Kinetics Of Multistep Reactions

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Kinetics of Multistep Reactions

Author : Friedrich G. Helfferich
Publisher : Elsevier
ISBN 13 : 0080473180
Total Pages : 508 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Kinetics of Multistep Reactions by : Friedrich G. Helfferich

Download or read book Kinetics of Multistep Reactions written by Friedrich G. Helfferich and published by Elsevier. This book was released on 2004-09-15 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses primarily the engineer in industrial process development, the research chemist in academia and industry, and the graduate student intending to become a reaction engineer. In industry, competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such development should be based on "fundamental" kinetics that reflect the elementary steps of which the reaction consists. The book forges fundamental kinetics into a practical tool by presenting new, effective methods for elucidation of mechanisms and reduction of complexity without unacceptable sacrifice in accuracy: fewer equations (lesser computational load), fewer coefficients (fewer experiment to determine them). For network elucidation, new rules relating network configurations to observable kinetic behaviour allow incorrect networks to be ruled out by whole classes instead of one by one. For modelling, general equations and algorithms are given from which equations for specific networks can be recovered by simple substitutions. The procedures are illustrated with examples of industrial reactions including, among others, paraffin oxidation, ethoxylation, hydroformylation, hydrocyanation, shape-selective catalysis, ethane pyrolysis, styrene polymerization, and ethene oligomerization. Many of the rate equations have not been published before. The expanded edition of the 2001 title, Kinetics of Homogeneous Multistep Reactions includes new chapters on heterogeneous catalysis and periodic and chaotic re-actions; new sections on adsorption, statistical methods, and lumping; and other new detail. Contains new chapters on heterogeneous catalysis, oscillations and chaos Includes new sections on statistical methods, lumping adsorption and software and databases Provides a better understanding of complex reaction mechanisms

Kinetics of Homogeneous Multistep Reactions

Author : Friedrich G. Helfferich
Publisher : Elsevier
ISBN 13 : 0080535267
Total Pages : 427 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Kinetics of Homogeneous Multistep Reactions by : Friedrich G. Helfferich

Download or read book Kinetics of Homogeneous Multistep Reactions written by Friedrich G. Helfferich and published by Elsevier. This book was released on 2001-01-25 with total page 427 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses primarily the chemist and engineer in industrial research and process development, where competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such scale-up should be based on "fundamental" kinetics, that is, mathematics that reflect the elementary steps of which the reactions consist. The book forges fundamental kinetics into a practical tool by presenting new effective methods for elucidation of mechanisms and reduction of mathematical complexity without unacceptable sacrifice in accuracy.

Chemical Kinetics with Mathcad and Maple

Author : Viktor Korobov
Publisher : Springer Science & Business Media
ISBN 13 : 3709105315
Total Pages : 353 pages
Book Rating : 4.7/5 (91 download)

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Book Synopsis Chemical Kinetics with Mathcad and Maple by : Viktor Korobov

Download or read book Chemical Kinetics with Mathcad and Maple written by Viktor Korobov and published by Springer Science & Business Media. This book was released on 2011-05-26 with total page 353 pages. Available in PDF, EPUB and Kindle. Book excerpt: The authors explain at length the principles of chemical kinetics and approaches to computerized calculations in modern software suites — mathcad and maple. Mathematics is crucial in determining correlations in chemical processes and requires various numerical approaches. Often significant issues with mathematical formalizations of chemical problems arise and many kinetic problems can ́t be solved without computers. Numerous problems encountered in solving kinetics ́ calculations with detailed descriptions of the numerical tools are given. Special attention is given to electrochemical reactions, which fills a gap in existing texts not covering this topic in detail. The material demonstrates how these suites provide quick and precise behavior predictions for a system over time (for postulated mechanisms).Examples, i.e., oscillating and non-isothermal reactions, help explain the use of mathcad more efficiently. Also included are the results of authors’ own research toward effective computations.

Reaction Rate Theory and Rare Events

Author : Baron Peters
Publisher : Elsevier
ISBN 13 : 0444594701
Total Pages : 634 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Reaction Rate Theory and Rare Events by : Baron Peters

Download or read book Reaction Rate Theory and Rare Events written by Baron Peters and published by Elsevier. This book was released on 2017-03-22 with total page 634 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reaction Rate Theory and Rare Events bridges the historical gap between these subjects because the increasingly multidisciplinary nature of scientific research often requires an understanding of both reaction rate theory and the theory of other rare events. The book discusses collision theory, transition state theory, RRKM theory, catalysis, diffusion limited kinetics, mean first passage times, Kramers theory, Grote-Hynes theory, transition path theory, non-adiabatic reactions, electron transfer, and topics from reaction network analysis. It is an essential reference for students, professors and scientists who use reaction rate theory or the theory of rare events. In addition, the book discusses transition state search algorithms, tunneling corrections, transmission coefficients, microkinetic models, kinetic Monte Carlo, transition path sampling, and importance sampling methods. The unified treatment in this book explains why chemical reactions and other rare events, while having many common theoretical foundations, often require very different computational modeling strategies. Offers an integrated approach to all simulation theories and reaction network analysis, a unique approach not found elsewhere Gives algorithms in pseudocode for using molecular simulation and computational chemistry methods in studies of rare events Uses graphics and explicit examples to explain concepts Includes problem sets developed and tested in a course range from pen-and-paper theoretical problems, to computational exercises

An Introduction to Chemical Kinetics

Author : Michel Soustelle
Publisher : John Wiley & Sons
ISBN 13 : 1118604229
Total Pages : 484 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis An Introduction to Chemical Kinetics by : Michel Soustelle

Download or read book An Introduction to Chemical Kinetics written by Michel Soustelle and published by John Wiley & Sons. This book was released on 2013-02-07 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a progressive presentation of kinetics of the chemical reactions. It provides complete coverage of the domain of chemical kinetics, which is necessary for the various future users in the fields of Chemistry, Physical Chemistry, Materials Science, Chemical Engineering, Macromolecular Chemistry and Combustion. It will help them to understand the most sophisticated knowledge of their future job area. Over 15 chapters, this book present the fundamentals of chemical kinetics, its relations with reaction mechanisms and kinetic properties. Two chapters are then devoted to experimental results and how to calculate the kinetic laws in both homogeneous and heterogeneous systems. The following two chapters describe the main approximation modes to calculate these laws. Three chapters are devoted to elementary steps with the various classes, the principles used to write them and their modeling using the theory of the activated complex in gas and condensed phases. Three chapters are devoted to the particular areas of chemical reactions, chain reactions, catalysis and the stoichiometric heterogeneous reactions. Finally the non-steady-state processes of combustion and explosion are treated in the final chapter.

Chemical and Catalytic Reaction Engineering

Author : James J. Carberry
Publisher : Courier Corporation
ISBN 13 : 9780486417363
Total Pages : 676 pages
Book Rating : 4.4/5 (173 download)

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Book Synopsis Chemical and Catalytic Reaction Engineering by : James J. Carberry

Download or read book Chemical and Catalytic Reaction Engineering written by James J. Carberry and published by Courier Corporation. This book was released on 2001-01-01 with total page 676 pages. Available in PDF, EPUB and Kindle. Book excerpt: Designed to give chemical engineers background for managing chemical reactions, this text examines the behavior of chemical reactions and reactors; conservation equations for reactors; heterogeneous reactions; fluid-fluid and fluid-solid reaction systems; heterogeneous catalysis and catalytic kinetics; diffusion and heterogeneous catalysis; and analyses and design of heterogeneous reactors. 1976 edition.

Chemical Kinetics and Process Dynamics in Aquatic Systems

Author : PatrickL. Brezonik
Publisher : Routledge
ISBN 13 : 1351461508
Total Pages : 540 pages
Book Rating : 4.3/5 (514 download)

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Book Synopsis Chemical Kinetics and Process Dynamics in Aquatic Systems by : PatrickL. Brezonik

Download or read book Chemical Kinetics and Process Dynamics in Aquatic Systems written by PatrickL. Brezonik and published by Routledge. This book was released on 2018-05-08 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Kinetics and Process Dynamics in Aquatic Systems is devoted to chemical reactions and biogeochemical processes in aquatic systems. The book provides a thorough analysis of the principles, mathematics, and analytical tools used in chemical, microbial, and reactor kinetics. It also presents a comprehensive, up-to-date description of the kinetics of important chemical processes in aquatic environments. Aquatic photochemistry and correlation methods (e.g., LFERs and QSARs) to predict process rates are covered. Numerous examples are included, and each chapter has a detailed bibliography and problems sets. The book will be an excellent text/reference for professionals and students in such fields as aquatic chemistry, limnology, aqueous geochemistry, microbial ecology, marine science, environmental and water resources engineering, and geochemistry.

Deterministic Kinetics in Chemistry and Systems Biology

Author : Gábor Lente
Publisher : Springer
ISBN 13 : 3319154826
Total Pages : 135 pages
Book Rating : 4.3/5 (191 download)

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Book Synopsis Deterministic Kinetics in Chemistry and Systems Biology by : Gábor Lente

Download or read book Deterministic Kinetics in Chemistry and Systems Biology written by Gábor Lente and published by Springer. This book was released on 2015-03-09 with total page 135 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book gives a concise overview of the mathematical foundations of kinetics used in chemistry and systems biology. The analytical and numerical methods used to solve complex rate equations with the widely used deterministic approach will be described, with primary focus on practical aspects important in designing experimental studies and the evaluation of data. The introduction of personal computers transformed scientific attitudes in the last two decades considerably as computational power ceased to be a limiting factor. Despite this improvement, certain time-honored approximations in solving rate equations such as the pre-equilibrium or the steady-state approach are still valid and necessary as they concern the information content of measured kinetic traces. The book shows the role of these approximations in modern kinetics and will also describe some common misconceptions in this field.

Unimolecular Kinetics

Author :
Publisher : Elsevier
ISBN 13 : 9780444642073
Total Pages : 0 pages
Book Rating : 4.6/5 (42 download)

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Book Synopsis Unimolecular Kinetics by :

Download or read book Unimolecular Kinetics written by and published by Elsevier. This book was released on 2019-05-31 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Unimolecular Kinetics: Part 2: Collisional Energy Transfer and the Master Equation, Volume 43 in Elsevier's Comprehensive Molecular Kinetics series, addresses collision energy transfer and the effects it has on gas phase reactions, particularly at low gas density. Such systems include combustion, industrial gas phase processes and atmospheric/environmental processes. The book also discusses The Master Equation to give a good overview of the mechanics underpinning unimolecular kinetics. This new volume will be of interest to researchers investigating gas phase processes which involve unimolecular reactions and the related intermolecular reactions.

The Art of Writing Reasonable Organic Reaction Mechanisms

Author : Robert B. Grossman
Publisher : Springer Science & Business Media
ISBN 13 : 0387954686
Total Pages : 371 pages
Book Rating : 4.3/5 (879 download)

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Book Synopsis The Art of Writing Reasonable Organic Reaction Mechanisms by : Robert B. Grossman

Download or read book The Art of Writing Reasonable Organic Reaction Mechanisms written by Robert B. Grossman and published by Springer Science & Business Media. This book was released on 2007-07-31 with total page 371 pages. Available in PDF, EPUB and Kindle. Book excerpt: Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction as is the case in most textbooks. Each chapter discusses common mechanistic pathways and suggests practical tips for drawing them. Worked problems are included in the discussion of each mechanism, and "common error alerts" are scattered throughout the text to warn readers about pitfalls and misconceptions that bedevil students. Each chapter is capped by a large problem set.

