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Luminescent Cyclometalated Gold Iii Complexes With Ancillary N Heterocyclic Carbene And Alkynyl Ligands
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Book Synopsis Luminescent Cyclometalated Gold (III) Complexes with Ancillary N-heterocyclic Carbene and Alkynyl Ligands by : Ka-man Au
Download or read book Luminescent Cyclometalated Gold (III) Complexes with Ancillary N-heterocyclic Carbene and Alkynyl Ligands written by Ka-man Au and published by . This book was released on 2012 with total page 510 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Luminescent Cyclometalated Gold (III) Complexes with Ancillary N-Heterocyclic Carbene and Alkynyl Ligands by : Ka-Man Au
Download or read book Luminescent Cyclometalated Gold (III) Complexes with Ancillary N-Heterocyclic Carbene and Alkynyl Ligands written by Ka-Man Au and published by Open Dissertation Press. This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Luminescent Cyclometalated Gold (III) Complexes With Ancillary N-heterocyclic Carbene and Alkynyl Ligands: From Design, Synthesis, Photophysics to Supramolecular Assembly and Functions" by Ka-man, Au, 區嘉雯, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: A library of luminescent cyclometalated gold(III) complexes containing various bis-cyclometalating R-C DEGREESN DEGREESC ligands derived from 2,6-diphenylpyridine and ancillary alkynyl ligands, [Au(R-C DEGREESN DEGREESC)(C≡CR')], has been synthesized. Some of the complexes have been structurally determined by X-ray crystallography. These complexes were found to exhibit intense emission in dichloromethane solution at 298 K, originating from metal-perturbed triplet intraligand (IL) excited states of the R-C DEGREESN DEGREESC ligand, with substantial charge transfer character from the aryl moiety to the pyridyl ring. In the presence of electron-rich alkynyl ligands, the emission origin could be switched to an alkynyl-to-cyclometalating ligand ligand-to-ligand charge transfer (LLCT) excited state. This class of complexes was also demonstrated to show rich electroluminescence properties as emitters in organic light-emitting devices. In addition, the supramolecular assembly of this class of complexes has also been revealed in gelation studies. N-Heterocyclic carbenes have been incorporated into the gold(III) metal center to prepare a series of luminescent mononuclear and dinuclear gold(III) complexes, [{Au(C DEGREESN DEGREESC)}n(NHC)](PF6)n and [{Au(tBuC DEGREESN DEGREESCtBu)}n(NHC)]- (PF6)n (n = 1, 2). The X-ray crystal structures of most of the complexes have been determined. The emissions of these complexes were assigned to originate from the metal-perturbed intraligand excited state of the bis-cyclometalating ligand. One of the C2-bridged dinuclear complexes was found to exhibit two distinct reduction couples, tentatively correlated to the presence of significant intramolecular π-π interaction in the complex. Two novel series of luminescent mononuclear alkynylgold(III) complexes, [Au(C DEGREESN)(C≡CR)2] (HC DEGREESN = 2-phenylpyridine (Hppy) and derivatives) and [Au(C DEGREESN DEGREESN)(C≡CR)]PF6 (HC DEGREESN DEGREESN = 6-phenyl-2,2'-bipyridine and derivatives), have been synthesized. Some of the X-ray crystal structures have been determined. The former class of complexes with bidentate C DEGREESN ligands has been observed to show tunable emission spanning across the visible spectrum from 462 to 697 nm. With the exception of [Au(ppy)(C≡C-C6H4-NH2-p)2] which showed a low-energy band originated