Leaching Behavior of Nuclear Waste Glasses Under Laboratory Simulated Repository Conditions

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ISBN 13 :
Total Pages : 246 pages
Book Rating : 4.:/5 (12 download)

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Book Synopsis Leaching Behavior of Nuclear Waste Glasses Under Laboratory Simulated Repository Conditions by : Rajani Adiga

Download or read book Leaching Behavior of Nuclear Waste Glasses Under Laboratory Simulated Repository Conditions written by Rajani Adiga and published by . This book was released on 1984 with total page 246 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Leaching Savannah River Plant Nuclear Waste Glass in a Saturated Tuff Environment

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (11 download)

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Book Synopsis Leaching Savannah River Plant Nuclear Waste Glass in a Saturated Tuff Environment by : Ned Eugene Bibler

Download or read book Leaching Savannah River Plant Nuclear Waste Glass in a Saturated Tuff Environment written by Ned Eugene Bibler and published by . This book was released on 1984 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Samples of SRP glass containing either simulated or actual radioactive waste were leached at 90°C under conditions simulating a saturated tuff repository environment. The leach vessels were fabricated of tuff and actual tuff groundwater was used. Thus, the glass was leached only in the presence of those materials (including the Type 304L stainless steel canister material) that would be in the actual repository. Tests were performed for time periods up t 6 months at a SA/V ratio of 100 m−1. Results with glass containing simulated waste indicated that stainless steel canister material around the glass did not significantly affect the leaching. Based on Li and B (elements not in significant concentrations in the tuff or tuff groundwater), glass containing simulated waste leached identically to glass containing actual radioactive waste. The tuff buffered the pH so that only a slight increase was observed as a result of leaching. Results with glass containing actual radioactive waste indicated that tuff reduced the concentrations of Cs-137, Sr-90, and Pu-238 in the free groundwater in the simulated repository by 10 to 100X. Also, radiolysis of the groundwater by the glass (approximately 1000 rad/h) did not significantly affect the pH in the presence of tuff. Measured normalized mass losses in the presence of tuff for the glass based on Cs-137, Sr-90, and Pu-238 in the free groundwater were extremely low, nominally 0.02, 0.02, and 0.005 g/m2, respectively, indicating that the glass-tuff system retained radionuclides well.

Nuclear Waste Glass Leaching in a Simulated Granite Repository

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ISBN 13 :
Total Pages : 424 pages
Book Rating : 4.:/5 (169 download)

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Book Synopsis Nuclear Waste Glass Leaching in a Simulated Granite Repository by : BingFu Zhu

Download or read book Nuclear Waste Glass Leaching in a Simulated Granite Repository written by BingFu Zhu and published by . This book was released on 1987 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Measurement of Leaching from Simulated Nuclear-waste Glass Using Radiotracers

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ISBN 13 :
Total Pages : pages
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Book Synopsis Measurement of Leaching from Simulated Nuclear-waste Glass Using Radiotracers by :

Download or read book Measurement of Leaching from Simulated Nuclear-waste Glass Using Radiotracers written by and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of radiotracer spiking as a method of measuring the leaching from simulated nuclear-waste glass is shown to give results comparable with other analytical detection methods. The leaching behavior of 85Sr, 1°6Ru, 133Ba, 137Cs, 141Ce, 152Eu, and other isotopes is measured for several defense waste glasses. These tests show that radiotracer spiking is a sensitive, multielement technique that can provide leaching data, for actual waste elements, that are difficult to obtain by other methods. Additionally, a detailed procedure is described that allows spiked glass to be prepared with a suitable distribution of radionuclides.

Leaching Behavior of Glass Ceramic Nuclear Waste Forms

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (873 download)

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Book Synopsis Leaching Behavior of Glass Ceramic Nuclear Waste Forms by :

Download or read book Leaching Behavior of Glass Ceramic Nuclear Waste Forms written by and published by . This book was released on 1981 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Glass ceramic waste forms have been investigated as alternatives to borosilicate glasses for the immobilization of high-level radioactive waste at Pacific Northwest Laboratory (PNL). Three glass ceramic systems were investigated, including basalt, celsian, and fresnoite, each containing 20 wt % simulated high-level waste calcine. Static leach tests were performed on seven glass ceramic materials and one parent glass (before recrystallization). Samples were leached at 90°C for 3 to 28 days in deionized water and silicate water. The results, expressed in normalized elemental mass loss, (g/m2), show comparable releases from celsian and fresnoite glass ceramics. Basalt glass ceramics demonstrated the lowest normalized elemental losses with a nominal release less than 2 g/m2 when leached in polypropylene containers. The releases from basalt glass ceramics when leached in silicate water were nearly identical with those in deionized water. The overall leachability of celsian and fresnoite glass ceramics was improved when silicate water was used as the leachant.

Leaching Savannah River Plant Nuclear Waste Glass in a Saturated Tuff Environment

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ISBN 13 :
Total Pages : 19 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Leaching Savannah River Plant Nuclear Waste Glass in a Saturated Tuff Environment by :

Download or read book Leaching Savannah River Plant Nuclear Waste Glass in a Saturated Tuff Environment written by and published by . This book was released on 1984 with total page 19 pages. Available in PDF, EPUB and Kindle. Book excerpt: Samples of SRP glass containing either simulated or actual radioactive waste were leached at 90°C under conditions simulating a saturated tuff repository environment. The leach vessels were fabricated of tuff and actual tuff groundwater was used. Thus, the glass was leached only in the presence of those materials (including the Type 304L stainless steel canister material) that would be in the actual repository. Tests were performed for time periods up t 6 months at a SA/V ratio of 100 m−1. Results with glass containing simulated waste indicated that stainless steel canister material around the glass did not significantly affect the leaching. Based on Li and B (elements not in significant concentrations in the tuff or tuff groundwater), glass containing simulated waste leached identically to glass containing actual radioactive waste. The tuff buffered the pH so that only a slight increase was observed as a result of leaching. Results with glass containing actual radioactive waste indicated that tuff reduced the concentrations of Cs-137, Sr-90, and Pu-238 in the free groundwater in the simulated repository by 10 to 100X. Also, radiolysis of the groundwater by the glass (approximately 1000 rad/h) did not significantly affect the pH in the presence of tuff. Measured normalized mass losses in the presence of tuff for the glass based on Cs-137, Sr-90, and Pu-238 in the free groundwater were extremely low, nominally 0.02, 0.02, and 0.005 g/m2, respectively, indicating that the glass-tuff system retained radionuclides well. 9 references, 2 figures, 3 tables.

Initial Comparison of Leach Behavior Between Fully Radioactive and Simulated Nuclear Waste Glass Through Long-term Testing

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ISBN 13 :
Total Pages : 15 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Initial Comparison of Leach Behavior Between Fully Radioactive and Simulated Nuclear Waste Glass Through Long-term Testing by :

Download or read book Initial Comparison of Leach Behavior Between Fully Radioactive and Simulated Nuclear Waste Glass Through Long-term Testing written by and published by . This book was released on 1992 with total page 15 pages. Available in PDF, EPUB and Kindle. Book excerpt: An initial comparison of glass behavior of simulated nuclear waste glasses has been made through long-term testing of general glass types SRL165, SRL131 and SRL200. The data demonstrate that up to 560 days at S/V of 2000/m, the reacted layers consist of one outer clay layer, which is undetermined by discontinuous etch pits. The regions between the etch pits are alkali depleted. The surface layer becomes thicker as test duration progresses and the reacted layer after the same test time is thinner at higher S/V than at lower S/V. The relative glass durability measured by the thickness of the reacted layer is 165/42S> 131/11S> 200S, which is consistent with solution analyses. In general, the reacted layers on all glass compositions are poorly crystallized which makes the clay identification difficult. The diffraction spacings and EDS compositions for 131/11S and 200S, although not unique to, are consistent with Na (or Ca- ) montmorillonite or nontronite. Both of these are dioctahedral smectite.

