Model Systems in Catalysis: Cluster Reactivity, Photocatalysis and Ligand-protection

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (123 download)

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Book Synopsis Model Systems in Catalysis: Cluster Reactivity, Photocatalysis and Ligand-protection by : Martin Tschurl

Download or read book Model Systems in Catalysis: Cluster Reactivity, Photocatalysis and Ligand-protection written by Martin Tschurl and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Model Systems in Catalysis

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Publisher : Springer Science & Business Media
ISBN 13 : 0387980490
Total Pages : 531 pages
Book Rating : 4.3/5 (879 download)

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Book Synopsis Model Systems in Catalysis by : Robert Rioux

Download or read book Model Systems in Catalysis written by Robert Rioux and published by Springer Science & Business Media. This book was released on 2009-11-11 with total page 531 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is an excellent compilation of cutting-edge research in heterogeneous catalysis and related disciplines – surface science, organometallic catalysis, and enzymatic catalysis. In 23 chapters by noted experts, the volume demonstrates varied approaches using model systems and their successes in understanding aspects of heterogeneous catalysis, both metal- and metal oxide-based catalysis in extended single crystal and nanostructured catalytic materials. To truly appreciate the astounding advances of modern heterogeneous catalysis, let us first consider the subject from a historical perspective. Heterogeneous catalysis had its beginnings in England and France with the work of scientists such as Humphrey Davy (1778–1829), Michael Faraday (1791–1867), and Paul Sabatier (1854–1941). Sabatier postulated that surface compounds, si- lar to those familiar in bulk to chemists, were the intermediate species leading to catalytic products. Sabatier proposed, for example, that NiH moieties on a Ni sur- 2 face were able to hydrogenate ethylene, whereas NiH was not. In the USA, Irving Langmuir concluded just the opposite, namely, that chemisorbed surface species are chemically bound to surfaces and are unlike known molecules. These chemisorbed species were the active participants in catalysis. The equilibrium between gas-phase molecules and adsorbed chemisorbed species (yielding an adsorption isotherm) produced a monolayer by simple site-filling kinetics.

Encyclopedia of Interfacial Chemistry

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Publisher : Elsevier
ISBN 13 : 0128098945
Total Pages : 5276 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Encyclopedia of Interfacial Chemistry by :

Download or read book Encyclopedia of Interfacial Chemistry written by and published by Elsevier. This book was released on 2018-03-29 with total page 5276 pages. Available in PDF, EPUB and Kindle. Book excerpt: Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry, Seven Volume Set summarizes current, fundamental knowledge of interfacial chemistry, bringing readers the latest developments in the field. As the chemical and physical properties and processes at solid and liquid interfaces are the scientific basis of so many technologies which enhance our lives and create new opportunities, its important to highlight how these technologies enable the design and optimization of functional materials for heterogeneous and electro-catalysts in food production, pollution control, energy conversion and storage, medical applications requiring biocompatibility, drug delivery, and more. This book provides an interdisciplinary view that lies at the intersection of these fields. Presents fundamental knowledge of interfacial chemistry, surface science and electrochemistry and provides cutting-edge research from academics and practitioners across various fields and global regions

Metal Nanocluster Chemistry

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Publisher : Elsevier
ISBN 13 : 0323904750
Total Pages : 396 pages
Book Rating : 4.3/5 (239 download)

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Book Synopsis Metal Nanocluster Chemistry by : Manzhou Zhu

Download or read book Metal Nanocluster Chemistry written by Manzhou Zhu and published by Elsevier. This book was released on 2023-01-18 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atomically precise metal nanoclusters occupy the gap between discrete atoms and plasmonic nanomaterials, and they offer intriguing physical-chemical properties that can be rationalized in terms of their quantum size effects and discrete electronic states. The atomically precise nature of their structures lends them well to structure-property relationship elucidation, making them particularly useful for informing the rational design of nanoclusters with enhanced performance. Metal Nanocluster Chemistry: Ligand-Protected Metal Nanoclusters With Atomic Precision provides a concise introduction to the study of these useful nanoclusters. Beginning with an introduction to the fundamental concepts of, and prospects for, metal nanoclusters, the book goes on to highlight synthetic methods for controllable preparation. The subsequent chapters then highlight characterization, mechanism of size growth and structure evolution, and physical-chemical properties. Later chapters examine theoretical approaches for calculating and evaluating structures and properties. They also highlight the assembly of nanocluster building blocks and their practical applications. Drawing on the knowledge of its expert author, Metal Nanocluster Chemistry is a useful introductory guide to these exciting structures. Provides a concise introduction to atomically-precise metal nanoclusters, ranging from characterization and property investigation to applications Includes insight into both current trends and future potential, encouraging and supporting further development Holistically combines physical approaches with theoretical calculation methods