from a 3LLCT [π(C≡C-C6H4-NH2)→π*(C DEGREESN)] excited state, all complexes exhibited vibronic-structured emission bands originated from the intraligand transition of the cyclometalating C DEGREESN ligand in dichloromethane solution at 298 K. On the other hand, most of the complexes with the tridentate C DEGREESN DEGREESN-type ligand have been observed to exhibit vibronic-structured emission bands attributed to the intraligand transition of the C DEGREESN DEGREESN ligand in low-temperature butyronitrile glass. DOI: 10.5353/th_b4775268 Subjects: Organogold compounds - Synthesis Carbenes (Methylene compounds) Heterocyclic compo
Book Synopsis DESIGN & SYNTHESIS OF LUMINESC by : Suk-Hang Lam
Download or read book DESIGN & SYNTHESIS OF LUMINESC written by Suk-Hang Lam and published by Open Dissertation Press. This book was released on 2017-01-26 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Design and Synthesis of Luminescent Platinum(II) and Gold(III) Complexes With Tridentate Pincer-type Ligands: From Computational Study to Experiments and Application Studies" by Suk-hang, Lam, 林淑恒, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of thesis entitled DESIGN AND SYNTHESIS OF LUMINESCENT PLATINUM(II) AND GOLD(III) COMPLEXES WITH TRIDENTATE PINCER-TYPE LIGANDS - FROM COMPUTATIONAL STUDY TO EXPERIMENTS AND APPLICATION STUDIES Submitted by LAM Suk Hang for the degree of Doctor of Philosophy at The University of Hong Kong in June 2015 Square planar platinum(II) and gold(III) complexes possess unique spectroscopic and photophysical properties which enable them as promising candidates for many applications such as optoelectronic devices and biological sensors. The understanding of the intrinsic properties of these complexes is therefore essential to optimize their performance as well as provide guidance on the molecular design for specific applications. This thesis aims to provide useful insights for the molecular design strategies with the aid of computational studies to tune the electronic properties of these complexes and electroluminescence studies in the fabrication of organic light-emitting devices (OLEDs). Computational studies have been performed to inspect electronic structures and photophysical properties as well as their correlation with the nature of ancillary ligands in the platinum(II) complexes of 1,3-bis(N-alkylbenzimidazol-2′-yl)benzene, [Pt(bzimb)(C≡C-R)], 1,3-bis-hetero-azolylbenzenes, [Pt(N DEGREESC DEGREESN)(C≡C-R)], and pyridine-based N-heterocyclic carbene, [Pt(NHC)(C≡C-R)] . It was found that the emission of the arylalkynylplatinum(II) complexes with pyridine-based N-heterocyclic carbene ligand was originated from the triplet alkynyl-to-tridentate pincer ligand-to-ligand charge transfer excited state mixed with platinum-to-tridentate pincer metal-to-ligand charge transfer character, and the excited state energy was found to be red-shifted according to the increasing π electron-donating ability of the aryl group attached to the alkynyl ligand. On the other hand, the emission energies of the platinum(II) complexes of 1,3-bis(N-alkylbenzimidazol-2′-yl)benzene and 1,3-bis-hetero-azolylbenzenes were found to be dependent on the different electron-donating substituents on the pincer ligands. Calculations have also been performed on the representative alkynylplatinum(II) + + complexes [Pt(trpy)(C≡C-R)] (trpy = 2,2′ 6′,2′′-terpyridine), [Pt(bzimpy)(C≡C-R)] (bzimpy = 2,6-bis(N-alkylbenzimidazol-2′-yl)pyridine) and [Pt(bzimb)(C≡C-R)] as well as alkynylgold(III) complexes [Au(C DEGREESN DEGREESC)(C≡C-R)] (C