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Author : Manfred Regitz
Publisher : Georg Thieme Verlag
ISBN 13 : 9783137522010
Total Pages : 478 pages
Book Rating : 4.5/5 (22 download)
Download or read book Multiple Bonds and Low Coordination in Phosphorus Chemistry written by Manfred Regitz and published by Georg Thieme Verlag. This book was released on 1990-01-01 with total page 478 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Manfred Regitz
Publisher : Thieme Medical Publishers
ISBN 13 :
Total Pages : 504 pages
Book Rating : 4.3/5 (91 download)
Download or read book Multiple Bonds and Low Coordination in Phosphorus Chemistry written by Manfred Regitz and published by Thieme Medical Publishers. This book was released on 1990 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work deals with phosphorus compounds that have double or triple bonds to another main group element, & also includes R-P fragments (phosphinidenes). It is concerned with a current trend that has developed over the last 25 years which has almost completely overturned the covalent bond rule. Specialist journals have often been excessive in their interest of this trend. The authors aim to present the whole field of 'low coordination' phosphorus chemistry in a series of specialized chapters, & to stimulate interest in future fields of research.
Author : Helmut Vorbrueggen
Publisher : John Wiley & Sons
ISBN 13 : 3527605924
Total Pages : 378 pages
Book Rating : 4.5/5 (276 download)
Download or read book Silicon-mediated Transformations of Functional Groups written by Helmut Vorbrueggen and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 378 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the first work to comprehensively cover this all-important topic, the recognized expert Helmut Vorbrüggen provides both organic and bioorganic chemists with much new and valuable information for preparative synthesis. Although every organic chemist may be familiar with different aspects of silylation for the protection of functional groups, this book covers the concept of protection while simultaneously silylating-activating various functional groups, such as amides and ureas. This novel methodology opens thus numerous synthetic pathways while effecting the elimination of water in it volatile persilylated form under rather mild reaction conditions, which are often advantageous compared to conventional methods. The compact form and clear structure of this monograph make this a long-awaited ready reference. From the contents: Introduction * Techniques of Preparative Silylations-Desilylations * Preparation and Properties of Siliconoxy-Leaving Groups * Reactions of Free and Derivatized Carboxylic Acids and Carbon Dioxide * Reactions of Aldehydes and Ketones * Reactions of Alcohols, Ethers and Epoxides * Reaction of N-O Systems * Reactions of S-O and Se-O Systems * Cyclizations and Ring Enlargements * Base and Acid-Catalyzed as well as Thermal Eliminations of Trimethylsilanol. Peterson Reactions * Formation of Carbon-Phosphorous Double- and Triple Bonds * Reductions and Oxidations * Dehydration-Activation as well as Silylation of Inorganic and Organic Salts and Metalorganic Compounds * Formation of Polymers
Author : Louis D. Quin
Publisher : John Wiley & Sons
ISBN 13 : 9780471318248
Total Pages : 416 pages
Book Rating : 4.3/5 (182 download)
Download or read book A Guide to Organophosphorus Chemistry written by Louis D. Quin and published by John Wiley & Sons. This book was released on 2000-02-04 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: Die organische Chemie des Phosphors - ein großes, äußerst lebendiges Forschungsfeld - umfaßt sowohl Verbindungen mit Kohlenstoff-Phosphor-Bindungen als auch organische Ester anorganischer Phosphorsäuren. Dieser Band behandelt die meisten phosphorhaltigen funktionellen Gruppen und daneben aktuelle Fragen wie z.B. ungewöhnliche Koordinationszustände, Heterocyclen, Anwendungen der 31P-NMR und andere spektroskopische Verfahren. Soweit bekannt, werden auch elektronische Reaktionsmechanismen und reaktive Intermediate diskutiert. Mit zahlreichen Literaturhinweisen! (03/00)
Author : Jean-Pierre Majoral
Publisher : Springer
ISBN 13 : 3540457313
Total Pages : 250 pages
Book Rating : 4.5/5 (44 download)
Download or read book New Aspects in Phosphorus Chemistry I written by Jean-Pierre Majoral and published by Springer. This book was released on 2003-07-01 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt: Undoubtedly the chemistry of phosphorus appears more and more attractive in the sense that phosphorus presents an extraordinary versatile behaviour that allows the synthesis of a large number of different phosphorus reagents usable for applications in different fields, from biology to material science without f- getting key applications in catalysis. The full maturity of this topic of research can be explained by all the acquired knowledge over these twenty last years. Organic and inorganic chemistries of P , P and P species have been the s- in ]V v ject of thousands of publications while the chemistry of low coordinated ph- phorus derivatives experienced its hour of glory from the 1970s to the early 1990s. In parallel, interactions between phosphorus compounds and transition metals afforded many complexes, a lot of which present fascinating properties as catalysts. The interest in all these themes really is not decreasing, indeed some fas- nating areas of research are emerging or are the subject of many investigations: the medicinal chemistry of bisphosphonates, the role of phosphorus in biology, phosphorus ligands in radiopharmaceutical chemistry, phosphorus in material science, new polymers and dendrimers incorporating phosphorus, and as- metric catalysis to name but a few. Indeed researchers, benefitting from their background in basic phosphorus chemistry are developing many new fields of research.
Author : Harold Goldwhite
Publisher : Cambridge University Press
ISBN 13 : 9780521229784
Total Pages : 132 pages
Book Rating : 4.2/5 (297 download)
Download or read book Introduction to Phosphorous Chemistry written by Harold Goldwhite and published by Cambridge University Press. This book was released on 1981-04-30 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt: This 1981 introduction to the chemistry of a single element, phosphorus, covers many of the major themes of chemistry. Important in inorganic and organic chemistry and in biochemistry, phosphorus is also of considerable economic significance and plays a vital role in the biosphere. By presenting a detailed treatment of selected topics, this book provides a concise account of phosphorus chemistry suitable for anyone with an interest in the field. The book provides a survey of phosphorus compounds by structural and bond types, a review of physical methods in phosphorus chemistry, a review of basicity and co-ordination chemistry of phosphorus donors, a discussion of phosphorus in its group, and a chapter on reagents containing phosphorus in general chemistry. A critical bibliography introduces the reader to the advanced literature. S. I. Units are used throughout, but c.g.s units are also given when appropriate.
Author :
Publisher :
ISBN 13 :
Total Pages : 38 pages
Book Rating : 4.:/5 (227 download)
Download or read book Applications of Low-Coordination Phosphorus Chemistry in the Chemical Modification of Surfaces written by and published by . This book was released on 1992 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt: Low-coordination phosphorus compounds of various types (RO-PO2, R-PO2, RO-P(S)O, R-P=CH2) were generated in the presence of suspended solids known to contain surface OH groups (silica gel, alumina, Zeolites, titanium dioxide). In all cases, the phosphorus atom became covalently attached to the 0 atom on the surface. CP-MAS 31P NMR was used extensively to prove the presence of the bonded group. Valuable HPLC characteristics were found for phosphorylated silica gel.
Author : N. L. Paddock
Publisher :
ISBN 13 :
Total Pages : 64 pages
Book Rating : 4.3/5 (91 download)
Download or read book Structure and Reactions in Phosphorus Chemistry written by N. L. Paddock and published by . This book was released on 1962 with total page 64 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Jean-Pierre Majoral
Publisher : Springer Science & Business Media
ISBN 13 : 3540440860
Total Pages : 268 pages
Book Rating : 4.5/5 (44 download)
Download or read book New Aspects in Phosphorus Chemistry II written by Jean-Pierre Majoral and published by Springer Science & Business Media. This book was released on 2002 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: Strong non-ionic bases are highly advantageous as stoichiometric reagents and as catalysts in synthetic organic chemistry owing to side reactions that f- quently occur when ionic bases such as LDA or alkali metal alkoxides are employed. A second reason that non-ionic bases are frequently more useful in these applications is that such bases are often more soluble in less polar organic solvents, particularly at low temperatures. Thirdly, non-ionic bases can provide reactive naked or tightly associated deprotonated substrate anions that are s- bilized by the relatively large, poorly solvated cations formed by the protonated base. In such cations, extensive positive charge delocalization can occur. Prior to our work on pro-azaphosphatranes of type 1 (Scheme 1), the very strong n- ionic bases utilized for organic transformations were largely confined to the nitrogenous bases shown below (Scheme 2). Scheme 1 Scheme 2 4 J.G. Verkade 2 Uses of Strong Nonionic Nitrogen Bases 2. 1 Amines One of the earliest strong non-ionic bases to make its appearance was Proton Sponge and its derivatives [1] and these systems have been reviewed [2]. More recently Proton Sponge has been used in the palladium-catalyzed arylation of 2,3-dihydrofuran [3], and it also catalyzes Knoevenagel condensations of s- strates possessing activated methylene groups [4]. Recently the synthesis of the macrocyclic tetramine below (Scheme 3) was reported [5]. The encrypted nitrogens are very basic (pK,24.
Author : Kenneth D. Karlin
Publisher : John Wiley & Sons
ISBN 13 : 0470167076
Total Pages : 711 pages
Book Rating : 4.4/5 (71 download)
Download or read book Progress in Inorganic Chemistry, Volume 49 written by Kenneth D. Karlin and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 711 pages. Available in PDF, EPUB and Kindle. Book excerpt: Breakthrough research and innovative science . . . PROGRESS in Inorganic Chemistry Nowhere is creative scientific talent busier than in the world of inorganic chemistry. This fascinating series provides the field of inorganic chemistry with a forum for critical and authoritative evaluations of advances in every area of the discipline. With contributions from internationally renowned chemists, this latest volume of Progress in Inorganic Chemistry continues to report the most recent advances with an innovative, cutting-edge style. "This series is distinguished not only by its scope and breadth, but also by the depth and quality of the reviews." -Journal of the American Chemical Society "[This series] has won a deservedly honored place on the bookshelf of the chemist attempting to keep afloat in the torrent of original papers on inorganic chemistry." -Chemistry in Britain CONTENTS OF VOLUME 49 * Nonclassical Metal Carbonyls (Anthony J. Lupinetti and Steven H. Strauss, Colorado State University, Fort Collins, Colorado, and Gernot Frenking, Philipps-Universitat Marburg, Germany) * The Influence of Ligands on Dirhodium(II) on Reactivity and Selectivity in Metal Carbene Reactions (Michael P. Doyle, University of Arizona, Tucson, Arizona, and Tong Ren, University of Miami, Coral Gables, Florida) * Coordination Chemistry of Transition Metals with Hydrogen Chalcogenide and Hydrochalcogenido Ligands (Maurizio Peruzzini and Isaac De Los Rios, Instituto per lo Studio della Stereochimica ed Energetica dei Composti de Coordinazione, CNR, Firenze, Italy, and Antonio Romerosa, Universidad de Almeria, Spain) * The Coordination Chemistry of Phosphinines, Their Polydentate and Macrocyclic Derivatives (Nicolas Mezailles, Francois Mathey, and Pascal le Floch, Ecole Polytechnique, Palaiseau Cedex, France) * Texaphyrins: Synthesis and Development of a Novel Class of Therapeutic Agents (Tarak D. Mody and Lei Fu, Pharmacyclics, Inc., Sunnyvale, California, and Jonathan L. Sessler, University of Texas at Austin, Texas) * The Chemistry of Synthetic Fe-Mo-S Clusters and Their Relevance to the Structure and Function of the Fe-Mo-S Center in Nitrogenase (Steve M. Malinak, Albion College, Michigan, and Dimitri Coucouvanis, University of Michigan, Ann Arbor, Michigan)
Author : D.E.C. Corbridge
Publisher : CRC Press
ISBN 13 : 1439840881
Total Pages : 1476 pages
Book Rating : 4.4/5 (398 download)
Download or read book Phosphorus written by D.E.C. Corbridge and published by CRC Press. This book was released on 2013-01-07 with total page 1476 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over two decades have passed since the fifth edition of Phosphorus: Chemistry, Biochemistry and Technology. Major advances in chemistry, materials science, electronics, and medicine have expanded and clarified the role of phosphorus in both our everyday appliances and groundbreaking research. Significantly expanded, updated, and reorganized, this sixth edition organizes and explains vital phosphorus research and relevant information available in highly specialized reviews and references on select related topics. An authoritative and comprehensive review of phosphorus chemistry and related technology, Phosphorus: Chemistry, Biochemistry and Technology covers historical, academic, industrial, agricultural, military, biological, and medical aspects of phosphorous. Furthermore, it offers a starting point for more extended studies of the highly specialized branches of phosphorus chemistry. Although this book deals with a small fraction of the > 106 known phosphorus compounds, it thoroughly covers the simpler derivatives and most key compounds of economic, sociological, and biological importance. Extensively updated and expanded with tables, figures, equations, structural formulae, and references, it is ideal for scientists in related fields seeking a rapid introduction to phosphorus chemistry.
Author : Viktor Iaroshenko
Publisher : John Wiley & Sons
ISBN 13 : 3527335722
Total Pages : 586 pages
Book Rating : 4.5/5 (273 download)
Download or read book Organophosphorus Chemistry written by Viktor Iaroshenko and published by John Wiley & Sons. This book was released on 2019-04-22 with total page 586 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling the gap for an up-to-date reference that presents the field of organophosphorus chemistry in a comprehensive and clearly structured way, this one-stop source covers the chemistry, properties, and applications from life science and medicine. Divided into two parts, the first presents the chemistry of various phosphorus-containing compounds and their synthesis, including ylides, acids, and heterocycles. The second part then goes on to look at applications in life science and bioorganic chemistry. Last but not least, such important practical aspects as 31P-NMR and protecting strategies for these compounds are presented. For organic, bioinorganic, and medicinal chemists, as well as those working on organometallics, and for materials scientists. The book, a contributed work, features a team of renowned scientists from around the world whose expertise spans the many aspects of modern organophosphorus chemistry.
Author : Jean-Pierre Majoral
Publisher : Springer Science & Business Media
ISBN 13 : 9783540224983
Total Pages : 300 pages
Book Rating : 4.2/5 (249 download)
Download or read book New Aspects in Phosphorus Chemistry V written by Jean-Pierre Majoral and published by Springer Science & Business Media. This book was released on 2005 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phosphorus chemistry is a diverse field and this volume focuses on new developments of "old themes" with different approaches and ideas, state of the art for two topics of general interest, and the emerging fields of research. This volume only describes in part the huge number of original papers on phosphorus-related topics.
Author : Egon Wiberg
Publisher : Academic Press
ISBN 13 : 9780123526519
Total Pages : 1958 pages
Book Rating : 4.5/5 (265 download)
Download or read book Inorganic Chemistry written by Egon Wiberg and published by Academic Press. This book was released on 2001 with total page 1958 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
Publisher : Academic Press
ISBN 13 : 0080580408
Total Pages : 429 pages
Book Rating : 4.0/5 (85 download)
Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 1996-02-12 with total page 429 pages. Available in PDF, EPUB and Kindle. Book excerpt: This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry--the study of compounds containing carbon metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry. In basic research, organometallics have contributed inter alia to: Metal cluster chemistry Surface chemistry The stabilization of highly reactive species by metal coordination Chiral synthesis The formulation of multiple bonds between carbon and the other elements and between the elements themselves
Author : Viktor Iaroshenko
Publisher : John Wiley & Sons
ISBN 13 : 3527672265
Total Pages : 738 pages
Book Rating : 4.5/5 (276 download)
Download or read book Organophosphorus Chemistry written by Viktor Iaroshenko and published by John Wiley & Sons. This book was released on 2019-01-07 with total page 738 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling the gap for an up-to-date reference that presents the field of organophosphorus chemistry in a comprehensive and clearly structured way, this one-stop source covers the chemistry, properties, and applications from life science and medicine. Divided into two parts, the first presents the chemistry of various phosphorus-containing compounds and their synthesis, including ylides, acids, and heterocycles. The second part then goes on to look at applications in life science and bioorganic chemistry. Last but not least, such important practical aspects as 31P-NMR and protecting strategies for these compounds are presented. For organic, bioinorganic, and medicinal chemists, as well as those working on organometallics, and for materials scientists. The book, a contributed work, features a team of renowned scientists from around the world whose expertise spans the many aspects of modern organophosphorus chemistry.
Author : Ralf Steudel
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 311057831X
Total Pages : 843 pages
Book Rating : 4.1/5 (15 download)
Download or read book Chemistry of the Non-Metals written by Ralf Steudel and published by Walter de Gruyter GmbH & Co KG. This book was released on 2020-02-24 with total page 843 pages. Available in PDF, EPUB and Kindle. Book excerpt: The current textbook is an excellent inroduction to the chemistry of the non-metallic elements. The book begins by reviewing the key theoretical concepts of chemical bonding and the properties of different bonding types. Subsequent chapters are focused on reactions, structures and applications of the non-metallic compounds. Combining careful pedagogy and clear writing style, the textbook is a must-have for students studying inorganic chemistry.
