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Microfluidic H2 O2 Fuel Cells For Contaminant And Electrode Analysis
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Book Synopsis Microfluidic H2/O2 Fuel Cells for Contaminant and Electrode Analysis by : Matt Naughton
Download or read book Microfluidic H2/O2 Fuel Cells for Contaminant and Electrode Analysis written by Matt Naughton and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Alkaline fuel cells (AFCs) are promising power sources due to superior cathode kinetics as compared to acidic media and the ability to use inexpensive non-noble metal catalysts. However, carbonate formation from carbon dioxide in air has long been considered a significant hurdle for liquid electrolyte-based AFC technologies. Carbonate formation consumes hydroxyl anions, which leads to (i) reduced electrode performance if formed salts precipitate from solution and (ii) lowered electrolyte conductivity, which reduces cell performance and operating lifetime. We have used a microfluidic H2/O2 fuel cell as an analytical platform to determine the effects of the carbonate formation problem in alkaline fuel cells. The microfluidic fuel cell has modular components that can easily be swapped to test electrodes, electrolyte, or other aspects of the fuel cell. A reference electrode placed at the outlet allows for individual electrode analysis, which is not normally possible in conventional membrane-based fuel cells. In this thesis, it is demonstrated that AFC performance can be resilient to a broad range of carbonate concentrations. Furthermore, the effects of carbonate formation rates on projected AFC operational lifetime are determined. A quantitative method to analyze individual electrode performance using single electrode plots and the two parameters Rohmic and Vkinetic is also developed. Results demonstrated that losses from both electrodes are substantial in an alkaline fuel cell, and that ohmic and mass transport losses are shown to only significantly affect Rohmic. IR-corrections were used to isolate individual kinetic and mass transport losses at each electrode within the operating fuel cell. These findings demonstrate great potential to broaden the scope of fuel cell research.
Book Synopsis Microfluidic Platforms for the Investigation of Fuel Cell Catalysts and Electrodes by : Fikile R. Brushett
Download or read book Microfluidic Platforms for the Investigation of Fuel Cell Catalysts and Electrodes written by Fikile R. Brushett and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A clear need exists for novel approaches to producing and utilizing energy in more efficient ways, in light of society0́9s ever increasing demand as well as growing concerns with respect to climate change related to CO2 emissions. The development of low temperature fuel cell technologies will continue to play an important role in many alternative energy conversion strategies, especially for portable electronics and automotive applications. However, widespread commercialization of fuel cell technologies has yet to be achieved due to a combination of high costs, poor durability and, system performance limitations (Chapter 1). Developing a better understanding of the complex interplay of electrochemical, transport, and degradation processes that govern the performance and durability of novel fuel cell components, particularly catalysts and electrodes, within operating fuel cells is critical to designing robust, inexpensive configurations that are required for commercial introduction. Such detailed in-situ investigations of individual electrode processes are complicated by other factors such as water management, uneven performance across electrodes, and temperature gradients. Indeed, too many processes are interdependent on the same few variable parameters, necessitating the development of novel analytical platforms with more degrees of freedom. Previously, membraneless microfluidic fuel cells have been developed to address some of the aforementioned fuel cell challenges (Chapter 2). At the microscale, the laminar nature of fluid flow eliminates the need for a physical barrier, such as a stationary membrane, while still allowing ionic transport between electrodes. This enables the development of many unique and innovative fuel cell designs. In addition to addressing water management and fuel crossover issues, these laminar flow-based systems allow for the independent specification of individual stream compositions (e.g., pH). Furthermore, the use of a liquid electrolyte enables the simple in-situ analysis of individual electrode performance using an off-the-shelf reference electrode. These advantages can be leveraged to develop microfluidic fuel cells as versatile electro-analytical platforms for the characterization and optimization of catalysts and electrodes for both membrane- and membraneless fuel cells applications. To this end, a microfluidic hydrogen-oxygen (H2/O2) fuel cell has been developed which utilizes a flowing liquid electrolyte instead of a stationary polymeric membrane. For analytical investigations, the flowing stream (i) enables autonomous control over electrolyte parameters (i.e., pH, composition) and consequently the local electrode environments, as well as (ii) allows for the independent in-situ analyses of catalyst and/or electrode performance and degradation characteristics via an external reference electrode (e.g., Ag/AgCl). Thus, this microfluidic analytical platform enables a high number of experimental degrees of freedom, previously limited to a three-electrode electrochemical cell, to be employed in the construct of working fuel cell. Using this microfluidic H2/O2 fuel cell as a versatile analytical platform, the focus of this work is to provide critical insight into the following research areas: 0́Ø Identify the key processes that govern the electrode performance and durability in alkaline fuel cells as a function of preparation methods and operating parameters (Chapter 3). 0́Ø Determine the suitability of a novel Pt-free oxygen reduction reaction catalyst embedded in gas diffusion electrodes for acidic and alkaline fuel cell applications (Chapter 4). 0́Ø Establish electrode structure-activity relationships by aligning in-situ electrochemical analyses with ex-situ microtomographic (MicroCT) structural analyses (Chapter 5). 0́Ø Investigate the feasibility and utility of a microfluidic-based vapor feed direct methanol fuel cell (VF-DMFC) configuration as a power source for portable applications (Chapter 6). In all these areas, the information garnered from these in-situ analytical platforms will advance the development of more robust and cost-effective electrode configurations and thus more durable and commercially-viable fuel cell systems (both membrane-based and membraneless).
Book Synopsis Microfluidic Fuel Cells and Batteries by : Erik Kjeang
Download or read book Microfluidic Fuel Cells and Batteries written by Erik Kjeang and published by Springer. This book was released on 2014-06-14 with total page 81 pages. Available in PDF, EPUB and Kindle. Book excerpt: Microfluidic fuel cells and batteries represent a special type of electrochemical power generators that can be miniaturized and integrated in a microfluidic chip. Summarizing the initial ten years of research and development in this emerging field, this SpringerBrief is the first book dedicated to microfluidic fuel cell and battery technology for electrochemical energy conversion and storage. Written at a critical juncture, where strategically applied research is urgently required to seize impending technology opportunities for commercial, analytical, and educational utility, the intention is for this book to be a ‘one-stop shop’ for current and prospective researchers in the general area of membraneless, microfluidic electrochemical energy conversion. As the overall goal of the book is to provide a comprehensive resource for both research and technology development, it features extensive descriptions of the underlying fundamental theory, fabrication methods, and cell design principles, as well as a thorough review of previous contributions in this field and a future outlook with recommendations for further work. It is hoped that the content will entice and enable new research groups and engineers to rapidly gain traction in their own laboratories towards the development of next generation microfluidic electrochemical cells.
Book Synopsis Exploration and Optimization of a Liquid Electrolyte H2/O2 Microfluidic Fuel Cell by : Geun Ho Gu
Download or read book Exploration and Optimization of a Liquid Electrolyte H2/O2 Microfluidic Fuel Cell written by Geun Ho Gu and published by . This book was released on 2012 with total page 36 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Ammonia Fuel Cells by : Ibrahim Dincer
Download or read book Ammonia Fuel Cells written by Ibrahim Dincer and published by Elsevier. This book was released on 2020-04-09 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ammonia Fuel Cells covers all aspects of ammonia fuel cell technologies and their applications, including their theoretical analysis, modeling studies and experimental investigations. The book analyzes the role of integrated ammonia fuel cell systems within various renewable energy resources and existing energy systems. Covers the types of ammonia fuel cells that have been developed over history Features explanations of the underlying fundamentals and principles of ammonia fuel cells, along with methods to assess the performance of different types of cell Includes case studies considering different applications of ammonia fuel cells and their significance in the future of clean energy
Book Synopsis Portable Hydrogen Energy Systems by : Paloma Ferreira-Aparicio
Download or read book Portable Hydrogen Energy Systems written by Paloma Ferreira-Aparicio and published by Academic Press. This book was released on 2018-08-04 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Portable Hydrogen Energy Systems: Fuel Cells and Storage Fundamentals and Applications covers the basics of portable fuel cells, their types, possibilities for fuel storage, in particular for hydrogen as fuel, and their potential application. The book explores electrochemistry, types, and materials and components, but also includes a chapter on the particularities of their use in portable devices, with a focus on proton exchange membrane (PEM) type. Topics cover fuel storage for these cells, in particular hydrogen storage and an analysis of current possibilities. In addition, portable fuel cell systems are examined, covering auxiliary elements required for operation and possibilities for their miniaturization. Engineers and developers of portable applications and electricity will find this book to provide fundamental information on the possibilities of portable hydrogen fuel cells, including costs and market information, for their planning, modeling, development and deployment. Graduate students and lecturers will find this to be a complementary resource in general hydrogen and fuel cell courses or in specialized courses covering portable systems. Presents a current view of the fundamentals and possibilities of portable hydrogen fuel cells, also comparing them with other market solutions, such as batteries Examines the applications where portable hydrogen fuel cell technology is a viable solution Explores future trends and needs in terms of materials, components and systems to improve the possibilities to make hydrogen fuel cells competitive and reliable for future portable applications
Book Synopsis Microbial Electrochemical Technologies by : Sonia M. Tiquia-Arashiro
Download or read book Microbial Electrochemical Technologies written by Sonia M. Tiquia-Arashiro and published by CRC Press. This book was released on 2020-01-06 with total page 497 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book encompasses the most updated and recent account of research and implementation of Microbial Electrochemical Technologies (METs) from pioneers and experienced researchers in the field who have been working on the interface between electrochemistry and microbiology/biotechnology for many years. It provides a holistic view of the METs, detailing the functional mechanisms, operational configurations, influencing factors governing the reaction process and integration strategies. The book not only provides historical perspectives of the technology and its evolution over the years but also the most recent examples of up-scaling and near future commercialization, making it a must-read for researchers, students, industry practitioners and science enthusiasts. Key Features: Introduces novel technologies that can impact the future infrastructure at the water-energy nexus. Outlines methodologies development and application of microbial electrochemical technologies and details out the illustrations of microbial and electrochemical concepts. Reviews applications across a wide variety of scales, from power generation in the laboratory to approaches. Discusses techniques such as molecular biology and mathematical modeling; the future development of this promising technology; and the role of the system components for the implementation of bioelectrochemical technologies for practical utility. Explores key challenges for implementing these systems and compares them to similar renewable energy technologies, including their efficiency, scalability, system lifetimes, and reliability.
Book Synopsis Electrochemical Water and Wastewater Treatment by : Carlos Alberto Martínez-Huitle
Download or read book Electrochemical Water and Wastewater Treatment written by Carlos Alberto Martínez-Huitle and published by Butterworth-Heinemann. This book was released on 2018-05-29 with total page 574 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemical Water Treatment Methods provides the fundamentals and applications of electrochemical water treatment methods to treat industrial effluents. Sections provide an overview of the technology, its current state of development, and how it is making its way into industry applications. Other sections deal with historical developments and the fundamentals of 18 methods, including coupled methods, such as Electrocoagulation, Peroxi-Coagulation and Electro-Fenton treatments. In addition, users will find discussions that relate to industries such as Pulp and Paper, Pharmaceuticals, Textiles, and Urban/Domestic wastewater, amongst others. Final sections present advantages, disadvantages and ways to combine renewable energy sources and electrochemical methods to design sustainable facilities. Environmental and Chemical Engineers will benefit from the extensive collection of methods and industry focused application cases, but researchers in environmental chemistry will also find interesting examples on how methods can be transitioned from lab environments to practical applications. Offers an excellent overview of the research advances and current applications of electrochemical technologies for water treatment Explains, in a comprehensive way, the fundamentals of different electrochemical uses and applications of different technologies Provides a large number of examples as evidence of practical applications of electrochemistry to environmental protection Explores the combination possibilities with other treatment technologies or emerging technologies for destroying water pollutants
Book Synopsis Laser-induced Graphene by : Ruquan Ye
Download or read book Laser-induced Graphene written by Ruquan Ye and published by . This book was released on 2020-11-30 with total page 88 pages. Available in PDF, EPUB and Kindle. Book excerpt: LIG is a revolutionary technique that uses a common CO2 infrared laser scriber, like the one used in any machine shop, for the direct conversion of polymers into porous graphene under ambient conditions. This technique combines the preparation and patterning of 3D graphene in a single step, without the use of wet chemicals. The ease in the structural engineering and excellent mechanical properties of the 3D graphene obtained have made LIG a versatile technique for applications across many fields. This book compiles cutting-edge research on LIG by different research groups all over the world. It discusses the strategies that have been developed to synthesize and engineer graphene, including controlling its properties such as porosity, composition, and surface characteristics. The authors are pioneers in the discovery and development of LIG and the book will appeal to anyone involved in nanotechnology, chemistry, environmental sciences, and device development, especially those with an interest in the synthesis and applications of graphene-based materials.
Download or read book Micro Fuel Cells written by Tim Zhao and published by Academic Press. This book was released on 2009-07-07 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Today's consumers of portable electronics consumers are demanding devices not only deliver more power but also work healthy for the environment. This fact alone has lead major corporations like Intel, BIC, Duracell and Microsoft to believe that Microfuel Cells could be the next-generation power source for electronic products. Compact and readable, Microfuels Principles and Applications, offers engineers and product designers a reference unsurpassed by any other in the market. The book starts with a clear and rigorous exposition of the fundamentals engineering principles governing energy conversion for small electronic devices, followed by self-contained chapters concerning applications. The authors provide original points of view on all types of commercially available micro fuel cells types, including micro proton exchange membrane fuel cells, micro direct methanol fuel cells, micro solid oxide fuel cells and micro bio-fuel cells. The book also contains a detailed introduction to the fabrication of the components and the assembly of the system, making it a valuable reference both in terms of its application to product design and understanding micro engineering principles. An overview of the micro fuel cell systems and applications A detailed introduction to the fabrication of the components and the assembly of the system Original points of view on prospects of micro fuel cells
Book Synopsis Anion Exchange Membrane Fuel Cells by : Liang An
Download or read book Anion Exchange Membrane Fuel Cells written by Liang An and published by Springer. This book was released on 2018-03-21 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a review of the latest advances in anion exchange membrane fuel cells. Starting with an introduction to the field, it then examines the chemistry and catalysis involved in this energy technology. It also includes an introduction to the mathematical modelling of these fuel cells before discussing the system design and performance of real-world systems. Anion exchange membrane fuel cells are an emerging energy technology that has the potential to overcome many of the obstacles of proton exchange membrane fuel cells in terms of the cost, stability, and durability of materials. The book is an essential reference resource for professionals, researchers, and policymakers around the globe working in academia, industry, and government.
Book Synopsis Bioelectrochemical Systems by : Korneel Rabaey
Download or read book Bioelectrochemical Systems written by Korneel Rabaey and published by IWA Publishing. This book was released on 2009-12-01 with total page 525 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the context of wastewater treatment, Bioelectrochemical Systems (BESs) have gained considerable interest in the past few years, and several BES processes are on the brink of application to this area. This book, written by a large number of world experts in the different sub-topics, describes the different aspects and processes relevant to their development. Bioelectrochemical Systems (BESs) use micro-organisms to catalyze an oxidation and/or reduction reaction at an anodic and cathodic electrode respectively. Briefly, at an anode oxidation of organic and inorganic electron donors can occur. Prime examples of such electron donors are waste organics and sulfides. At the cathode, an electron acceptor such as oxygen or nitrate can be reduced. The anode and the cathode are connected through an electrical circuit. If electrical power is harvested from this circuit, the system is called a Microbial Fuel Cell; if electrical power is invested, the system is called a Microbial Electrolysis Cell. The overall framework of bio-energy and bio-fuels is discussed. A number of chapters discuss the basics – microbiology, microbial ecology, electrochemistry, technology and materials development. The book continues by highlighting the plurality of processes based on BES technology already in existence, going from wastewater based reactors to sediment based bio-batteries. The integration of BESs into existing water or process lines is discussed. Finally, an outlook is provided of how BES will fit within the emerging biorefinery area.
Book Synopsis Electro-Fenton Process by : Minghua Zhou
Download or read book Electro-Fenton Process written by Minghua Zhou and published by Springer. This book was released on 2017-11-25 with total page 437 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume discusses the theoretical fundamentals and potential applications of the original electro-Fenton (EF) process and its most innovative and promising versions, all of which are classified as electrochemical advanced oxidation processes. It consists of 15 chapters that review the latest advances and trends, material selection, reaction and reactor modeling and EF scale-up. It particularly focuses on the applications of EF process in the treatment of toxic and persistent organic pollutants in water and soil, showing highly efficient removal for both lab-scale and pre-pilot setups. Indeed, the EF technology is now mature enough to be brought to market, and this collection of contributions from leading experts in the field constitutes a timely milestone for scientists and engineers.
Book Synopsis Progress and Recent Trends in Microbial Fuel Cells by : Patit Paban Kundu
Download or read book Progress and Recent Trends in Microbial Fuel Cells written by Patit Paban Kundu and published by Elsevier. This book was released on 2018-06-07 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress and Recent Trends in Microbial Fuel Cells provides an in-depth analysis of the fundamentals, working principles, applications and advancements (including commercialization aspects) made in the field of Microbial Fuel Cells research, with critical analyses and opinions from experts around the world. Microbial Fuel cell, as a potential alternative energy harnessing device, has been progressing steadily towards fruitful commercialization. Involvements of electrolyte membranes and catalysts have been two of the most critical factors toward achieving this progress. Added applications of MFCs in areas of bio-hydrogen production and wastewater treatment have made this technology extremely attractive and important. . Reviews and compares MFCs with other alternative energy harnessing devices, particularly in comparison to other fuel cells Analyses developments of electrolyte membranes, electrodes, catalysts and biocatalysts as critical components of MFCs, responsible for their present and future progress Includes commercial aspects of MFCs in terms of (i) generation of electricity, (ii) microbial electrolysis cell, (iii) microbial desalination cell, and (iv) wastewater and sludge treatment
Book Synopsis Fuel Cell Engines by : Matthew M. Mench
Download or read book Fuel Cell Engines written by Matthew M. Mench and published by John Wiley & Sons. This book was released on 2008-03-07 with total page 530 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fuel Cell Engines is an introduction to the fundamental principles of electrochemistry, thermodynamics, kinetics, material science and transport applied specifically to fuel cells. It covers scientific fundamentals and provides a basic understanding that enables proper technical decision-making.
Book Synopsis Recent Trends in Fuel Cell Science and Technology by : S. Basu
Download or read book Recent Trends in Fuel Cell Science and Technology written by S. Basu and published by Springer Science & Business Media. This book was released on 2007-10-20 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers all the proposed fuel cell systems including PEMFC, SOFC, PAFC, MCFC, regenerative fuel cells, direct alcohol fuel cells, and small fuel cells to replace batteries.
Book Synopsis Biochemical Fuel Cells by : Miroslav Cenek
Download or read book Biochemical Fuel Cells written by Miroslav Cenek and published by . This book was released on 1969 with total page 68 pages. Available in PDF, EPUB and Kindle. Book excerpt: A review is provided which covers the development, present status, and future outlook of biochemical fuel cell research. Its contents include: Bioelectrochemistry; Biofuel cells; (Fuels for Biofuel cells, Oxidation agents for biofuel cells, Organisms for biofuel cells, Classification of biofuel cells, Electrochemical and biological metabolism, Interelectrode separation, Suitability of materials used in Biofuel Cells, The influence of the Electrode on the Biological Substance); Biogalvanic cells; Biosolar cells; Bioanodes; Biocathodes; Some types of biofuel cells (Biofuel cell urea-oxygen-urease, Biofuel cell lactate-atmospheric oxygen); Comparison of biofuel cells with fuel cells (Advantages of biofuel cells over fuel cells, Drawbacks of biofuel cells in comparison with fuel cells); The medium of the ocean as a giant biofuel cell.
