Mineral-Surfactant Interactions for Minimum Reagents Precipitation and Adsorption for Improved Oil Recovery

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Total Pages : pages
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Book Synopsis Mineral-Surfactant Interactions for Minimum Reagents Precipitation and Adsorption for Improved Oil Recovery by :

Download or read book Mineral-Surfactant Interactions for Minimum Reagents Precipitation and Adsorption for Improved Oil Recovery written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical EOR can be an effective method for increasing oil recovery and reducing the amount of produced water; however, reservoir fluids are chemically complex and may react adversely to the polymers and surfactants injected into the reservoir. While a major goal is to alter rock wettability and interfacial tension between oil and water, rock-fluid and fluid-fluid interactions must be understood and controlled to minimize reagent loss, maximize recovery and mitigate costly failures. The overall objective of this project was to elucidate the mechanisms of interactions between polymers/surfactants and the mineral surfaces responsible for determining the chemical loss due to adsorption and precipitation in EOR processes. The role of dissolved inorganic species that are dependent on the mineralogy is investigated with respect to their effects on adsorption. Adsorption, wettability and interfacial tension are studied with the aim to control chemical losses, the ultimate goal being to devise schemes to develop guidelines for surfactant and polymer selection in EOR. The adsorption behavior of mixed polymer/surfactant and surfactant/surfactant systems on typical reservoir minerals (quartz, alumina, calcite, dolomite, kaolinite, gypsum, pyrite, etc.) was correlated to their molecular structures, intermolecular interactions and the solution conditions such as pH and/or salinity. Predictive models as well as general guidelines for the use of polymer/surfactant surfactant/surfactant system in EOR have been developed The following tasks have been completed under the scope of the project: (1) Mineral characterization, in terms of SEM, BET, size, surface charge, and point zero charge. (2) Study of the interactions among typical reservoir minerals (quartz, alumina, calcite, dolomite, kaolinite, gypsum, pyrite, etc.) and surfactants and/or polymers in terms of adsorption properties that include both macroscopic (adsorption density, wettability) and microscopic (orientation/conformation of the adsorbed layers), as well as precipitation/abstraction characteristics. (3) Investigation of the role of dissolved species, especially multivalent ions, on interactions between reservoir minerals and surfactants and/or polymers leading to surfactant precipitation or activated adsorption. (4) Solution behavior tests--surface tension, interaction, ultra filtration, and other tests. (5) Surfactant-mineral interactions relative to adsorption, wettability, and electrophoresis. (6) Work on the effects of multivalent ions, pH, temperature, salinity, and mixing ratio on the adsorption. Developments of adsorption models to explain interactions between surfactants/polymers/minerals. (7) General guidelines for the use of certain surfactants, polymers and their mixtures in micelle flooding processes.

MINERAL-SURFACTANT INTERACTIONS FOR MINIMUM REAGENTS PRECIPITATION AND ADSORPTION FOR IMPROVED OIL RECOVERY.

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ISBN 13 :
Total Pages : pages
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Book Synopsis MINERAL-SURFACTANT INTERACTIONS FOR MINIMUM REAGENTS PRECIPITATION AND ADSORPTION FOR IMPROVED OIL RECOVERY. by : P. Somasundaran

Download or read book MINERAL-SURFACTANT INTERACTIONS FOR MINIMUM REAGENTS PRECIPITATION AND ADSORPTION FOR IMPROVED OIL RECOVERY. written by P. Somasundaran and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: During this reporting period, further fundamental studies were conducted to understand the mechanism of the interactions between surfactants and minerals with the aim of minimizing chemical loss by adsorption. The effects of pH and mixing ratio on the chemical loss by adsorption were investigated. Some preliminary modeling work has been done towards the aim of developing a guide book to design optimal polymer/surfactant formula based on the understanding of adsorption and orientation of surfactants and their aggregates at solid/liquid interfaces. The study of adsorption of mixed system of n-dodecyl-{beta}-D-maltoside (DM) and dodecyl sulfonate (C{sub 12}SO{sub 3}Na) was continued during this period. Based on the adsorption results, the effects of pH and mixing ratio on reagent loss were quantitatively evaluated. Adsorption of dodecyl maltoside showed a maximum at certain mixing ratio at low pH (3{approx}5), while adsorption of dodecyl maltoside steadily decreased with the increase in C{sub 12}SO{sub 3}Na. Analytical ultracentrifuge technique was employed to study the micellization of DM/C{sub 12}SO{sub 3}Na mixtures. Compositional changes of the aggregates were observed the mixing ratio of the components. Surfactant mixture micellization affects the conformation and orientation of adsorption layer at mineral/water interface and thus the wettability and as a result, the oil release efficiency of the chemical flooding processes. A preliminary term, Reagent Loss Index (RLI), has been proposed to represent the adsorption of all the surfactants in a standardized framework for the development of the models. Previously reported adsorption data have been analyzed using the theoretical framework for the preparation of a guidebook to help optimization of chemical combinations and selection of reagent scheme for enhanced oil recovery.

Mineral-Surfactant Interaction for Minimum Reagents Precipitation and Adsorption for Improved Oil Recovery

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ISBN 13 :
Total Pages : pages
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Book Synopsis Mineral-Surfactant Interaction for Minimum Reagents Precipitation and Adsorption for Improved Oil Recovery by : P. Somasundaran

Download or read book Mineral-Surfactant Interaction for Minimum Reagents Precipitation and Adsorption for Improved Oil Recovery written by P. Somasundaran and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In this project, fundamental studies were conducted to understand the mechanisms of the interactions between polymers/surfactants and minerals with the aim of minimizing chemical loss by adsorption. The effects of structures of the surface active molecules on critical solid/liquid interfacial properties such as adsorption, wettability and surface tension in mineral/surfactant systems were investigated. The final aim is to build a guideline to design optimal polymer/surfactant formula based on the understanding of adsorption and orientation of surfactants and their aggregates at solid/liquid interfaces. During this period, the wettability of alumina was tested using two-phase extraction at different pHs. The results were explained using the adsorption data obtain previously. It was found that the wettability is determined by both the nano-structure of the hemimicelles and the surface coverage. It was found that pH plays a critical role in controlling the total adsorption and the mineral wettability. At pH 4, the alumina surface remains hydrophilic in the surfactant concentration range tested because of the low surface coverage, even though hemimicelles are formed. Adsorption of sodium dodecyl sulfate (SDS) on alumina and silica, the component minerals reservoir rocks, was conducted at different pHs. The adsorption of SDS on silica is negligible, while the adsorption on alumina is high due to the different charge of the latter. Tests of adsorption of a modified polymer S-19703-35HT on alumina were also conducted at different pHs. Adsorption density decreases with pH. The results suggest that alkaline pH range is more cost-effective for a SDS/polymer system because of the low adsorption density. A new term, reagent loss index (RLI), was used to analyze the adsorption data for different surfactants and minerals. It was shown that the chemical loss is very high in the case of SDS on gypsum and limestone, while it is low in the case of silica. The mixed Dodecyl maltoside (DM)/C12SO3Na system was also evaluated using this standard term. It is fairly easy to find the optimal conditions, including mixing ratio and pH, for minimum chemical loss using polymer/surfactant mixtures.

MINERAL-SURFACTANT INTERACTIONS FOR MINIMUM REAGENTS PRECIPITATION AND ADSOPTION FOR IMPROVED OIL RECOVERY.

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ISBN 13 :
Total Pages : pages
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Book Synopsis MINERAL-SURFACTANT INTERACTIONS FOR MINIMUM REAGENTS PRECIPITATION AND ADSOPTION FOR IMPROVED OIL RECOVERY. by :

Download or read book MINERAL-SURFACTANT INTERACTIONS FOR MINIMUM REAGENTS PRECIPITATION AND ADSOPTION FOR IMPROVED OIL RECOVERY. written by and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of the project is to delineate the role of mineralogy of reservoir rocks in determining interactions between reservoir minerals and externally added reagents (surfactants/polymers) and its effect on the solid-liquid and liquid-liquid interfacial properties such as adsorption, wettability and interfacial tension in systems relevant to reservoir conditions. Previous studies have suggested that significant surfactant loss by precipitation or adsorption on reservoir minerals can cause chemical schemes to be less than satisfactory for enhanced oil recovery. Both macroscopic adsorption, wettability and microscopic orientation and conformation studies for various surfactant/polymer mixtures/reservoir rocks systems will be conducted to explore the cause of chemical loss by means of precipitation or adsorption, and the effect of rock mineralogy on the chemical loss. During this reporting period, the minerals used have been characterized, for particle size distribution and surface area. Also a series of novel cationic Gemini surfactants: butane-1,4-bis(quaternary ammonium chloride), has been synthesized. The solution and adsorption behavior of individual surfactants, the highly surface-active Gemini surfactant C[sub 12]-C[sub 4]-C[sub 12], the sugar-based nonionic surfactant n-dodecyl-[beta]-D-maltoside (DM) and their mixture has been studied. DM alone shows low adsorption on silica because of the lack of any electrostatic attraction between the surfactant and the silica particle. On the other hand, the cationic Gemini adsorbs markedly on the oppositely charged silica surface. Marked synergism has been observed in the case of DM/C[sub 12]-C[sub 4]-C[sub 12] mixture adsorption on silica. Adsorption of DM from the mixtures increases dramatically in both the rising part and the plateau regions. Adsorption of the cationic Gemini C[sub 12]-C[sub 4]-C[sub 12] from the mixture on the other hand increases in the rising part, but decreases in the plateau regions due to the competition for adsorption sites from DM. Desired mineral surface property, that may be obtained using the proper mixtures of DM and Gemini under optimal conditions, can help to control the mineral wettability to facilitate oil liberation in improved oil recovery processes.

Phenomena in Mixed Surfactant Systems

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ISBN 13 :
Total Pages : 370 pages
Book Rating : 4.:/5 (44 download)

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Book Synopsis Phenomena in Mixed Surfactant Systems by : John F. Scamehorn

Download or read book Phenomena in Mixed Surfactant Systems written by John F. Scamehorn and published by . This book was released on 1986 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Chemical Enhanced Oil Recovery

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Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110640430
Total Pages : 260 pages
Book Rating : 4.1/5 (16 download)

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Book Synopsis Chemical Enhanced Oil Recovery by : Patrizio Raffa

Download or read book Chemical Enhanced Oil Recovery written by Patrizio Raffa and published by Walter de Gruyter GmbH & Co KG. This book was released on 2019-07-22 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book aims at presenting, describing, and summarizing the latest advances in polymer flooding regarding the chemical synthesis of the EOR agents and the numerical simulation of compositional models in porous media, including a description of the possible applications of nanotechnology acting as a booster of traditional chemical EOR processes. A large part of the world economy depends nowadays on non-renewable energy sources, most of them of fossil origin. Though the search for and the development of newer, greener, and more sustainable sources have been going on for the last decades, humanity is still fossil-fuel dependent. Primary and secondary oil recovery techniques merely produce up to a half of the Original Oil In Place. Enhanced Oil Recovery (EOR) processes are aimed at further increasing this value. Among these, chemical EOR techniques (including polymer flooding) present a great potential in low- and medium-viscosity oilfields. • Describes recent advances in chemical enhanced oil recovery. • Contains detailed description of polymer flooding and nanotechnology as promising boosting tools for EOR. • Includes both experimental and theoretical studies. About the Authors Patrizio Raffa is Assistant Professor at the University of Groningen. He focuses on design and synthesis of new polymeric materials optimized for industrial applications such as EOR, coatings and smart materials. He (co)authored about 40 articles in peer reviewed journals. Pablo Druetta works as lecturer at the University of Groningen (RUG) and as engineering consultant. He received his Ph.D. from RUG in 2018 and has been teaching at a graduate level for 15 years. His research focus lies on computational fluid dynamics (CFD).

Handbook of Flotation Reagents: Chemistry, Theory and Practice

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Publisher : Elsevier
ISBN 13 : 0080471374
Total Pages : 459 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Handbook of Flotation Reagents: Chemistry, Theory and Practice by : Srdjan M. Bulatovic

Download or read book Handbook of Flotation Reagents: Chemistry, Theory and Practice written by Srdjan M. Bulatovic and published by Elsevier. This book was released on 2007-02-19 with total page 459 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Flotation Reagents: Chemistry, Theory and Practice is a condensed form of the fundamental knowledge of chemical reagents commonly used in flotation and is addressed to the researchers and plant metallurgists who employ these reagents. Consisting of three distinct parts: 1) provides detailed description of the chemistry used in mineral processing industry; 2) describes theoretical aspects of the action of flotation reagents3) provides information on the use of reagents in over 100 operating plants treating Cu, Cu/Zn, Cu/Pb, Zn, Pb/Zn/Ag, Cu/Ni and Ni ores.* Looks at the theoretical aspects of flotation reagents* Examines the practical aspects of using chemical reagents in operating plants* Provides guidelines for researchers and engineers involved in process design and development

Microemulsion Systems

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Publisher : CRC Press
ISBN 13 : 9780824774394
Total Pages : 464 pages
Book Rating : 4.7/5 (743 download)

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Book Synopsis Microemulsion Systems by : Henri L. Rosano

Download or read book Microemulsion Systems written by Henri L. Rosano and published by CRC Press. This book was released on 1987-03-27 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Formation Damage during Improved Oil Recovery

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Publisher : Gulf Professional Publishing
ISBN 13 : 9780128137826
Total Pages : 0 pages
Book Rating : 4.1/5 (378 download)

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Book Synopsis Formation Damage during Improved Oil Recovery by : Bin Yuan

Download or read book Formation Damage during Improved Oil Recovery written by Bin Yuan and published by Gulf Professional Publishing. This book was released on 2018-06-02 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Formation Damage during Improved Oil Recovery: Fundamentals and Applications bridges the gap between theoretical knowledge and field practice by presenting information on formation damage issues that arise during enhanced oil recovery. Multi-contributed technical chapters include sections on modeling and simulation, lab experiments, field case studies, and newly proposed technologies and methods that are related to formation damage during secondary and tertiary recovery processes in both conventional and unconventional reservoirs. Focusing on both the fundamental theories related to EOR and formation damage, this reference helps engineers formulate integrated and systematic designs for applying EOR processes while also considering formation damage issues.

Improved Oil Recovery by Surfactant and Polymer Flooding

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Publisher : Elsevier
ISBN 13 : 0323141579
Total Pages : 589 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Improved Oil Recovery by Surfactant and Polymer Flooding by : D.O. Shah

Download or read book Improved Oil Recovery by Surfactant and Polymer Flooding written by D.O. Shah and published by Elsevier. This book was released on 2012-12-02 with total page 589 pages. Available in PDF, EPUB and Kindle. Book excerpt: Improved Oil Recovery by Surfactant and Polymer Flooding contains papers presented at the 1976 AIChE Symposium on Improved Oil Recovery by Surfactant and Polymer Flooding held in Kansas City. Organized into 18 chapters, the book includes papers that introduce petroleum reservoirs and discuss interfacial tension; molecular forces; molecular aspects of ultralow interfacial tension; the structure, formation, and phase inversion of microemulsions; and thermodynamics of micellization and related phenomena. Papers on adsorption phenomena at solid/liquid interfaces and reservoir rocks, as well as on flow through porous media studies on polymer solutions, microemulsions, and soluble oils are also provided. Significant topics on molecular, microscopic, and macroscopic aspects of oil displacement in porous media by surfactant and polymer solutions and related phenomena are also discussed. The literature cited in this book forms a comprehensive list of references in relation to improved oil recovery by surfactant and polymer flooding. This book will be useful to experts and non-experts in this field of research.

Froth Flotation

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Publisher : SME
ISBN 13 : 9780873352529
Total Pages : 910 pages
Book Rating : 4.3/5 (525 download)

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Book Synopsis Froth Flotation by : Maurice C. Fuerstenau

Download or read book Froth Flotation written by Maurice C. Fuerstenau and published by SME. This book was released on 2007 with total page 910 pages. Available in PDF, EPUB and Kindle. Book excerpt: &Quot;Froth Flotation: A Century of Innovation comprehensively describes state-of-the-art research and practice in mineral froth flotation a century after its introduction. Recognized experts from around the world provide in-depth coverage on many facets of flotation, including the historical aspects; fundamentals; chemistry; flotation cells, modeling, and simulation; and flotation plant practice. This commemorative volume is an invaluable reference for industry professionals, researchers, and graduate students."--BOOK JACKET.

Enhanced Oil Recovery Field Case Studies

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Publisher : Gulf Professional Publishing
ISBN 13 : 0123865468
Total Pages : 710 pages
Book Rating : 4.1/5 (238 download)

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Book Synopsis Enhanced Oil Recovery Field Case Studies by : James J.Sheng

Download or read book Enhanced Oil Recovery Field Case Studies written by James J.Sheng and published by Gulf Professional Publishing. This book was released on 2013-04-10 with total page 710 pages. Available in PDF, EPUB and Kindle. Book excerpt: Enhanced Oil Recovery Field Case Studies bridges the gap between theory and practice in a range of real-world EOR settings. Areas covered include steam and polymer flooding, use of foam, in situ combustion, microorganisms, "smart water"-based EOR in carbonates and sandstones, and many more. Oil industry professionals know that the key to a successful enhanced oil recovery project lies in anticipating the differences between plans and the realities found in the field. This book aids that effort, providing valuable case studies from more than 250 EOR pilot and field applications in a variety of oil fields. The case studies cover practical problems, underlying theoretical and modeling methods, operational parameters, solutions and sensitivity studies, and performance optimization strategies, benefitting academicians and oil company practitioners alike. - Strikes an ideal balance between theory and practice - Focuses on practical problems, underlying theoretical and modeling methods, and operational parameters - Designed for technical professionals, covering the fundamental as well as the advanced aspects of EOR

Encyclopedia of Colloid and Interface Science

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Publisher : Springer
ISBN 13 : 9783642206641
Total Pages : 0 pages
Book Rating : 4.2/5 (66 download)

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Book Synopsis Encyclopedia of Colloid and Interface Science by : Tharwat Tadros

Download or read book Encyclopedia of Colloid and Interface Science written by Tharwat Tadros and published by Springer. This book was released on 2013-06-28 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: An authoritative and comprehensive reference relevant to all scientists and engineers in the field. This encyclopedia not only helps chemistry, materials science and physics researchers to understand the principles, but also provides practicing engineers with the necessary information for implementing practical applications, such as Food and agrochemicals Polymers and ceramics Cosmetics and detergents Paints and coatings Pharmaceuticals and drug delivery In addition, the encyclopedia is an important reference for industrial chemists and chemical engineers faced with a multitude of industrial systems of a colloidal nature. As wide as the range of applications that colloid and interface science has is the range of scientific disciplines that contribute to research and development in this field. These encompass chemistry, physics, biology and mathematics as well as nanoscience and nanotechnology. The encyclopedia provides easy-to-digest information for meeting these interdisciplinary challenges. While providing numerous concise definitions of key terms, the encyclopedia also features more than forty in-depth essays on topics ranging from Agrochemical Formulations to Zeta Potential. All entries are cross-referenced and include selected references to original literature as well as synonyms.

Modern Chemical Enhanced Oil Recovery

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Publisher : Gulf Professional Publishing
ISBN 13 : 0080961630
Total Pages : 648 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Modern Chemical Enhanced Oil Recovery by : James J.Sheng

Download or read book Modern Chemical Enhanced Oil Recovery written by James J.Sheng and published by Gulf Professional Publishing. This book was released on 2010-11-25 with total page 648 pages. Available in PDF, EPUB and Kindle. Book excerpt: Crude oil development and production in U.S. oil reservoirs can include up to three distinct phases: primary, secondary, and tertiary (or enhanced) recovery. During primary recovery, the natural pressure of the reservoir or gravity drive oil into the wellbore, combined with artificial lift techniques (such as pumps) which bring the oil to the surface. But only about 10 percent of a reservoir's original oil in place is typically produced during primary recovery. Secondary recovery techniques to the field's productive life generally by injecting water or gas to displace oil and drive it to a production wellbore, resulting in the recovery of 20 to 40 percent of the original oil in place. In the past two decades, major oil companies and research organizations have conducted extensive theoretical and laboratory EOR (enhanced oil recovery) researches, to include validating pilot and field trials relevant to much needed domestic commercial application, while western countries had terminated such endeavours almost completely due to low oil prices. In recent years, oil demand has soared and now these operations have become more desirable. This book is about the recent developments in the area as well as the technology for enhancing oil recovery. The book provides important case studies related to over one hundred EOR pilot and field applications in a variety of oil fields. These case studies focus on practical problems, underlying theoretical and modelling methods, operational parameters (e.g., injected chemical concentration, slug sizes, flooding schemes and well spacing), solutions and sensitivity studies, and performance optimization strategies. The book strikes an ideal balance between theory and practice, and would be invaluable to academicians and oil company practitioners alike. - Updated chemical EOR fundamentals providing clear picture of fundamental concepts - Practical cases with problems and solutions providing practical analogues and experiences - Actual data regarding ranges of operation parameters providing initial design parameters - Step-by-step calculation examples providing practical engineers with convenient procedures

Chemistry and Technology of Surfactants

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Publisher : John Wiley & Sons
ISBN 13 : 1405171790
Total Pages : 336 pages
Book Rating : 4.4/5 (51 download)

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Book Synopsis Chemistry and Technology of Surfactants by : Richard J. Farn

Download or read book Chemistry and Technology of Surfactants written by Richard J. Farn and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: Surfactants are used throughout industry as components in a hugerange of formulated products or as effect chemicals in theproduction or processing of other materials. A detailedunderstanding of the basis of their activity is required by allthose who use surfactants, yet the new graduate or postgraduatechemist or chemical engineer will generally have little or noexperience of how and why surfactants work. Chemistry & Technology of Surfactants is aimed at newgraduate or postgraduate level chemists and chemical engineers atthe beginning their industrial careers and those in later life whobecome involved with surfactants for the first time. The book is astraightforward and practical survey of the chemistry ofsurfactants and their uses, providing a basic introduction tosurfactant theory, information on the various types of surfactantand some application details. This will allow readers to build ontotheir scientific education the concepts and principles on which thesuccessful use of surfactants, across a wide range of industries,is based.

Surfactant Science and Technology

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Publisher : John Wiley & Sons
ISBN 13 : 1119465850
Total Pages : 416 pages
Book Rating : 4.1/5 (194 download)

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Book Synopsis Surfactant Science and Technology by : Drew Myers

Download or read book Surfactant Science and Technology written by Drew Myers and published by John Wiley & Sons. This book was released on 2020-08-04 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: A solid introduction to the field of surfactant science, this new edition provides updated information about surfactant uses, structures, and preparation, as well as seven new chapters expanding on technology applications. Offers a comprehensive introduction and reference of the science and technology of surface active materials Elaborates, more fully than prior editions, aspects of surfactant crystal structure as well as their effects on applications Adds more information on new classes and applications of natural surfactants in light of environmental consequences of surfactant use

Phosphorus: Polluter and Resource of the Future

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Publisher : IWA Publishing
ISBN 13 : 1780408358
Total Pages : 592 pages
Book Rating : 4.7/5 (84 download)

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Book Synopsis Phosphorus: Polluter and Resource of the Future by : Christian Schaum

Download or read book Phosphorus: Polluter and Resource of the Future written by Christian Schaum and published by IWA Publishing. This book was released on 2018-03-15 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive book provides an up-to-date and international approach that addresses the Motivations, Technologies and Assessment of the Elimination and Recovery of Phosphorus from Wastewater. This book is part of the Integrated Environmental Technology Series.