Introduction to Non-equilibrium Physical Chemistry

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Publisher : Elsevier
ISBN 13 : 0080551807
Total Pages : 357 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Introduction to Non-equilibrium Physical Chemistry by : R. P. Rastogi

Download or read book Introduction to Non-equilibrium Physical Chemistry written by R. P. Rastogi and published by Elsevier. This book was released on 2007-10-16 with total page 357 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction to Non-equilibrium Physical Chemistry presents a critical and comprehensive account of Non-equilibrium Physical Chemistry from theoretical and experimental angle. It covers a wide spectrum of non-equilibrium phenomena from steady state close to equilibrium to non-linear region involving transition to bistability, temporal oscillations, spatio-temporal oscillations and finally to far from equilibrium phenomena such as complex pattern formation, dynamic instability at interfaces, Chaos and complex growth phenomena (fractals) in Physico-chemical systems. Part I of the book deals with theory and experimental studies concerning transport phenomena in membranes (Thermo-osmosis,Electroosmotic ) and in continuous systems (Thermal diffusion,Soret effect) close to equilibrium Experimental tests provide insight into the domain of validity of Non-equilibrium Thermodynamics ,which is the major theoretical tool for this region. Later developments in Extended Irreversible Thermodynamics and Non-equilibrium Molecular dynamics have been discussed in the Appendix. Part II deals with non-linear steady states and bifurcation to multistability, temporal and spatio- temporal oscillations (Chemical waves). Similarly Part II deals with more complex phenomena such as Chaos and fractal growth occurring in very far from equilibrium region. Newer mathematical techniques for investigating such phenomena along with available experimental studies. Part IV deals with analogous non-equilibrium phenomena occurring in the real systems (Socio-political, Finance and Living systems etc.) for which physico-chemical systems discussed in earlier chapters provide a useful model for development of theories based on non-linear science and science of complexity. - The book provides a critical account of theoretical studies on non-equilibrium phenomenon from region close to equilibrium to far equilibrium - Experimental studies have been reported which provide test of the theories and their limitations - Impacts of the concepts developed in non-equilibrium Physical Chemistry in sociology, economics and other social science and living systems has been discussed

Non-Equilibrium Dynamics in Chemical Systems

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Publisher : Springer Science & Business Media
ISBN 13 : 3642701965
Total Pages : 260 pages
Book Rating : 4.6/5 (427 download)

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Book Synopsis Non-Equilibrium Dynamics in Chemical Systems by : C. Vidal

Download or read book Non-Equilibrium Dynamics in Chemical Systems written by C. Vidal and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Markedly apart from elementary particle physics, another current has been building up and cont i nuous ly growi ng within contemporary phys i cs for severa 1 decades, and even expanding into many other disciplines, especially chemistry, biology and, quite recently, economics. Several reasons account for this: presumably the most impor tant one lies in the fact that, whatever the specific problem, model or material concerned, the same basic mathematical features are always involved. In this way, a general phenomenology has emerged which, unlike thermodynamics, is no longer depen dent upon the details or specifics: what largely prevails is the nonlinear charac ter of the underlying dynamics. Perhaps we are witnessing the emergence of a "non linear physics"--In a way similar to the birth of "quantum physics" in the twen ties - a physics which deals with the general behaviour of systems, whatever they are or may be. Over the past fifteen years, chemical systems evolving sufficiently far from equilibrium have proved to be particularly well fitted to experimental research on nonlinear behaviour: oscillation, multistability, birhythmicity, chaotic evolution, spatial self-organization and hysteresis are displayed by chemical reactions whose number is growing each year. In this volume are collected the lectures, communica tions and posters (abstracts) presented at an international meeting entitled: "Non-Equilibrium Dynamics in Chemical Systems", held in Bordeaux (France), Septem ber 3 rd-lth, 1984.

Non-equilibrium Thermodynamics of Heterogeneous Systems

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Publisher : World Scientific
ISBN 13 : 9812779132
Total Pages : 451 pages
Book Rating : 4.8/5 (127 download)

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Book Synopsis Non-equilibrium Thermodynamics of Heterogeneous Systems by : Signe Kjelstrup

Download or read book Non-equilibrium Thermodynamics of Heterogeneous Systems written by Signe Kjelstrup and published by World Scientific. This book was released on 2008 with total page 451 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems.The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight.

