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Modern Aspects Of Electrochemistry 41
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Author :Constantinos G. Vayenas Publisher :Springer Science & Business Media ISBN 13 :0387461086 Total Pages :308 pages Book Rating :4.3/5 (874 download)
Book Synopsis Modern Aspects of Electrochemistry 41 by : Constantinos G. Vayenas
Download or read book Modern Aspects of Electrochemistry 41 written by Constantinos G. Vayenas and published by Springer Science & Business Media. This book was released on 2007-05-06 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 41 of the prominent series Modern Aspects of Electrochemistry covers a range of topics in Electrochemistry and Electrochemical Engineering. The topics include the second chapter on the survey of experimental techniques and devices of solid state electrochemistry begun by Professor Joachim Maier in Volume 39. Chapter two contains a review of synthesis and characterization of nanoporous carbons and their electrochemical applications. The next chapter reviews and discusses the use of graphs in the study of chemical reaction network. The book also reviews and discusses mathematical models of three dimensional electrode structures.
Book Synopsis Modern Aspects of Electrochemistry by : Brian E. Conway
Download or read book Modern Aspects of Electrochemistry written by Brian E. Conway and published by Springer Science & Business Media. This book was released on 2013-11-09 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume of Modern Aspects of Electrochemistry contains six chapters. The first four chapters are about phenomena of interest at the microscopic level and the last two are on phenomena at the macroscopic level. In the first chapter, Uosaki and Kita review various theoretical models that have been presented to describe the phenomena that occur at an electrolyte/ semiconductor interface under illumination. In the second chapter, Orazem and Newman discuss the same phenomena from a different point of view. In Chapter 3, Bogus lavsky presents state-of-the-art considerations of transmembrane potentials and other aspects of active transport in biological systems. Next, Burke and Lyons present a survey of both the theoretical and the experimental work that has been done on hydrous oxide films on several metals. The last two chapters cover the topics of the production of chlorine and caustic and the phenomena of electrolytic gas evol ution. In Chapter 5, Hine et al. describe the engineering aspects of the three processes used in the chi or-alkali industry, and in Chapter 6, Sides reviews the macroscopic phenomena of nucleation, growth, and detachment of bubbles, and the effect of bubbles on the conduc tivity of and mass transfer in electrolytes.
Book Synopsis Modern Aspects of Electrochemistry by : John O'M. Bockris
Download or read book Modern Aspects of Electrochemistry written by John O'M. Bockris and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt: Integrating both theoretical and applied aspects of electrochemistry, this acclaimed monograph series presents a review of the latest advances in the field. The current volume includes chapters on the mechanism of nerve excitation from an electrochemical standpoint, the electronic factor in the kinetics of charge-transfer reaction, and five other subjects.
Author :Constantinos G. Vayenas Publisher :Springer Science & Business Media ISBN 13 :0387317015 Total Pages :296 pages Book Rating :4.3/5 (873 download)
Book Synopsis Modern Aspects of Electrochemistry 39 by : Constantinos G. Vayenas
Download or read book Modern Aspects of Electrochemistry 39 written by Constantinos G. Vayenas and published by Springer Science & Business Media. This book was released on 2006-12-22 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume of Modern Aspects covers a wide spread of topics presented in an authoritative, informative and instructive manner by some internationally renowned specialists. Professors Politzer and Dr. Murray provide a comprehensive description of the various theoretical treatments of solute-solvent interactions, including ion-solvent interactions. Both continuum and discrete molecular models for the solvent molecules are discussed, including Monte Carlo and molecular dynamics simulations. The advantages and drawbacks of the resulting models and computational approaches are discussed and the impressive progress made in predicting the properties of molecular and ionic solutions is surveyed. The fundamental and applied electrochemistry of the silicon/electrolyte interface is presented in an authoritative review by Dr. Gregory Zhang, with emphasis in the preparation of porous silicon, a material of significant technological interest, via anodic dissolution of monocrystalline Si. The chapter shows eloquently how fundamental electrokinetic principles can be utilized to obtain the desired product morphology. Markov chains theory provides a powerful tool for modeling several important processes in electrochemistry and electrochemical engineering, including electrode kinetics, anodic deposit formation and deposit dissolution processes, electrolyzer and electrochemical reactors performance and even reliability of warning devices and repair of failed cells. The way this can be done using the elegant Markov chains theory is described in lucid manner by Professor Thomas Fahidy in a concise chapter which gives to the reader only the absolutely necessary mathematics and is rich in practical examples.
Download or read book Electrochemistry written by P.H. Rieger and published by Springer Science & Business Media. This book was released on 1993-11-30 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: It has been fashionable to describe electrochemistry as a discipline at the interface between the branches of chemistry and many other sciences. A perusal of the table of contents will affirm that view. Electrochemistry finds applications in all branches of chemistry as well as in biology, biochemistry, and engineering; electrochemistry gives us batteries and fuel cells, electroplating and electrosynthesis, and a host of industrial and technological applications which are barely touched on in this book. However, I will maintain that electrochemistry is really a branch of physical chemistry. Electrochemistry grew out of the same tradition which gave physics the study of electricity and magnetism. The reputed founders of physical chemistry-Arrhenius, Ostwald, and van't Hoff-made many of their contributions in areas which would now be regarded as electrochemistry. With the post-World War II capture of physical chemistry by chemical physicists, electrochemists have tended to retreat into analytical chemistry, thus defining themselves out of a great tradition. G. N. Lewis defined physical chemistry as "the study of that which is interesting." I hope that the readers of this book will find that electrochemistry qualifies.
Book Synopsis Modern Aspects of Electrochemistry, Number 38 by : B. E. Conway
Download or read book Modern Aspects of Electrochemistry, Number 38 written by B. E. Conway and published by Springer Science & Business Media. This book was released on 2006-02-02 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume comprises six chapters on aspects of fundamental and applied electrochemical science that will be of interest both to researchers in the basic areas of the subject and to those involved in aspects of electrochemical technologies. Chapter 1 is the first part of a 2-part, major contribution by Joachim Maier on Solid State Electrochemistry: Thermodynamics and Kinetics of Charge Carriers in Solids. Part 2 will follow in volume 39 to be published in year 2005. This contribution reviews modern concepts of the equilibria involving charge carriers in solids in terms of concentrations of defects in solids and at grain-boundaries, including doping effects. Complementarily, kinetics of charge transfer and ion transfer are treated in some detail in relation to conductance, kinetics of surface processes and electrode-kinetics involving solid-state processes. This chapter will be of major interest to electrochemists and physicists in the semiconductor field and that involving ionic solids. In the second chapter, Appleby presents a detailed discussion and review in modern terms of a central aspect of electrochemistry: Electron Transfer Reactions With and Without Ion Transfer. Electron transfer is the most fundamental aspect of most processes at electrode interfaces and is also involved intimately with the homogeneous chemistry of redox reactions in solutions.
Book Synopsis Modern Aspects of Electrochemistry 28 by : John O'M. Bockris
Download or read book Modern Aspects of Electrochemistry 28 written by John O'M. Bockris and published by Springer Science & Business Media. This book was released on 1995-04-30 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: From reviews of previous volumes: 'This volume continues the valuable service that has been rendered by the Modern Aspects series.'-Journal of Electroanalytical Chemistry 'Extremely well referenced and very readable....Maintains the overall high standards of the series.'-Journal of the American Chemical Society
Book Synopsis Modern Aspects of Electrochemistry 40 by : Ralph E. White
Download or read book Modern Aspects of Electrochemistry 40 written by Ralph E. White and published by Springer Science & Business Media. This book was released on 2010-04-28 with total page 367 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume in the acclaimed series Modern Aspects of Electrochemistry starts with a dedication to the late Professor Brian Conway who for 50 years helped to guide this series to its current prominence. The remainder of the volume is then devoted to the following topics: PEM fuel cells; the use of graphs in electrochemical reaction newtworks; nanomaterials in Lithium-ion batteries; direct methanolf fuel cells (two chapters); fuel cell catalyst layers. The book is for electrochemists, electrochemical engineers, fuel cell workers and energy generation workers.
Book Synopsis Modern Aspects of Electrochemistry No. 7 by : B. E. Conway
Download or read book Modern Aspects of Electrochemistry No. 7 written by B. E. Conway and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Despite reductions in the level of research activity in most fields which, for reasons of economic decline, have taken place in the U.S. during the last year or two, world progress in the fundamental aspects has continued actively. An important aspect of such recent work has been the use of nonaqueous solvents in studies on the constitution of the double-layer and electrochemical reactions. Interpretation of the behavior of electrode interfaces in such solvents demands more knowledge of the solvation properties of ions in nonaqueous media. Chapter 1 by Pad ova on "Ionic Solvation in Nonaqueous and Mixed Solvents" gives an up to date review of the present state of knowledge in this field, together with tabulations of data that are likely to be of quantitative value in further investigations of both homogeneous and heterogeneous electrochemistry in such media. Electrochemical studies of cathodic processes in nonaqueous solvents have, in recent years, revealed the role of solvated electrons. These are of interest in new approaches to reductive electro-organic synthesis. Similarly, the generation of hydrated electrons in photo cathodic processes is of great interest. In Chapter 2, by Conway, the conditions under which solvated electrons can arise in electrode processes are critically examined and the electro-organic reactions that hwe been investigated are reviewed. The supposed electro generation of hydrated electrons in the water solvent and as inter mediates in cathodic hydrogen evolution is shown to be unlikely.
Book Synopsis Modern Aspects of Electrochemistry by : B. E. Conway
Download or read book Modern Aspects of Electrochemistry written by B. E. Conway and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 497 pages. Available in PDF, EPUB and Kindle. Book excerpt: As the subject of electrochemistry moves into the final quarter of the century, a number of developed areas can be assessed in depth while some new areas provide quantitatively and qualitatively novel data and results. The first chapter, by Kebarle, deals with an example of the latter type of field in which new information of the energetics and equilibria of reactions between ions and solvent molecules is studied in the gas phase and provides interesting basic information for treatments of ions in solution, i.e., ionic solvation. Chapter 2, by Hamann, discusses the behavior of electrolyte solutions under high pressures, a matter of intrinsic interest in relation to ion-solvent interaction and the structural aspects of the properties of ionic solutions, especially in water. This topic is also of current interest with regard to the physical chemistry of the marine environment, especially at great depths. In the article by Bloom and Snook (Chapter 3), models for treatments of molten salt systems are examined quantitatively in relation to the structure of molten ionic liquids and to the statistical mechanical approaches that can be meaningfully made to interpret their properties and electrochemical behavior.
Book Synopsis Modern Aspects of Electrochemistry No. 4 by : J. O’M. Bockris
Download or read book Modern Aspects of Electrochemistry No. 4 written by J. O’M. Bockris and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 323 pages. Available in PDF, EPUB and Kindle. Book excerpt: The fourth volume of Modern Aspects of Electrochemistry is being prepared at a time of great growth of interest in electro chemistry. The situation can be summarized by saying that the realization is spreading among scientists that electrochemistry represents a broad interdisciplinary field, which has applications to many areas in physics, chemistry, metallurgy, and biology. Among the reasons for this awakening is the reorientation of what is understood under electrochemistry toward electrodics "the study of charged interfaces"-with the ionic-solution aspects of electrochemistry being regarded increasingly as aspects of physical chemistry which are helpful auxiliaries to the broad subject of charged interfaces. The pervasiveness of electrochemistry be comes clearer when one recalls that most interfaces carry a charge, or undergo local charge transfers, even though they are not con nected with a source of power. A further reason for the rapid increase in electrochemical studies arises from the technological aspects, in particular in energy conversion and storage, syntheses, extractions, devices, the stability and finishing of surfaces, the treatment of water, etc. The fact that electrodics allows the conversion of chemical to electric energy and the storage of the latter, at the same time producing fresh water as a by-product, presents an aspect of the subject which appears to have far-reaching significance.
Author :Constantinos G. Vayenas Publisher :Springer Science & Business Media ISBN 13 :0387494898 Total Pages :434 pages Book Rating :4.3/5 (874 download)
Book Synopsis Modern Aspects of Electrochemistry 42 by : Constantinos G. Vayenas
Download or read book Modern Aspects of Electrochemistry 42 written by Constantinos G. Vayenas and published by Springer Science & Business Media. This book was released on 2008-03-08 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume analyzes and summarizes recent developments in several key interfacial electrochemical systems in the areas of fuel cell electrocatatalysis, electrosynthesis and electrodeposition. The six Chapters are written by internationally recognized experts in these areas and address both fundamental and practical aspects of several existing or emerging key electrochemical technologies. The Chapter by R. Adzic, N. Marinkovic and M. Vukmirovic provides a lucid and authoritative treatment of the electrochemistry and electrocatalysis of Ruthenium, a key element for the devel- ment of efficient electrodes for polymer electrolyte (PEM) fuel cells. Starting from fundamental surface science studies and interfacial considerations, this up-to-date review by some of the pioneers in this field, provides a deep insight in the complex catalytic-electrocatalytic phenomena occurring at the interfaces of PEM fuel cell electrodes and a comprehensive treatment of recent developments in this extremely important field. Several recent breakthroughs in the design of solid oxide fuel cell (SOFC) anodes and cathodes are described in the Chapter of H. Uchida and M. Watanabe. The authors, who have pioneered several of these developments, provide a lucid presentation d- cribing how careful fundamental investigations of interfacial electrocatalytic anode and cathode phenomena lead to novel electrode compositions and microstructures and to significant practical advances of SOFC anode and cathode stability and enhanced electrocatalysis.
