Chemical Bonds Outside Metal Surfaces

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Publisher : Springer Science & Business Media
ISBN 13 : 1461321174
Total Pages : 292 pages
Book Rating : 4.4/5 (613 download)

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Book Synopsis Chemical Bonds Outside Metal Surfaces by : Norman H. March

Download or read book Chemical Bonds Outside Metal Surfaces written by Norman H. March and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: The problem of molecules interacting with metal surfaces has for a very long time been recognized to be of considerable technological as well as fundamental importance. Thus in the former category, a substantial number of important synthetic reactions for industrial purposes make use of metal surfaces as catalysts. Or again, problems of corrosion of metals are of great practical importance, such as in nuclear-reactor technology [see, for instance, my earlier articles, in: Physics Bulletin, Volume 25, p. 582, Institute of Physics, UK (1974); and in: Physics and Contemporqry Needs (Riazuddin, ed. ), Vol. 1, p. 53, Plenum Press, New York (1977)]. It is therefore of significance to strive to gain a more fundamental understand ing of the atomic, and ultimately the electronic, processes that occur when a molecule is brought into the proximity of a metal surface. The present volume focuses mainly on the theory and concepts involved; however, it is intended for readers in chemistry, physics, and materials science who are not specialists in theory but nevertheless wish to learn more about this truly interdisciplinary area of theoretical science. The aim of the book is to present the way in which valence theory can be synthesized with the understanding of metals that has been gained over the last half century or so. While advanced theory has at times been necessary, is largely presented in an extensive set of Appendixes.

Model Chemistry on Metal Surfaces

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Publisher :
ISBN 13 :
Total Pages : 462 pages
Book Rating : 4.:/5 (167 download)

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Book Synopsis Model Chemistry on Metal Surfaces by : Yun Chi

Download or read book Model Chemistry on Metal Surfaces written by Yun Chi and published by . This book was released on 1986 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Electronic Structure and Reactivity of Metal Surfaces

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Publisher : Springer Science & Business Media
ISBN 13 : 1468427962
Total Pages : 636 pages
Book Rating : 4.4/5 (684 download)

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Book Synopsis Electronic Structure and Reactivity of Metal Surfaces by : E. Derouane

Download or read book Electronic Structure and Reactivity of Metal Surfaces written by E. Derouane and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: Imagine that a young physicist would approach a granting agen cy and propose to contribute to heterogeneous catalysis by studying the heat conductivity of gases in contact with a hot filament. How would he be received now? How would he have been treated sixty years ago ? Yet, more than sixty years ago, Irving Langmuir, through his study of heat transfer from a tungsten filament, uncovered most of the fundamental ideas which are used to-day by the scientific com munity in pure and applied heterogeneous catalysis. Through his work with what were for the first time "clean" metal surfaces, Langmuir formulated during a period of a little over ten years un til the early thirties, the concepts of chemisorption, monolayer, adsorption sites, adsorption isotherm, sticking probability, cata lytic mechanisms by way of the interaction between chemisorbed spe cies, behavior of non-uniform surfaces and repulsion between adsor bed dipoles. It is fair to say that many of these ideas constituting the first revolution in surface chemistry have since been refined through thousands of investigations. Countless papers have been pu blished on the subject of the Langmuir adsorption isotherm, the Langmuir catalytic kinetics and the Langmuir site-exclusion adsorp tion kinetics. The refinements have been significant. ThE original concepts in their primitive or amended form are used everyday by catalytic chemists and chemical engineers allover the world in their treatment of experimental data, design of reactors or inven tion of new processes.

Chemical Bonding at Surfaces and Interfaces

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Publisher : Elsevier
ISBN 13 : 0080551912
Total Pages : 533 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Chemical Bonding at Surfaces and Interfaces by : Anders Nilsson

Download or read book Chemical Bonding at Surfaces and Interfaces written by Anders Nilsson and published by Elsevier. This book was released on 2011-08-11 with total page 533 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular surface science has made enormous progress in the past 30 years. The development can be characterized by a revolution in fundamental knowledge obtained from simple model systems and by an explosion in the number of experimental techniques. The last 10 years has seen an equally rapid development of quantum mechanical modeling of surface processes using Density Functional Theory (DFT). Chemical Bonding at Surfaces and Interfaces focuses on phenomena and concepts rather than on experimental or theoretical techniques. The aim is to provide the common basis for describing the interaction of atoms and molecules with surfaces and this to be used very broadly in science and technology. The book begins with an overview of structural information on surface adsorbates and discusses the structure of a number of important chemisorption systems. Chapter 2 describes in detail the chemical bond between atoms or molecules and a metal surface in the observed surface structures. A detailed description of experimental information on the dynamics of bond-formation and bond-breaking at surfaces make up Chapter 3. Followed by an in-depth analysis of aspects of heterogeneous catalysis based on the d-band model. In Chapter 5 adsorption and chemistry on the enormously important Si and Ge semiconductor surfaces are covered. In the remaining two Chapters the book moves on from solid-gas interfaces and looks at solid-liquid interface processes. In the final chapter an overview is given of the environmentally important chemical processes occurring on mineral and oxide surfaces in contact with water and electrolytes. Gives examples of how modern theoretical DFT techniques can be used to design heterogeneous catalysts This book suits the rapid introduction of methods and concepts from surface science into a broad range of scientific disciplines where the interaction between a solid and the surrounding gas or liquid phase is an essential component Shows how insight into chemical bonding at surfaces can be applied to a range of scientific problems in heterogeneous catalysis, electrochemistry, environmental science and semiconductor processing Provides both the fundamental perspective and an overview of chemical bonding in terms of structure, electronic structure and dynamics of bond rearrangements at surfaces

Corrosion and Surface Chemistry of Metals

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Publisher : EPFL Press
ISBN 13 : 9780849382338
Total Pages : 640 pages
Book Rating : 4.3/5 (823 download)

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Book Synopsis Corrosion and Surface Chemistry of Metals by : Dieter Landolt

Download or read book Corrosion and Surface Chemistry of Metals written by Dieter Landolt and published by EPFL Press. This book was released on 2007-05-02 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: Textbook; grad.

Metal Clusters at Surfaces

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Publisher : Springer Science & Business Media
ISBN 13 : 9783540665625
Total Pages : 332 pages
Book Rating : 4.6/5 (656 download)

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Book Synopsis Metal Clusters at Surfaces by : Karl-Heinz Meiwes-Broer

Download or read book Metal Clusters at Surfaces written by Karl-Heinz Meiwes-Broer and published by Springer Science & Business Media. This book was released on 2000-04-05 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: Numerous experiments and calculations have shown that isolated metal clusters possess many interesting features, quite different from those known from surface and solid- state physics or from atomic and molecular physics. The technological exploitation of these new properties, e.g. in miniature electronic or mechanical components, requires the cluster to be brought into an environment such as an encapsulating matrix or a surface. Due to the interaction with the contact medium, the properties of the clusters may change or even disappear. Thus the physics of cluster-on-surface systems -- the main subject of this book -- is of fundamental importance. The book addresses a wide audience, from the newcomer to the expert. Starting from fundamental concepts of adsorbate-surface interactions, the modification of electronic properties through electron confinement, and concepts of cluster production, it elucidates the distinct properties of the new metallic nanostructures.

Metal Surfaces

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Publisher : MDPI
ISBN 13 : 3036510125
Total Pages : 146 pages
Book Rating : 4.0/5 (365 download)

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Book Synopsis Metal Surfaces by : Roberto Montanari

Download or read book Metal Surfaces written by Roberto Montanari and published by MDPI. This book was released on 2021-08-31 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt: This collection covers the physical and chemical phenomena of metal surfaces, including surface modifications and treatments. It is targeted at researchers working in materials science and also at newcomers to the research field of metal surfaces and surface analysis.