DEGREESN DEGREESC = 2,6-diphenylpyridine), [Au{C(Np) DEGREESN DEGREESC(Np)}(C≡C-R)] (C(Np) DEGREESN DEGREESC(Np) = 2,6-di(2-naphthyl)pyridine) and [Au(N DEGREESN DEGREESN)(C≡C-R)] (N DEGREESN DEGREESN = 2,6-bis(1H-benzimidazol-2-yl)pyridine) in order to have a better understanding on their nature of the emissive origins as well as the radiative and nonradiative processes. In particular, factors governing the ordering of the triplet excited states and radiative decay rate constants of the emissive state ( ES) have been examined. Their potential energy profiles for the deactivation process from the ES via triplet metal-centered states have also been explored. This study revealed for the first time the potential energy profiles for the thermal deactivation pathway of square planar platinum(II) and gold(III) complexes. In addition to the computational
Book Synopsis Novel Luminescent Cyclometalated Gold (III) Alkynyls by : Ling-Ling Hung
Download or read book Novel Luminescent Cyclometalated Gold (III) Alkynyls written by Ling-Ling Hung and published by Open Dissertation Press. This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Novel Luminescent Cyclometalated Gold (III) Alkynyls: Design, Synthesis, Photophysics and Their Multinuclear Assemblies" by Ling-ling, Hung, 熊靈玲, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of thesis entitled NOVEL LUMINESCENT CYCLOMETALATED GOLD(III) ALKYNYLS - DESIGN, SYNTHESIS, PHOTOPHYSICS AND THEIR MULTINUCLEAR ASSEMBLIES Submitted by HUNG Ling Ling for the Degree of Doctor of Philosophy at The University of Hong Kong in November 2007 A new class of luminescent mononuclear cyclometalated gold(III) complexes containing various monoynyl ligands, [Au(RC DEGREESN(R′) DEGREESCR)(C≡CR′′)], i.e. [Au(C DEGREESN DEGREESC)(C≡CR′′)] (HC DEGREESN DEGREESCH = 2,6-diphenylpyridine; R′′ = C H, C H-Cl-p, 6 5 6 4 C H-C H -p, C H-OCH -p, C H-NO -p, C H-NH -p, C H-N(CH ) -p, 6 4 6 13 6 4 3 6 4 2 6 4 2 6 4 3 2 t t t t C H-N(C H ) -p, C H ), [Au( BuC DEGREESN DEGREESC Bu)(C≡CR′′)] (H BuC DEGREESN DEGREESCBuH = 2,6- 6 4 6 5 2 6 13 bis(4-tert-butylphenyl)pyridine; R′′ = C H, C H-NH -p, Si(CH ), H), 6 5 6 4 2 3 3 [Au(FC DEGREESN DEGREESCF)(C≡CR′′)] (HFC DEGREESN DEGREESCFH = 2,6-bis(4-fluorophenyl)pyridine; R′′ = C H, 6 5 C H-NH -p) and [Au(C DEGREESNTol DEGREESC)(C≡CC H-C H -p)] (HC DEGREESNTol DEGREESCH = 2,6- 6 4 2 6 4 6 13 diphenyl-4-p-tolylpyridine) have been synthesized. Most of the complexes have been structurally determined by X-ray crystallography which revealed the presence of intermolecular π-π stacking interaction with interplanar separations between [Au(RC DEGREESN(R′) DEGREESCR)] units of ca. 3.343-3.570 A. The lowest-lying excited states of 3 these complexes in dichloromethane were assigned as the metal-perturbed IL [π → π*(RC DEGREESN(R′) DEGREESCR)] origin, with substantial charge transfer character from the aryl ring to the pyridyl unit, whereas a switch in the lowest-lying excited states origin to LLCT [π(C≡CC H NR′′′ ) → π*(RC DEGREESN(R′) DEGREESCR)] was observed in complexes 6 4 2 containing aminophenyl alkynyl ligands. The low-energy emissions in the solid state were attributed to the π-π excimeric intraligand phosphorescence, arising from the intermolecular π-π stacking interactions of the RC DEGREESN(R′) DEGREESCR ligands in the solid state as revealed from the crystal packing diagrams. A series of luminescent mononuclear cyclometalated gold(III) complexes with various oligoynyl ligands, [Au(RC DEGREESN DEGREESCR)(C≡CR′)] (R = H, R′ = C≡CH, C H-C≡CH, C≡CC H, C≡CC H-CH -p, C≡CC H-CF -p, C≡CC H-NH -p, 6 4 6 5 6 4 3 6 4 3 6 4 2 C≡C-C≡CC H; R = Bu, R′ = C≡CH, C H-C≡CH) have also been synthesized. 