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Author :
Publisher :
ISBN 13 :
Total Pages : 36 pages
Book Rating : 4.:/5 (227 download)
Download or read book KINETICS OF RAPID GAS PHASE REACTIONS. THE ADDITION OF LEWIS ACIDS TO BASES. written by and published by . This book was released on 1963 with total page 36 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Defense Documentation Center (U.S.)
Publisher :
ISBN 13 :
Total Pages : 1148 pages
Book Rating : 4.:/5 (5 download)
Download or read book Technical Abstract Bulletin written by Defense Documentation Center (U.S.) and published by . This book was released on 1964 with total page 1148 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : James Alistair Kerr
Publisher :
ISBN 13 :
Total Pages : 400 pages
Book Rating : 4.F/5 ( download)
Download or read book Evaluated Kinetic Data on Gas Phase Addition Reactions written by James Alistair Kerr and published by . This book was released on 1972 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : B. Levitt
Publisher : Springer Science & Business Media
ISBN 13 : 1468426850
Total Pages : 342 pages
Book Rating : 4.4/5 (684 download)
Download or read book Physical Chemistry of Fast Reactions written by B. Levitt and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chapters in this book are devoted to the elementary reactions of small molecules in the gas phase, with some emphasis on reactions important in combustion. The first three chapters cover experimental measurements made at high temperatures, mainly using shock waves and flames; the final chapter describes discharge flow methods near room temperature. The authors-all active in the fields they describe were asked to aim at a level intermediate between a textbook and a review, designed for readers not already familiar with this branch of chemical kinetics. We hope the book will prove especially useful to research workers in related subjects, to research students, and perhaps as source material for the preparation of lectures. The examples have been chosen to illustrate the theoretical basis of the topics rather than attempt a complete coverage. Professors Wagner and Troe describe the remarkable progress made in recent years in measuring dissociation rates for small molecules. Tests ofunimolecular reaction theories are usually made in the 'fall-off' region of pressure: the kinetics change from first order to second order as the pressure is reduced. For large molecules this region lies below atmospheric pressure and is relatively easily accessible. For molecules with four or less atoms, however, the fall-off region lies well above atmospheric pressure: it has been explored using the high pressure shock tube techniques developed by the authors.
Author : V.N. Kondratiev
Publisher : Springer Science & Business Media
ISBN 13 : 3642676081
Total Pages : 254 pages
Book Rating : 4.6/5 (426 download)
Download or read book Gas-Phase Reactions written by V.N. Kondratiev and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present monograph appears after the death of Professor V. N. Kondratiev, one of those scientists who have greatly contributed to the foundation of contem porary gas kinetics. The most fundamental idea of chemical kinetics, put for ward at the beginning of the twentieth century and connected with names such as W. Nernst, M. Bodenstein, N. N. Semenov, and C. N. Hinshelwood, was that the complex chemical reactions are in fact a manifestation of a set of simpler elementary reactions involving but a small number of species. V. N. Kondratiev was one of the first to adopt this idea and to start investigations on the elementary chemical reactions proper. These investigations revealed explicitly that every elementary reaction in turn consisted of many elementary events usually referred to as elementary processes. It took some time to realize that an elementary reaction, represented in a very simple way by a macroscopic kinetic equation, can be described on a microscopic level by a generalized Boltzmann equation. Neverheless, up to the middle of the twentieth century, gas kinetics was mainly concerned with the interpretation of complex chemical reactions via a set of elementary reactions. But later on, the situation changed drastically. First, the conditions for reducing microscopic cquations to macroscopic ones were clearly set up. These are essentially based on the fact that the small perturbations of the Maxwell-Boltzmann distribution are caused by the reaction proper.
Author : S. H. Bauer
Publisher :
ISBN 13 :
Total Pages : 33 pages
Book Rating : 4.:/5 (227 download)
Download or read book The Gas Phase Association of Lewis Acids and Bases. Ii. N(ch3)3 and Nh(ch3)2 in Competition for Bf3 written by S. H. Bauer and published by . This book was released on 1943 with total page 33 pages. Available in PDF, EPUB and Kindle. Book excerpt: A detailed analysis is presented of the rate laws expected for Lewis acid-base gas phase association reactions at pressures above several mm Hg. It is shown that in a competive system (B2 and B3 competing for A) the ratio of association rate constants, k3/k2, is given by (AB3/AB2)(B2/B3), irrespective of the relative efficiencies for stabilization of the vibrationally excited AB3 and AB2 by internal energy conversion vs energy transfer to the ambient gas. However, if the latter process were to dominate, the measured (k3/k2) would depend on the nature of the ambient gas. An experimental procedure was developed for measuring the relative amounts of salt produced in a competitive system, based on IR analyses of acetonitrile solutions of the mixed salts. This procedure is particularly applicable to systems in which the residual gases are preferentially absorbed in the solids produced. Data on the (CH3)3N - (CH3)2HN BF3 system are presented. The results show that at room temperature the ratio of association rate constants, k3/k2 = 0.89 = 0.17, over the range 3 to 43 mm Hg total pressure. This ratio rose slightly (to 0.95) at about 0.6 mm Hg, the lowest pressure studied. (Author).
Author :
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ISBN 13 :
Total Pages : 116 pages
Book Rating : 4.:/5 (319 download)
Download or read book Keywords Index to U.S. Government Technical Reports written by and published by . This book was released on 1963-08 with total page 116 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : United States. Department of Commerce. Office of Technical Services
Publisher :
ISBN 13 :
Total Pages : 618 pages
Book Rating : 4.3/5 (91 download)
Download or read book Keywords Index to U.S. Government Technical Reports (permuted Title Index). written by United States. Department of Commerce. Office of Technical Services and published by . This book was released on 1963 with total page 618 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Harold S. Johnston
Publisher :
ISBN 13 :
Total Pages : 390 pages
Book Rating : 4.:/5 (37 download)
Download or read book Gas Phase Reaction Rate Theory written by Harold S. Johnston and published by . This book was released on 1966 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : J. A. Kerr
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (5 download)
Download or read book Evaluated Kinetics Data on Gas Phase Addition Reactions written by J. A. Kerr and published by . This book was released on 1972 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Vladimir Ya. Lee
Publisher : John Wiley & Sons
ISBN 13 : 1119956269
Total Pages : 390 pages
Book Rating : 4.1/5 (199 download)
Download or read book Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb written by Vladimir Ya. Lee and published by John Wiley & Sons. This book was released on 2011-07-22 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: Until recently the low-coordinate compounds of the heavier elements of group 14 were known only as transient, unstable species which were difficult to isolate. However recent developments have led to the stabilisation of these compounds and today heavier group 14 element cations, radicals, anions, carbene analogues, alkene and alkyne analogues and aromatics have all been prepared as highly reactive, stable, fully characterizable and readily available organometallic reagents. Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb describes the chemistry of this exciting new class of organometallics, with an emphasis on their major similarities and differences with the analogous species in organic chemistry. Topics covered include include the synthesis, structure, reactions and synthetic applications of : Si-, Ge-, Sn and Pb-centered cations, radicals and anions heavy analogues of carbenes: silylenes, germylenes, stannylenes and plumbylenes heavy analogues of alkenes: disilenes, digermenes, distannenes, diplumbenes heavy analogues of alkynes: disilynes, digermynes, distannynes, diplumbynes, and their valence isomers heteronuclear derivatives: silenes, germenes, stannenes, silagermenes, silastannenes, germastannenes heavy analogues of alkenes of the type: >E14=E13-, >E14=E15-, >E14=E16 [where E13, E14, E15 and E16 are elements of the groups 13, 14, 15 and 16] cyclic compounds (three-, four-, five-, and six-membered rings) heavy analogues of 1,3-dienes, allenes and other cumulenes heavy analogues of aromatic compounds; including a comparison between organometallic and organic aromaticity Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb is an essential guide to this emerging class of organometallic reagents for researchers and students in main group, organometallic, synthetic and silicon chemistry
Author : William Dean Burch
Publisher :
ISBN 13 :
Total Pages : 100 pages
Book Rating : 4.:/5 (514 download)
Download or read book Experimental Techniques in the Kinetic Study of Rapid Gas Phase Reactions written by William Dean Burch and published by . This book was released on 1952 with total page 100 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : J.A. Kerr
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (989 download)
Download or read book Evaluated Kinetic Data Gas Phase Addition Reactions: Reactions of Atoms and Redicals with Alkenes, Alkynes and Aromatic Compunds written by J.A. Kerr and published by . This book was released on 1972 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Joseph M. Pilato
Publisher :
ISBN 13 :
Total Pages : 62 pages
Book Rating : 4.:/5 (476 download)
Download or read book Development of a Method for the Kinetic Study of Rapid Gas Phase Reactions Involving written by Joseph M. Pilato and published by . This book was released on 1953 with total page 62 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
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ISBN 13 :
Total Pages : 518 pages
Book Rating : 4.0/5 ( download)
Download or read book Energy Research Abstracts written by and published by . This book was released on 1992-05 with total page 518 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Edward S. Lewis
Publisher :
ISBN 13 :
Total Pages : 1503 pages
Book Rating : 4.:/5 (258 download)
Download or read book Investigation of Rates and Mechanisms of Reactions written by Edward S. Lewis and published by . This book was released on 1974 with total page 1503 pages. Available in PDF, EPUB and Kindle. Book excerpt: General methods of rate and mechanism study; Activated-complex theory: current status, extensions, and applications; Homogeneous gas-phase reactions; Kinetics in solution; Kinetic isotope effects; Tracer methods; Stereochemistry and reaction mechanism; From kinetic data to reaction mechanism; Rapid flow methods; Theoretical basis of relaxation spectrometry; Temperature-jump methods; Pressure-jump methods; Eletric fiel methods.
Author : Ozcan Konur
Publisher : CRC Press
ISBN 13 : 1000958736
Total Pages : 401 pages
Book Rating : 4.0/5 (9 download)
Download or read book Evaluation and Utilization of Bioethanol Fuels. II. written by Ozcan Konur and published by CRC Press. This book was released on 2023-12-22 with total page 401 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents the direct use of bioethanol fuels in electric cars and the indirect use of bioethanol fuels in electric cars in the form of biohydrogen produced from bioethanol fuels Discusses bioethanol fuel-based bioelectricity production, bioethanol fuel-based biochemical and biohydrocarbon production Discusses direct bioethanol fuel cells, bioethanol fuel electrooxidation, catalysts for bioethanol fuel oxidation, and nanotechnology applications in fuel cells Includes case studies of bioethanol fuel-based biochemical and biohydrocarbon production, nanosensors, ZnO-based nanosensors, and SnO2-based nanosensors