Catalysis with Supported Size-selected Pt Clusters

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Publisher : Springer Science & Business Media
ISBN 13 : 3319014994
Total Pages : 222 pages
Book Rating : 4.3/5 (19 download)

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Book Synopsis Catalysis with Supported Size-selected Pt Clusters by : Florian Frank Schweinberger

Download or read book Catalysis with Supported Size-selected Pt Clusters written by Florian Frank Schweinberger and published by Springer Science & Business Media. This book was released on 2013-11-01 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: In his thesis, Florian Schweinberger investigates the influence of the precise size of catalytically active species on reactivity. In order to do this he carries out studies both in UHV and under ambient conditions for supported, size-selected Platium clusters (8-68 atoms). Schweinberger probed the electronic structure, adsorption properties and reactivity of two olefins on surfaces and Pt clusters in the submonolayer range. With adsorbed trichloroethene (TCE) a possible cluster-adsorbate induced change in the electronic structure, and for ethene a low-temperature, size-dependent self-/hydrogenation was observed.In a collaborative approach, Schweinberger and colleagues investigated Pt clusters under ambient pressure conditions. They characterised the clusters at at the local and integral level and tested for temperature stability. Experiments in gas phase ?-reactors and in liquid, as part of a hybrid photocatalytic system, revealed size-dependent reactivity.Overall this thesis is not only of interest for those who want to perform similar experiments but also provides superb scientific insights for researchers in the field.

Atomically Precise Metal Clusters

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Publisher : John Wiley & Sons
ISBN 13 : 352784208X
Total Pages : 338 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Atomically Precise Metal Clusters by : Shuang-Quan Zang

Download or read book Atomically Precise Metal Clusters written by Shuang-Quan Zang and published by John Wiley & Sons. This book was released on 2024-04-30 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atomically Precise Metal Clusters Thorough discussion on how surface modification and self-assembly play roles in the atomically precise formation and property tailoring of molecular clusters Atomically Precise Metal Clusters: Surface Engineering and Hierarchical Assembly summarizes and discusses the surface modification, assembly, and property tailoring of a wide variety of nanoclusters, including the well-explored metal clusters, addressing the structure–property relationships throughout. The atomic-level control in synthesis, new types of structures, and physical/chemical properties of nanoclusters are illustrated in various chapters. The controlled modification and assembly of metal nanoclusters is expected to have a major impact on future nanoscience research and other areas, with distinctive metal cluster-based function materials with precise structures uncovering exciting opportunities in both fundamental research and practical applications. Written by a highly qualified academic with significant research experience in the field, Atomically Precise Metal Clusters includes information on: Ligand engineering and assembly of coinage metal nanoclusters such as gold, silver, and copper Recent advances in post-modification of polyoxometalates and small transition metal chalcogenide superatom clusters Synthesis and assembly of cadmium chalcogenide supertetrahedral clusters and modification and assembly of Fe-S clusters Indium phosphide magic-sized clusters, ligand-tailoring platinum and palladium clusters, and metal oxo clusters (MOCs) Enabling access to desired functions in metal clusters for catalysis, optics, biomedicine, and other fields through surface engineering and supramolecular assembly A timely and comprehensive book that summarizes the recent progress in the surface modification and self-assembly of metal nanoclusters, Atomically Precise Metal Clusters provides essential guidance for graduate students and advanced researchers in material science, chemistry, biomedicine, and other disciplines.

Model Systems in Catalysis

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Publisher : Springer
ISBN 13 : 9780387980416
Total Pages : 526 pages
Book Rating : 4.9/5 (84 download)

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Book Synopsis Model Systems in Catalysis by : Robert Rioux

Download or read book Model Systems in Catalysis written by Robert Rioux and published by Springer. This book was released on 2009-11-12 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is an excellent compilation of cutting-edge research in heterogeneous catalysis and related disciplines – surface science, organometallic catalysis, and enzymatic catalysis. In 23 chapters by noted experts, the volume demonstrates varied approaches using model systems and their successes in understanding aspects of heterogeneous catalysis, both metal- and metal oxide-based catalysis in extended single crystal and nanostructured catalytic materials. To truly appreciate the astounding advances of modern heterogeneous catalysis, let us first consider the subject from a historical perspective. Heterogeneous catalysis had its beginnings in England and France with the work of scientists such as Humphrey Davy (1778–1829), Michael Faraday (1791–1867), and Paul Sabatier (1854–1941). Sabatier postulated that surface compounds, si- lar to those familiar in bulk to chemists, were the intermediate species leading to catalytic products. Sabatier proposed, for example, that NiH moieties on a Ni sur- 2 face were able to hydrogenate ethylene, whereas NiH was not. In the USA, Irving Langmuir concluded just the opposite, namely, that chemisorbed surface species are chemically bound to surfaces and are unlike known molecules. These chemisorbed species were the active participants in catalysis. The equilibrium between gas-phase molecules and adsorbed chemisorbed species (yielding an adsorption isotherm) produced a monolayer by simple site-filling kinetics.

