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Neutralizations Of High Aluminum Low Uranium Used Nuclear Fuel Solutions Containing Gadolinium As A Neutron Poison
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Book Synopsis Neutralizations of High Aluminum Low Uranium Used Nuclear Fuel Solutions Containing Gadolinium as a Neutron Poison by :
Download or read book Neutralizations of High Aluminum Low Uranium Used Nuclear Fuel Solutions Containing Gadolinium as a Neutron Poison written by and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: H-Canyon will begin dissolving High Aluminum - Low Uranium (High Al/Low U) Used Nuclear Fuel (UNF) following approval by DOE which is anticipated in CY2011. High Al/Low U is an aluminum/enriched uranium UNF with small quantities of uranium relative to aluminum. The maximum enrichment level expected is 93% 235U. The High Al/Low U UNF will be dissolved in H-Canyon in a nitric acid/mercury/gadolinium solution. The resulting solution will be neutralized and transferred to Tank 39H in the Tank Farm. To confirm that the solution generated could be poisoned with Gd, neutralized, and discarded to the Savannah River Site (SRS) high level waste (HLW) system without undue nuclear safety concerns the caustic precipitation of simulant solutions was examined. Experiments were performed with three simulant solutions representative of the H-Canyon estimated concentrations in the final solutions after dissolution. The maximum U, Gd, and Al concentration were selected for testing from the range of solution compositions provided. Simulants were prepared in three different nitric acid concentrations, ranging from 0.5 to 1.5 M. The simulant solutions were neutralized to four different endpoints: (1) just before a solid phase was formed (pH 3.5-4), (2) the point where a solid phase was obtained, (3) 0.8 M free hydroxide, and (4) 1.2 M free hydroxide, using 50 wt % sodium hydroxide (NaOH). The settling behavior of the neutralized solutions was found to be slower compared to previous studies, with settling continuing over a one week period. Due to the high concentration of Al in these solutions, precipitation of solids was observed immediately upon addition of NaOH. Precipitation continued as additional NaOH was added, reaching a point where the mixture becomes almost completely solid due to the large amount of precipitate. As additional NaOH was added, some of the precipitate began to redissolve, and the solutions neutralized to the final two endpoints mixed easily and had expected densities of typical neutralized waste. Based on particle size and scanning electron microscopy analyses, the neutralized solids were found to be homogeneous and less than 20 microns in size. The majority of solids were less than 4 microns in size. Compared to previous studies, a larger percentage of the Gd was found to precipitate in the partially neutralized solutions (at pH 3.5-4). In addition the Gd:U mass ratio was found to be at least 1.0 in all of the solids obtained after partial or full neutralization. The hydrogen to U (H:U) molar ratios for two accident scenarios were also determined. The first was for transient neutralization and agitator failure. Experimentally this scenario was determined by measuring the H:U ratio of the settled solids. The minimum H:U molar ratio for solids from fully neutralized solutions was 388:1. The second accident scenario is for the solids drying out in an unagitiated pump box. Experimentally, this scenario was determined by measuring the H:U molar ratio in centrifuged solids. The minimum H:U atom ratios for centrifuged precipitated solids was 250:1. It was determined previously that a 30:1 H:Pu atom ratio was sufficient for a 1:1 Gd:Pu mass ratio. Assuming a 1:1 equivalence with 239Pu, the results of these experiments show Gd is a viable poison for neutralizing U/Gd solutions with the tested compositions.
Download or read book ERDA Energy Research Abstracts written by and published by . This book was released on 1977 with total page 724 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Proceedings of the International Topical Meeting on Nuclear and Hazardous Waste Management, Spectrum '96 by :
Download or read book Proceedings of the International Topical Meeting on Nuclear and Hazardous Waste Management, Spectrum '96 written by and published by . This book was released on 1996 with total page 850 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis ERDA Energy Research Abstracts by : United States. Energy Research and Development Administration
Download or read book ERDA Energy Research Abstracts written by United States. Energy Research and Development Administration and published by . This book was released on 1977 with total page 1030 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Thorium Fuel Cycle by : International Atomic Energy Agency
Download or read book Thorium Fuel Cycle written by International Atomic Energy Agency and published by . This book was released on 2005 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a critical review of the thorium fuel cycle: potential benefits and challenges in the thorium fuel cycle, mainly based on the latest developments at the front end of the fuel cycle, applying thorium fuel cycle options, and at the back end of the thorium fuel cycle.
Book Synopsis Proceedings of the International Topical Meeting on Nuclear and Hazardous Waste Management, Spectrum ... by :
Download or read book Proceedings of the International Topical Meeting on Nuclear and Hazardous Waste Management, Spectrum ... written by and published by . This book was released on 1994 with total page 970 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis ERDA Energy Research Abstracts by : United States. Energy Research and Development Administration
Download or read book ERDA Energy Research Abstracts written by United States. Energy Research and Development Administration and published by . This book was released on 1977-04 with total page 576 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Production of Yellow Cake and Uranium Fluorides by : International Atomic Energy Agency
Download or read book Production of Yellow Cake and Uranium Fluorides written by International Atomic Energy Agency and published by . This book was released on 1980 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book INIS Atomindeks written by and published by . This book was released on 1977 with total page 1072 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy Research Abstracts written by and published by . This book was released on 1977 with total page 854 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Extractive Metallurgy of Niobium by : A.K. Suri
Download or read book Extractive Metallurgy of Niobium written by A.K. Suri and published by Routledge. This book was released on 2017-11-13 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: The growth and development witnessed today in modern science, engineering, and technology owes a heavy debt to the rare, refractory, and reactive metals group, of which niobium is a member. Extractive Metallurgy of Niobium presents a vivid account of the metal through its comprehensive discussions of properties and applications, resources and resource processing, chemical processing and compound preparation, metal extraction, and refining and consolidation. Typical flow sheets adopted in some leading niobium-producing countries for the beneficiation of various niobium sources are presented, and various chemical processes for producing pure forms of niobium intermediates such as chloride, fluoride, and oxide are discussed. The book also explains how to liberate the metal from its intermediates and describes the physico-chemical principles involved. It is an excellent reference for chemical metallurgists, hydrometallurgists, extraction and process metallurgists, and minerals processors. It is also valuable to a wide variety of scientists, engineers, technologists, and students interested in the topic.
Book Synopsis Nuclear Power Reactor Instrumentation Systems Handbook by : Joseph M. Harrer
Download or read book Nuclear Power Reactor Instrumentation Systems Handbook written by Joseph M. Harrer and published by . This book was released on 1973 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The New Nuclear Forensics by : Vitaly Fedchenko
Download or read book The New Nuclear Forensics written by Vitaly Fedchenko and published by Oxford University Press. This book was released on 2015 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nuclear material changes its form and properties as it moves through the nuclear fuel cycle, from one facility to another. Each step of the fuel cycle or each use of the material will inevitably leave its mark. The science of determining the history of a sample of nuclear material through the study of these characteristics is known as nuclear forensics. While nuclear forensic analysis has normally been associated with investigations and prosecutions in the contextof trafficking of nuclear materials or nuclear terrorism, it had wider applications in in national security contexts, such as nuclear non-proliferation, disarmament, and arms control. The New Nuclear Forensics is the first book to give a definitive guide to this broader definition of nuclear forensic analysis. This book describes the various methods used in nuclear forensics, giving first a broad introduction to the process followed by details of relevant measurement techniques and procedures. In each case, the advantages and limitations are outlined. To put these methods in context, the book also recounts the history of the discipline anddescribes the diverse contemporary applications of nuclear forensics.
Book Synopsis Design and Operation of High Level Waste Vitrification and Storage Facilities by : International Atomic Energy Agency
Download or read book Design and Operation of High Level Waste Vitrification and Storage Facilities written by International Atomic Energy Agency and published by . This book was released on 1992 with total page 114 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report gives an up to date review of high level waste vitrification and storage facilities currently in an advanced stage of implementation.
Book Synopsis CRC Handbook of Metal Etchants by : Perrin Walker
Download or read book CRC Handbook of Metal Etchants written by Perrin Walker and published by CRC Press. This book was released on 1990-12-11 with total page 1434 pages. Available in PDF, EPUB and Kindle. Book excerpt: This publication presents cleaning and etching solutions, their applications, and results on inorganic materials. It is a comprehensive collection of etching and cleaning solutions in a single source. Chemical formulas are presented in one of three standard formats - general, electrolytic or ionized gas formats - to insure inclusion of all necessary operational data as shown in references that accompany each numbered formula. The book describes other applications of specific solutions, including their use on other metals or metallic compounds. Physical properties, association of natural and man-made minerals, and materials are shown in relationship to crystal structure, special processing techniques and solid state devices and assemblies fabricated. This publication also presents a number of organic materials which are widely used in handling and general processing...waxes, plastics, and lacquers for example. It is useful to individuals involved in study, development, and processing of metals and metallic compounds. It is invaluable for readers from the college level to industrial R & D and full-scale device fabrication, testing and sales. Scientific disciplines, work areas and individuals with great interest include: chemistry, physics, metallurgy, geology, solid state, ceramic and glass, research libraries, individuals dealing with chemical processing of inorganic materials, societies and schools.
Download or read book Brittle Power written by Amory B. Lovins and published by . This book was released on 1982 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Engineering for Nuclear Fuel Reprocessing by : Justin T. Long
Download or read book Engineering for Nuclear Fuel Reprocessing written by Justin T. Long and published by . This book was released on 1967 with total page 1044 pages. Available in PDF, EPUB and Kindle. Book excerpt:
