Author :
Publisher :
ISBN 13 :
Total Pages : 7 pages
Book Rating : 4.:/5 (682 download)
Book Synopsis Low Temperature Absorption Spectra and Ground State Electronic Structure of Tetrakis(2,6-di-tert-butylphenoxide)uranium(IV). by :
Download or read book Low Temperature Absorption Spectra and Ground State Electronic Structure of Tetrakis(2,6-di-tert-butylphenoxide)uranium(IV). written by and published by . This book was released on 1993 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt: The optical spectroscopy of the homoleptic U(IV) aryloxide compound U(O-2,6-t-Bu2C6H3)4 could give unique insight into actinide electronic structure because the complex has unusually high symmetry. Its synthesis and characterization were described in a recent paper. The characterization included presentation of several optical spectra in solution accompanied by a brief, qualitative discussion of the molecular properties that give rise to the observed features. This paper presents optical absorption data on microcrystalline solid samples at low temperature. Discussion of the data focuses generally on effect of the ligands on 5f2 electronic configuration of central U(IV) ion and specifically on properties of the ground state and the lowest lying electronic state.