Fundamentals of Electrochemical Deposition

Author : Milan Paunovic
Publisher : John Wiley & Sons
ISBN 13 : 047000939X
Total Pages : 388 pages
Book Rating : 4.4/5 (7 download)

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Book Synopsis Fundamentals of Electrochemical Deposition by : Milan Paunovic

Download or read book Fundamentals of Electrochemical Deposition written by Milan Paunovic and published by John Wiley & Sons. This book was released on 2006-08-11 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: Excellent teaching and resource material . . . it is concise, coherently structured, and easy to read . . . highly recommended for students, engineers, and researchers in all related fields." -Corrosion on the First Edition of Fundamentals of Electrochemical Deposition From computer hardware to automobiles, medical diagnostics to aerospace, electrochemical deposition plays a crucial role in an array of key industries. Fundamentals of Electrochemical Deposition, Second Edition is a comprehensive introduction to one of today's most exciting and rapidly evolving fields of practical knowledge. The most authoritative introduction to the field so far, the book presents detailed coverage of the full range of electrochemical deposition processes and technologies, including: * Metal-solution interphase * Charge transfer across an interphase * Formation of an equilibrium electrode potential * Nucleation and growth of thin films * Kinetics and mechanisms of electrodeposition * Electroless deposition * In situ characterization of deposition processes * Structure and properties of deposits * Multilayered and composite thin films * Interdiffusion in thin film * Applications in the semiconductor industry and the field of medicine This new edition updates the prior edition to address the new developments in the science and its applications, with new chapters on innovative applications of electrochemical deposition in semiconductor technology, magnetism and microelectronics, and medical instrumentation. Added coverage includes such topics as binding energy, nanoclusters, atomic force, and scanning tunneling microscopy.Example problems at the end of chapters and other features clarify and improve understanding of the material. Written by an author team with extensive experience in both industry and academe, this reference and text provides a well-rounded introduction to the field for students, as well as a means for professional chemists, engineers, and technicians to expand and sharpen their skills in using the technology.

Multi-Step Enzyme Catalysis

Author : Eduardo Garcia-Junceda
Publisher : John Wiley & Sons
ISBN 13 : 3527623396
Total Pages : 256 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Multi-Step Enzyme Catalysis by : Eduardo Garcia-Junceda

Download or read book Multi-Step Enzyme Catalysis written by Eduardo Garcia-Junceda and published by John Wiley & Sons. This book was released on 2008-11-21 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first comprehensive coverage of this unique and interdisciplinary field provides a complete overview, covering such topics as chemoenzymatic synthesis, microbial production of DNA building blocks, asymmetric transformations by coupled enzymes and much more. By combining enzymatic and synthetic organic steps, the use of multi-enzyme complexes and other techniques opens the door to reactions hitherto unknown, making this monograph of great interest to biochemists, organic chemists, and chemists working with/on organometallics, as well as catalytic chemists, biotechnologists, and those working in the pharmaceutical and fine chemical industries.

Chemical Kinetics and Mechanism

Author : Michael Mortimer
Publisher : Royal Society of Chemistry
ISBN 13 : 9780854046706
Total Pages : 270 pages
Book Rating : 4.0/5 (467 download)

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Book Synopsis Chemical Kinetics and Mechanism by : Michael Mortimer

Download or read book Chemical Kinetics and Mechanism written by Michael Mortimer and published by Royal Society of Chemistry. This book was released on 2002 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: Annotation This book considers the role of the rate of reaction, starting with an introduction to chemical kinetics (measuring rates of reaction, order of reaction, reaction mechanisms). It then illustrates how the outcome of predictions can be made, where this is determined by the reaction rate. The concept of the functional group is introduced and is followed by a discussion of the characteristic reactions of several functional groups and the common mechanisms of organic reactions, substitution and elimination. An interactive CD-ROM accompanies the book. This book is part of The Molecular World series which aims to provide a broad foundation in chemistry.

Kinetics of Enzyme Action

Author : Ross L. Stein
Publisher : John Wiley & Sons
ISBN 13 : 1118084403
Total Pages : 322 pages
Book Rating : 4.1/5 (18 download)

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Book Synopsis Kinetics of Enzyme Action by : Ross L. Stein

Download or read book Kinetics of Enzyme Action written by Ross L. Stein and published by John Wiley & Sons. This book was released on 2011-08-08 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Few scientists have the knowledge to perform the studies that are necessary to discover and characterize enzyme inhibitors, despite the vested interest the pharmaceutical industry has in this field. Beginning with the most basic principles pertaining to simple, one-substrate enzyme reactions and their inhibitors, and progressing to a thorough treatment of two-substrate enzymes, Kinetics of Enzyme Action: Essential Principles for Drug Hunters provides biochemists, medicinal chemists, and pharmaceutical scientists with numerous case study examples to outline the tools and techniques necessary to perform, understand, and interpret detailed kinetic studies for drug discovery.

Physical Chemistry for the Biosciences

Author : Raymond Chang
Publisher : University Science Books
ISBN 13 : 9781891389337
Total Pages : 706 pages
Book Rating : 4.3/5 (893 download)

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Book Synopsis Physical Chemistry for the Biosciences by : Raymond Chang

Download or read book Physical Chemistry for the Biosciences written by Raymond Chang and published by University Science Books. This book was released on 2005-02-11 with total page 706 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is ideal for use in a one-semester introductory course in physical chemistry for students of life sciences. The author's aim is to emphasize the understanding of physical concepts rather than focus on precise mathematical development or on actual experimental details. Subsequently, only basic skills of differential and integral calculus are required for understanding the equations. The end-of-chapter problems have both physiochemical and biological applications.

Kinetics and Mechanism

Author : John W. Moore
Publisher : John Wiley & Sons
ISBN 13 : 9780471035589
Total Pages : 486 pages
Book Rating : 4.0/5 (355 download)

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Book Synopsis Kinetics and Mechanism by : John W. Moore

Download or read book Kinetics and Mechanism written by John W. Moore and published by John Wiley & Sons. This book was released on 1981-09-30 with total page 486 pages. Available in PDF, EPUB and Kindle. Book excerpt: The third edition of a classic text originally by Frost and Pearson, that describes the fundamental principles and established practices that apply to the study and the rates and mechanisms of homogeneous chemical reactions in the gas phase and in solution. Incorporates new advances made during the past 20 years in the study of individual molecular collisions by molecular-beam, laser applications to experimental kinetics, theoretical treatments of reaction rates and our understanding of the principles that govern rates of reaction in solution. Presents numerous examples of the deduction of mechanism from experiment, including intimate details such as stereochemistry and the dependence of reaction pathway on the exact energy states of reacting particles.

Handbook of Thermal Analysis and Calorimetry

Author :
Publisher : Elsevier
ISBN 13 : 0444640630
Total Pages : 860 pages
Book Rating : 4.4/5 (446 download)

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Book Synopsis Handbook of Thermal Analysis and Calorimetry by :

Download or read book Handbook of Thermal Analysis and Calorimetry written by and published by Elsevier. This book was released on 2018-03-12 with total page 860 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Thermal Analysis and Calorimetry: Recent Advances, Techniques and Applications, Volume Six, Second Edition, presents the latest in a series that has been well received by the thermal analysis and calorimetry community. This volume covers recent advances in techniques and applications that complement the earlier volumes. There has been tremendous progress in the field in recent years, and this book puts together the most high-impact topics selected for their popularity by new editors Sergey Vyazovkin, Nobuyoshi Koga and Christoph Schick—all editors of Thermochimica Acta. Among the important new techniques covered are biomass conversion; sustainable polymers; polymer nanocompsoties; nonmetallic glasses; phase change materials; propellants and explosives; applications to pharmaceuticals; processes in ceramics, metals, and alloys; ionic liquids; fast-scanning calorimetry, and more. Features 19 all-new chapters to bring readers up to date on the current status of the field Provides a broad overview of recent progress in the most popular techniques and applications Includes chapters authored by a recognized leader in each field and compiled by a new team of editors, each with at least 20 years of experience in the field of thermal analysis and calorimetry Enables applications across a wide range of modern materials, including polymers, metals, alloys, ceramics, energetics and pharmaceutics Overviews the current status of the field and summarizes recent progress in the most popular techniques and applications