6 5 6 4 The di- and trinuclear cyclometalated gold(III) alkynyl complexes, [1,4- t t t t {Au( BuC DEGREESN DEGREESC Bu)C≡C} C H ] and [1,3,5-{Au( BuC DEGREESN DEGREESC Bu)C≡C} C H ], have also 2 6 4 3 6 3 been prepared. The X-ray crystal structures of [Au(RC DEGREESN DEGREESCR)(C≡CR′)] (R = H, R′ = C≡CH, C H-C≡CH, C≡CC H-CH -p, C≡CC H-CF -p; R = Bu, R′ = 6 4 6 4 3 6 4 3 t t C H-C≡CH) and [1,3,5-{Au( BuC DEGREESN DEGREESC Bu)C≡C} C H ] have been determined. The 6 4 3 6 3 t t molecular structure of [1,3,5-{Au( BuC DEGREESN DEGREESC Bu)C≡C} C H ] showed the twisting of 3 6 3 t t the three coordination planes, [Au( BuC DEGREESN DEGREESCBu)], relative to the central phenyl ring with dihedral angles of 6.1, 48.4 and 60.7. Similarly, the emissions of most of the complexes in fluid solution were attributed to the metal-perturbed IL [π → π*(RC DEGREESN DEGREESCR)] phosphorescence with substantial charge transfer character from the aryl group to the pyridyl unit, while the emission origin was assigned as derived 3 f
Book Synopsis Synthesis and Characterization of Luminescent Gold(III) Complexes by : Amanda N. Sulicz
Download or read book Synthesis and Characterization of Luminescent Gold(III) Complexes written by Amanda N. Sulicz and published by . This book was released on 2017 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of cyclometalated gold(III) has been relatively slow to emerge, but recent advances in catalyst and material design have driven a renewed interest. Reported here are synthetic, structural, and optical studies of cyclometalated gold(III) aryl complexes. These new complexes show ligand-centered luminescence that is perturbed by the heavy-atom effect of gold. Traditionally, metal-carbon bond formation relied on organometallic complexes of electropositive elements, including lithium and magnesium. The easily reducible nature of gold(III) often interferes with these conventional reagents, thus resulting in the use of toxic metals like mercury or thallium. Reported here is the use of palladium-catalyzed Suzuki-Miyaura cross-coupling for the attachment of aryl ligands to cyclometalated gold(III) chloride complexes. The resulting di- and mono-arylated species were luminescent. Several complexes have been crystallographically characterized. Luminescent derivatives of a previously published gold(III) chloro precursor, initially reported for catalytic purposes, were prepared through boron transmetalation reactions. Complexes bearing both aryl and cyanide ligands were synthesized. These luminescent materials are diamagnetic and were be characterized by multinuclear NMR, absorption and emission spectroscopies (including time-resolved emission), and by X-ray diffraction crystallography. The synthesized gold(I) complexes were designed to display reverse saturable absorption and be a two photon acceptor. The BTF (BTF = 2-(9,9’-diethyl-9H-fluoren-2-yl)-benzothiazole) ligand was chosen as it has been previously demonstrated to have favorable photophysical effects on platinum(II) and ruthenium(II) complexes for applications in photodynamic therapy and optical power limiting (OPL). Gold(I) complexes with the BTF ligand are sought for potential OPL applications. Synthesized complexes are luminescent and were characterized by multinuclear NMR, absorption and emission spectroscopies, photoluminescent quantum yields, time-resolved emission. Two complexes were crystallographically characterized.
Book Synopsis Photoluminescent Materials and Electroluminescent Devices by : Nicola Armaroli
Download or read book Photoluminescent Materials and Electroluminescent Devices written by Nicola Armaroli and published by Springer. This book was released on 2017-05-25 with total page 397 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Book Synopsis Bioorganometallic Chemistry by : Gérard Jaouen
Download or read book Bioorganometallic Chemistry written by Gérard Jaouen and published by John Wiley & Sons. This book was released on 2014-11-13 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: An up-to-date reference reflecting the significant advances and important breakthroughs made in this emerging discipline over the last decade. As such, the book provides an overview of the latest developments and future trends in the field, focusing on such applications as the development of potentially active organometallic drugs against incurable diseases, as well as in such areas as catalysis, energy, analytical chemistry, and imaging. The renowned editor, who established the term "bioorganometallics", and his international team of experts have put together a valuable resource for researchers in organometallic, inorganic, medicinal, and biochemistry.
Book Synopsis Electrogenerated Chemiluminescence by : Allen J. Bard
Download or read book Electrogenerated Chemiluminescence written by Allen J. Bard and published by CRC Press. This book was released on 2004-07-20 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first source on this expanding analytical science, this reference explores advances in the instrumentation, design, and application of techniques with electrogenerated chemiluminescence (ECL), examining the use and impact of ECL-based assays in clinical diagnostics, life science research, environmental testing, food and water evaluation, and th
Book Synopsis Advances in Organometallic Chemistry by :
Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 2019-05-04 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Organometallic Chemistry, Volume 71, contains authoritative review articles on researchers in the field of organometallic chemistry. This longstanding serial is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications. New chapters cover Titanium in Catalysis: Applications in Amine and N-Heterocycle Synthesis, Gold-alkynyl complexes for biomedical applications, Catalytic Nonreductive Valorization of Carbon Dioxide into Fine Chemicals, Transition-metal catalyzed CO2 hydrogenation in the presence of ionic liquids, and much more. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on the latest developments in the field Carefully edited to provide easy-to-read material
Book Synopsis Photoluminescent Iridium(III), Platinum(II) and Gold(I) Complexes Containing Bis-N-heterocyclic Carbene And/or 2-acetylbenzo[b]thiophen-3-olate Ligands and Their Applications in Photo-catalysis and Materials Science by : 杨琛
Download or read book Photoluminescent Iridium(III), Platinum(II) and Gold(I) Complexes Containing Bis-N-heterocyclic Carbene And/or 2-acetylbenzo[b]thiophen-3-olate Ligands and Their Applications in Photo-catalysis and Materials Science written by 杨琛 and published by . This book was released on 2017 with total page 287 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis N-Heterocyclic Carbenes in Synthesis by : Steven P. Nolan
Download or read book N-Heterocyclic Carbenes in Synthesis written by Steven P. Nolan and published by John Wiley & Sons. This book was released on 2006-10-27 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first handbook to focus solely on the application of N-heterocyclic carbenes in synthesis covers metathesis, organocatalysis, oxidation and asymmetric reactions, along with experimental procedures. Written by leading international experts this is a valuable and practical source for every organic chemist.
Book Synopsis Synthesis of N-heterocyclic Carbene Gold(I) Complexes by : Luca Boselli
Download or read book Synthesis of N-heterocyclic Carbene Gold(I) Complexes written by Luca Boselli and published by . This book was released on 2014 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomedical applications of gold complexes based on N-heterocyclic carbenes (NHCs) are beginning to unfold. Some cationic gold(I) NHCs complexes show antimitochondrial activities, a very promising action mode in the fight against cancer; due to their positive charge these complexes target preferentially tumor cells, leading to cell death. In this work of thesis, three groups of new NHC-based gold and heterobimetallic complexes involving aliphatic or aromatic amino-functionalized NHCs with interesting potential in biomedical research have been synthesized and characterized. The first group is formed by three luminescent heterobimetallic gold(I)-ruthenium(II) complexes containing heteroditopic bipyridine-NHC ligands. These compounds have been biologically investigated by in vitro tests for their antitumoral, antileishmanial and antimalarial activities. Finally, imaging studies in cancer cells have been performed exploiting the luminescent properties of the most active compound. The second group of molecules is concerned by cationic gold(I) complexes containing two 1-[2-(diethylamino)ethyl]imidazolydene ligands. First the complexes have been tested for their antiproliferative activity in prostate cancer cell line PC-3. Lipophilicity (Log P) has been determined for these complexes. The most active complex has been tested for the cytotoxic activities in five human cancer cell lines and primary endothelial cells demonstrating a potent action and selectivity for cancer cells. In addition, antileishmanial and antimalarial activities of these compounds have been investigated showing interesting results. The third group is formed by a hetero-dinuclear gold(I)-silver(I) and a trinuclear gold(I)-copper(II) complexes containing phenanthroline-NHC ligands. The compounds are formed by two different organometallic units potentially able to act as multi-targeting anticancer drug.
Book Synopsis Iridium(III) in Optoelectronic and Photonics Applications by : Eli Zysman-Colman
Download or read book Iridium(III) in Optoelectronic and Photonics Applications written by Eli Zysman-Colman and published by John Wiley & Sons. This book was released on 2017-03-07 with total page 736 pages. Available in PDF, EPUB and Kindle. Book excerpt: The fundamental photophysical properties of iridium(III) materials make this class of materials the pre-eminent transition metal complex for use in optoelectronic applications. Iridium(III) in Optoelectronic and Photonics Applications represents the definitive account of photoactive iridium complexes and their use across a wide variety of applications. This two-volume set begins with an overview of the synthesis of these complexes and discusses their photophysical properties. The text highlights not only mononuclear complexes but also the properties of multinuclear and polymeric iridium-based materials and the assembly of iridium complexes into larger supramolecular architectures such as MOFs and soft materials. Chapters devoted to the use of these iridium-based materials in diverse optoelectronic applications follow, including: electroluminescent devices such as organic light emitting diodes (OLEDs) and light-emitting electrochemical cells (LEECs); electrochemiluminescence (ECL); bioimaging; sensing; light harvesting in the context of solar cell applications; in photoredox catalysis and as components for solar fuels. Although primarily targeting a chemistry audience, the wide applicability of these compounds transcends traditional disciplines, making this text also of use to physicists, materials scientists or biologists who have interests in these areas.
Book Synopsis Cyclometalation Reactions by : Iwao Omae
Download or read book Cyclometalation Reactions written by Iwao Omae and published by Springer Science & Business Media. This book was released on 2014-01-23 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a review of cyclometalation reactions and organometallic intramolecular-coordination five-membered ring products, the most active type of reactions in synthetic organic reactions and their products. Included is the discovery of intramolecular-coordination bonds in cyclometalation reactions and the characteristics of those reactions, as well as the reasons that their five-membered ring compounds are very easily synthesized through such reactions. In addition, the applications of cyclometalation reactions and five-membered ring products, synthetic applications, catalysts, and other products are described. These topics are of special interest for industrial researchers.
Book Synopsis Medicinal Inorganic Chemistry by : Jonathan L. Sessler
Download or read book Medicinal Inorganic Chemistry written by Jonathan L. Sessler and published by . This book was released on 2005 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reviews the current diagnostic and therapeutic uses of metal-containing compounds in medicine, as well as the role of metals in disease.
Book Synopsis Transition Metal and Rare Earth Compounds III by : Hartmut Yersin
Download or read book Transition Metal and Rare Earth Compounds III written by Hartmut Yersin and published by Springer Science & Business Media. This book was released on 2004-11-18 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contribution by numerous experts
Book Synopsis Luminescent and Photoactive Transition Metal Complexes as Biomolecular Probes and Cellular Reagents by : Kenneth Kam-Wing Lo
Download or read book Luminescent and Photoactive Transition Metal Complexes as Biomolecular Probes and Cellular Reagents written by Kenneth Kam-Wing Lo and published by Springer. This book was released on 2015-06-30 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors. Readership: research scientists at universities or in industry, graduate students Special offer For all customers who have a standing order to the print version of Structure and Bonding, we offer free access to the electronic volumes of the Series published in the current year via SpringerLink.
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