Stable Radicals

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Publisher : John Wiley & Sons
ISBN 13 : 111995696X
Total Pages : 628 pages
Book Rating : 4.1/5 (199 download)

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Book Synopsis Stable Radicals by : Robin Hicks

Download or read book Stable Radicals written by Robin Hicks and published by John Wiley & Sons. This book was released on 2011-08-02 with total page 628 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stable radicals - molecules with odd electrons which are sufficiently long lived to be studied or isolated using conventional techniques - have enjoyed a long history and are of current interest for a broad array of fundamental and applied reasons, for example to study and drive novel chemical reactions, in the development of rechargeable batteries or the study of free radical reactions in the body. In Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds a team of international experts provide a broad-based overview of stable radicals, from the fundamental aspects of specific classes of stable neutral radicals to their wide range of applications including synthesis, materials science and chemical biology. Topics covered include: triphenylmethyl and related radicals polychlorinated triphenylmethyl radicals: towards multifunctional molecular materials phenalenyls, cyclopentadienyls, and other carbon-centered radicals the nitrogen oxides: persistent radicals and van der Waals complex dimers nitroxide radicals: properties, synthesis and applications the only stable organic sigma radicals: di-tert-alkyliminoxyls. delocalized radicals containing the hydrazyl [R2N-NR] unit metal-coordinated phenoxyl radicals stable radicals containing the thiazyl unit: synthesis, chemical, and materials properties stable radicals of the heavy p-block elements application of stable radicals as mediators in living-radical polymerization nitroxide-catalyzed alcohol oxidations in organic synthesis metal-nitroxide complexes: synthesis and magneto-structural correlations rechargeable batteries using robust but redox-active organic radicals spin labeling: a modern perspective functional in vivo EPR spectroscopy and imaging using nitroxides and trityl radicals biologically relevant chemistry of nitroxides Stable Free Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds is an essential guide to this fascinating area of chemistry for researchers and students working in organic and physical chemistry and materials science.

The Spectra and Structures of Simple Free Radicals

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Author :
Publisher : Courier Corporation
ISBN 13 : 048665821X
Total Pages : 242 pages
Book Rating : 4.4/5 (866 download)

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Book Synopsis The Spectra and Structures of Simple Free Radicals by : Gerhard Herzberg

Download or read book The Spectra and Structures of Simple Free Radicals written by Gerhard Herzberg and published by Courier Corporation. This book was released on 1988-01-01 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Authoritative and clearly written."—Applied Optics The direct observation of short-lived free radicals and the consequent study of their structure and reactions have led to important developments in almost every branch of chemistry as well as in other areas. This volume by a Nobel laureate offers an excellent introduction to the essentials of molecular spectroscopy. The introductory chapter discusses experimental methods and illustrates the observed spectra of various molecules and free radicals. Subsequent chapters explore rotational, vibrational, and electronic energy levels of diatomic molecules and ions; radiative transitions; linear and nonlinear polyatomic radicals and ions; continuous and diffuse spectra; predissociation and pre-ionization; and recombination. The well-illustrated text features more than 100 figures and spectra. A distilled version of the author's monumental three-volume study, Molecular Spectra and Molecular Structure, it constitutes a superb resource for anyone wishing a concise but complete treatment of the fundamentals of molecular spectroscopy.

The Chemistry of Free Radicals

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Author :
Publisher : Hodder Education
ISBN 13 :
Total Pages : 264 pages
Book Rating : 4.:/5 (51 download)

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Book Synopsis The Chemistry of Free Radicals by : Rayson L. Huang

Download or read book The Chemistry of Free Radicals written by Rayson L. Huang and published by Hodder Education. This book was released on 1974 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Free-Radical Chemistry

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Author :
Publisher : CUP Archive
ISBN 13 : 9780521201490
Total Pages : 620 pages
Book Rating : 4.2/5 (14 download)

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Book Synopsis Free-Radical Chemistry by : D. C. Nonhebel

Download or read book Free-Radical Chemistry written by D. C. Nonhebel and published by CUP Archive. This book was released on 1974-01-31 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Reaction of Atoms and Radicals with Various Molecules

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Publisher :
ISBN 13 :
Total Pages : 1 pages
Book Rating : 4.:/5 (227 download)