Book Synopsis Modern Electrochemistry 2A by : John O'M. Bockris
Download or read book Modern Electrochemistry 2A written by John O'M. Bockris and published by Springer Science & Business Media. This book was released on 2007-05-08 with total page 812 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book had its nucleus in some lectures given by one of us (J. O’M. B. ) in a course on electrochemistry to students of energy conversion at the University of Pennsyl- nia. It was there that he met a number of people trained in chemistry, physics, biology, metallurgy, and materials science, all of whom wanted to know something about electrochemistry. The concept of writing a book about electrochemistry which could be understood by people with very varied backgrounds was thereby engendered. The lectures were recorded and written up by Dr. Klaus Muller as a 293-page manuscript. At a later stage, A. K. N. R. joined the effort; it was decided to make a fresh start and to write a much more comprehensive text. Of methods for direct energy conversion, the electrochemical one is the most advanced and seems the most likely to become of considerable practical importance. Thus, conversion to electrochemically powered transportation systems appears to be an important step by means of which the difficulties of air pollution and the effects of an increasing concentration in the atmosphere of carbon dioxide may be met. Cor- sion is recognized as having an electrochemical basis. The synthesis of nylon now contains an important electrochemical stage. Some central biological mechanisms have been shown to take place by means of electrochemical reactions. A number of American organizations have recently recommended greatly increased activity in training and research in electrochemistry at universities in the United States.
Book Synopsis Modern Aspects of Electrochemistry No. 6 by : J. O'M. Bockris
Download or read book Modern Aspects of Electrochemistry No. 6 written by J. O'M. Bockris and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 393 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last decade, the evolution of electrochemistry away from concern with the physical chemistry of solutions to its more fruitful goal in the study of the widespread consequences of the transfer of electric charges across interphases has come to fruition. The turning of technology away from an onward rush, regardless, to progress which takes into account repercussions of techno logical activity on the environment, and the consequent need for a reduction and then termination of the injection of CO into 2 the atmosphere (greenhouse effect), together with a reckoning with air and water pollution in general, ensures a long-term need for advances in a basic knowledge of electrochemical systems, an increased technological use of which seems to arise from the environmental necessities. But a mighty change in attitude needs to spread among electro chemists (indeed, among all surface chemists) concerning the terms and level in which their field is discussed. The treatment of charge transfer reactions has often been made too vaguely, in terms, it seemed, of atom transfer, with the electron-transfer step, the essence of electrochemistry, an implied accompaniment to the transfer of ions across electrical double layers. The treatment has been in terms of classical mechanics, only tenable while inadequate questions were asked concerning the behavior of the electron in the interfacial transfer. No process demands a more exclusively quantal discussion than does electron transfer.
Book Synopsis Comprehensive Treatise of Electrochemistry by : Peter Horsman
Download or read book Comprehensive Treatise of Electrochemistry written by Peter Horsman and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Quantum Electrochemistry by : John O'M. Bockris
Download or read book Quantum Electrochemistry written by John O'M. Bockris and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: The origin of this book lies in a time before one of the authors (J. O'M. B.) left the University of Pennsylvania bound for the Flinders University. His collaboration with Dennis Matthews at the University of Pennsylvania had contributed a singular experimental datum to the quantum theory of elec trode processes: the variation of the separation factor with potential, which could only be interpreted in terms of a quantum theory of electrode kinetics. The authors came together as a result of grad~ate work of one of them (S. U. M. K.) on the quantum mechanics and photo aspects of elec trode processes, and this book was written during a postdoctoral fellowship held by him at the Flinders University. Having stated the book's origin, it is worthwhile stating the rational izations the authors had for writing it. Historically, quantization in elec trochemistry began very early (1931) in the applications of the quantum theory to chemistry. (See the historical table on pages xviii-xix.) There was thereafter a cessation of work on the quantum theory in electrochemistry until a continuum dielectric viewpoint, based on Born's equation for solvation energy, began to be developed in the 1950s and snowballed during the 1960s.
Book Synopsis Electrochemical Materials Science by : John Bockris
Download or read book Electrochemical Materials Science written by John Bockris and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 579 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is now time for a comprehensive treatise to look at the whole field of electrochemistry. The present treatise was conceived in 1974, and the earliest invitations to authors for contributions were made in 1975. The completion of the early been delayed by various factors. volumes has There has been no attempt to make each article emphasize the most recent situation at the expense of an overall statement of the modern view. This treatise is not a collection of articles from Recent Advances in Electrochemistry or Modern Aspects of Electrochemistry. It is an attempt at making a mature statement about the present position in the vast area of what is best looked at as a new interdisciplinary field. Texas A & M University J. O'M. Bockris University of Ottawa B. E. Conway Case Western Reserve University Ernest Yeager Texas A & M University Ralph E. White Preface to Volume 4 The science of degradation of materials involves a vast area of science and technology, the economic importance of which rivals that of any other clearly defined area affecting the standard of life. The basis of the corrosion process is the electrochemical charge-transfer reaction, and the center of the subject of the degradation of materials is electrochemical material science.
