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Ligand Exchange And Substitution On Five Coordinate Complexes Of Copper Ii Nickel Ii And Cobalt Ii
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Book Synopsis Ligand Exchange and Substitution on Five-coordinate Complexes of Copper (II), Nickel (II) and Cobalt (II) by : Bruce Germein Doddridge
Download or read book Ligand Exchange and Substitution on Five-coordinate Complexes of Copper (II), Nickel (II) and Cobalt (II) written by Bruce Germein Doddridge and published by . This book was released on 1986 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Study of Ligand Substitution Reactions in the Five Coordinate Complexes, [Cu (TREN)OH2]2+ [Cu (Me6 TREN)OH2]2+ and [Cu (Me6 TREN)OH] +. by : Peter Ralph Collins
Download or read book A Study of Ligand Substitution Reactions in the Five Coordinate Complexes, [Cu (TREN)OH2]2+ [Cu (Me6 TREN)OH2]2+ and [Cu (Me6 TREN)OH] +. written by Peter Ralph Collins and published by . This book was released on 1979 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Ligand Substitution Processes by : Cooper Harold Langford
Download or read book Ligand Substitution Processes written by Cooper Harold Langford and published by . This book was released on 1966 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subject of the mechanistic study of ligand substitution reactions is currently undergoing an exciting growth. New fast-reaction techniques have removed the upper limit on rates that can be measured, and extension to less familiar central metal atoms has begun in earnest. This might seem the wrong moment for review of the field. As yet, definitive treatment is possible only for those complexes involving monodentate ligands with cobalt(III) and platinurn(II). But, because information is so extensive for these systems, it is clear that they are functioning as models from which concepts and experiments are generated for application over the fast-growing range of the subject. We believe that this is an important moment to reopen debate on fundamentals so that concepts will be most felicitously formulated to aid growth of understanding. This monograph is centrally concerned with three aspects of those fundamentals. We have attempted to develop an approach to classification of ligand substitution reactions that is adapted to what seem to have emerged as the characteristic features of these reactions and is susceptible to operational tests. (We do recognize that any such scheme of ideas is necessarily obsolescent once it is formulated since new experiments will certainly follow immediately.) We have tried to evaluate the basis for making generalizations about ligand substitution processes and to formulate tests to show whether new reactions fall within familiar patterns. Finally, we have sought to base the models of ligand substitution processes in the language of molecular-orbital theory. We believe that MO theory is most useful, because it may be used to correlate rate data on complexes with the extensive information available from spectral and magnetic studies, yet differs from crystal-field theory in providing a natural place for consideration of the bonding electrons, which must be a principal determinant of reaction processes. To keep this essay within bounds, we assume familiarity with the elements of experimental kinetics, transition-state theory, and the simple molecular-orbital theory of complexes. Introductory physical chemistry, some familiarity with the study of reaction mechanisms, and mastery of one of the qualitative treatments of MO theory as applied to transition-metal complexes should provide sufficient background. Thus, we hope that this book will be useful to students, relatively early in their careers, who wish to explore this field.
Book Synopsis Coordination Chemistry of Macrocyclic Compounds by : Gordon Melson
Download or read book Coordination Chemistry of Macrocyclic Compounds written by Gordon Melson and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 676 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemists have been aware of the existence of coordination compounds con taining organic macrocyclic ligands since the first part of this century ; however, only during the past few years have they expanded research into the chemistry of these compounds. The expansion was initiated in the early 1960s by the synthesis and characterization of compounds containing some new macrocyclic ligands. The synthesis of compounds which may serve as model systems for some natural products containing large rings as ligands provided the main goal for the early expansion of research effort; indeed, a recurrent theme behind much of the reported chemistry has been the analogy between synthetic macrocyclic compounds and many natural-product systems. More recently, the emphases of reported research have ranged over the whole spectrum of chemistry, and the number of publications that discuss macrocyclic chemistry has increased at a dramatic rate. The completed research has been reported in a variety of journals throughout the world but there has been no previous attempt to bring the major developments together under one cover. This book, therefore, attempts to satisfy the need for a single source in which there is both a collection and a correlation of information concerning the coordination chemistry of macrocyclic compounds. The chapters in this book discuss various aspects of macrocyclic chemistry, and while these chapters as a whole constitute an in-depth survey of the state-of the-art of the field, each chapter is written as a complete unit.
Book Synopsis Mechanisms of Inorganic and Organometallic Reactions by : M.V. Twigg
Download or read book Mechanisms of Inorganic and Organometallic Reactions written by M.V. Twigg and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt: This series provides a continuing critical review of the literature concerned with mechanistic aspects of inorganic and organometallic reactions in solu tion, with coverage over the whole area being complete in each volume. The format of this second volume is very similar to that of the first, with material arranged according to reaction type and compound type along generally accepted lines. Papers discussed are selected on the basis of relevance to the elucidation of reaction mechanisms but may also include results of a nonkinetic nature, such as stereochemical studies and product ratios, when useful mechanistic information can be deduced. In this volume extra space has been given to areas concerned with electron transfer processes and substitution reactions of inert complexes, and to improve convenience for the reader the text has been further divided to form three additional chapters. Electron transfer processes are discussed in three chapters: "General and Theoretical," "Reactions between Two Complexes," and "Metal-Ligand Redox Reactions," while six chapters are concerned with substitution and related reactions. Here reactions of inert chromium and cobalt complexes are discussed in separate chapters. The period of literature coverage is January 1981 through June 1982 inclusive and in a few instances, where delays in delivery of journals have been encountered, the issues not covered will be included in the next volume.
Book Synopsis Mechanisms of Reactions of Metal Complexes by : Debabrata Banerjea
Download or read book Mechanisms of Reactions of Metal Complexes written by Debabrata Banerjea and published by Royal Society of Chemistry. This book was released on 2022-09-21 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reaction Mechanisms of Metal Complexes in Solution provides a comprehensive overview of an often-overlooked research area. Despite its importance and recent reshaping of the field, many inorganic chemists have lost an appreciation for the significance of stability constants and the thermodynamic aspects of complex formation. Ideal for newcomers and established researchers in the field this book is a complete treatment of the area covering advanced topics with relevance to biomedical applications, extraction metallurgy, food chemistry and a wealth of other industrial processes and research areas. The book will be of particular interest to postgraduates with an interest in coordination chemistry, catalysis, supramolecular chemistry, metallobiology and related aspects of biochemistry.
Book Synopsis An Investigation of the Distorted Geometries of Copper(II), Nickel(II), and Cobalt(II) Complexes Induced by 1,3-Bis(pyridylimino)isoindoline Derivatives by : Amanda Courtney Robinson
Download or read book An Investigation of the Distorted Geometries of Copper(II), Nickel(II), and Cobalt(II) Complexes Induced by 1,3-Bis(pyridylimino)isoindoline Derivatives written by Amanda Courtney Robinson and published by . This book was released on 2019 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomimetic properties of copper, nickel, and cobalt coordination compounds have been studied extensively as these metals are found in the active sites of numerous proteins. Coordinating ligands with nitrogen donor atoms are especially of interest because nitrogen is also extremely common at these active sites. By changing the structure of the ligand, the complexes can be modified to mimic a wide array of enzymes. Studying these complexes has led researchers to propose mechanisms for many enzymes. In this work, tridentate ligands with nitrogen donor atoms were complexed with Cu(II), Ni(II), and Co(II) to form tetracoordinate and pentacoordinate systems. Syntheses and characterizations will be presented including X-ray crystallographic data, electron spin resonance, and electronic absorption data. [phi]t, [omega], and [tau] parameters will be given to describe the distorted geometries of the metal-ligand complexes.
Book Synopsis Mechanisms of Inorganic and Organometallic Reactions Volume 7 by : M.V. Twigg
Download or read book Mechanisms of Inorganic and Organometallic Reactions Volume 7 written by M.V. Twigg and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of Mechanisms of Inorganic and Organometallic Reactions is to provide an ongoing critical review of the literature concerned with the mechanisms of reactions of inorganic and organometallic compounds. The main focus is on reactions in solution, although solid state and gas phase studies are included where they provide relevant mechanistic insight. Each volume covers an eighteen month literature period, and this, the seventh volume in the series, deals with papers published during July 1988 through December 1989. Where appropriate, there are references to earlier work, and also to specific sections in previous volumes. Coverage continues to span the whole area as comprehensively as possible in each volume, and although it is impossible be absolutely complete, every effort is made to include all the important for it to published work that is relevant to the elucidation of reaction mechanisms. Numerical data are reported in the units used by the original authors, and they are only converted to common units when making comparisons. The basic format of earlier volumes is retained to facilitate tracing progress over several years in a particular topic; this can now be done for more than a decade worth of research. In the last volume, ligand reactivity of both coordination and organometallic compounds were brought together in Chapter 12, and, in response to numerous positive comments from readers, this arrangement has been maintained. There have been some similar suggestions about oscillating reactions, and this topic may have a separate section in the next volume.
Book Synopsis Ligand Exchange Chromatography by : Vadim A. Davankov
Download or read book Ligand Exchange Chromatography written by Vadim A. Davankov and published by CRC Press. This book was released on 2018-01-18 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a systematic and comprehensive review of the information on chromatographic processes that involve the formation of coordination compounds, aiming not only to demonstrate the achievements that have been made in the theory of praxis of chromatography, but also to point out, as far as possible, the future of potential of ligand exchange chromatography.
Book Synopsis Inorganic Chemistry by : Egon Wiberg
Download or read book Inorganic Chemistry written by Egon Wiberg and published by Academic Press. This book was released on 2001 with total page 1958 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Research and Development Abstracts of the USAEC by : U.S. Atomic Energy Commission. Division of Technical Information
Download or read book Research and Development Abstracts of the USAEC written by U.S. Atomic Energy Commission. Division of Technical Information and published by . This book was released on 1963 with total page 626 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Research and Development Abstracts of the USAEC by : U.S. Atomic Energy Commission
Download or read book Research and Development Abstracts of the USAEC written by U.S. Atomic Energy Commission and published by . This book was released on 1963 with total page 144 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Inorganic Reaction Mechanisms by : A McAuley
Download or read book Inorganic Reaction Mechanisms written by A McAuley and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 418 pages. Available in PDF, EPUB and Kindle. Book excerpt: Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Download or read book Cumulated Index Medicus written by and published by . This book was released on 1975 with total page 1352 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis American Doctoral Dissertations by :
Download or read book American Doctoral Dissertations written by and published by . This book was released on 1978 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Study of the Copper (II) and Nickel (II) Complexes of Some 5-substituted Tetrazoles by : Ned Arthur Daugherty
Download or read book A Study of the Copper (II) and Nickel (II) Complexes of Some 5-substituted Tetrazoles written by Ned Arthur Daugherty and published by . This book was released on 1961 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Bibliography of Mass Spectroscopy Literature for 1970 by :
Download or read book Bibliography of Mass Spectroscopy Literature for 1970 written by and published by . This book was released on 1972 with total page 900 pages. Available in PDF, EPUB and Kindle. Book excerpt:
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