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Book Synopsis The Reaction of Atoms and Radicals with Various Molecules by : J. W. LINNETT

Download or read book The Reaction of Atoms and Radicals with Various Molecules written by J. W. LINNETT and published by . This book was released on 1961 with total page 1 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Atoms, Inorganic Radicals and Radicals in Metal Complexes / Atome, anorganische Radikale und Radikale in Metallkomplexen

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Publisher : Springer
ISBN 13 : 9783540080190
Total Pages : 341 pages
Book Rating : 4.0/5 (81 download)

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Book Synopsis Atoms, Inorganic Radicals and Radicals in Metal Complexes / Atome, anorganische Radikale und Radikale in Metallkomplexen by : C. Daul

Download or read book Atoms, Inorganic Radicals and Radicals in Metal Complexes / Atome, anorganische Radikale und Radikale in Metallkomplexen written by C. Daul and published by Springer. This book was released on 1977-07-01 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Frontiers of Free Radical Chemistry

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Author :
Publisher : Elsevier
ISBN 13 : 032315221X
Total Pages : 400 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Frontiers of Free Radical Chemistry by : William Pryor

Download or read book Frontiers of Free Radical Chemistry written by William Pryor and published by Elsevier. This book was released on 2012-12-02 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Frontiers of Free Radical Chemistry covers the proceedings of the 1979 symposium on Frontiers of Free Radical Chemistry, held in Louisiana State University Chemistry Department, supported by the Exxon Education Foundation. The contributors discuss the mechanisms of hydrocarbon cracking; oxidation processes; inhibition; and the theory of organic radical reactions, halogenations, and organic peroxide chemistry. This book is organized into three parts encompassing 15 chapters. Part I deals with the understanding of molecular and free radical mechanisms in predicting thermochemical data for radicals and molecules. This part also describes the relationship between distortions of organic molecules and the reactions of pericyclic, ionic, and radical molecules. Part II presents quantitative evaluations of gas phase reactions or carbynes and hydrocarbon pyrolysis and cracking. Discussions on the reactions of free atoms and radicals in the chemistry of the stratosphere and natural troposphere, with an emphasis on the ozone layer and its potential depletion by artificial pollutants, are included in this part. Part III explores the pertinent free radical reactions related to fuel research. Petroleum chemists, researchers, and engineers will find this book invaluable.

EPR of Free Radicals in Solids

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Publisher : Springer Science & Business Media
ISBN 13 : 1475751664
Total Pages : 649 pages
Book Rating : 4.4/5 (757 download)

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Book Synopsis EPR of Free Radicals in Solids by : Anders Lund

Download or read book EPR of Free Radicals in Solids written by Anders Lund and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 649 pages. Available in PDF, EPUB and Kindle. Book excerpt: EPR of Free Radicals in Solids: Trends in Methods and Applications presents methods and applications of modern EPR for the study of free radical processes in solids, which so far are only available in the journal literature. The first part of the book, covering trends in methods, contains experimentally oriented chapters on continuous wave and pulsed EPR techniques and special methods involving muon magnetic resonance and optical detection and theory for dynamic studies. New simulation schemes, including the influence of dynamics, are presented as well as advances in the calculation of hyperfine and electronic g-tensors. The second part of the book presents applications involving studies of radiation and photo-induced inorganic and organic radicals in inert matrices, including novel results of quantum effects in small radicals. High-spin molecules and complexes are also considered as well as radical processes in photosynthesis. Recent advances in EPR dosimetry are summarized.

Free Radicals in Chemistry and Biology

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Author :
Publisher : CRC Press
ISBN 13 : 9780849353871
Total Pages : 322 pages
Book Rating : 4.3/5 (538 download)

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Book Synopsis Free Radicals in Chemistry and Biology by : Milan Lazar

Download or read book Free Radicals in Chemistry and Biology written by Milan Lazar and published by CRC Press. This book was released on 1989-03-31 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Elementary radical reactions are described in terms of fundamental knowledge of organic chemistry and chemical physics in this valuable reference text. The complex radical processes of nonchain and chain mechanisms, such as dimerization, alkylation, polymerization, telomerization, halogenation pyrolysis, oxidation and combustion, are complemented by reactions in chemical lasers and in the cosmos, as well as by reactions in biological objects under normal or pathological metabolism. The text also provides the synthesis of facts from various fields of research and involves mechanisms where free radicals appear either as main or side intermediates in one of the several alternatives of the reaction pathway. Highlights include 38 tables and 39 figures.

Biomimetic Radical Chemistry and Applications

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Publisher : MDPI
ISBN 13 : 3039283928
Total Pages : 300 pages
Book Rating : 4.0/5 (392 download)

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Book Synopsis Biomimetic Radical Chemistry and Applications by : Chryssostomos Chatgilialoglu

Download or read book Biomimetic Radical Chemistry and Applications written by Chryssostomos Chatgilialoglu and published by MDPI. This book was released on 2020-03-25 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: The enormous importance of free radical chemistry for a variety of biological events, including ageing and inflammation, has attracted a strong interest in understanding the related mechanistic steps at the molecular level. Modelling the free radical chemical reactivity of biological systems is an important research area. When studying free-radical-based chemical mechanisms, biomimetic chemistry and the design of established biomimetic models come into play to perform experiments in a controlled environment that is suitably designed to be in strict connection with cellular conditions. This Special Issue gives the reader a wide overview of biomimetic radical chemistry, where molecular mechanisms have been defined and molecular libraries of products are developed to also be used as traces for the discovery of some relevant biological processes. Several subjects are presented, with 12 articles and 6 reviews written by specialists in the fields of DNA, proteins, lipids, biotechnological applications, and bioinspired synthesis, having “free radicals” as a common denominator.

Handbook of Free Radical Initiators

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Publisher : John Wiley & Sons
ISBN 13 : 0471281832
Total Pages : 903 pages
Book Rating : 4.4/5 (712 download)

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Book Synopsis Handbook of Free Radical Initiators by : E. T. Denisov

Download or read book Handbook of Free Radical Initiators written by E. T. Denisov and published by John Wiley & Sons. This book was released on 2005-01-14 with total page 903 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radical initiators–chemical molecules which easily decompose into free radicals–serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: Dialkyl Peroxides and Hydroperoxides Diacyl Peroxides, Peresters, and Organic Polyoxides Azo-Compounds Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules Free Radical Abstraction Reactions Free Radical Addition Reactions Free Radical Recombination and Disproportoination Reactions Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.

Free Radicals in Synthesis and Biology

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Publisher : Springer Science & Business Media
ISBN 13 : 9400908970
Total Pages : 487 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Free Radicals in Synthesis and Biology by : F. Minisci

Download or read book Free Radicals in Synthesis and Biology written by F. Minisci and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 487 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free-radical reactions have been for long time the domain of the physical chemists and the basic chemical industry (polymerization of vinyl monomers, oxidation by molecular oxygen, chlorination of methane etc.), where the use of simple molecules and the possibility of partial conversions without heavy problems of product separations makes less dramatic the aspects of regio and chemoselectivity. As synonym of unselectivity, free radical reactions were considered of poor use in the synthesis of fine chemicals or sophisticated molecules, where a high selectivity is an essential condition for the success, or in the involvement of biological processes. Within the last 15 years, however, an authentic explosion of synthetic applications of free radical reactions occurred; they have gained a remarkable position among the selective methods of synthesis. At the same time the great importance of free radical reactions in fundamental biological processes and in the metabolism of drugs has been recognized. Thus a specialized meeting on these topics was generally felt appropriate. I had the honour and the onus to organize this workshop because for more than 30 years I have been involved in the research of free radical reactions. Thanks to a generous grant from NATO Scientific Affairs Division and the financial support of CNR and chemical industry (Montedison, Enichem, Zambon) such a meeting among almost 50 specialists and 15 observers of sufficient standard to take advantage of the discussion, became possible at Bardolino (Italy).

Reaction Dynamics Involving Ions, Radicals, Neutral and Excited Species

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Publisher : Frontiers Media SA
ISBN 13 : 2889634302
Total Pages : 345 pages
Book Rating : 4.8/5 (896 download)

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Book Synopsis Reaction Dynamics Involving Ions, Radicals, Neutral and Excited Species by : Stefano Falcinelli

Download or read book Reaction Dynamics Involving Ions, Radicals, Neutral and Excited Species written by Stefano Falcinelli and published by Frontiers Media SA. This book was released on 2020-01-22 with total page 345 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Free Radicals in Organic Chemistry

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Publisher :
ISBN 13 :
Total Pages : 328 pages
Book Rating : 4.:/5 (319 download)

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Book Synopsis Free Radicals in Organic Chemistry by : Jacques Fossey

Download or read book Free Radicals in Organic Chemistry written by Jacques Fossey and published by . This book was released on 1995-11-09 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radicals constitute the most frequently used class of reaction intermediates in organic chemistry. This study describes the structure and reactivity of free radicals, and explores their role in both natural phenomena and in the design of new reaction pathways.

Radicals for Life

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Publisher : Elsevier
ISBN 13 : 0080489591
Total Pages : 444 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Radicals for Life by : Ernst van Faassen

Download or read book Radicals for Life written by Ernst van Faassen and published by Elsevier. This book was released on 2011-10-13 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radicals for Life: the Various Forms of Nitric Oxide provides an up-to-date overview of the role of nitrosocompounds and nitrosyl-iron complexes in physiology. Nitrosocompounds can be considered as stabilised forms of nitric oxide, one of the most important regulatory molecules in physiology today. Many nitrosocompounds share some of the physiological functions of nitric oxide, and may be formed inside living organisms. This is the first book to be published that is dedicated to the role of such nitrosocompounds in physiology, with particular emphasis on the nitrosocompounds that are endogenously formed in higher organisms and humans. Points of discussion include: physical and chemical properties of the compounds, the main chemical pathways in vivo, as well as the physiological effects that have been recognised to date. Each of the nineteen chapters is written by distinguished specialists in the field, well known for their original and important contributions to the subject. Also included are results from a wide range of studies in vitro, in cell cultures, animal models and human volunteers. Examples of alternative forms of nitric oxide, with special emphasis on their protective role against widespread human diseases like atherosclerosis, Alzheimer's disease, diabetes, sexual dysfunction, and renal insufficiency to stroke and ischemia are also included. First monograph to consider and provide an overview of endogenous nitrosocompounds and nitrosyl-iron complexes Extensive bibliographic references, written by specialists of human physiology Providing high scientific quality with a focus on implications for human diseases

Inorganic Radicals, Metal Complexes and Nonconjugated Carbon Centered Radicals 2

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Author :
Publisher : Springer
ISBN 13 : 9783540432777
Total Pages : 0 pages
Book Rating : 4.4/5 (327 download)

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Book Synopsis Inorganic Radicals, Metal Complexes and Nonconjugated Carbon Centered Radicals 2 by : W. Kaim

Download or read book Inorganic Radicals, Metal Complexes and Nonconjugated Carbon Centered Radicals 2 written by W. Kaim and published by Springer. This book was released on 2006-10-25 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume II/26 supplements the previous compilations II/l, II/9 and II/17 of the magnetic properties of free radicals. Due to the still rapid growth of the field and the inclusion of new subjects the volume is divided into subvolumes which will appear in fast succession. Together with the earlier publications volume II/26 offers an up-to-date and comprehensive survey and collection of structures and data on the important chemical intermediates.

Free Radicals in Biology V1

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Author :
Publisher : Elsevier
ISBN 13 : 0323156827
Total Pages : 304 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Free Radicals in Biology V1 by : William Pryor

Download or read book Free Radicals in Biology V1 written by William Pryor and published by Elsevier. This book was released on 2012-12-02 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free Radicals in Biology, Volume 1, provides an introduction to some of the basic concepts of free radical biology. The book emerged from the President's Symposium of the American Society for Experimental Pathology held in Atlantic City in April 1970. The book's opening chapter introduces a mechanistic view of free radical reactions using examples from biological systems. This is followed by a discussion of autoxidative damage to lipids in membranes. Some of the special chemistry of lipid oxidation are presented, and a number of novel ideas are suggested. The third chapter deals with the uses of electron-spin resonance in biology. Spin labeling is also discussed, which is one of the most useful methods of probing the chemical and physical environment of molecules in cells. The remaining chapters cover free radicals which occur in photosynthesis and the importance of the enzyme, superoxide dismutase. The study of the occurrence and reactions of this enzyme provides an important and extensive body of data clearly pointing to the significance of free radicals in cellular chemistry.