Long-term Leaching Behavior of Simulated Savannah River Plant Waste Glass

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (26 download)

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Book Synopsis Long-term Leaching Behavior of Simulated Savannah River Plant Waste Glass by : G. G. Wicks

Download or read book Long-term Leaching Behavior of Simulated Savannah River Plant Waste Glass written by G. G. Wicks and published by . This book was released on 1986 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Masters Theses in the Pure and Applied Sciences

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Publisher : Springer Science & Business Media
ISBN 13 : 1468451979
Total Pages : 407 pages
Book Rating : 4.4/5 (684 download)

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Book Synopsis Masters Theses in the Pure and Applied Sciences by : Wade H. Shafer

Download or read book Masters Theses in the Pure and Applied Sciences written by Wade H. Shafer and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: Masters Theses in the Pure and Applied Sciences was first conceived, published, and disseminated by the Center for Information and Numerical Data Analysis and Synthesis (CINDAS) * at Purdue University in 1 957, starting its coverage of theses with the academic year 1955. Beginning with Volume 13, the printing and dissemination phases of the activity were transferred to University Microfilms/Xerox of Ann Arbor, Michigan, with the thought that such an arrangement would be more beneficial to the academic and general scientific and technical community. After five years of this joint undertaking we had concluded that it was in the interest of all con cerned if the printing and distribution of the volumes were handled by an interna tional publishing house to assure improved service and broader dissemination. Hence, starting with Volume 18, Masters Theses in the Pure and Applied Sciences has been disseminated on a worldwide basis by Plenum Publishing Cor poration of New York, and in the same year the coverage was broadened to include Canadian universities. All back issues can also be ordered from Plenum. We have reported in Volume 29 (thesis year 1984) a total of 12,637 theses titles from 23 Canadian and 202 United States universities. We are sure that this broader base for these titles reported will greatly enhance the value of this important annual reference work. While Volume 29 reports theses submitted in 1984, on occasion, certain univer sities do report theses submitted in previous years but not reported at the time.

Initial Comparison of Leach Behavior Between Fully Radioactive and Simulated Nuclear Waste Glasses Through Long-term Testing

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ISBN 13 :
Total Pages : 10 pages
Book Rating : 4.:/5 (929 download)

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Book Synopsis Initial Comparison of Leach Behavior Between Fully Radioactive and Simulated Nuclear Waste Glasses Through Long-term Testing by :

Download or read book Initial Comparison of Leach Behavior Between Fully Radioactive and Simulated Nuclear Waste Glasses Through Long-term Testing written by and published by . This book was released on 1992 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Optimization of High-level Waste Loading in a Borosilicate Glass Matrix by Using Chemical Durability Modeling Approach

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ISBN 13 :
Total Pages : pages
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Book Synopsis Optimization of High-level Waste Loading in a Borosilicate Glass Matrix by Using Chemical Durability Modeling Approach by : Javeed Mohammad

Download or read book Optimization of High-level Waste Loading in a Borosilicate Glass Matrix by Using Chemical Durability Modeling Approach written by Javeed Mohammad and published by . This book was released on 2002 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A laboratory scale study was carried out on a set of 6 borosilicate waste glasses made from simulated high-level nuclear waste. The test matrix was designed to explore the composition region suitable for the long-term geologic disposal of high-temperature-and high-waste-containing glasses. The glass compositions were selected to achieve maximum waste loading without a sacrifice in glass durability. The relationship between glass composition and chemical durability was examined. The qualitative effect of increasing B2O3 content on the overall waste glass leaching behavior has also been addressed. The glass composition matrix was designed by systematically varying the factors: %waste loading and (SiO2+Frit):B2O3 ratio, with (SiO2:Frit) ratio being held constant. In order to assess the chemical durability, the Product Consistency Test (ASTM C-1285) was performed. Under PCT protocol, crushed glass was allowed to react with ASTM type I water under static conditions. All leachate solutions were analyzed by the technique; Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES). A statistical regression technique was utilized to model the normalized release of the major soluble elements, Na, Si, and B, as a function of the individual as well as interactive chemical effects (B2O3, Al2O3, Fe2O3, MnO, SiO2, SrO, Na2O, B2O3*SiO2, B2O3*Al2O3, Fe2O3*Na2O, Al2O3*Na2O, and MnO*SiO2). Geochemical modeling was performed using the computer code EQ3/6 to: (1) determine the saturation states of the possible silicate minerals, a-cristobalite and chalcedony; and (2) predict the most stable mineral phase based on the mineral thermodynamic data. Mineral/water interactions were analyzed by representing the resultant glass data on a Na-Al-Si-O-H stability diagram.

Radioactive Waste Management

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ISBN 13 :
Total Pages : 630 pages
Book Rating : 4.X/5 (1 download)

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Book Synopsis Radioactive Waste Management by :

Download or read book Radioactive Waste Management written by and published by . This book was released on 1981 with total page 630 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Energy Research Abstracts

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ISBN 13 :
Total Pages : 754 pages
Book Rating : 4.3/5 (129 download)

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Book Synopsis Energy Research Abstracts by :

Download or read book Energy Research Abstracts written by and published by . This book was released on 1993 with total page 754 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Glass as a Waste Form and Vitrification Technology

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Publisher : National Academies Press
ISBN 13 : 0309056829
Total Pages : 172 pages
Book Rating : 4.3/5 (9 download)

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Book Synopsis Glass as a Waste Form and Vitrification Technology by : National Research Council

Download or read book Glass as a Waste Form and Vitrification Technology written by National Research Council and published by National Academies Press. This book was released on 1997-03-02 with total page 172 pages. Available in PDF, EPUB and Kindle. Book excerpt:

NRC Nuclear Waste Geochemistry '83

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ISBN 13 :
Total Pages : 568 pages
Book Rating : 4.3/5 (243 download)

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Book Synopsis NRC Nuclear Waste Geochemistry '83 by : Donald H. Alexander

Download or read book NRC Nuclear Waste Geochemistry '83 written by Donald H. Alexander and published by . This book was released on 1984 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Leaching of Actinide-doped Nuclear Waste Glass in a Tuff-dominated System

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ISBN 13 :
Total Pages : 14 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Leaching of Actinide-doped Nuclear Waste Glass in a Tuff-dominated System by :

Download or read book Leaching of Actinide-doped Nuclear Waste Glass in a Tuff-dominated System written by and published by . This book was released on 1987 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt: A laboratory leaching test has been performed as part of a project to evaluate the suitability of tuff rocks at Yucca Mountain, Nevada, as a site for a high-level nuclear waste repository. Glass samples were placed in water inside tuff vessels, and then the tuff vessels were placed in water inside Teflon containers. Glass-component leach rates and migration through the tuff were measured for samples of the ATM-8 actinide glass, which is a PNL 76-68 based glass doped with low levels of 99Tc, 237Np, 238U, and 239Pu to simulate wastes. Disc samples of this glass were leached at 90°C for 30, 90, and 183 days inside tuff vessels using a natural groundwater (J-13 well-water) as the leachant. At the end of each leaching interval, the J-13 water present inside and outside the rock vessel was analyzed for glass components in solutions. Boron, molybdenum, and technetium appear to migrate through the rock at rates that depend on the porosity of each vessel and the time. The actinide elements were found only in the inner leachate. Normalized elemental mass loss values for boron, molybdenum, and technetium were calculated using concentrations of the inner and outer leachates and assuming a negligible retention on the rock. The maximum normalized release was 2.3 g/m2 for technetium. Boron, molybdenum, technetium, and neptunium were released linearly with respect to each other, with boron and molybdenum released at about 85% of the technetium rate, and neptunium at 5 to 10% of the technetium rate. Plutonium was found at low levels in the inner leachate but was strongly sorbed on the steel and Teflon supports. Neptunium was sorbed to a lesser extent. 8 refs., 6 figs., 6 tabs.

Envoi à feu Ferry

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (46 download)

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Download or read book Envoi à feu Ferry written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: