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Author : John Ioannis Sachinidis
Publisher :
ISBN 13 :
Total Pages : 316 pages
Book Rating : 4.:/5 (222 download)
Download or read book Ligand Exchange Reactions of Neutral Metal Ion Complexes written by John Ioannis Sachinidis and published by . This book was released on 1981 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Bruce Averill
Publisher :
ISBN 13 : 9780321413703
Total Pages : 1233 pages
Book Rating : 4.4/5 (137 download)
Download or read book Chemistry written by Bruce Averill and published by . This book was released on 2007 with total page 1233 pages. Available in PDF, EPUB and Kindle. Book excerpt: Emphasises on contemporary applications and an intuitive problem-solving approach that helps students discover the exciting potential of chemical science. This book incorporates fresh applications from the three major areas of modern research: materials, environmental chemistry, and biological science.
Author : Y. Marcus
Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 1064 pages
Book Rating : 4.:/5 (318 download)
Download or read book Ion Exchange and Solvent Extraction of Metal Complexes written by Y. Marcus and published by John Wiley & Sons. This book was released on 1969 with total page 1064 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : P.S. Braterman
Publisher : Springer Science & Business Media
ISBN 13 : 1461307554
Total Pages : 419 pages
Book Rating : 4.4/5 (613 download)
Download or read book Reactions of Coordinated Ligands written by P.S. Braterman and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: This, the second and final volume of Reactions of Coordinated Ligands, describes the chemistry of ligands bound through non-carbon atoms, and of coordinated carbon dioxide. As before, emphasis is on the underlying mechanisms, which provide a unity of understanding for superficially disparate processes. The wide range of topics covered illustrates well both the versatility and the usefulness of coordination chemistry in the controlled activation of ligands. Looking to the future, carbon dioxide is the feedstock of last resort. The homogeneous reduction of dinitrogen to ammonia now seems unlikely to replace the Haber process, but solution reactions also lead to more complex, varied, and valuable products. Nitrogen monoxide, a "non innocent" ligand, impinges as pollutant and reagent. Its rich chemistry stems from its linked roles as three-electron donor, and as extremely powerful -acceptor. In the hydrolysis and condensation of complexed amides, esters etc. , metals act both as templates and as tunable and poly functional Lewis acids. Here the control of hydrophobic and steric interactions begins to model the subtle mechanisms of biological specificity. Finally, phosphorus and sulfur are imporant both as ligand atoms in themselves, and as anchors for other functionalities. I would like to thank all those who have been involved in the writing and production of this work, and also my colleagues old and new, at Glasgow and the University of North Texas, for their support. Paul S. Braterman v CONTENTS 1. Reactions of Coordinated Carbon Dioxide 1 J. D. Miller 1.
Author : Fred Basolo
Publisher : World Scientific
ISBN 13 : 9812380876
Total Pages : 654 pages
Book Rating : 4.8/5 (123 download)
Download or read book On Being Well-coordinated written by Fred Basolo and published by World Scientific. This book was released on 2003 with total page 654 pages. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry.Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance.Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature.
![Download The Gas-phase Ligand Exchange of Trivalent Metal [beta]-diketonates PDF Online Free](https://books.google.com/books/content/images/frontcover/-ZPqswEACAAJ?fife=w200-h370)
Author : James Kole Gasior
Publisher :
ISBN 13 :
Total Pages : 400 pages
Book Rating : 4.:/5 (11 download)
Download or read book The Gas-phase Ligand Exchange of Trivalent Metal [beta]-diketonates written by James Kole Gasior and published by . This book was released on 2017 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: The gas-phase ligand exchange reactions incorporating main group and transition metal [beta]-diketonate complexes were investigated using a Finnigan TSQ 7000 triple quadrupole electron impact mass spectrometer. Specifically, trivalent iron and aluminum complexes were reacted with a variety of other metal [beta]-diketonates during mass spectrometric analysis, and the ensuing gas-phase reactions were shown to generate a variety of products. Relative peak heights of parent ions in the resultant cosublimation spectra were compared to the reactants' baseline spectra to discern the relative reactivity of each parent ion, and subsequently, propose reaction mechanisms accounting for the production of mixed ligand products. To attain a more complete understanding of certain gas-phase reactions, tandem mass spectrometry was implemented to study selective reactions between specific parent ions and a neutral gas species. Analysis and interpretation of the resulting spectra allowed for the formulation of specific reaction mechanisms for each product detected. Finally, for the first time, the mechanism of partial ligand exchange was proposed and modeled using the PM3 semiempirical method to elucidate general features thought to be employed during the simultaneous mass analysis of homo-metal [beta]-diketonates.
Author : Cooper Harold Langford
Publisher :
ISBN 13 :
Total Pages : 130 pages
Book Rating : 4.3/5 (91 download)
Download or read book Ligand Substitution Processes written by Cooper Harold Langford and published by . This book was released on 1966 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subject of the mechanistic study of ligand substitution reactions is currently undergoing an exciting growth. New fast-reaction techniques have removed the upper limit on rates that can be measured, and extension to less familiar central metal atoms has begun in earnest. This might seem the wrong moment for review of the field. As yet, definitive treatment is possible only for those complexes involving monodentate ligands with cobalt(III) and platinurn(II). But, because information is so extensive for these systems, it is clear that they are functioning as models from which concepts and experiments are generated for application over the fast-growing range of the subject. We believe that this is an important moment to reopen debate on fundamentals so that concepts will be most felicitously formulated to aid growth of understanding. This monograph is centrally concerned with three aspects of those fundamentals. We have attempted to develop an approach to classification of ligand substitution reactions that is adapted to what seem to have emerged as the characteristic features of these reactions and is susceptible to operational tests. (We do recognize that any such scheme of ideas is necessarily obsolescent once it is formulated since new experiments will certainly follow immediately.) We have tried to evaluate the basis for making generalizations about ligand substitution processes and to formulate tests to show whether new reactions fall within familiar patterns. Finally, we have sought to base the models of ligand substitution processes in the language of molecular-orbital theory. We believe that MO theory is most useful, because it may be used to correlate rate data on complexes with the extensive information available from spectral and magnetic studies, yet differs from crystal-field theory in providing a natural place for consideration of the bonding electrons, which must be a principal determinant of reaction processes. To keep this essay within bounds, we assume familiarity with the elements of experimental kinetics, transition-state theory, and the simple molecular-orbital theory of complexes. Introductory physical chemistry, some familiarity with the study of reaction mechanisms, and mastery of one of the qualitative treatments of MO theory as applied to transition-metal complexes should provide sufficient background. Thus, we hope that this book will be useful to students, relatively early in their careers, who wish to explore this field.
![Download The Examination of the Stability and Reactivity of Select Transition Metal [beta]-diketonate Complexes During Gas-phase Ligand Exchange Reactions PDF Online Free](https://books.google.com/books/content/images/frontcover/uhn7SAAACAAJ?fife=w200-h370)
Author : Gerald O. Hunter (Jr.)
Publisher :
ISBN 13 :
Total Pages : 316 pages
Book Rating : 4.:/5 (527 download)
Download or read book The Examination of the Stability and Reactivity of Select Transition Metal [beta]-diketonate Complexes During Gas-phase Ligand Exchange Reactions written by Gerald O. Hunter (Jr.) and published by . This book was released on 2009 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: Gas-phase ligand exchange reactions between M(acac)2, M(hfac)2, and M(tftm)2 species, where M is Cu(II), Ni(II), Co(II) and/or Zn(II) were observed to occur in a triple quadrupole mass spectrometer. The gas-phase mixed ligand products, namely [M(acac)(hfac)], [M(acac)(tftm)]+ or [M(hfac)(tftm)]+, were formed following the co-sublimation of either homo-metal or hetero-metal precursors. The mixed ligand products of these species were also observed to occur following ion-neutral reactions between the mass-selected fluorinated acetylacetonate precursor ion and the target M(acac)2 neutral. The gas-phase formation of [Cu(acac)(tftm)]+, [Cu(hfac)(tftm)]+, [Ni(acac)(tftm)]+, [Ni(hfac)(tftm)]+, [Co(acac)(tftm)]+, [Co(hfac) tftm)]+, [Zn(acac)(tftm)]+, and [Zn(hfac)(tftm)]+ are reported herein for the first time along with the corresponding fragmentation patterns of these mixed ligand species and those of Cu(tftm)2, Ni(tftm)2, Co(tftm)2 and Zn(tftm)2.
Author : Xue Duan
Publisher : Springer
ISBN 13 : 9783540104940
Total Pages : 204 pages
Book Rating : 4.1/5 (49 download)
Download or read book Metal Complexes written by Xue Duan and published by Springer. This book was released on 1981-03-01 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Friedrich G. Helfferich
Publisher : Courier Corporation
ISBN 13 : 9780486687841
Total Pages : 642 pages
Book Rating : 4.6/5 (878 download)
Download or read book Ion Exchange written by Friedrich G. Helfferich and published by Courier Corporation. This book was released on 1995-01-01 with total page 642 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive text provides sound understanding of the relevant factors in ion exchange and the theoretical tools needed to solve specific problems. Detailed coverage of ion exchangers, equilibria, kinetics, electrochemical properties, ion-exchanger membranes, much more. Each chapter contains helpful summary and references. Accessible to nonmathematical students. Introduction. 1962 edition.
Author : Danilo Corradini
Publisher : CRC Press
ISBN 13 : 9780203909751
Total Pages : 1018 pages
Book Rating : 4.9/5 (97 download)
Download or read book Handbook of HPLC written by Danilo Corradini and published by CRC Press. This book was released on 2011-01-03 with total page 1018 pages. Available in PDF, EPUB and Kindle. Book excerpt: Delineating its usage in separation, purification and detection processes across a variety of disciplines, from industry to applied research, this work discusses the principles, techniques and instrumentation involving HPLC within a detailed framework. Over 100 tables present previously scattered experimental data.
Author : B.S. Freiser
Publisher : Springer Science & Business Media
ISBN 13 : 9400901119
Total Pages : 341 pages
Book Rating : 4.4/5 (9 download)
Download or read book Organometallic Ion Chemistry written by B.S. Freiser and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: A study covering the gas-phase chemistry of organometallic ions. Topics covered include: periodic trends in gas-phase thermochemistry of transition metal-ligand systems; ab initio calculations to determine electronic structure, geometric structure, and thermochemistry of metal-containing systems; electronic state effects on metal ion reactivity; organometallic ion photochemistry; and applications of gas-phase electron transfer equilibria in organometallic redox thermochemistry. Also included are state-of-the-art mass spectrometric instrumentation used in such studies. It also features a comprehensive list (containing over 1500 entries) of metal ion-ligand bond energies, obtained from theory and experiment.
Author : Mandeep Dalal
Publisher : Dalal Institute
ISBN 13 : 8193872002
Total Pages : 480 pages
Book Rating : 4.1/5 (938 download)
Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author : Edwin C. Constable
Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 332 pages
Book Rating : 4.3/5 (91 download)
Download or read book Metals and Ligand Reactivity written by Edwin C. Constable and published by Wiley-VCH. This book was released on 1996-01-18 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: Edwin C. Constable Metals and Ligand Reactivity An Introduction to the Organic Chemistry of Metal Complexes New, revised and expanded edition This book is a highly readable introduction to the reactions of coordinated ligands, which have become a useful tool in organic synthesis. Bridging the gap between the traditional fields, this text presents the basic concepts of ligand reactivity as well as synthetic applications of these reactions. Topics covered include Principles of metal-ligand interaction Reactions of coordinated ligands with nucleophiles and electrophiles Oxidation and reduction of coordinated ligands Cyclic and encapsulating ligands, template effects and supramolecular chemistry Carefully selected examples, lucidly designed figures and schemes as well as numerous study problems make this book an ideal guide for students and practitioners of organic synthesis. References to further reading are also included.
Author : Christopher Talbot
Publisher : Hodder Education
ISBN 13 : 1471899527
Total Pages : 499 pages
Book Rating : 4.4/5 (718 download)
Download or read book Chemistry for the IB Diploma Study and Revision Guide written by Christopher Talbot and published by Hodder Education. This book was released on 2017-07-24 with total page 499 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exam Board: IB Level: IB Subject: Chemistry First Teaching: September 2014 First Exam: Summer 2016 Stretch your students to achieve their best grade with these year round course companions; providing clear and concise explanations of all syllabus requirements and topics, and practice questions to support and strengthen learning. - Consolidate revision and support learning with a range of exam practice questions and concise and accessible revision notes - Practise exam technique with tips and trusted guidance from examiners on how to tackle questions - Focus revision with key terms and definitions listed for each topic/sub topic
Author : Otilia Costisor
Publisher : World Scientific
ISBN 13 : 9789812794819
Total Pages : 316 pages
Book Rating : 4.7/5 (948 download)
Download or read book Metal Mediated Template Synthesis of Ligands written by Otilia Costisor and published by World Scientific. This book was released on 2004 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role of the metal ions and the specific properties of the formed complexes. Metal Mediated Template Synthesis of Ligands offers a comprehensive analysis with wide-ranging references and provides an extensive overview of research on metal-directed organic ligands over the past five decades. Contents: The Template Effect; Alkylation Reactions; Schiff Condensation; Mannich Condensation; Self Condensation of Nitriles; Self-Assembled Systems. Readership: Upper level undergraduates, graduate students, academics, researchers industrialists in inorganic, solid-state, supramolecular and organic chemistry.
Author : C.H. Bamford
Publisher : Elsevier
ISBN 13 : 0080868029
Total Pages : 614 pages
Book Rating : 4.0/5 (88 download)
Download or read book Reactions of Metallic Salts and Complexes, and Organometallic Compounds written by C.H. Bamford and published by Elsevier. This book was released on 1972-01-01 with total page 614 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactions of Metallic Salts and Complexes, and Organometallic Compounds