The Surface Chemistry of Metals and Semiconductors

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Publisher :
ISBN 13 :
Total Pages : 550 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis The Surface Chemistry of Metals and Semiconductors by : Electrochemical Society. Corrosion Division

Download or read book The Surface Chemistry of Metals and Semiconductors written by Electrochemical Society. Corrosion Division and published by . This book was released on 1960 with total page 550 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces

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Publisher : Springer Science & Business Media
ISBN 13 : 9401128227
Total Pages : 428 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces by : Dennis R. Salahub

Download or read book Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces written by Dennis R. Salahub and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-ligand interactions are currently being studied in different fields, from a variety of points of view, and recent progress has been substantial. Whole new classes of compounds and reactions have been found; an arsenal of physical methods has been developed; mechanistic detail can be ascertained to an increasingly minute degree; and the theory is being developed to handle systems of ever-growing complexity. As usual, such multidisciplinarity leads to great opportunities, coupled with great problems of communication between specialists. It is in its promotion of interactions across these fields that Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces makes its timely contribution: the tools, both theoretical and experimental, are highly developed, and fundamental questions remain unanswered. The most fundamental of these concerns the nature of the microscopic interactions between metal atoms (clusters, surfaces) and ligands (atoms, molecules, absorbates, reagents, products) and the changes in these interactions during physical and chemical transformation. In Metal-Ligand Interactions, leading experts discuss the following, vital aspects: ab initio theory, semi-empirical theory, density functional theory, complexes and clusters, surfaces, and catalysis.

Surface Reactions

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Publisher : Springer Science & Business Media
ISBN 13 : 3642787460
Total Pages : 291 pages
Book Rating : 4.6/5 (427 download)

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Book Synopsis Surface Reactions by : R.J. Madix

Download or read book Surface Reactions written by R.J. Madix and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: A treatment of the important aspects of physical chemistry on metal surfaces, including selective oxidation, desulfurization, cyclization, metal-organic chemical vapor deposition, alkane activation and hydrogen dissociation dynamics. Case studies focus on on the chemistry of selected systems, rather than the techniques, to convey the excitement of recent developments.

Characterization of Metal and Polymer Surfaces V1

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Publisher : Elsevier
ISBN 13 : 0323146910
Total Pages : 533 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Characterization of Metal and Polymer Surfaces V1 by : Lieng-Huang Lee

Download or read book Characterization of Metal and Polymer Surfaces V1 written by Lieng-Huang Lee and published by Elsevier. This book was released on 2012-12-02 with total page 533 pages. Available in PDF, EPUB and Kindle. Book excerpt: Characterization of Metal and Polymer Surfaces, Volume 1: Metal Surfaces presents the proceedings of the Symposium on Advances in Characterization of Metal and Polymer Surfaces, held in New York, on April 5–8, 1976. This book provides information pertinent to surface science and discusses the applications of surface analyses to polymer technology. Organized into five parts encompassing 19 chapters, this compilation of papers starts with an overview of the important innovations of surface analyses and discusses the possible applications of each method to polymer technology. This text then explores atom-probe field ion microscopy, which is the most sensitive micro-analytical tool that combines the single atom resolution of a field ion microscope with mass spectrometric single ion identification. Other chapters discuss the application of Mössbauer spectroscopy as a technique for studying corrosion phenomena. The final chapter deals with the capabilities and limitations of the method of inelastic electron tunnelling. This book is a valuable resource for analytical and polymer chemists.

Modeling of Complex Interfaces: From Surface Chemistry to Nano Chemistry

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Publisher : MDPI
ISBN 13 : 3039361945
Total Pages : 166 pages
Book Rating : 4.0/5 (393 download)

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Book Synopsis Modeling of Complex Interfaces: From Surface Chemistry to Nano Chemistry by : Frederik Tielens

Download or read book Modeling of Complex Interfaces: From Surface Chemistry to Nano Chemistry written by Frederik Tielens and published by MDPI. This book was released on 2020-12-02 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introducing the interdisciplinary field of interface chemistry modelling across a wide range of academic disciplines and industry sectors. Ten original research articles are presented that bridge knowledge acquisition and practical work, providing a starting point for the research and development of applications. The book describes the characterization of interfaces at the nanoscale, using a wide range of key nanomaterials, such as graphene, TiO2, zeolites, semimetals, and organic polymers; and the study of their different physical chemical properties, such as catalysis, adsorption, friction, diffusion, and the characterization of nanocomposites and heterojunctions, with many different industrial applications. The resulting collection of papers is equally relevant for advanced students (senior and graduate) and for engineers and scientists from a variety of different academic backgrounds working in the multidisciplinary field of nanotechnology.

Reactions of Organic Molecules on Metal Surfaces Studied by STM

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Publisher : Cuvillier Verlag
ISBN 13 : 3867271399
Total Pages : 23 pages
Book Rating : 4.8/5 (672 download)

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Book Synopsis Reactions of Organic Molecules on Metal Surfaces Studied by STM by : Markus Wahl

Download or read book Reactions of Organic Molecules on Metal Surfaces Studied by STM written by Markus Wahl and published by Cuvillier Verlag. This book was released on 2007 with total page 23 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Laser Spectroscopy and Photochemistry on Metal Surfaces

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Publisher : World Scientific
ISBN 13 : 9812831894
Total Pages : 645 pages
Book Rating : 4.8/5 (128 download)

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Book Synopsis Laser Spectroscopy and Photochemistry on Metal Surfaces by : Hai-Lung Dai

Download or read book Laser Spectroscopy and Photochemistry on Metal Surfaces written by Hai-Lung Dai and published by World Scientific. This book was released on 1995 with total page 645 pages. Available in PDF, EPUB and Kindle. Book excerpt: Using lasers to induce and probe surface processes has the advantages of quantum state specificity, species selectivity, surface sensitivity, fast time-resolution, high frequency resolution, and accessibility to full pressure ranges. These advantages make it highly desirable to use light to induce, control, or monitor surface chemical and physical processes. Recent applications of laser based techniques in studying surface processes have stimulated new developments and enabled the understanding of fundamental problems in energy transfer and reactions. This volume will include discussions on spectroscopic techniques, energy transfer, desorption dynamics, and photochemistry.

Physics and Chemistry of Metal Cluster Compounds

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Publisher : Springer Science & Business Media
ISBN 13 : 9401512949
Total Pages : 326 pages
Book Rating : 4.4/5 (15 download)

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Book Synopsis Physics and Chemistry of Metal Cluster Compounds by : L.J. de Jongh

Download or read book Physics and Chemistry of Metal Cluster Compounds written by L.J. de Jongh and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt: On Friday, February 20, 1980, I had the pleasure to be present at the inaugural lecture of my colleague Jan Reedijk, who had just been named at the Chair of Inorganic Chemistry of Leiden University. According to tradition, the ceremony took place in the impressive Hall of the old University Academy Building. In the course of his lecture, Jan mentioned a number of recent developments in chemistry which had struck him as particularly important or interesting. Among those was the synthesis of large metal cluster compounds, and, to my luck, he showed a slide ofthe molecular structure of [PtI9(C)b]4-. (To my luck, since at traditional Leiden University it is quite unusual to show slides at such ceremonies.) This constituted my first acquaintance with this exciting new class of materials. I became immediately fascinated by this molecule, partly because of the esthetic beauty of its fivefold symmetry, partly because as a physicist it struck me that it could be visualized as an "embryonically small" metal particle, embedded in a shell of CO ligands.

Laser Spectroscopy and Photochemistry on Metal Surfaces

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Publisher : World Scientific
ISBN 13 : 9789810229962
Total Pages : 650 pages
Book Rating : 4.2/5 (299 download)

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Book Synopsis Laser Spectroscopy and Photochemistry on Metal Surfaces by : Hai-Lung Dai

Download or read book Laser Spectroscopy and Photochemistry on Metal Surfaces written by Hai-Lung Dai and published by World Scientific. This book was released on 1995 with total page 650 pages. Available in PDF, EPUB and Kindle. Book excerpt: Using lasers to induce and probe surface processes has the advantages of quantum state specificity, species selectivity, surface sensitivity, fast time-resolution, high frequency resolution, and accessibility to full pressure ranges. These advantages make it highly desirable to use light to induce, control, or monitor surface chemical and physical processes. Recent applications of laser based techniques in studying surface processes have stimulated new developments and enabled the understanding of fundamental problems in energy transfer and reactions. This volume will include discussions on spectroscopic techniques, energy transfer, desorption dynamics, and photochemistry.

Theory of Metal Surface Tension

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Publisher :
ISBN 13 :
Total Pages : 24 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Theory of Metal Surface Tension by : S. W. Mayer

Download or read book Theory of Metal Surface Tension written by S. W. Mayer and published by . This book was released on 1961 with total page 24 pages. Available in PDF, EPUB and Kindle. Book excerpt: