Book Synopsis Optimization of a Non-arsenic Iron-based Superconductor for Wire Fabrication by :
Download or read book Optimization of a Non-arsenic Iron-based Superconductor for Wire Fabrication written by and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Here we report on the optimization of synthesis of iron selenide-based superconducting powders and the fabrication of selenide-based wire. The powders were synthesized by an ammonothermal method, whereby Ba is intercalated between FeSe layers to produce Bax(NH3)yFe2Se2, with tetragonal structure similar to AFe2X2 (X: As, Se), '122', superconductors. The optimal Tc (up to 38 K) and Meissner and shielding superconducting fractions are obtained from the shortest reaction time (t) of reactants in liquid ammonia (30 min). With the increase of t, a second crystalline 122 phase, with a smaller unit cell, emerges. A small amount of NH3 is released from the structure above ~200 °C, which results in loss of superconductivity. However, in the confined space of niobium/Monel tubing, results indicate there is enough pressure for some of NH3 to remain in the crystal lattice, and thermal annealing can be performed at temperatures of up to 780 °C, increasing wire density and yielded a reasonable Tc H"16 K. Here, we report of the first successful wire fabrication of non-arsenic high-Tc iron-based superconductor. We find that although bulk materials are estimated to carry critical current densities>100 kA cm2 (4 K, self-field), the current transport within wires need to be optimized (Jc ~ 1 kA cm−2).
