided into sections on fundamental and applied surface organometallic chemistry. Backed by numerous examples from the recent literature, this is a key reference for all chemists.
Book Synopsis Advances in Organometallic Chemistry by :
Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 1996-02-12 with total page 429 pages. Available in PDF, EPUB and Kindle. Book excerpt: This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry--the study of compounds containing carbon metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry. In basic research, organometallics have contributed inter alia to: Metal cluster chemistry Surface chemistry The stabilization of highly reactive species by metal coordination Chiral synthesis The formulation of multiple bonds between carbon and the other elements and between the elements themselves
Book Synopsis Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials by : J.F. Harrod
Download or read book Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials written by J.F. Harrod and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the ten years since the scientific rationale for the design, synthesis and application of inorganic and organometallic polymers (IOPs) was first conceptualised, we have witnessed the first tentative exploration of IOPs as precursors to new materials, with efforts focusing on the design and synthesis of novel ceramic precursors. Developing expertise led to precursor studies combined with the characterisation of the transformation processes that occur when IOPs are converted to ceramic materials. Now at maturity, the science presented in this volume reveals the polymer precursor approach to materials synthesis together with examples of processing ceramic shapes for a range of mechanical properties, the development of sophisticated, noninvasive analytical techniques, and IOP design rationales relying on well-defined processing-property relationships. The production of multifunctional IOPs is described, providing ion conductivity, gas sensing, bioactivity, magnetic properties, etc., combined with processability. The existence of well-defined IOPs and the exquisite control that can be exerted on sol-gel systems now provide access to such a variety of mixed organic-organometallic and/or inorganic hybrid systems that their exploitation is likely to develop into an entirely new field of materials chemistry. Future exciting avenues of research are also being opened up with the advent of buckyballs, Met-Cars, dopable preceramics, rigid-rod organometallics, and molecular tinkertoys.
Book Synopsis Surface and Interfacial Organometallic Chemistry and Catalysis by : C. Copéret
Download or read book Surface and Interfacial Organometallic Chemistry and Catalysis written by C. Copéret and published by Springer Science & Business Media. This book was released on 2005-11-03 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by numerous experts
Book Synopsis Organometallic Bonding and Reactivity by : J.M. Brown
Download or read book Organometallic Bonding and Reactivity written by J.M. Brown and published by Springer. This book was released on 2003-07-01 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt: The making and breaking of carbon-metal bonds is fundamental to all the processes of organometallic chemistry and metal mediated homogeneous or heterogeneous catalysis. The ever expanding scope of highly specific stoichiometric and catalytic transformations or organic substrates involving metals requires a thorough physical and theoretical understanding of fundamental principles of organometallic structure and reactivity. Diffraction experiments form the basis of tailoring the molecular architecture of organometallic compounds for specific functions. Mass spectrometric techniques possess the power to provide direct information on the energetics of transient species generated in the gas-phase. Computational chemistry with ab initio or density functional methods make a reliable numerical assessment of structures and (relative) energies increasingly feasible. Embedding methods, combining quantum chemistry with force field of semiempirical MO treatments, quantum dynamic studies and the computational modelling of solvent effects extend the utility of the basic methods. This volume in the series Topics in Organometallic Chemistry presents a survey by renowned experts of important experimental and theoretical developments to elucidate basic aspects of bonding, energetics, reaction mechanisms, molecular geometries and solid-state structures of organometallic compounds. Written by authors with frontier research expertise in their fields, both experimental and quantum chemical techniques, methodologies, results and interpretations are detailed in a manner suitable for the non-specialist, who seeks state-of-the-art information in the respective field.
Book Synopsis Advances in Organometallic Chemistry by :
Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 1998-09-29 with total page 439 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is an essential reference work for the academic and industrial chemists and will provide up-to-date material at the cutting edge of chemistry research. This widely-acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry. In basic research, organometallics have contributed inter alia to: Metal cluster chemistry Surface chemistry The stabilization of highly reactive species by metal coordination Chiral synthesis The formulation of multiple bonds between carbon and the other elements and between the elements themselves
Book Synopsis Advances in Organometallic Chemistry by :
Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 1989-06-01 with total page 363 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Organometallic Chemistry
Book Synopsis Metal-Metal Bonds and Clusters in Chemistry and Catalysis by : John P. Fackler Jr.
Download or read book Metal-Metal Bonds and Clusters in Chemistry and Catalysis written by John P. Fackler Jr. and published by Springer Science & Business Media. This book was released on 2013-11-22 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book contains a series of papers and abstracts from the 7th Industry-University Cooperative Chemistry Program symposium held in the spring of 1989 at Texas A&M University. The symposium was larger than previous IUCCP symposia since it also celebrated the 25 years that had elapsed since the initial discovery by F. A. Cotton and his co-workers of the existence of metal-metal quadruple bonds. Cotton's discovery demonstrated that multiple bonding in inorganic systems is not governed by the same constraints observed in organic chemistry regarding s and p orbital involvement. The d orbitals are involved in the multiple bonding description. The quadruple bond involves considerable d orbital overlap between adjacent metal centers. Part I of this series of papers focuses upon the impact of this discovery and describes further contributions to the development of the field. Multiple metal-metal bonding now is known to permeate broad areas of transition metal chemistry. The understanding of metal-metal bonding that developed as a result of the discovery of multiple metal-metal bonding awakened a new chemistry involving metal clusters. Clusters were defined by Cotton to be species containing metal-metal bonding. Clusters in catalysis therefore seemed a logical grouping of papers in this symposium. Clusters play an every increasing role in the control of chemical reactions. Part II of this book describes some of the interesting new developments in this field. In Part III the papers examine the role clusters play in describing and understanding solid state materials.
Book Synopsis Scientific and Technical Aerospace Reports by :
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1995 with total page 704 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organometallics by : Christoph Elschenbroich
Download or read book Organometallics written by Christoph Elschenbroich and published by John Wiley & Sons. This book was released on 2006-03-10 with total page 839 pages. Available in PDF, EPUB and Kindle. Book excerpt: THE textbook on organometallic chemistry. Comprehensive and up-to-date, the German original is already a classic, making this third completely revised and updated English edition a must for graduate students and lecturers in chemistry, inorganic chemists, chemists working with/on organometallics, bioinorganic chemists, complex chemists, and libraries. Over one third of the chapters have been expanded to incorporate developments since the previous editions, while the chapter on organometallic catalysis in synthesis and production appears for the first time in this form. From the reviews of the first English editions: 'The selection of material and the order of its presentation is first class ... Students and their instructors will find this book extraordinarily easy to use and extraordinarily useful.' -Chemistry in Britain 'Elschenbroich and Salzer have written the textbook of choice for graduate or senior-level courses that place an equal emphasis on main group element and transition metal organometallic chemistry. ... this book can be unequivocally recommended to any teacher or student of organometallic chemistry.' - Angewandte Chemie International Edition 'The breadth and depth of coverage are outstanding, and the excitement of synthetic organometallic chemistry comes across very strongly.' - Journal of the American Chemical Society
Book Synopsis The Chemistry of Mixed-metal Organometallic Clusters by : Saifun Nahar
Download or read book The Chemistry of Mixed-metal Organometallic Clusters written by Saifun Nahar and published by . This book was released on 1998 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy Research Abstracts written by and published by . This book was released on 1995 with total page 782 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Organometallic Chemistry of the Transition Metals by : Robert H. Crabtree
Download or read book The Organometallic Chemistry of the Transition Metals written by Robert H. Crabtree and published by Wiley-Interscience. This book was released on 2001 with total page 560 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive introduction to principles and practices There have been a number of notable advances in the field of organometallic chemistry over the past decade. Transition metal organometallic chemistry has provided researchers- especially those working in the pharmaceuticals, natural product synthesis, and polymer industries-with powerful new synthetic tools, and the field has expanded to include certain life science aspects, such as metalloenzymes involving organometallic intermediates. Fully updated and expanded to reflect recent advances, this Third Edition of the classic text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds. It also supplies a wealth of practical information about relevant reaction mechanisms, along with detailed descriptions of contemporary applications to organic synthesis, organized by reaction type. Additionally, the numerous references to pertinent literature found throughout the text are appreciated by students and professional chemists alike. New to this edition are sections covering: * Coupling reactions * C-F bond activation * Giant molecules * Paramagnetic organometallics * Surface organometallic chemistry Additionally, those sections covering metal alkyls, aryls, hydrides, metallocene polymerization, and related s-bonded ligands have been substantially revised and updated. The Organometallic Chemistry of the Transition Metals, Third Edition is an unparalleled pedagogic resource, appropriate as a main text for courses in inorganic chemistry and organometallic chemistry, and as a supplementary text for courses in bioinorganic chemistry. It is also a valuable working reference for professional chemists who need to become better acquainted with the subject.
Book Synopsis Organometallic Chemistry by : R. C. Mehrotra
Download or read book Organometallic Chemistry written by R. C. Mehrotra and published by New Age International. This book was released on 2007 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Book Is A Revised Edition Of A Lucid And Stimulating Introductory Account Of Organometallic Chemistry, An Exciting And Rapidly Developing Interdisciplinary Branch Of Science.A Characteristic Feature Of This Book Is The Presentation Of An Integrated (Covering Different Facets Usually Dealt With Either In Organic Or/And Inorganic Texts) View Of The Rapidly Developing Field Of Organometallic Chemistry. Attempts Have Been Made To Choose The Latest Examples To Illustrate The Fundamental Properties As Well As The Synthetic Procedures Of Organometallic Chemistry. Other Features Include: (A) An Interesting Brief Historical Background Of The Subject Including Some Quotations From Relevant Nobel Lecture Accounts Of Epoch Making Advances By The Discoverers Themselves, (B) The Adoption As Far As Possible Of The Iupac Rules Of Nomenclature, (C) A Brief Account Of The Rapidly Emerging Organometallic Chemistry Of The F-Elements, And (D) Inclusion Of Study Questions At The End Of Each Chapter.During The Revision Of The Book, The Latest Examples Have Replaced The Older Ones Wherever Feasible. The Book Would Be Extremely Useful As A Basic Text For B.Sc. (Hons.) And M.Sc. Chemistry Students.
