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Mechanistic Studies Of Reactions Of Some Platinum Metal Complexes
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Book Synopsis Mechanistic studies of reactions of some platinum metal complexes by : David Huw Vaughan
Download or read book Mechanistic studies of reactions of some platinum metal complexes written by David Huw Vaughan and published by . This book was released on 1968 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Substitution reactions of platinum metal complexes by : Carol Penelope Jill Viuk
Download or read book Substitution reactions of platinum metal complexes written by Carol Penelope Jill Viuk and published by . This book was released on 1974 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Preparative and Mechanistic Studies on Some Carboxylate Complexes of the Platinum Metals by : D. S. Moore
Download or read book Preparative and Mechanistic Studies on Some Carboxylate Complexes of the Platinum Metals written by D. S. Moore and published by . This book was released on 1980 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Preparative and Mechanistic Studies on Some Carboxylate Complexes of the Platinum Metals by : D. S. Moore
Download or read book Preparative and Mechanistic Studies on Some Carboxylate Complexes of the Platinum Metals written by D. S. Moore and published by . This book was released on 1980 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reaction Mechanisms of Metal Complexes by : R W Hay
Download or read book Reaction Mechanisms of Metal Complexes written by R W Hay and published by Elsevier. This book was released on 2000-03-01 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands. It is relevant in other fields such as organic, bioinorganic and biological chemistry, providing a bridge to organic reaction mechanisms. The book also contains a chapter on the kinetic background to the subject with many illustrative examples which should prove useful to those beginning research. Provides a general background as a course module in the area of inorganic reaction mechanisms, which has important research applications in the metallurgical industry Contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands
Book Synopsis Kinetic and Mechanistic Studies on the Reactions of Some Organic Compounds with Palladium (II) Complexes by : Bin Md Yamin Bohari
Download or read book Kinetic and Mechanistic Studies on the Reactions of Some Organic Compounds with Palladium (II) Complexes written by Bin Md Yamin Bohari and published by . This book was released on 1977 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Mechanistic Studies on Some Oxidation Reactions of Palladium(II) Complexes by : Paul Lawrence Rispoli
Download or read book Mechanistic Studies on Some Oxidation Reactions of Palladium(II) Complexes written by Paul Lawrence Rispoli and published by . This book was released on 1978 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Mechanistic Studies of Carbon-carbon and Carbon-hydrogen Reductive Elimination Reactions from Platinum(IV) Complexes by : Dawn M. Crumpton
Download or read book Mechanistic Studies of Carbon-carbon and Carbon-hydrogen Reductive Elimination Reactions from Platinum(IV) Complexes written by Dawn M. Crumpton and published by . This book was released on 2000 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthetic and Mechanistic Studies on Allylic and Tertiary Phosphine Complexes of the Platinum Metals by : Alan Bright
Download or read book Synthetic and Mechanistic Studies on Allylic and Tertiary Phosphine Complexes of the Platinum Metals written by Alan Bright and published by . This book was released on 1970 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Synthesis of One-dimensional Platinum Complexes by : Stephen Oliver Dunham
Download or read book The Synthesis of One-dimensional Platinum Complexes written by Stephen Oliver Dunham and published by . This book was released on 1992 with total page 362 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reaction Rates of Isotopic Molecules by : Lars C. S. Melander
Download or read book Reaction Rates of Isotopic Molecules written by Lars C. S. Melander and published by . This book was released on 1987 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Mechanistic Studies on the Reactions of Dienes and Palladium(II) Complexes by : H. M. Asfour
Download or read book Mechanistic Studies on the Reactions of Dienes and Palladium(II) Complexes written by H. M. Asfour and published by . This book was released on 1984 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Characterization, and Mechanistic Studies on a Group of Platinum Complexes Using 195PT Nuclear Magnetic Resonance by : Danny Richard Bedgood
Download or read book Synthesis, Characterization, and Mechanistic Studies on a Group of Platinum Complexes Using 195PT Nuclear Magnetic Resonance written by Danny Richard Bedgood and published by . This book was released on 1991 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis of Group 9 and 10 Metal Complexes Supported by Chelating Nitrogen-based Ligands and Mechanistic Studies of Their Role in Catalytic Transformations by : Jennifer Lauren McBee
Download or read book Synthesis of Group 9 and 10 Metal Complexes Supported by Chelating Nitrogen-based Ligands and Mechanistic Studies of Their Role in Catalytic Transformations written by Jennifer Lauren McBee and published by . This book was released on 2009 with total page 840 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Lewis Acid Mediated Reactions by : Allegra Lauren Liberman-Martin
Download or read book Lewis Acid Mediated Reactions written by Allegra Lauren Liberman-Martin and published by . This book was released on 2015 with total page 110 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chapter 1. A strategy for the control of electron density at a metal center is reported, using a remote chemical switch involving second-sphere Lewis acid binding that modulates electron density in the first coordination sphere. Binding of the Lewis acid B(C6F5)3 at remote nitrogen positions of a bipyrazine-diarylplatinum(II) complex accelerates biaryl reductive elimination by a factor of 64,000. Chapter 2. The silicon and zinc Lewis acids Si(cat)2 (cat = catecholato), Si(catF)2 (catF = tetrafluorocatecholato), and Zn(C6F5)2 bind to the remote ligand site of a 2,2́-bipyrimidyl–platinum diaryl complex. This platinum complex provides a platform to systematically evaluate electronic and reactivity differences triggered by Lewis acid binding. The electron density of the bipyrimidine ligand is substantially depleted upon Lewis acid binding, as evidenced by UV-vis spectroscopy and cyclic voltammetry. Biaryl reductive elimination studies allowed quantification of the effect of Lewis acid binding on reactivity, and Lewis acid binding accelerated reductive elimination rates by up to eight orders of magnitude. Kinetics experiments in combination with DFT studies support an unusual mechanism featuring complete dissociation of the bidentate bipyrimidine ligand prior to reductive elimination. Chapter 3. Z-type interactions between bis(perfluorophenyl)zinc and platinum(II) diaryl complexes supported by phenanthroline (phen), bipyridine (bpy), and bis(dimethylphosphino)ethane (dmpe) ligands are reported. In the solid state, there is an unsupported Pt–Zn bond for the phen complex, while the dmpe derivative features additional bridging aryl interactions. The Pt–Zn complexes featuring phen and bpy ligands undergo facile reductive elimination, whereas aryl exchange between Pt and Zn is observed for the dmpe complex. Chapter 4. Bis(perfluorocatecholato)silane Si(catF)2 was prepared, and stoichiometric binding to Lewis bases was demonstrated with fluoride, triethylphosphine oxide, and N,N'-diisopropylbenzamide. The potent Lewis acidity of Si(catF)2 was suggested from catalytic hydrosilation and silylcyanation reactions with aldehydes. Mechanistic studies of hydrosilation using an optically active silane substrate, R-(+)-methyl(1-napthyl)phenylsilane, proceeded with predominant stereochemical retention at silicon, consistent with a carbonyl activation pathway. The enantiospecificity was dependent on solvent and salt effects, with increasing solvent polarity or addition of NBu4BArF4 leading to a diminished enantiomeric ratio. The medium effects are consistent with an ionic mechanism, wherein hydride transfer occurs prior to silicon–oxygen bond formation.
Book Synopsis Synthesis, Properties and Reaction Mechanisms of Platinum Metal Compounds by : Fred Basolo
Download or read book Synthesis, Properties and Reaction Mechanisms of Platinum Metal Compounds written by Fred Basolo and published by . This book was released on 1963 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research on the chemistry of metals called noble or platinum metals is reviewed: (1) New Linkage Isomers. Making use of studies on the mechanism of formation of the Co(III) linkage isomers (NH3)5Co-ONO (2) (nitrito) and (NH3)5Co NO2 (2) (nitro), analogous isomers for Rh(III), Ir(III) and Pt(IV) were synthesized and studied. (2) Chloroamminerhodium(III) Complexes. Several new complexes of Rh(III) were prepared and kinet ic study made of their acid and base hydrolysis. (3) Carboxylatopentamminemetal(III) Complexes. Compounds of the type M(NH3)5(RCOO) (2), where MCo(III), Rh(III), Ir(III) and RCOO( - ) CH3COO( - ), (CH3)3CCOO( - ), CF3COO( - ), where syn thesized. Kinetic studies show that the rate of hydrolysis of these complexes is acid catalyzed. (4) (Acidoamminegold(III) Complexes. Solution chemistry of the new compounds Au(dien)X X (where dien NH2CH2CH2NHCH2CH2NH2 and X Cl( - ), Br( - ), I( - )) was investigated in some detail. (Author).
Book Synopsis Chemistry of the Platinum Group Metals by : F.R. Hartley
Download or read book Chemistry of the Platinum Group Metals written by F.R. Hartley and published by Elsevier. This book was released on 2013-10-22 with total page 645 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of platinum group metals is a rapidly expanding commercially important field. It is dominated by the catalytic properties of the metals. They are useful in petrochemical and general chemical plants and are becoming increasingly important as autocatalysts for pollution control. The book covers recent developments in the chemistry of the six platinum group metals, namely, platinum, palladium, rhodium, iridium, ruthenium and osmium. The material falls into three broad areas. Firstly, the occurrence, extraction and use of the metals, especially in catalysis, electrochemistry, energy and electronics. Secondly, organometallic and homogeneous catalytic chemistry and last but not least coordination chemistry including biochemistry and cancer therapy. The work is aimed at scientists in universities and in industry using any of the six platinum group metals in research. It will be useful for those studying the compounds of the metals themselves, and those considering to use either the metals or their complexes and catalysts in their experimental work.