Nonequilibrium Thermodynamics

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Author :
Publisher : Newnes
ISBN 13 : 0444595813
Total Pages : 787 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Nonequilibrium Thermodynamics by : Yasar Demirel

Download or read book Nonequilibrium Thermodynamics written by Yasar Demirel and published by Newnes. This book was released on 2013-12-16 with total page 787 pages. Available in PDF, EPUB and Kindle. Book excerpt: Natural phenomena consist of simultaneously occurring transport processes and chemical reactions. These processes may interact with each other and may lead to self-organized structures, fluctuations, instabilities, and evolutionary systems. Nonequilibrium Thermodynamics, Third Edition emphasizes the unifying role of thermodynamics in analyzing the natural phenomena. This third edition updates and expands on the first and second editions by focusing on the general balance equations for coupled processes of physical, chemical, and biological systems. The new edition contains a new chapter on stochastic approaches to include the statistical thermodynamics, mesoscopic nonequilibrium thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems in thermodynamic analysis. This new addition also comes with more examples and practice problems. - Informs and updates on all the latest developments in the field - Contributions from leading authorities and industry experts - A useful text for seniors and graduate students from diverse engineering and science programs to analyze some nonequilibrium, coupled, evolutionary, stochastic, and dissipative processes - Highlights fundamentals of equilibrium thermodynamics, transport processes and chemical reactions - Expands the theory of nonequilibrium thermodynamics and its use in coupled transport processes and chemical reactions in physical, chemical, and biological systems - Presents a unified analysis for transport and rate processes in various time and space scales - Discusses stochastic approaches in thermodynamic analysis including fluctuation and information theories - Has 198 fully solved examples and 287 practice problems - An Instructor Resource containing the Solution Manual can be obtained from the author: [email protected]

Out-of-Equilibrium (Supra)molecular Systems and Materials

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Publisher : John Wiley & Sons
ISBN 13 : 3527821988
Total Pages : 448 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Out-of-Equilibrium (Supra)molecular Systems and Materials by : Nicolas Giuseppone

Download or read book Out-of-Equilibrium (Supra)molecular Systems and Materials written by Nicolas Giuseppone and published by John Wiley & Sons. This book was released on 2021-03-30 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: A must-have resource that covers everything from out-of-equilibrium chemical systems and materials to dissipative self-assemblies Out-of-Equilibrium Supramolecular Systems and Materials presents a comprehensive overview of the synthetic approaches that use supramolecular bonds in various out-of-thermodynamic equilibrium situations. With contributions from noted experts on the topic, the text contains information on the design of dissipative self-assemblies that maintain their structures when fueled by an external source of energy. The contributors also examine molecules and nanoscale objects and materials that can produce mechanical work based on molecular machines. Additionally, the book explores non-equilibrium supramolecular polymers that can be trapped in kinetically stable states, as well as out-of-equilibrium chemical systems and oscillators that are important to understand the emergence of complex behaviors and, in particular, the origin of life. This important book: Offers comprehensive coverage of fields from design of dissipative self-assemblies to non-equilibrium supramolecular polymers Presents information on a highly emerging and interdisciplinary topic Includes contributions from internationally renowned scientists Written for chemists, physical chemists, biochemists, material scientists, Out-of-Equilibrium Supramolecular Systems and Materials is an indispensable resource written by top scientists in the field.

Non-Equilibrium Thermodynamics

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Publisher : Courier Corporation
ISBN 13 : 0486153509
Total Pages : 532 pages
Book Rating : 4.4/5 (861 download)

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Book Synopsis Non-Equilibrium Thermodynamics by : S. R. De Groot

Download or read book Non-Equilibrium Thermodynamics written by S. R. De Groot and published by Courier Corporation. This book was released on 2013-01-23 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: Classic monograph treats irreversible processes and phenomena of thermodynamics: non-equilibrium thermodynamics. Covers statistical foundations and applications with chapters on fluctuation theory, theory of stochastic processes, kinetic theory of gases, more.

Nonequilibrium Gas Dynamics and Molecular Simulation

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Publisher : Cambridge University Press
ISBN 13 : 1107073448
Total Pages : 383 pages
Book Rating : 4.1/5 (7 download)

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Book Synopsis Nonequilibrium Gas Dynamics and Molecular Simulation by : Iain D. Boyd

Download or read book Nonequilibrium Gas Dynamics and Molecular Simulation written by Iain D. Boyd and published by Cambridge University Press. This book was released on 2017-03-23 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: 7.1 Introduction -- 7.2 Rotational Energy Exchange Models -- 7.2.1 Constant Collision Number -- 7.2.2 The Parker Model -- 7.2.3 Variable Probability Exchange Model of Boyd -- 7.2.4 Nonequilibrium Direction Dependent Model -- 7.2.5 Model Results -- 7.3 Vibrational Energy Exchange Models -- 7.3.1 Constant Collision Number -- 7.3.2 The Millikan-White Model -- 7.3.3 Quantized Treatment for Vibration -- 7.3.4 Model Results -- 7.4 Dissociation Chemical Reactions -- 7.4.1 Total Collision Energy Model -- 7.4.2 Redistribution of Energy Following a Dissociation Reaction -- 7.4.3 Vibrationally Favored Dissociation Model -- 7.5 General Chemical Reactions -- 7.5.1 Reaction Rates and Equilibrium Constant -- 7.5.2 Backward Reaction Rates in DSMC -- 7.5.3 Three-Body Recombination Reactions -- 7.5.4 Post-Reaction Energy Redistribution and General Implementation -- 7.5.5 DSMC Solutions for Reacting Flows -- 7.6 Summary -- Appendix A: Generating Particle Properties -- Appendix B: Collisional Quantities -- Appendix C: Determining Post-Collision Velocities -- Appendix D: Macroscopic Properties -- Appendix E: Common Integrals -- References -- Index

Non-Equilibrium Reacting Gas Flows

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Publisher : Springer Science & Business Media
ISBN 13 : 3642013902
Total Pages : 255 pages
Book Rating : 4.6/5 (42 download)

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Book Synopsis Non-Equilibrium Reacting Gas Flows by : Ekaterina Nagnibeda

Download or read book Non-Equilibrium Reacting Gas Flows written by Ekaterina Nagnibeda and published by Springer Science & Business Media. This book was released on 2009-07-09 with total page 255 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the present monograph, we develop the kinetic theory of transport phenomena and relaxation processes in the flows of reacting gas mixtures and discuss its applications to strongly non-equilibrium conditions. The main attention is focused on the influence of non-equilibrium kinetics on gas dynamics and transport properties. Closed systems of fluid dynamic equations are derived from the kinetic equations in different approaches. We consider the most accurate approach taking into account the state-to-state kinetics in a flow, as well as simplified multi-temperature and one-temperature models based on quasi-stationary distributions. Within these approaches, we propose the algorithms for the calculation of the transport coefficients and rate coefficients of chemical reactions and energy exchanges in non-equilibrium flows; the developed techniques are based on the fundamental kinetic theory principles. The theory is applied to the modeling of non-equilibrium flows behind strong shock waves, in the boundary layer, and in nozzles. The comparison of the results obtained within the frame of different approaches is presented, the advantages of the new state-to-state kinetic model are discussed, and the limits of validity for simplified models are established. The book can be interesting for scientists and graduate students working on physical gas dynamics, aerothermodynamics, heat and mass transfer, non-equilibrium physical-chemical kinetics, and kinetic theory of gases.

Self-Organization in Nonequilibrium Systems

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Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 520 pages
Book Rating : 4.:/5 (318 download)

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Book Synopsis Self-Organization in Nonequilibrium Systems by : Gregoire Nicolis

Download or read book Self-Organization in Nonequilibrium Systems written by Gregoire Nicolis and published by Wiley-VCH. This book was released on 1977-05-13 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt: Membranes, Dissipative Structures, and Evolution Edited by G. Nicolis & R. Lefever Focuses on the problem of the emergence/maintenance of biological order at successively higher levels of complexity. Covers the spatiotemporal organization of simple biochemical networks; the formation of pluricellular or macromolecular assemblies; the evolution of these structures; and the functions of specific biological structures. Volume 29 in Advances in Chemical Physics Series, I. Prigogine & Stuart A. Rice, Editors. 1975 Theory and Applications of Molecular Paramagnetism Edited by E. A. Boudreaux & L. N. Mulay Comprehensively treats the basic theory of paramagnetic phenomena from both the classical and mechanical vantages. It examines the magnetic behavior of Lanthanide and Actinide elements as well as traditional transition metals. For each class of compounds, appropriate details of descriptive and mathematical theory are given before their applications. 1976 Theory and Aapplications of Molecular Diamagnetism Edited by L. N. Mulay & E. A. Boudreaux An invaluable reference for solving chemical problems in magnetics, magnetochemistry, and related areas where magnetic data are important, such as solid-state physics and optical spectroscopy. 1976

Statistical Thermodynamics of Nonequilibrium Processes

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Publisher : Springer Science & Business Media
ISBN 13 : 1461210542
Total Pages : 517 pages
Book Rating : 4.4/5 (612 download)

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Book Synopsis Statistical Thermodynamics of Nonequilibrium Processes by : Joel Keizer

Download or read book Statistical Thermodynamics of Nonequilibrium Processes written by Joel Keizer and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 517 pages. Available in PDF, EPUB and Kindle. Book excerpt: The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and limited in validity to a neighborhood of equilibrium. In recent years it has been possible to extend the statistical theory of nonequilibrium processes to include nonlinear effects. The modern theory, as expounded in this book, is applicable to a wide variety of systems both close to and far from equilibrium. The theory is based on the notion of elementary molecular processes, which manifest themselves as random changes in the extensive variables characterizing a system. The theory has a hierarchical character and, thus, can be applied at various levels of molecular detail.

Statistical Mechanics of Nonequilibrium Liquids

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Publisher : ANU E Press
ISBN 13 : 1921313234
Total Pages : 318 pages
Book Rating : 4.9/5 (213 download)

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Book Synopsis Statistical Mechanics of Nonequilibrium Liquids by : Denis J. Evans

Download or read book Statistical Mechanics of Nonequilibrium Liquids written by Denis J. Evans and published by ANU E Press. This book was released on 2007-08-01 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt: "There is a symbiotic relationship between theoretical nonequilibrium statistical mechanics on the one hand and the theory and practice of computer simulation on the other. Sometimes, the initiative for progress has been with the pragmatic requirements of computer simulation and at other times, the initiative has been with the fundamental theory of nonequilibrium processes. This book summarises progress in this field up to 1990"--Publisher's description.

Far-from-equilibrium Dynamics of Chemical Systems

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Author :
Publisher : World Scientific
ISBN 13 : 981453417X
Total Pages : 374 pages
Book Rating : 4.8/5 (145 download)

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Book Synopsis Far-from-equilibrium Dynamics of Chemical Systems by :

Download or read book Far-from-equilibrium Dynamics of Chemical Systems written by and published by World Scientific. This book was released on 1994 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Noise-Induced Transitions

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Publisher : Springer Science & Business Media
ISBN 13 : 3540368523
Total Pages : 322 pages
Book Rating : 4.5/5 (43 download)

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Book Synopsis Noise-Induced Transitions by : W. Horsthemke

Download or read book Noise-Induced Transitions written by W. Horsthemke and published by Springer Science & Business Media. This book was released on 2006-09-12 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of phase transitions is among the most fascinating fields in physics. Originally limited to transition phenomena in equilibrium systems, this field has outgrown its classical confines during the last two decades. The behavior of far from equilibrium systems has received more and more attention and has been an extremely active and productive subject of research for physicists, chemists and biologists. Their studies have brought about a more unified vision of the laws which govern self-organization processes of physico-chemical and biological sys tems. A major achievement has been the extension of the notion of phase transi tion to instabilities which occur only in open nonlinear systems. The notion of phase transition has been proven fruitful in apphcation to nonequilibrium ins- bihties known for about eight decades, like certain hydrodynamic instabilities, as well as in the case of the more recently discovered instabilities in quantum optical systems such as the laser, in chemical systems such as the Belousov-Zhabotinskii reaction and in biological systems. Even outside the realm of natural sciences, this notion is now used in economics and sociology. In this monograph we show that the notion of phase transition can be extend ed even further. It apphes also to a new class of transition phenomena which occur only in nonequilibrium systems subjected to a randomly fluctuating en vironment.

Non-equilibrium Thermodynamics For Engineering Applications

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Publisher : World Scientific
ISBN 13 : 9811294607
Total Pages : 357 pages
Book Rating : 4.8/5 (112 download)

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Book Synopsis Non-equilibrium Thermodynamics For Engineering Applications by : Signe Kjelstrup

Download or read book Non-equilibrium Thermodynamics For Engineering Applications written by Signe Kjelstrup and published by World Scientific. This book was released on 2024-07-23 with total page 357 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the theory of non-equilibrium thermodynamics in a pedagogical and practical way that targets engineering applications. In it, tools to take advantage of the second as well as the first law of thermodynamics are provided.The book starts by explaining how the entropy production is the cornerstone of non-equilibrium thermodynamics — the basis to describe coupled transport phenomena, which are highly relevant for several renewable energy technologies. The book also uses entropy production as the foundation for a systematic methodology to analyze and improve energy efficiency, and shows how entropy production can be used to test the consistency of transport models. The link between transport theory and energy efficiency is also shown, and the relationship to exergy analysis is demonstrated. The theory is applied using examples from practical cases like evaporation, heat exchange, reactor optimization, distillation and more.Non-Equilibrium Thermodynamics for Engineering Applications may be used as a textbook for undergraduate and graduate university curricula containing thermodynamics or energy conversion issues at large, chemical and mechanical engineering, applied chemistry and applied physics.

Nonlinear Nonequilibrium Thermodynamics II

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Publisher : Springer Science & Business Media
ISBN 13 : 3662030705
Total Pages : 237 pages
Book Rating : 4.6/5 (62 download)

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Book Synopsis Nonlinear Nonequilibrium Thermodynamics II by : Rouslan L. Stratonovich

Download or read book Nonlinear Nonequilibrium Thermodynamics II written by Rouslan L. Stratonovich and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 237 pages. Available in PDF, EPUB and Kindle. Book excerpt: This two-volume work gives the first detailed coherent treatment of a relatively young branch of statistical physics - nonlinear nonequilibrium and fluctuational dissipative thermodynamics. This area of research has taken shape rather recently: its de~elopment began in 1959. The earlier theory - linear nonequilibrium ther modynamics - is in principle a simple special case of the new theory. Despite the fact that the title of the book includes the word 'nonlinear', it also covers the results of linear nonequilibrium thermodynamics. The presentation of the linear and nonlinear theories is done within a common theoretical framework that is not subject to the linearity condition. The author hopes that the reader will perceive the intrinsic unjty of this dis cipline, the uniformity and generality of its constituent parts. This theory has a wide variety of applications in various domains of physics and physical chemistry, enabling one to calculate thermal fluctuations in various nonlinear systems. The book is divided into two volumes. Fluctuation-dissipation theorems (or relations) of various types (linear, quadratic and cubic, classical and quantum) are considered in the first volume. There one encounters the Markov and non-Markov fluctuation-dissipation theorems (FDTs), theorems of the first, second and third kinds. Nonlinear FDTs are less known than their linear counterparts. The present second volume of the book deals with the advanced theory. It consists of four chapters. The connection and interdependence of the material in the various chapters of both volumes are illustrated in the accompanying diagram.

Far-from-equilibrium Dynamics

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Publisher : American Mathematical Soc.
ISBN 13 : 9780821826256
Total Pages : 340 pages
Book Rating : 4.8/5 (262 download)

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Book Synopsis Far-from-equilibrium Dynamics by : Yasumasa Nishiura

Download or read book Far-from-equilibrium Dynamics written by Yasumasa Nishiura and published by American Mathematical Soc.. This book was released on 2002 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is devoted to the study of evolution of nonequilibrium systems. Such a system usually consists of regions with different dominant scales, which coexist in the space-time where the system lives. In the case of high nonuniformity in special direction, one can see patterns separated by clearly distinguishable boundaries or interfaces. The author considers several examples of nonequilibrium systems. One of the examples describes the invasion of the solid phase into the liquidphase during the crystallization process. Another example is the transition from oxidized to reduced states in certain chemical reactions. An easily understandable example of the transition in the temporal direction is a sound beat, and the author describes typical patterns associated with thisphenomenon. The main goal of the book is to present a mathematical approach to the study of highly nonuniform systems and to illustrate it with examples from physics and chemistry. The two main theories discussed are the theory of singular perturbations and the theory of dissipative systems. A set of carefully selected examples of physical and chemical systems nicely illustrates the general methods described in the book.

Far-from-equilibrium Dynamics Of Chemical Systems - Proceedings Of The Second International Symposium

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Author :
Publisher : World Scientific
ISBN 13 : 9814569275
Total Pages : 440 pages
Book Rating : 4.8/5 (145 download)

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Book Synopsis Far-from-equilibrium Dynamics Of Chemical Systems - Proceedings Of The Second International Symposium by : Popielawski J

Download or read book Far-from-equilibrium Dynamics Of Chemical Systems - Proceedings Of The Second International Symposium written by Popielawski J and published by World Scientific. This book was released on 1991-03-29 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: The proceedings discuss the theoretical methods used to describe a chemical system which is far from the equilibrium state, and this is illustrated by selected applications. Special attention is paid to very fast chemical reactions and systems in which external or internal noise is present. In particular, the following topics are covered:-the generalized Boltzmann/ Enskog equation for nonequilibrium systems,-stochastic methods for description of noise in chemical systems,-numerical simulations of systems far from equilibrium.