Supramolecular Gold Chemistry

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Publisher : MDPI
ISBN 13 : 3039285505
Total Pages : 182 pages
Book Rating : 4.0/5 (392 download)

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Book Synopsis Supramolecular Gold Chemistry by : Rodolphe Antoine

Download or read book Supramolecular Gold Chemistry written by Rodolphe Antoine and published by MDPI. This book was released on 2020-06-23 with total page 182 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is about supramolecular gold chemistry. This book provides a unique international forum aimed at covering a broad description of results involving the supramolecular chemistry of gold with a special focus on the gold–sulfur interface leading to hybrid materials ranging from gold–thiolate complexes to thiolate-protected gold nanoclusters and gold–thiolate supramolecular assemblies or nanoparticles. The role of thiolates on the structure and optical features of gold nanohybrid systems (ranging from plasmonic gold nanoparticles and fluorescent gold nanoclusters to self-assembled Au-containing thiolated coordination polymers) is highlighted in the 12 papers presented in this book.

Luminescent Metal Nanoclusters

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Publisher : Woodhead Publishing
ISBN 13 : 0323886418
Total Pages : 728 pages
Book Rating : 4.3/5 (238 download)

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Book Synopsis Luminescent Metal Nanoclusters by : Sabu Thomas

Download or read book Luminescent Metal Nanoclusters written by Sabu Thomas and published by Woodhead Publishing. This book was released on 2022-06-28 with total page 728 pages. Available in PDF, EPUB and Kindle. Book excerpt: Luminescent Metal Nanoclusters: Synthesis, Characterization, and Applications provides a comprehensive accounting of various protocols used for the synthesis of metal nanoclusters, their characterization techniques, toxicity evaluation and various applications and future prospects. The book provides detailed experimental routes, along with mechanisms on the formation of benign metallic clusters using biomaterials and a comprehensive review regarding the preparation, properties and prospective applications of these nano clusters in various fields, including therapeutic applications. Various methods to protect nanocluster materials to increase their stability are emphasized, including the incorporation of ligands (protein, small molecule, DNA, thiols). This book addresses a gap in the current literature by bringing together the preparation, characterization and applications of all the possible types of reported metal nanoclusters and their hybrids. It is suitable for materials scientists and engineers in academia and those working in research and development in industry. It may also be of interest to those working in the interdisciplinary nanotechnology community, such as physical chemists. Covers the most relevant material categories of luminescent nanoclusters such as metal nanoclusters, nano composites and alloy nanoclusters Provides a comprehensive overview of the various available methods used for the protection of nanoclusters Discusses the latest advances and future opportunities in addressing challenges in producing benign nanomaterials such as toxicity and stability

Atomically Precise Metal Nanoclusters

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Publisher : Springer Nature
ISBN 13 : 3031023897
Total Pages : 129 pages
Book Rating : 4.0/5 (31 download)

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Book Synopsis Atomically Precise Metal Nanoclusters by : Zhikun Wu

Download or read book Atomically Precise Metal Nanoclusters written by Zhikun Wu and published by Springer Nature. This book was released on 2022-06-01 with total page 129 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atomically precise metal nanocluster research has emerged as a new frontier. This book serves as an introduction to metal nanoclusters protected by ligands. The authors have summarized the synthesis principles and methods, the characterization methods and new physicochemical properties, and some potential applications. By pursuing atomic precision, such nanocluster materials provide unprecedented opportunities for establishing precise relationships between the atomic-level structures and the properties. The book should be accessible to senior undergraduate and graduate students, researchers in various fields (e.g., chemistry, physics, materials, biomedicine, and engineering), R&D scientists, and science policy makers.

Catalysis by Materials with Well-Defined Structures

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Publisher : Academic Press
ISBN 13 : 0128013400
Total Pages : 392 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Catalysis by Materials with Well-Defined Structures by : Zili Wu

Download or read book Catalysis by Materials with Well-Defined Structures written by Zili Wu and published by Academic Press. This book was released on 2015-03-26 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysis by Materials with Well-Defined Structures examines the latest developments in the use of model systems in fundamental catalytic science. A team of prominent experts provides authoritative, first-hand information, helping readers better understand heterogeneous catalysis by utilizing model catalysts based on uniformly nanostructured materials. The text addresses topics and issues related to material synthesis, characterization, catalytic reactions, surface chemistry, mechanism, and theoretical modeling, and features a comprehensive review of recent advances in catalytic studies on nanomaterials with well-defined structures, including nanoshaped metals and metal oxides, nanoclusters, and single sites in the areas of heterogeneous thermal catalysis, photocatalysis, and electrocatalysis. Users will find this book to be an invaluable, authoritative source of information for both the surface scientist and the catalysis practitioner Outlines the importance of nanomaterials and their potential as catalysts Provides detailed information on synthesis and characterization of nanomaterials with well-defined structures, relating surface activity to catalytic activity Details how to establish the structure-catalysis relationship and how to reveal the surface chemistry and surface structure of catalysts Offers examples on various in situ characterization instrumental techniques Includes in-depth theoretical modeling utilizing advanced Density Functional Theory (DFT) methods

Metal Nanoclusters in Catalysis and Materials Science: The Issue of Size Control

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Publisher : Elsevier
ISBN 13 : 0080555004
Total Pages : 471 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Metal Nanoclusters in Catalysis and Materials Science: The Issue of Size Control by : Benedetto Corain

Download or read book Metal Nanoclusters in Catalysis and Materials Science: The Issue of Size Control written by Benedetto Corain and published by Elsevier. This book was released on 2011-08-11 with total page 471 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Nanoclusters in Catalysis and Materials Science: The Issue of Size Control deals with the synthesis of metal nanoclusters along all known methodologies. Physical and chemical properties of metal nanoclusters relevant to their applications in chemical processing and materials science are covered thoroughly. Special attention is given to the role of metal nanoclusters size and shape in catalytic processes and catalytic applications relevant to industrial chemical processing.An excellent text for expanding the knowledge on the chemistry and physics of metal nanoclusters. Divided in two parts; Part I deals with general aspects of the matter and Part II has to be considered a useful handbook dealing with the production of metal nanoclusters, especially from their size-control point of view. * Divided into two parts for ease of reference: general and operational * Separation of synthetic aspects, physical properties and applications* Specific attention is given to the task of metal nanoclusters size-control

Photocatalysis

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Publisher : Royal Society of Chemistry
ISBN 13 : 1782627103
Total Pages : 394 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Photocatalysis by : Dionysios D Dionysiou

Download or read book Photocatalysis written by Dionysios D Dionysiou and published by Royal Society of Chemistry. This book was released on 2016-03-30 with total page 394 pages. Available in PDF, EPUB and Kindle. Book excerpt: From environmental remediation to alternative fuels, this book explores the numerous important applications of photocatalysis. The book covers topics such as the photocatalytic processes in the treatment of water and air; the fundamentals of solar photocatalysis; the challenges involved in developing self-cleaning photocatalytic materials; photocatalytic hydrogen generation; photocatalysts in the synthesis of chemicals; and photocatalysis in food packaging and biomedical and medical applications. The book also critically discusses concepts for the future of photocatalysis, providing a fascinating insight for researchers. Together with Photocatalysis: Fundamentals and Perspectives, these volumes provide a complete overview to photocatalysis.

Lignin Valorization

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Publisher : Royal Society of Chemistry
ISBN 13 : 1782625542
Total Pages : 528 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Lignin Valorization by : Gregg T. Beckham

Download or read book Lignin Valorization written by Gregg T. Beckham and published by Royal Society of Chemistry. This book was released on 2018-03-29 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive, interdisciplinary picture of how lignocellulosic biorefineries could potentially employ lignin valorization technologies.

Annual Review

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Publisher :
ISBN 13 :
Total Pages : 342 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Annual Review by : Bunshi Kagaku Kenkyūjo

Download or read book Annual Review written by Bunshi Kagaku Kenkyūjo and published by . This book was released on 2003 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Concepts of Semiconductor Photocatalysis

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Publisher : BoD – Books on Demand
ISBN 13 : 1789850878
Total Pages : 152 pages
Book Rating : 4.7/5 (898 download)

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Book Synopsis Concepts of Semiconductor Photocatalysis by : Mohammed Muzibur Rahman

Download or read book Concepts of Semiconductor Photocatalysis written by Mohammed Muzibur Rahman and published by BoD – Books on Demand. This book was released on 2019-12-18 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book "Concepts of Semiconductor Photocatalysis" contains recent research on the preparation, characterization, and potential applications of the semiconductor photocatalyst. This research is promising and has received a lot of interest in the last few decades. The book covers advanced topics on the optical, physical, structural, and electro-catalysis and photo-catalysis applications. Development of new and noble efficient technology is pointing researchers toward the safe, facile, non-toxic, eco-friendly route of synthesis-to-applications, which can be used for manufacture at a large scale. This book presents an overview of the current photocatalyst fundamental theory, substantial applications, and use of the research worldwide. It is an important book for research organizations, government research-centers, academic libraries, and R

C-C Bond Activation

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Publisher : Springer
ISBN 13 : 364255055X
Total Pages : 262 pages
Book Rating : 4.6/5 (425 download)

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Book Synopsis C-C Bond Activation by : Guangbin Dong

Download or read book C-C Bond Activation written by Guangbin Dong and published by Springer. This book was released on 2014-09-18 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students