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Author : Christos Tsenoglou
Publisher :
ISBN 13 :
Total Pages : 152 pages
Book Rating : 4.:/5 (52 download)
Download or read book Nonlinear Viscoelasticity of Polymer Melts and Molecular Constitutive Theories written by Christos Tsenoglou and published by . This book was released on 1987 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Y.-H. Lin
Publisher : World Scientific
ISBN 13 : 9814313033
Total Pages : 441 pages
Book Rating : 4.8/5 (143 download)
Download or read book Polymer Viscoelasticity written by Y.-H. Lin and published by World Scientific. This book was released on 2011 with total page 441 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers in great detail the Rouse-segment-based molecular theories in polymer viscoelasticity ? the Rouse theory and the extended reptation theory (based on the framework of the Doi?Edwards theory) ? that have been shown to explain experimental results in a consistently quantitative way. The explanation for the 3.4 power law of viscosity, quantitative line-shape analyses of viscoelastic responses and agreements between different sorts of viscoelastic responses, the consistency between the viscoelasticity and diffusion results, the clarification of the onset of entangelement, the discovery of the number of entanglement strands per cubed entanglement distance being a universal constant and the basic mechanism of the glass transition-related thermorheological complexity are discussed or shown in great detail. The mystery behind the success of the Rouse-segment-based molecular theories over the entropic region of a viscoelastic response is revealed by the Monte Carlo simulations on the Fraenkel chains. Specifically, the simulation studies give a natural explanation for the coexistence of the energy-driven and entropy-driven modes in a viscoelastic response and provide a theoretical basis resolving the paradox that the experimentally determined sizes of Rouse and Kuhn segments are nearly the same. This book starts from a very fundamental level; each chapter is built upon the contents of the previous chapters. Thus, the readers may use the book as a textbook and eventually reach an advanced research level. This book is also a useful source of reference for physicists, chemists and material scientists.
Author : Ronald G. Larson
Publisher : Butterworth-Heinemann
ISBN 13 : 1483162869
Total Pages : 381 pages
Book Rating : 4.4/5 (831 download)
Download or read book Constitutive Equations for Polymer Melts and Solutions written by Ronald G. Larson and published by Butterworth-Heinemann. This book was released on 2013-10-22 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: Constitutive Equations for Polymer Melts and Solutions presents a description of important constitutive equations for stress and birefringence in polymer melts, as well as in dilute and concentrated solutions of flexible and rigid polymers, and in liquid crystalline materials. The book serves as an introduction and guide to constitutive equations, and to molecular and phenomenological theories of polymer motion and flow. The chapters in the text discuss topics on the flow phenomena commonly associated with viscoelasticity; fundamental elementary models for understanding the rheology of melts, solutions of flexible polymers, and advanced constitutive equations; melts and concentrated solutions of flexible polymer; and the rheological properties of real liquid crystal polymers. Chemical engineers and physicists will find the text very useful.
Author : Kwang Soo Cho
Publisher : Springer
ISBN 13 : 9401775648
Total Pages : 615 pages
Book Rating : 4.4/5 (17 download)
Download or read book Viscoelasticity of Polymers written by Kwang Soo Cho and published by Springer. This book was released on 2016-05-30 with total page 615 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive introduction to polymer rheology with a focus on the viscoelastic characterization of polymeric materials. It contains various numerical algorithms for the processing of viscoelastic data, from basic principles to advanced examples which are hard to find in the existing literature. The book takes a multidisciplinary approach to the study of the viscoelasticity of polymers, and is self-contained, including the essential mathematics, continuum mechanics, polymer science and statistical mechanics needed to understand the theories of polymer viscoelasticity. It covers recent achievements in polymer rheology, such as theoretical and experimental aspects of large amplitude oscillatory shear (LAOS), and numerical methods for linear viscoelasticity, as well as new insights into the interpretation of experimental data. Although the book is balanced between the theoretical and experimental aspects of polymer rheology, the author’s particular interest in the theoretical side will not remain hidden. Aimed at readers familiar with the mathematics and physics of engineering at an undergraduate level, the multidisciplinary approach employed enables researchers with various scientific backgrounds to expand their knowledge of polymer rheology in a systematic way.
Author : Victor Hugo Rólon Garrido
Publisher : Univerlagtuberlin
ISBN 13 : 3798320640
Total Pages : 161 pages
Book Rating : 4.7/5 (983 download)
Download or read book Molecular Structure and Constitutive Modelling of Polymer Melts written by Victor Hugo Rólon Garrido and published by Univerlagtuberlin. This book was released on 2007 with total page 161 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Ken-ichiro Mori
Publisher : CRC Press
ISBN 13 : 9789026518225
Total Pages : 1170 pages
Book Rating : 4.5/5 (182 download)
Download or read book Simulation of Material Processing: Theory, Methods and Application written by Ken-ichiro Mori and published by CRC Press. This book was released on 2001-01-01 with total page 1170 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains about 180 papers including seven keynotes presented at the 7th NUMIFORM Conference. It reflects the state-of-the-art of simulation of industrial forming processes such as rolling, forging, sheet metal forming, injection moulding and casting.
Author : Arthur S. Lodge
Publisher : Academic Press
ISBN 13 : 1483263355
Total Pages : 456 pages
Book Rating : 4.4/5 (832 download)
Download or read book Viscoelasticity and Rheology written by Arthur S. Lodge and published by Academic Press. This book was released on 2014-06-28 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: Viscoelasticity and Rheology covers the proceedings of a symposium by the same title, conducted by the Mathematics Research Center held at the University of Wisconsin-Madison on October 16-18, 1984. The contributions to the symposium are divided into four broad categories, namely, experimental results, constitutive theories, mathematical analysis, and computation. This 16-chapter work begins with experimental topics, including the motion of bubbles in viscoelastic fluids, wave propagation in viscoelastic solids, flows through contractions, and cold-drawing of polymers. The next chapters covering constitutive theories explore the molecular theories for polymer solutions and melts based on statistical mechanics, the use and limitations of approximate constitutive theories, a comparison of constitutive laws based on various molecular theories, network theories and some of their advantages in relation to experiments, and models for viscoplasticity. These topics are followed by discussions of the existence, regularity, and development of singularities, change of type, interface problems in viscoelasticity, existence for initial value problems and steady flows, and propagation and development of singularities. The remaining chapters deal with the numerical simulation of flow between eccentric cylinders, flow around spheres and bubbles, the hole pressure problem, and a review of computational problems related to various constitutive laws. This book will prove useful to chemical engineers, researchers, and students.
Author : A.I. Leonov
Publisher : Springer Science & Business Media
ISBN 13 : 9401112584
Total Pages : 492 pages
Book Rating : 4.4/5 (11 download)
Download or read book Nonlinear Phenomena in Flows of Viscoelastic Polymer Fluids written by A.I. Leonov and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph presents theoretical and experimental studies of flows of elastic liquids. Falling into this category are particularly the melts and concentrated solutions of such flexible-chain polymers as polyethylene, polyisobutylene and polypropylene, all of which are widely used in polymer processing. These polydisperse polymers vary greatly, from batch to batch, in their mechanical properties and 20% variation in a property is believed to be good enough. l 7 All recent books - devoted to the rheology of polymers do not answer the question of which constitutive equations should be used for solving the fluid mechanic problems of polymer processing in the usual case of an appreciable nonlinear region of deformation where nonlinear effects of shear and extensional elasticity are very important. Viscoelastic constitut ive equations cited commonly (see, e.g. Refs 5 and 6) do not describe simultaneously even the simplest cases of deformations, viz. simple shear and uniaxial extension. Moreover, some of them are internally inconsist ent and sometimes display highly unstable behaviour in simple flows without any fundamental reasons. Even more respected molecular ap free from these defects.
Author : Yn-hwang Lin
Publisher : World Scientific
ISBN 13 : 9814485802
Total Pages : 265 pages
Book Rating : 4.8/5 (144 download)
Download or read book Polymer Viscoelasticity: Basics, Molecular Theories And Experiments written by Yn-hwang Lin and published by World Scientific. This book was released on 2003-12-22 with total page 265 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book, the studies of the Rouse, Doi-Edwards, and extended reptation theories are developed in a consistent manner from a basic level and discussed in detail. Viscoelastic properties of nearly monodisperse linear flexible polymers in both the entanglement and entanglement-free regions are analyzed quantitatively in terms of the molecular theories.
Author : Ronald G. Larson
Publisher : Butterworth-Heinemann
ISBN 13 : 9780409901191
Total Pages : 364 pages
Book Rating : 4.9/5 (11 download)
Download or read book Constitutive Equations for Polymer Melts and Solutions written by Ronald G. Larson and published by Butterworth-Heinemann. This book was released on 1988-01-01 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : John D. Ferry
Publisher : John Wiley & Sons
ISBN 13 : 9780471048947
Total Pages : 676 pages
Book Rating : 4.0/5 (489 download)
Download or read book Viscoelastic Properties of Polymers written by John D. Ferry and published by John Wiley & Sons. This book was released on 1980-09-16 with total page 676 pages. Available in PDF, EPUB and Kindle. Book excerpt: Viscoelastic behavior reflects the combined viscous and elastic responses, under mechanical stress, of materials which are intermediate between liquids and solids in character. Polymers the basic materials of the rubber and plastic industries and important to the textile, petroleum, automobile, paper, and pharmaceutical industries as well exhibit viscoelasticity to a pronounced degree. Their viscoelastic properties determine the mechanical performance of the final products of these industries, and also the success of processing methods at intermediate stages of production. Viscoelastic Properties of Polymers examines, in detail, the effects of the many variables on which the basic viscoelastic properties depend. These include temperature, pressure, and time; polymer chemical composition, molecular weight and weight distribution, branching and crystallinity; dilution with solvents or plasticizers; and mixture with other materials to form composite systems. With guidance by molecular theory, the dependence of viscoelastic properties on these variables can be simplified by introducing certain ancillary concepts such as the fractional free volume, the monomeric friction coefficient, and the spacing between entanglement loci, to provide a qualitative understanding and in many cases a quantitative prediction of how to achieve desired results. The phenomenological theory of viscoelasticity which permits interrelation of the results of different types of experiments is presented first, with many useful approximation procedures for calculations given. A wide variety of experimental methods is then described, with critical evaluation of their applicability to polymeric materials of different consistencies and in different regions of the time scale (or, for oscillating deformations, the frequency scale). A review of the present state of molecular theory follows, so that viscoelasticity can be related to the motions of flexible polymer molecules and their entanglements and network junctions. The dependence of viscoestic properties on temperature and pressure, and its descriptions using reduced variables, are discussed in detail. Several chapters are then devoted to the dependence of viscoelastic properties on chemical composition, molecular weight, presence of diluents, and other features, for several characteristic classes of polymer materials. Finally, a few examples are given to illustrate the many potential applications of these principles to practical problems in the processing and use of rubbers, plastics, and fibers, and in the control of vibration and noise. The third edition has been brought up to date to reflect the important developments, in a decade of exceptionally active research, which have led to a wider use of polymers, and a wider recognition of the importance and range of application of viscoelastic properties. Additional data have been incorporated, and the book s chapters on dilute solutions, theory of undiluted polymers, plateau and terminal zones, cross-linked polymers, and concentrated solutions have been extensively rewritten to take into account new theories and new experimental results. Technical managers and research workers in the wide range of industries in which polymers play an important role will find that the book provides basic information for practical applications, and graduate students in chemistry and engineering will find, in its illustrations with real data and real numbers, an accessible introduction to the principles of viscoelasticity.
Author : J.-M. Piau
Publisher : Elsevier
ISBN 13 : 0080540562
Total Pages : 435 pages
Book Rating : 4.0/5 (85 download)
Download or read book Rheology for Polymer Melt Processing written by J.-M. Piau and published by Elsevier. This book was released on 1996-10-10 with total page 435 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the main results obtained by different laboratories involved in the research group Rheology for polymer melt processing which is associated with French universities, schools of engineering, and the CNRS (Centre National de la Recherche Scientifique - France). The group comprises some 15 research laboratories of varied disciplines (chemistry, physics, material sciences, mechanics, mathematics), but with a common challenge viz. to enhance the understanding of the relationships between macromolecular species, their rheology and their processing. Some crucial issues of polymer science have been addressed: correlation of viscoelastic macroscopic bulk property measurements and models, slip at the wall, extrusion defects, correlation between numerical flow simulations and experiments. Features of the book: • The book is unique in that it allows one to grasp the key issues in polymer rheology and processing at once through a series of detailed state-of-the-art contributions, which were previously scattered throughout the literature. • Each paper was reviewed by experts and the book editors and some coordination was established in order to achieve a readable and easy access style. • Papers have been grouped in sections covering successively: Molecular dynamics, Constitutive equations and numerical modelling, Simple and complex flows. • Each paper can be read independently. Since the book is intended as an introduction to the main topics in polymer processing, it will be of interest to graduate students as well as to scientists in academic and industrial laboratories.
Author : Richard A. Pethrick
Publisher : CRC Press
ISBN 13 : 9783718648580
Total Pages : 498 pages
Book Rating : 4.6/5 (485 download)
Download or read book Polymer Yearbook written by Richard A. Pethrick and published by CRC Press. This book was released on 1989 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains reviews on state-of-the-art Japanese research presented in the annual Spring and Autumn meetings of the Japanese Polymer Science Society. The aim of this section is to make information on the progress of Japanese Polymer Science, and on topics of current interest to polymer scientists in Japan, more easily available worldwide.
Author : Vladimir N. Pokrovskii
Publisher : Springer Science & Business Media
ISBN 13 : 9048122317
Total Pages : 256 pages
Book Rating : 4.0/5 (481 download)
Download or read book The Mesoscopic Theory of Polymer Dynamics written by Vladimir N. Pokrovskii and published by Springer Science & Business Media. This book was released on 2009-12-16 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: The theory presented in this book explains in a consistent manner all dynamics effects observed in very concentrated solutions and melts of linear polymers from a macromolecular point of view. The presentation is compact and self-contained.
Author : Anil Kumar
Publisher : CRC Press
ISBN 13 : 0429676301
Total Pages : 523 pages
Book Rating : 4.4/5 (296 download)
Download or read book Fundamentals of Polymer Engineering, Third Edition written by Anil Kumar and published by CRC Press. This book was released on 2018-12-07 with total page 523 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exploring the chemistry of synthesis, mechanisms of polymerization, reaction engineering of step-growth and chain-growth polymerization, polymer characterization, thermodynamics and structural, mechanical, thermal and transport behavior of polymers as melts, solutions and solids, Fundamentals of Polymer Engineering, Third Edition covers essential concepts and breakthroughs in reactor design and polymer production and processing. It contains modern theories and real-world examples for a clear understanding of polymer function and development. This fully updated edition addresses new materials, applications, processing techniques, and interpretations of data in the field of polymer science. It discusses the conversion of biomass and coal to plastics and fuels, the use of porous polymers and membranes for water purification, and the use of polymeric membranes in fuel cells. Recent developments are brought to light in detail, and there are new sections on the improvement of barrier properties of polymers, constitutive equations for polymer melts, additive manufacturing and polymer recycling. This textbook is aimed at senior undergraduate students and first year graduate students in polymer engineering and science courses, as well as professional engineers, scientists, and chemists. Examples and problems are included at the end of each chapter for concept reinforcement.
Author : Richard A. Pethrick
Publisher : CRC Press
ISBN 13 : 9789057024733
Total Pages : 394 pages
Book Rating : 4.0/5 (247 download)
Download or read book Polymer Yearbook 16 written by Richard A. Pethrick and published by CRC Press. This book was released on 1999-06-23 with total page 394 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer Yearbooks provide reviews of Japanese and Russian polymer science not otherwise readily available in English. An essential desk reference of general interest to polymer scientists, they contain reviews covering topics in polymer synthesis, degradation, renewable polymer sources, drug release, thermodynamics of polymers under shear, etc. The books also contain lists of recent publications in polymer science and a compilation of dissertation abstracts. Names and addresses of research annuals in polymer science and their editors are listed, together with useful information such as standard abbreviations and trade names. Containing summaries of useful physical, chemical, and mathematical data along with definitions of terms in polymer science, the Polymer Yearbook is a must for any practicing polymer chemist.This volume also contains reviews on state-of-the-art Japanese research presented in the annual Spring and Fall meetings of the Japanese Polymer Science Society. The aim of this section is to make information on the progress of Japanese polymer science, and on topics of current interest to polymer scientists in Japan, more easily available worldwide.
Author : Vladimir N. Pokrovskii
Publisher : Springer Science & Business Media
ISBN 13 : 0306471302
Total Pages : 243 pages
Book Rating : 4.3/5 (64 download)
Download or read book The Mesoscopic Theory of Polymer Dynamics written by Vladimir N. Pokrovskii and published by Springer Science & Business Media. This book was released on 2007-05-08 with total page 243 pages. Available in PDF, EPUB and Kindle. Book excerpt: Our brutal century of atom bombs and spaceships can also be called the century ofpolymers. In any case, the broad spreading ofsynthetic polymer materials is one of thesigns of our time. A look at the various aspects of our life is enough to convince us that polymeric materials (textiles, pl- tics, rubbers) are as widely spread and important in our life as are other materials (metals and non-metals) derived from small molecules. Polymers have entered the life of the twentieth century as irreplaceable construction materials. Polymers differ from other substances by the size of their molecules which, appropriately enough, are referred to as macromolecules, since they consist of thousands or tens of thousands of atoms (molecular weight up to -4 6 10 ormore) andhave a macroscopic rectilinear length (upto 10 cm). The atoms ofa macromolecule are firmly held together by valence bonds, fo- ing a single entity. In polymeric substances, the weaker van der Waals forces have an effect on the components of the macromolecules which form the system. The structure of polymeric systems is more complicated than that oflow-molecular solids or liquids, but there are some common features: the atoms within a given macromolecule are ordered, but the centres ofmass of the individual macromolecules and parts of them are distributed randomly. Remarkably, the mechanical response of polymeric systems combines the elasticity of a solid with the fluidity of a liquid.
